The described technology relates to fabrication of light-emitting devices, for example fabrication of light-emitting devices that include a scattering element of arbitrary shape.
The present technology relates generally to light-emitting devices and, in particular, to light-emitting devices that feature a solid state light-emitting element and a scattering element and an extractor element remote from a light-emitting element.
Light-emitting elements are ubiquitous in the modern world, being used in applications ranging from general illumination (e.g., light bulbs) to lighting electronic information displays (e.g., backlights and front-lights for LCDs) to medical devices and therapeutics. Solid state light emitting devices, which include light emitting diodes (LEDs), are increasingly being adopted in a variety of fields, promising low power consumption, high luminous efficacy and longevity, particularly in comparison to incandescent and other conventional light sources.
One example of a SSL device increasingly being used for in luminaires is a so-called “white LED.” Conventional white LEDs typically include an LED that emits blue or ultraviolet light and a phosphor or other luminescent material. The device generates white light via down-conversion of blue or UV light from the LED (referred to as “pump light”) by the phosphor. Such devices are also referred to as phosphor-based LEDs (PLEDs). Although subject to losses due to light-conversion, various aspects of PLEDs promise reduced complexity, better cost efficiency and durability of PLED-based luminaires in comparison to other types of luminaires.
While new types of phosphors are being actively investigated and developed, configuration of PLED-based light-emitting devices, however, provides further challenges due to the properties of available luminescent materials. Challenges include light-energy losses from photon conversion, phosphor self-heating from Stokes loss, dependence of photon conversion properties on operating temperature, degradation due to permanent changes of the chemical and physical composition of phosphors in effect of overheating or other damage, dependence of the conversion properties on intensity of light, propagation of light in undesired directions in effect of the random emission of converted light that is emitted from the phosphor, undesired chemical properties of phosphors, and controlled deposition of phosphors in light-emitting devices, for example.
The described technology relates to fabrication of light-emitting devices, for example fabrication of light-emitting devices that include a scattering element of arbitrary shape.
In one aspect, a light-emitting device includes a base substrate that has a base surface; a light-emitting element (LEE) that is configured to emit light, where the LEE is disposed on the base surface; a first optical element having a first surface that is spaced apart from the LEE and positioned to receive light from the LEE, where the first optical element includes scattering centers that are arranged to scatter light from the LEE, and where the first optical element has a non-hemispherical shape; a second optical element that has an exit surface, where the second optical element is transparent and in contact with the first optical element, there being an optical interface between the first and second optical elements at the place of contact, where the optical interface is opposite the first surface of the first optical element, and where the second optical element is arranged to receive at least a portion of the light through the optical interface; and a transparent shell that has an inner surface and an opposing outer surface, where the inner surface is in contact with the exit surface of the second optical element, where: a medium adjacent to the first surface of the first optical element has a refractive index n0, the first optical element includes a material that has a refractive index n1, where n0<n1, the second optical element includes a material that has a refractive index n2, where n0<n2, and the transparent shell includes a material that has a refractive index n3, where n3≧n2.
The foregoing and other embodiments can each optionally include one or more of the following features, alone or in combination. In some embodiments, the first optical element includes phosphor. In some embodiments, a hardness of the transparent shell can be larger than a hardness of the second optical element. In some embodiments, the material of the transparent shell can be solid and the material of the second optical element can be liquid or gel. In some embodiments, the light-emitting device can further include a reflective layer disposed on the base surface of the base substrate. In some embodiments, the outer surface of the transparent shell can be a transparent surface that is shaped such that an angle of incidence on the outer surface of the light provided by the first optical element that directly impinges on the outer surface is less than a critical angle for total internal reflection. In some embodiments, the outer surface of the transparent shell can be a transparent surface that is shaped such that an angle of incidence on the outer surface of the light provided by the first optical element that directly impinges on the outer surface is less than a Brewster angle.
In another aspect, a method for forming a light-emitting device includes providing a light-emitting element (LEE) on a base surface of a base substrate; coupling a first optical element with the base surface of the base substrate, where the first optical element has a first surface facing the LEE and a second surface opposing the first surface, the first surface is spaced apart from the LEE, the first optical element includes a material that has a first refractive index n1, and where a medium adjacent to the first surface of the first optical element has a refractive index n0<n1; disposing the first optical element in a curable or settable fluid so that the fluid conforms to the second surface; and curing or setting the fluid to form a second optical element adjacent the second surface of the first optical element, where the second optical element has a refractive index n2>n0.
The foregoing and other embodiments can each optionally include one or more of the following features, alone or in combination. In some embodiments the second optical element includes a molded transparent layer. In some embodiments, the second surface of the first optical element has a non-hemispherical shape. In some embodiments, the fluid is provided in a transparent shell. In some embodiments, the transparent shell has an outer surface that corresponds to the exit surface of the second optical element. In some embodiments, the transparent shell remains with the light-emitting device and an outer surface of the transparent shell can be a transparent surface that is shaped such that an angle of incidence on the outer surface of the light provided by the second optical element that directly impinges on the outer surface is less than a critical angle for total internal reflection.
In some embodiments, the curing or setting includes exposing the fluid to UV radiation. In some embodiments, the curing or setting includes heating the fluid. In some embodiments, the method further includes providing a reflective layer on the base surface, where the reflective layer can be configured to diffusely or specularly reflect light. In some embodiments, the exit surface of the second optical element can be a transparent surface that is shaped such that an angle of incidence on the exit surface of the light provided by the first optical element that directly impinges on the exit surface is less than a critical angle for total internal reflection. In some embodiments, the exit surface of the second optical element can be a transparent surface that is shaped such that an angle of incidence on the exit surface of the light provided by the first optical element that directly impinges on the exit surface is less than a Brewster angle.
Like reference symbols in the various drawings indicate like elements.
The shape of the optical interface 125 between the scattering element 120 and the extractor element 130 can affect the distribution of light output by the light-emitting device 100. For example, an optical interface 125 shaped as an oblate dome (having a dome height shorter than a base diameter) provides an intensity distribution biased along the optical axis of the light-emitting device 100, e.g., the +z axis. As another example, an optical interface 125 shaped as an oblong dome (having a dome height longer than a base diameter) provides a laterally-biased intensity distribution (biased away from the optical axis of the light-emitting device 100.) In general, when fabricating light-emitting devices, the shape of the optical interface between the scattering element and extractor element can be limited by available machining processes. The fabrication processes described in detail below provide the capability to produce light-emitting devices having a variety of shapes of the optical interfaces between the scattering element and extractor element not readily producible by conventional fabrication processes.
In some implementations, the scattering element 120 can have an irregular shape (as illustrated). Furthermore, the scattering element 120 can have a uniform or non-uniform geometrical or effective thickness, generally referred to as thickness and as the case may be referring to a geometrical or effective thickness as appropriate. The effective thickness refers to a combination of geometrical thickness and scattering/conversion properties of the scattering element 120. Depending on the embodiment, a regular or irregular shaped scattering element 120 may have a regular or irregular thickness. The scattering element 120 includes a plurality of scattering centers configured to scatter light. Depending on the embodiment, the scattering centers can be configured to elastically, inelastically, or elastically and inelastically scatter light.
In some implementations, the light-emitting elements can be pre-packaged LEDs, for example LED dies encapsulated in silicone. A size of encapsulated LEDs can be 1, 3 or 5 mm in diameter. The base substrate 105 has a surface 108 on which the light-emitting element 110 can be disposed. The surface 108 of the base substrate 105 can be reflective (e.g., a mirror). In some implementations, a reflective layer 145 can be deposited on the surface 108 of the base substrate 105, as described below in connection with
At least a portion of light emitted by the light-emitting element 110, or back-scattered by the scattering element 120, can be reflected by the surface 108 (or the reflective layer 145). The scattering element 120 can include active scattering centers, e.g., phosphors configured to inelastically scatter pump (e.g., blue) light emitted by the light-emitting element 110 to inelastically scattered light (green, yellow, etc.). The scattering element 120 can include passive scattering centers configured to elastically scatter the pump light, without changing its color. The scattering element 120 has a first surface 115 spaced apart from the light-emitting element 110 and positioned to receive the light from the light-emitting element 110. In some implementations, the scattering element 120 has uniform thickness. The thickness of the scattering element 120 can be 0.02, 0.20, 0.50, or 1 mm, for example. In general, the first surface 115 of the scattering element 120 can have a desired shape, e.g., spherical, parabolic, elliptical, or an arbitrary, mostly concave (with respect to the enclosure 140) shape, as illustrated in
The light-emitting element 110 is disposed on the surface 108 of the base substrate 105, in an opening/enclosure 140 that is, at least in part, defined by the first surface 115. The enclosure 140 is referred to as a recovery enclosure, as described below. In some implementations, the reflective layer 145 disposed on the surface 108 of the base substrate 105 extends to at least the first surface 115 of the scattering element 120. In other implementations, the reflective layer 145 extends to at least an exit surface 135 of the extractor element 130. In some implementations, the reflective layer 145 extends beyond the exit surface 135 of the extractor element 130. The enclosure 140 can be filled with a medium (e.g., gas or air) and encloses the light-emitting element 110, and at least a portion of the reflective layer 145.
In general, the shape of exit surface 135 can vary as desired, e.g., spherical or cylindrical (as shown in
In this example, light propagation asymmetry arises from the relative values of the indexes of refraction of materials in the enclosure 140 (index n0), in the scattering element 120 (index np), and in the extractor element 130 (index n1). For instance, if np=1.5 and n0=1.0, that is n0<np, a large fraction (˜75%) of the isotropically distributed photons impinging on the first surface 115 will be reflected by total internal reflection (TIR) back into the scattering element 120 and only a smaller fraction (˜25%) will be transmitted backwards into the recovery enclosure 140 from where only few may reach the light-emitting element 110. At the optical interface 125, the condition np≦n1 will guarantee that substantially all photons reaching the optical interface 125 will transition into the extractor element 130, and the Brewster condition will further guarantee that practically all these photons will transmit into air without TIR through the exit surface 135. Only a small fraction (down to about ˜4% depending on incidence angle) will be returned by Fresnel reflection at the exit surface 135. For the above examples, when the radius RO of the notional surface enclosing the scattering element 120 is 3 mm, the Weierstrass radius R1W=4.50 mm, and the Brewster radius R1B=5.41 mm.
In some implementations, the scattering element 120 can be pre-formed in a desired shape. For example, scattering elements can be fabricated (e.g., molded) separately and procured/provided as pre-formed components. As noted above, the shape of an optical interface 125 between the scattering element 120 and the extractor element 130 can influence the illumination pattern output by the light-emitting device 100. Accordingly, it is desirable to form (e.g., mold) the extractor element 130 to correspond to a desired shape of the outer surface of the scattering element 120.
At 210, a base substrate 105 having a surface 108 is provided, as shown in
At 220, the light-emitting element 110 is disposed on the base substrate 105 in gap 147, as shown in
At 230, a scattering element 120 (e.g., a phosphor-containing composite) is secured to base substrate 105, as shown in
At 240, an extractor element is formed to accommodate a shape of the outer surface 127 of the scattering element 120, as shown in
In some implementations, the cavity 246 (i) is sized to contain a notional surface of radius RO (not shown in
The fill level of the fluid 130-u in the cavity 246 can be configured such that an unfilled volume enclosed by the cavity 246 is slightly less (e.g., 2%, 5%, 10% less) than a volume enclosed by an outer surface 127 of the scattering element 120.
In some implementations, a hard optical-quality surface 244 (e.g., having a surface polished to a 0.01, 0.1, 1 of a wavelength) is disposed in the cavity 246 before it is filled with the fluid 130-u. In this case, the hard optical-quality surface remains integrated with the extractor element 130 after the curing operation performed at 250. The mold 242 can include one or more channels (not shown) to dispose of excess fluid displaced at 240 when forming the extractor.
In some implementations, the hard optical-quality surface can be configured to provide a shell for the uncured fluid 130-u. Such a shell can be configured to be held in place by the mold 242 as illustrated in
The base substrate 105 is brought against the mold 242 such that the scattering element 120 is immersed in the fluid 130-u. The base substrate 105 and the mold 242 can be brought together in a motion in the Z-direction as indicated by the arrows shown in
At 250, the fluid 130-u that forms the extractor element is cured to a solid state, as indicated in
The cured extractor element 130 has an index of refraction n1c that is substantially the same or larger than the index of refraction np of the scattering element 120. If a hard optical-quality surface 244 was disposed in the cavity 246 at 240, the hard optical-quality surface 244 can form a part of the cured extractor element 130, for example, to form a protective shell around the exit surface 135 of the cured extractor element 130. In this case, the hard optical-quality surface 244 has an index of refraction that is substantially the same or larger than the index of refraction n1c of the bulk of the cured extractor element 130. In some implementations, a hardness of the hard optical-quality surface 244 can be larger than a hardness of the bulk of the extractor element 130, e.g., 1.05×, 1.10×, 1.50×, 2×, 10× harder.
The mold 242 can be decoupled from the light-emitting device prior to, during or after curing, at 250, the extractor element 130. In some implementations, post-curing can be performed to further harden the extractor element 130. In some embodiments, a release agent is used to facilitate removal of the extractor element from the mold. In some implementations, it is desirable to fabricate extractor elements that have shapes extending beyond hemispheres, such that a pattern of light output from the light-emitting devices subtends more than 180°. In such cases, the mold 242 can include two or more pieces that are separated after cure.
In some implementations, the extractor element 130 can be formed using an injection molding process. The base substrate 105 with the scattering element 120 can be brought together with the mold 242 and the fluid 130-u can be pressure injected into the mold 242 through inlet channels (not shown in
In some implementations, the hard optical-quality surface 244 can be coupled to the base substrate (e.g., by using silicone as adhesive) to form an enclosure for the fluid 130-u, which can remain in a liquid or gel state. In such configurations, the fluid 130-u has an index of refraction n1u that is substantially the same as or smaller than the index of refraction of the hard optical-quality surface 244, but larger than the index of refraction np of the scattering element 120. In this case, a hardness of the hard optical-quality surface 244 can be larger than a hardness of the bulk of the extractor element 130, as the latter is in gel state.
Though the example fabrication process has been described with respect to a light-emitting device including a single light-emitting element, the process described herein can also be implemented for an array of light-emitting elements that can be separated into individual light-emitting devices after completing the fabrication process, for example. In some implementations, a light-emitting device 100 can include multiple light-emitting elements. In some implementations, a light-emitting device 100 can include multiple scattering elements.
This application claims the benefit under 35 U.S.C. §119(e)(1) of U.S. Provisional Application No. 61/780,537, filed on Mar. 13, 2013, which is incorporated by reference herein.
Number | Date | Country | |
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61780537 | Mar 2013 | US |