Patent Application
20240094557
The disclosure relates to a spectacle lens, a primer layer-forming composition, and a spectacle lens manufacturing method.
A primer layer is disposed on a lens base in order to improve the adhesion between the lens base and a hard coat layer or an antireflective layer disposed over the lens base, in some cases (see, for example, Patent Literature 1).
The present disclosure relates to a spectacle lens comprising: a lens base; a primer layer disposed on at least one of an object side surface and an eyeball side surface of the lens base; and at least one layer selected from the group consisting of a hard coat layer and an antireflective layer, the at least one layer being disposed on the primer layer, wherein the primer layer contains a polycarbonate polyurethane resin and inorganic oxide particles, wherein the polycarbonate polyurethane resin has a tensile strength of greater than 40 N/mm2, wherein the polycarbonate polyurethane resin has an elongation of not less than 300%, and wherein a content of the inorganic oxide particles is 10 to 40 vol % based on a total volume of the primer layer.
The present disclosure also relates to a primer layer-forming composition comprising a polycarbonate polyurethane resin, inorganic oxide particles, and a solvent, wherein the polycarbonate polyurethane resin has a tensile strength of greater than 40 N/mm2, wherein the polycarbonate polyurethane resin has an elongation of not less than 300%, and wherein a content of the inorganic oxide particles is 10 to 40 vol % based on a volume of total solids of the primer layer-forming composition.
The present disclosure further relates to a spectacle lens manufacturing method comprising a step of forming a primer layer by applying the above primer layer-forming composition onto at least one of an object side surface and an eyeball side surface of a lens base to form a coating and curing the coating.
A spectacle lens, a primer layer-forming composition, and a spectacle lens manufacturing method in the present embodiment are described below in detail.
Note that, in the description, numerical values given before and after “to” are included in the range as the lower and upper limits.
Conventionally, spectacle lenses in which a hard coat layer, an antireflective layer or the like is disposed over a lens base via a primer layer have been studied. It is desired for spectacle lenses to have such characteristics as excellent crazing resistance, impact resistance and adhesion.
The term “crazing resistance” refers to the property of suppressing cracking that may occur when a spectacle lens is applied with a load and thereby fixed by use of a working machine during lens shape machining of the spectacle lens. The term “adhesion” refers to the adhesion of a coating (e.g., a primer layer, a hard coat layer, an antireflective layer) disposed on a lens base.
The spectacle lens in the embodiment is excellent in all of the crazing resistance, the impact resistance and the adhesion. The spectacle lens in the embodiment also has excellent transparency.
With the primer layer-forming composition in the embodiment, the spectacle lens having the foregoing properties can be manufactured.
In the following, the primer layer-forming composition is first detailed, and then the spectacle lens and a manufacturing method thereof are detailed.
The primer layer-forming composition contains a predetermined polycarbonate polyurethane resin, inorganic oxide particles and a solvent. The components contained in the primer layer-forming composition are described below in detail.
The primer layer-forming composition contains a polycarbonate polyurethane resin (hereinafter also simply called “specified resin”).
The polycarbonate polyurethane resin is a polyurethane resin having a polycarbonate skeleton. More specifically, the polycarbonate polyurethane resin is a polyurethane resin composed of a diol component and a diisocyanate component, and polycarbonate polyol is used as the diol component.
The type of polycarbonate polyol is not particularly limited, and examples thereof include poly(alkylene carbonates) such as poly(hexamethylene carbonate).
The type of polyisocyanate is not particularly limited, and examples thereof include: aromatic isocyanate compounds such as tolylene diisocyanate, 4,4-diphenylmethane diisocyanate, xylene diisocyanate, 1,5-naphthalene diisocyanate, toluidine diisocyanate, phenylene diisocyanate, and 4,4-diphenyl diisocyanate; and aliphatic isocyanate compounds such as 1,3,3-trimethylhexamethylene diisocyanate, hexamethylene diisocyanate, isophorone diisocyanate, hydrogenated xylene diisocyanate, lysine diisocyanate, lysine ester triisocyanate, 1,6,11-undecane triisocyanate, 1,8-diisocyanate-4-isocyanatemethyloctane, and 1,3,6-hexamethylene triisocyanate.
The tensile strength of the specified resin is greater than 40 N/mm2, and because the resulting spectacle lens can have excellent crazing resistance, preferably not less than 45 N/mm2. The upper limit of the tensile strength is not particularly limited and may be 70 N/mm2 or less, for example.
The tensile strength is the value obtained at 25° C.
One method of measuring the tensile strength of the specified resin is as follows:
First, a film of the specified resin with 15-mm width, 200-mm length and 450- to 550-μm thickness is prepared, and gage marks are given at 50-mm intervals in the central region of the film. This film is attached to a tensile tester (Autograph AGS-X, manufactured by Shimadzu Corporation), the distance between the grips of the tensile tester is set to 100 mm, and the film is pulled to its breaking point at a rate of 200 mm/min. The stress at the breaking point is defined as the tensile strength of the specified resin. The measurement temperature is 25° C.
The method of manufacturing the above film of the specified resin is not particularly limited, and one exemplary method involves applying a solution containing the specified resin onto a substrate to a film thickness after drying of 450 to 550 μm, drying the coating to form a film, and cutting the resulting film to the predetermined size. The method of drying the coating is not particularly limited, and one exemplary method involves drying at room temperature for 12 to 36 hours and then further drying at a temperature of 60° C. to 100° C. for 5 to 10 hours.
The elongation of the specified resin is not less than 300%, and because the resulting spectacle lens can have more excellent impact resistance, preferably not less than 320%. The upper limit of the elongation is not particularly limited and may be 1500% or less, for example.
The elongation is the value obtained at 25° C.
The elongation of the specified resin may be measured concurrently with the foregoing measurement of the tensile strength. The elongation is calculated as follows:
Elongation (%)=((Gage distance at breaking point−Gage distance before testing)/(Gage distance before testing)×100
The specified resin may be dispersed in a particulate form in the primer layer-forming composition.
When the specified resin is dispersed in a particulate form, the average particle size of the specified resin particles is not particularly limited and is preferably less than 50 nm and more preferably 48 nm or less because the resulting primer layer can have more excellent transparency. The lower limit of the average particle size is not particularly limited and may be 10 nm or greater, for example.
The average particle size is calculated through dynamic light scattering using Nanotrac UPA-EX150 particle size distribution analyzer manufactured by Nikkiso Co., Ltd.
Commercial products may be used for the specified resin. For instance, “EVAFANOL” series manufactured by Nicca Chemical Co., Ltd. may be used.
The primer layer-forming composition contains inorganic oxide particles.
The type of the inorganic oxide particles is not particularly limited, and examples thereof include particles of an oxide of at least one metal selected from Ti, Zr, Si, Al, Sn, Sb, Ta, Ce, La, Fe, Zn, W and In or composite oxide particles of these. The composite oxide refers to an oxide including two or more types of metals (metal atoms) from among those listed above.
Commercial products of those inorganic oxide particles are easily available. Examples of such commercial products include a sol in which particles are dispersed in water or an organic solvent, the particles containing a component selected from the group consisting of titanium oxide, zirconium oxide, silicon oxide, tin oxide, aluminum oxide, and composite oxides of these.
The inorganic oxide particles may be of so-called core-shell type.
The average particle size of the inorganic oxide particles is not particularly limited and is preferably 1 to 200 nm and more preferably 5 to 30 nm, for instance.
The average particle size above is determined by measuring the diameters of at least one hundred inorganic oxide particles with a transmitted light microscope and calculating the arithmetic mean of the measurements. When the inorganic oxide particles do not have a perfect circle shape, the major axis length is taken as the diameter.
Various functional groups (e.g., epoxy group) may optionally be introduced to the surfaces of the inorganic oxide particles.
The inorganic oxide particles may be used in the form of sol obtained by dispersing the inorganic oxide particles in a dispersion medium such as water or a water-soluble organic solvent (particularly, alcoholic solvent).
Examples of the water-soluble organic solvent include water-soluble organic solvents described in the following section <Solvent>.
The primer layer-forming composition contains a solvent.
Examples of the solvent include water and organic solvents. The type of the organic solvent is not particularly limited, and examples thereof include alcoholic solvents, ketone solvents, ether solvents, ester solvents, hydrocarbon solvents, halogenated hydrocarbon solvents, amide solvents, sulfone solvents and sulfoxide solvents.
In particular, the solvent is preferably selected from the group consisting of water and water-soluble organic solvents.
The water-soluble organic solvent refers to an organic solvent having compatibility with water, and more specifically, an organic solvent having a solubility of not less than 10 wt % and preferably not less than 50 wt % with respect to water, at a temperature of 25° C.
Examples of the water-soluble organic solvent include: alcohols such as methanol, ethanol, isopropanol, n-butanol, ethylene glycol, propylene glycol, diethylene glycol, dipropylene glycol, cyclohexanediol, trimethylene glycol, tripropylene glycol, 1,2-butanediol, 1,3-butanediol, 1,4-butanediol, 1,4-butenediol, hexylene glycol, trimethylolpropane, hexylene glycol, and pentaerythritol; ethers such as ethylene glycol monomethyl ether, ethylene glycol monoisopropyl ether, ethylene glycol monoethyl ether, ethylene glycol mono-n-propyl ether, ethylene glycol mono-n-butyl ether, ethylene glycol mono-t-butyl ether, propylene glycol monomethyl ether, propylene glycol monoethyl ether(1-methoxy-2-propanol), propylene glycol mono-n-propyl ether, propylene glycol mono-n-butyl ether, and propylene glycol monomethyl ether acetate; and ketones such as acetone, diacetone alcohol, and acetylacetone.
In particular, for the sake of liquid stability of the primer layer-forming composition, it is preferable that the solvent contain water and the water-soluble organic solvent, with the water-soluble organic solvent content being not greater than 50 wt % based on the total weight of the solvent. The lower limit of the water-soluble organic solvent content is not particularly limited and may be for example 1 wt % or greater for the sake of transparency of the resulting primer layer.
When the solvent is as described above, even if the primer layer-forming composition is left at room temperature, the generation of deposits and the gelation are further suppressed.
The primer layer-forming composition may optionally contain various additives such as a surfactant, a UV absorber, an antiaging agent, a coating adjusting agent, a light stabilizer, an antioxidant, a discoloration preventing agent, and a dye.
Exemplary surfactants include silicone surfactants, fluorosurfactants, acrylic surfactants and vinyl surfactants. The surfactant content is preferably 10 to 10,000 ppm by weight based on the total weight of the primer layer-forming composition.
The primer layer-forming composition contains various components described above.
The method of manufacturing the primer layer-forming composition is not particularly limited; for example, the foregoing components may be mixed at one time or in separate steps.
The order of adding the components and the mixing conditions are not particularly limited.
One exemplary method is mixing an aqueous dispersion of the specified resin (a solution in which the specified resin is dispersed in a particulate form in water), a sol of the inorganic oxide particles (a sol in which the inorganic oxide particles are dispersed in water or the water-soluble organic solvent), the solvent, and other necessary components at one time.
The specified resin content of the primer layer-forming composition is not particularly limited and is preferably 20 to 80 wt % and more preferably 25 to 70 wt % based on the total solids (primer layer constituents) of the primer layer-forming composition because the resulting spectacle lens can have better balance between the crazing resistance and the impact resistance.
The total solids (primer layer constituents) refer to components that constitute the primer layer. The specified resin and the inorganic oxide particles described above correspond to the total solids, while the solvent is not included in the total solids. Even if a certain component constituting the primer layer is a liquid, this component is accounted as a solid.
The inorganic oxide particle content of the primer layer-forming composition is 10 to 40 vol % based on the volume of the total solids of the primer layer-forming composition. In particular, the content is preferably 15 to 40 vol % because the resulting spectacle lens can have more excellent crazing resistance.
The solvent content of the primer layer-forming composition is not particularly limited and is preferably 65 to 95 wt % and more preferably 70 to 90 wt % based on the total weight of the primer layer-forming composition for the sake of handleability of the primer layer-forming composition.
The primer layer-forming composition as above is a composition for forming a primer layer on a lens base.
A spectacle lens 10 shown in
While in
While in
Members included in the spectacle lens 10 are described below in detail.
A lens base is a member on which a primer layer, a hard coat layer and an antireflective layer are formed.
The type of the lens base is not particularly limited, and examples thereof include a lens base made of plastic and a lens base made of inorganic glass, with a plastic lens base being preferred because of excellent handleability.
The material of the plastic lens base is not particularly limited, and examples thereof include acrylic resin, thiourethane resin, methacrylic resin, allyl resin, episulfide resin, polycarbonate resin, polyurethane resin, polyester resin, polystyrene resin, polyethersulfone resin, poly-4-methylpentene-1 resin, diethylene glycol bis(allyl carbonate) resin (CR-39), polyvinyl chloride resin, halogen-containing copolymer, and sulfur-containing copolymer.
The thickness of the lens base is not particularly limited and may be for example about 1 to about 30 mm for the sake of handleability.
The lens base need not be transparent as long as it is translucent, and may be colored.
The shape of the lens base 12 is not limited to the embodiment shown in
The primer layer is a layer disposed between the lens base and the hard coat layer or the antireflective layer, which will be described later. Typically, the primer layer is disposed between two layers to improve the adhesion therebetween.
The primer layer contains the polycarbonate polyurethane resin and the inorganic oxide particles.
The definition of the polycarbonate polyurethane resin (specified resin) is as described above, and the specified resin has the predetermined tensile strength and elongation.
The definition of the inorganic oxide particles is also as described above.
The specified resin content of the primer layer is not particularly limited and is preferably 20 to 80 wt % and more preferably 25 to 70 wt % based on the total weight of the primer layer because the resulting spectacle lens can have much better balance between the crazing resistance and the impact resistance.
The inorganic oxide particle content of the primer layer is 10 to 40 vol % based on the total volume of the primer layer. In particular, the content is preferably 15 to 40 vol % because the resulting spectacle lens can have more excellent crazing resistance.
The primer layer may optionally contain various additives such as a surfactant, a UV absorber, an antiaging agent, a light stabilizer, an antioxidant, a discoloration preventing agent, and a dye.
The thickness of the primer layer is not particularly limited and is preferably from 0.1 to 5.0 μm.
The method of forming the primer layer is not particularly limited, and it is preferable to use the primer layer-forming composition described above. One specific example of the method is a method involving bringing the primer layer-forming composition into contact with the lens base to form a coating, and optionally curing the coating. This method is described in detail below.
The method of bringing the primer layer-forming composition into contact with the lens base is not particularly limited, and examples thereof include dip coating and spin coating. Of these, dip coating is preferred for the sake of productivity.
Various pretreatments may optionally be performed on the surface(s) of the lens base before the primer layer-forming composition is brought into contact with the lens base. Exemplary pretreatments include degreasing treatment using an organic solvent, chemical treatment using a basic aqueous solution or an acidic aqueous solution, polishing treatment using an abrasive, plasma treatment, corona discharge treatment, flame treatment, and UV ozone treatment.
Formation of the coating on the lens base may be followed by curing treatment for curing the coating. One exemplary method of curing treatment is heating the coating. The solvent may be removed from the coating at heating. The heating temperature is not particularly limited and is preferably 25° C. to 120° C. and more preferably 25° C. to 100° C. for the purpose of preventing deformation and discoloring of the lens base that may be caused by heating.
The heating time is not particularly limited and is preferably from 1 minute to 1 hour.
The hard coat layer is a layer disposed on the primer layer and imparting scratch resistance to the lens base.
In the present description, the hard coat layer is defined as having, in terms of pencil hardness, the hardness “H” or higher hardness determined by the test method according to JIS K 5600.
For the hard coat layer, known hard coat layers are usable, and examples thereof include organic hard coat layers, inorganic hard coat layers, and organic-inorganic hybrid hard coat layers. In the spectacle lens field, organic-inorganic hybrid hard coat layers are typically employed.
The organic-inorganic hybrid hard coat layer is a layer formed using inorganic particles such as inorganic oxide particles as well as a hydrolyzable group-bearing organic silicon compound (silane coupling agent), a hydrolysate thereof and a hydrolyzed condensate thereof. Examples of the hydrolyzable group-bearing organic silicon compound include γ-glycidoxypropyltrimethoxysilane, γ-glycidoxypropylmethyldimethoxysilane, tetraethoxysilane, methyltriethoxysilane, and 1,2-bis(triethoxysilyl)ethane. Examples of the inorganic oxide particles include oxide particles of silicon, tin, zircon and titanium or composite particles thereof. The organic-inorganic hybrid hard coat layer is a hybrid material and therefore has excellent adhesion with the lens base or an underlayer (organic layer) which is the primer layer and with the antireflective layer (typically, a multilayer film of an inorganic oxide) formed on the hard coat surface, while having excellent surface hardness. Thus, the organic-inorganic hybrid hard coat layer is generally used in the spectacle lens field.
The organic hard coat layer is a hard coat layer formed using an organic compound. Examples of the organic compound include (meth)acrylate compounds, melamine compounds, and epoxy compounds. The organic hard coat layer is an organic substance and therefore has excellent adhesion with the lens base or an underlayer (organic layer) which is the primer layer but poor adhesion with an inorganic antireflective film. In the spectacle lens field, UV curing-type hard coat layer materials such as (meth)acrylate compounds are used in a part of products having no antireflective film.
The inorganic hard coat layer is provided by forming an inorganic substance, e.g., silica, into a film by a dry method such as vacuum evaporation, sputtering, ion plating, ion-beam assisted deposition or CVD. The inorganic hard coat layer has excellent surface hardness but has poor adhesion with the lens base or an underlayer (organic layer) which is the primer layer, and is thus hardly used in the spectacle lens field.
The thickness of the hard coat layer is not particularly limited and is preferably from 1 to 5 μm.
The method of forming the hard coat layer is not particularly limited, and a method using a hard coat layer-forming composition containing a predetermined component (e.g., the foregoing organic compounds, inorganic compounds) is preferred for the sake of productivity. More specifically, a method that involves bringing the lens base having the primer layer thereon into contact with the hard coat layer-forming composition containing a predetermined component to form a coating on the primer layer, and optionally curing the coating, may be used. This method is described in detail below.
The method of bringing the lens base having the primer layer thereon into contact with the hard coat layer-forming composition containing a predetermined component is not particularly limited, and examples thereof include dip coating and spin coating. Of these, dip coating is preferred for the sake of productivity.
Formation of the coating on the primer layer may be followed by curing treatment in which the coating is heated and a solvent is removed from the coating. The heating temperature is not particularly limited and is preferably 90° C. to 130° C. and more preferably 90° C. to 110° C. for the purpose of preventing deformation and discoloring of the lens base that may be caused by heating. The heating time is not particularly limited and is preferably from 1 to 5 hours. The coating may be heated in stages under varied heating conditions.
The antireflective layer is a layer having the function of preventing the reflection of incident light.
In the present description, the antireflective layer is defined as a layer having refection characteristics in which the reflectance is reduced to about 5% or lower in the visible range of 400 to 700 nm.
The antireflective layer is not particularly limited in structure and may be of a single layer structure or a multilayer structure.
In the case of multilayer structure, it is preferable to have the structure in which a low refractive index layer(s) and a high refractive index layer(s) are alternately stacked. Examples of materials constituting the high refractive index layer include oxides of titanium, zircon, aluminum, tantalum and lanthanum. Examples of materials constituting the low refractive index layer include silica.
For the antireflective layer, a wet antireflective layer using a hollow silicon oxide may be used.
The thickness of the antireflective layer is not particularly limited and is typically 0.2 to 0.6 μm.
The method of producing the antireflective layer is not particularly limited, and examples thereof include dry methods such as vacuum evaporation, sputtering, ion plating, ion-beam assisted deposition and CVD.
The spectacle lens in this embodiment may include another layer in addition to the primer layer, the hard coat layer and the antireflective layer.
For instance, the spectacle lens may include a water and oil repellent layer at its outermost layer for the purpose of improving water and oil repellency. The water and oil repellent layer decreases surface energy of the spectacle lens and thus provides a contamination preventing function to the spectacle lens. In addition, the water and oil repellent layer improves sliding properties of a surface of the spectacle lens and thereby improves abrasion resistance of the spectacle lens.
The water and oil repellent layer contains a water and oil repellent component. The type of the water and oil repellent component is not particularly limited, and examples thereof include fluorine-containing compounds, silicone compounds, and compounds having a long-chain alkyl group, with fluorine-containing compounds being preferred, and fluorine-containing silane compounds being more preferred. The fluorine-containing silane compounds are fluorine-containing compounds having an alkoxysilyl group. The alkoxysilyl group is not particularly limited as long as it is a group with one to three alkoxy groups being bonded to a silicon atom, and examples thereof include a methoxy group, an ethoxy group and a propoxy group.
The method of forming the water and oil repellent layer is not particularly limited, and one exemplary method is a method involving applying a composition containing the water and oil repellent component onto a predetermined substrate. Exemplary application methods include dipping and spin coating. When dipping is employed for instance, a spectacle lens is dipped into a composition containing a water and oil repellent component and pulled out under specific conditions, thus applying the composition onto the spectacle lens.
The composition as above typically includes an organic solvent. Examples of the organic solvent for use include perfluorohexane, perfluoro-4-methoxybutane, perfluoro-4-ethoxybutane and m-xylene hexafluoride.
The water and oil repellent component content of the composition is not particularly limited and is preferably 0.01 to 0.5 wt % and more preferably 0.03 to 0.1 wt %. The content within the above range makes it possible to readily form the water and oil repellent layer while preventing the generation of coating unevenness.
Other methods of forming the water and oil repellent layer include dry methods such as vacuum evaporation.
The spectacle lens in this embodiment is obtained by sequentially forming the respective layers as described above. Specifically, one embodiment of the spectacle lens manufacturing method includes a step of forming a primer layer by applying the above-described primer layer-forming composition onto at least one of the object side surface and the eyeball side surface of the lens base to form a coating and curing the coating, a step of forming a hard coat layer on the primer layer, and a step of forming an antireflective layer on the hard coat layer.
To a spectacle lens in which the antireflective layer is disposed on the primer layer, a step of forming the antireflective layer on the primer layer is carried out.
The spectacle lens and the primer layer-forming composition are described below in further detail by way of examples and comparative examples; however, the invention should not be construed as being limited to the following examples.
To 210 parts by weight of water dispersible polyurethane (manufactured by Nicca Chemical Co., Ltd.; commercial name, EVAFANOL HA-170) with a nonvolatile content of 37.4 wt %, 353 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE; solvent, water; density (g/cm3), 3.6) with a nonvolatile content of 20 wt %, 394 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain a primer layer-forming composition P-1.
The primer layer-forming composition P-1 was applied onto a plastic lens base (MR8; refractive index, 1.60; power S, −2.00; central thickness, 1.10 to 1.30 mm) by dipping. Then, the plastic lens base applied with the primer layer-forming composition P-1 was heated at 80° C. for 20 minutes for precuring the composition, thereby forming a primer layer with 1.0-μm thickness on the plastic lens base.
To a reaction vessel, 197 parts by weight of a hydrolyzable group-bearing organic silicon compound (manufactured by Shin-Etsu Chemical Co., Ltd.; commercial name, KBM-403) was charged, and 45 parts by weight of 0.1 N aqueous hydrochloric acid solution was gradually added dropwise under stirring the reaction solution so that hydrolysis proceeded for a whole day and night, thus obtaining a hydrolysate and a partially hydrolyzed condensate of the hydrolyzable group-bearing organic silicon compound.
Then, to the thus-obtained hydrolysate and partially hydrolyzed condensate, 356 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE 1130F-2 (A-8)) with a nonvolatile content of 30 wt % as inorganic oxide particles, 16 parts by weight of acetylacetone aluminum as a metal catalyst, 385 parts by weight of methyl alcohol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain a hard coat layer-forming composition.
The hard coat layer-forming composition was applied onto the plastic lens base having the primer layer thereon by dip coating. Then, the plastic lens base applied with the hard coat layer-forming composition was heated at 80° C. for 20 minutes for precuring the composition and subsequently heated at 110° C. for 3 hours for completely curing the same, thus forming a hard coat layer with 2.5-μm thickness.
The plastic lens base provided with the primer layer and the hard coat layer was placed in a vapor deposition device to deposit a vapor deposition material by an electron beam heating process, thereby forming an antireflective layer composed of first to fifth layers stated below. The layer structure of the antireflective layer is as stated below, in order from the hard coat layer side. In the following, nd represents the refractive index, and nλ represents the film thickness.
In 796 parts by weight of fluorine solvent (manufactured by Sumitomo 3M Limited; commercial name, HFE-7200), 4 parts by weight of water and oil repellent (manufactured by Shin-Etsu Chemical Co., Ltd.; commercial name, KY-130) with a nonvolatile content of 20 wt % was dissolved to thereby obtain a water and oil repellent with a nonvolatile content of 0.1 wt %.
Thereafter, the plastic lens base provided with the antireflective layer as obtained above was dipped in the water and oil repellent for 5 seconds, subsequently pulled out at a rate of 12 mm/sec and then heated at 50° C. for 60 minutes, thereby forming the water and oil repellent layer.
A spectacle lens having the plastic lens base provided on each surface with the primer layer, the hard coat layer, the antireflective layer and the water and oil repellent layer was obtained through the foregoing procedures.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-2 was used in place of the primer layer-forming composition P-1.
To 284 parts by weight of water dispersible polyurethane (manufactured by Nicca Chemical Co., Ltd.; commercial name, EVAFANOL HA-170) with a nonvolatile content of 37.4 wt %, 213 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE; solvent, water; density (g/cm3), 3.6) with a nonvolatile content of 20 wt %, 460 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain a primer layer-forming composition P-2.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-3 was used in place of the primer layer-forming composition P-1.
To 118 parts by weight of water dispersible polyurethane (manufactured by Nicca Chemical Co., Ltd.; commercial name, EVAFANOL HA-170) with a nonvolatile content of 37.4 wt %, 528 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE; solvent, water; density (g/cm3), 3.6) with a nonvolatile content of 20 wt %, 312 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain a primer layer-forming composition P-3.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-4 was used in place of the primer layer-forming composition P-1.
To 204 parts by weight of water dispersible polyurethane (manufactured by Nicca Chemical Co., Ltd.; commercial name, EVAFANOL HA-170) with a nonvolatile content of 37.4 wt %, 191 parts by weight of colloidal zirconium oxide (manufactured by Nissan Chemical Industries, Ltd.; commercial name, Suncolloid HZ-400M7; solvent, water; density (g/cm3), 3.8) with a nonvolatile content of 38%, 561 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain the primer layer-forming composition P-4.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-5 was used in place of the primer layer-forming composition P-1.
To 210 parts by weight of water dispersible polyurethane (manufactured by Nicca Chemical Co., Ltd.; commercial name, EVAFANOL HA-170) with a nonvolatile content of 37.4 wt %, 353 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE; solvent, water; density (g/cm3), 3.6) with a nonvolatile content of 20 wt %, 436 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain the primer layer-forming composition P-5.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-6 was used in place of the primer layer-forming composition P-1.
To 304 parts by weight of water dispersible polyurethane (manufactured by Nicca Chemical Co., Ltd.; commercial name, EVAFANOL HA-50C) with a nonvolatile content of 35 wt %, 213 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE; solvent, water; density (g/cm3), 3.6) with a nonvolatile content of 20 wt %, 441 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain the primer layer-forming composition P-6.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-7 was used in place of the primer layer-forming composition P-1.
To 304 parts by weight of water dispersible polyurethane (manufactured by DKS Co. Ltd.; commercial name, SUPERFLEX 130) with a nonvolatile content of 35 wt %, 213 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE; solvent, water; density (g/cm3), 3.6) with a nonvolatile content of 20 wt %, 441 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain the primer layer-forming composition P-7.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-8 was used in place of the primer layer-forming composition P-1.
To 278 parts by weight of water dispersible polyurethane (manufactured by DKS Co. Ltd.; commercial name, SUPERFLEX 460) with a nonvolatile content of 38 wt %, 213 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE; solvent, water; density (g/cm3), 3.6) with a nonvolatile content of 20 wt %, 465 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain the primer layer-forming composition P-8.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-9 was used in place of the primer layer-forming composition P-1.
To 266 parts by weight of water dispersible polyurethane (manufactured by DKS Co. Ltd.; commercial name, SUPERFLEX 740) with a nonvolatile content of 40 wt %, 213 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE; solvent, water; density (g/cm3), 3.6) with a nonvolatile content of 20 wt %, 479 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain the primer layer-forming composition P-9.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-10 was used in place of the primer layer-forming composition P-1.
To 401 parts by weight of water dispersible polyurethane (manufactured by Nicca Chemical Co., Ltd.; commercial name, EVAFANOL HA-170) with a nonvolatile content of 37.4 wt %, 556 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain the primer layer-forming composition P-10.
A spectacle lens was obtained according to the same procedures as those of Example 1 except that a primer layer-forming composition P-11 was used in place of the primer layer-forming composition P-1.
To 87 parts by weight of water dispersible polyurethane (manufactured by Nicca Chemical Co., Ltd.; commercial name, EVAFANOL HA-170) with a nonvolatile content of 37.4 wt %, 586 parts by weight of colloidal titanium oxide (manufactured by JGC Catalysts and Chemicals Ltd.; commercial name, OPTOLAKE; solvent, water; density (g/cm3), 3.6) with a nonvolatile content of 20%, 285 parts by weight of water, 42 parts by weight of 1-methoxy-2-propanol, and 1 part by weight of surfactant (manufactured by Dow Corning Toray Co., Ltd.; commercial name, L7001) were added, and the resulting mixture was stirred to thereby obtain the primer layer-forming composition P-11.
Those polyurethane resins used in Examples and Comparative Examples above were each evaluated for the tensile strength and the elongation as well as the average particle size of polyurethane resin particles, as follows.
An aqueous dispersion containing each of the polyurethane resins was taken into a Petri dish in such an amount that a film obtained after drying would have a thickness of about 500 μm, and dried at room temperature for 24 hours and subsequently at 80° C. for 6 hours to form a polyurethane resin film.
Thereafter, the film was cut into a size of 15-mm width and 200-mm length, and then gage marks were given at 50-mm intervals in the central region, thus producing a sample. The obtained sample was attached to a tensile tester (Autograph AGS-X, manufactured by Shimadzu Corporation), the distance between the grips of the tensile tester was set to 100 mm, the film was pulled to its breaking point at a rate of 200 mm/min, and the stress at the breaking point was defined as the tensile strength. The measurement temperature was 25° C.
The elongation was measured concurrently with the foregoing measurement (tensile strength measurement) and calculated as follows.
Elongation (%)=((Gage distance at breaking point−Gage distance before testing)/(Gage distance before testing)×100
The average particle size of each urethane resin was measured through dynamic light scattering using Nanotrac UPA-EX150 particle size distribution analyzer manufactured by Nikkiso Co., Ltd. For specimens, the water dispersible polyurethanes used in Examples and Comparative Examples were used.
With the spectacle lenses of Examples and Comparative Examples obtained above, the evaluations below were conducted.
The crazing resistance was evaluated with a device shown in
In the device shown in
The evaluation was continued until cracking occurred to such a level that cracking was observable under the fluorescent lamp, and the average between a load with which cracking occurrence was visually confirmed under the fluorescent lamp and its immediately preceding load was defined as a cracking occurrence load. The evaluation criteria are as follows:
The device shown in
Spectacle lenses for impact resistance evaluation to be described below were obtained according to the same procedures as those of Examples 1 to 5 and Comparative Examples 1 to 6 except that a plastic lens base (N19; refractive index, 1.74; power S, −1.50) was used in place of the plastic lens base (MR8; refractive index, 1.60; power S, −2.00; central thickness, 1.10 to 1.30 mm).
Subsequently, using an impact tester, a 340 g tup was dropped from a height of 60 cm toward each of the spectacle lenses for impact resistance evaluation, and when the spectacle lens was broken, the maximum energy applied until the spectacle lens was broken was used for the evaluation. The evaluation criteria are as follows:
After dirt on a surface of the spectacle lens manufactured in each of Examples and Comparative Examples was removed with acetone, the transmittance was measured and the luminous transmittance for 380 to 780 nm was measured using U-4100 spectrophotometer (manufactured by Hitachi, Ltd.), and the evaluation was conducted according to the following criteria.
The spectacle lens manufactured in each of Examples and Comparative Examples was put in a weather resistance evaluation apparatus (SUN TESTER) and irradiated with UV light for 200 hours. Then, the adhesion of the coating on the plastic lens base was evaluated by a cross-cut method (by reference to JIS K 5400-8.5). The evaluation criteria are as follows:
The primer layer-forming composition used in each of Examples and Comparative Examples was stirred at room temperature for 1 week, and the presence of a deposit and the occurrence of gelation were visually checked. The evaluation criteria are as follows:
In Table 1, “SF130,” “SF460” and “SF740” in the “resin name” column represent “SUPERFLEX 130,” “SUPERFLEX 460” and “SUPERFLEX 740,” respectively.
The “skeleton” column shows the types of polyurethane resins. “Polycarbonate” refers to a polycarbonate polyurethane resin, “polyether” to a polyether polyurethane resin, and “polyester” to polyester polyurethane resin. The polyether polyurethane resin represents a polyurethane resin formed using polyether as a diol component, and the polyester polyurethane resin represents a polyurethane resin formed using polyester as a diol component.
The “content (vol %)” in the “inorganic oxide particles” column represents the content (vol %) of the inorganic oxide particles based on the total volume of the primer layer. Note that these values are the same as the inorganic oxide particle contents (vol %) based on the volume of the total solids of the primer layer-forming composition.
The “water-soluble organic solvent (%/solvent)” column of the “solvent” column represents the water-soluble organic solvent content (wt %) based on the total weight of the solvent.
As can be seen from Table 1, the spectacle lenses of Examples exhibited the desired effects (crazing resistance, impact resistance, transparency). Examples 1 to 5 were excellent also in adhesion.
In particular, the comparison of Examples 1 to 3 revealed that when the inorganic oxide particle content was from 15 to 40 vol %, the crazing resistance was more excellent.
The comparison between Examples 1 to 4 and Example 5 revealed that when the water-soluble organic solvent content was not greater than 50 wt % based on the total weight of the solvent, the primer layer-forming composition had more excellent liquid stability.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2017-107529 | May 2017 | JP | national |
This application is a Divisional of U.S. patent application Ser. No. 17/981,876 filed on Nov. 7, 2022, which is a Divisional of U.S. patent application Ser. No. 16/698,576 filed on Nov. 27, 2019, which is a Continuation of PCT International Application No. PCT/JP2018/020402 filed on May 28, 2018, which claims priority under 35 U.S.C. § 119(a) to Japanese Patent Application No. 2017-107529 filed on May 31, 2017, all of which above applications are hereby expressly incorporated by reference, in their entireties, into the present application.
| Number | Date | Country | |
|---|---|---|---|
| Parent | 17981876 | Nov 2022 | US |
| Child | 18516283 | US | |
| Parent | 16698576 | Nov 2019 | US |
| Child | 17981876 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | PCT/JP2018/020402 | May 2018 | US |
| Child | 16698576 | US |
