The invention relates to a fastener for a container evacuator and a method, in particular for a drum evacuator for pressing silicone gum or other viscous material from a container to a continuous compounding system.
In a compounding system, a viscous material is fed to a processing line where feed is mixed and additives are injected in proportions to produce a customized product. The feed material for these processes can be delivered in various containers to the compounding site. When delivered, the material must be removed from the container for processing. For example, a compounding system can require emptying material such as silicone gum from drums or similar containers. However, the feed material may be very viscous and resistant to flow and hence, resistant to removal from the delivery container.
Some emptying processes use a plunger to drive through a container content to express the content for further processing. A considerable amount of pressure is needed in these processes to express a viscous material such as a silicone gum. The high expressing force exposes the materials container to very high mechanical stress. For reasons of weight and expense, the containers are usually designed with very thin walls and a structure that is just sufficient to avoid damage to the container during transport. The container is not designed to withstand stress imposed during the emptying operation and the high pressure developed during an emptying operation can easily burst a container structure.
Reinforcing split metal sleeves or half-shells can be placed around a container during an emptying operation. However, the mounting and closing off of the sleeves and half-shells can be very complicated operations, requiring considerable manual labor. Another disadvantage is that the sleeves or half-shells must be adapted in an exact manner to the outside container dimensions thus sometimes requiring an inventory of sleeves or half-shells to accommodate various sized containers.
Accordingly, there is a need to facilitate the removal of a viscous feed material from a container, particularly removal of a viscous feed material such a viscous silicone from a delivery container such as a drum.
The invention provides an improved viscous material container evacuator and method to remove viscous material from a delivery container to a processing system. The invention is describable as a viscous material container evacuator, comprising: a chamber to hold a container and a plunger axially and slidably accommodated within the chamber to express material from the container; at least one hinged closure that closes to define the chamber and to securely enclose the container; and at least one motor activated fastener that secures the closure around the container.
In an embodiment, the invention is a method to secure a closure of a viscous material container evacuator, comprising: activating a motor drive shaft to drive a connected threaded shaft into a complimentary threaded channel of a clamp block that comprises an opposing nub wall; and driving the threaded shaft to impose the nub upon a first lug of an evacuator and to foreshorten a distance between a head of the threaded shaft and the opposing nub to impose the nub against a second lug of a closure to secure the lugs together to secure the container.
Another embodiment of the invention is viscous material processing system, comprising: a viscous material feed system comprising: a viscous material container evacuator comprising a chamber to hold a container and a plunger axially and slidably accommodated within the chamber to express material from a container held within the evacuator chamber and enclosable by hinged closures that define the chamber, the closures securable by at least one motor activated fastener that secures the closure around the container; and a viscous material compounding system that receives material expressed from the feed system.
Another embodiment is a viscous material feed system, comprising: a container evacuator comprising a chamber to hold a container and a plunger axially and slidably accommodated within the chamber to express material from the container held within the evacuator chamber; and at least one hinged closure that closes to define the chamber and to securely enclose the container; and at least one motor activated fastener that secures the closure around the container; a feed tube that receives material expressed from a container by the container evacuator; and a cutting apparatus that meters material from the feed tube to a processing system.
And, another embodiment is a viscous material feed method, comprising: placing a viscous silicone gum containing drum into a material extracting apparatus; securing closure of the material extracting apparatus around the drum by activating a motor drive shaft to drive a connected threaded shaft into a complimentary threaded channel of a clamp block that comprises an opposing nub wall; and driving the threaded shaft to impose upon a first lug of closure of the apparatus and to foreshorten a distance between a head of the threaded shaft and the opposing nub to impose the nub against a second lug of a closure of the apparatus to secure the lugs together; and evacuating viscous material from the drum by driving a plunger through the drum to express the silicone gum a viscous material compounding process.
Another embodiment is a viscous material container evacuator, comprising: a chamber to hold a container and a plunger axially and slidably accommodated within the chamber to express material from the container; at least one hinged closure that closes to define the chamber and to securely enclose the container; at least one motor activated fastener that secures the closure around the container; and a hydraulic system that powers the motor, comprising a hydraulic pressure supply, and a relief cartridge that controls the pressure supply to activate the motor by diverting pressure supply from the motor when a set point pressure is attained.
And, another embodiment is a method of controlling a battery of hydraulically operated fasteners to a viscous material container evacuator, comprising: setting a set point pressure for each fastener of the battery; supplying an activating hydraulic fluid pressure to each fastener; and diverting the applied pressure from each fastener as the set point for that fastener is attained.
The invention relates to the handling of a viscous material such as a silicone gum. “Silicone gum” includes a viscous silicone or polysiloxane or organopolysiloxane that has the chemical formula [R2SiO]n, where R=organic groups such as methyl, ethyl, and phenyl. These materials typically comprise an inorganic silicon-oxygen backbone ( . . . —Si—O—Si—O—Si—O— . . . ) with attached organic side groups, which can be four-coordinate. In some cases organic side groups can be used to link two or more of these —Si—O— backbones together.
By varying the —Si—O— chain lengths, side groups, and crosslinking, silicones can be synthesized with a wide variety of properties and compositions. They can vary in consistency from liquid to gel to rubber to hard plastic. Silicone rubber or silicone gum is a silicone elastomer, typically having high temperature properties. Silicone rubber offers resistance to extreme temperatures, being able to operate normally from minus 100° C. to plus 500° C. In such conditions tensile strength, elongation, tear strength and compression set can be superior to conventional rubbers.
A silicone gum can be extruded or molded into custom shapes and designs such as tubes, strips, solid cord or custom profiles within size restrictions specified by a manufacturer. Cord can be joined to make “O” Rings and extruded profiles can also be joined to make up seals.
It is desirable to provide a viscous feed system that accurately and efficiently processes viscous materials such as silicone gum for use in various applications. However, these materials can be highly resistant to flow, highly adhering, highly cohering, and/or shear thickening and consequently difficult to handle. Accuracy of a packaging process and/or accuracy of a process of obtaining a defined quantity of such material, for example in a continuous process is costly when substantial time is required for cutting or separating of a quantity of the material from a larger quantity. Also, it is costly and wasteful to have to clean processing equipment on a frequent basis when the fluid material sticks to a cutting tool or instrument; also, it is costly, and disadvantageous when an incorrect amount of material is used in a downstream process.
A material evacuation process exerts substantial force against a container wall to threaten rupture of the container. Both the evacuator and any fastener to the evacuator closures must be robustly capable of securing closure against the substantial force. The invention provides a secure closure with a fastener that can with stand high forces exerted on a container wall during material evacuation. The fastener can include a hydraulic motor that drives a lock mechanism that includes a threaded shaft and a clamp block with a nub and a threaded channel that accepts the threaded shaft. The motor drives the threaded shaft to foreshorten the distance between a first closure lug and a lug on a second closure or on the evacuator wall to enclose the container for evacuation. Also, an embodiment of the fastener addresses problems of misalignment between the drive shaft and threaded shaft that arise on account of part tolerance divergence and operational wear.
In this application, the term “play” means movement or space for movement, as of mechanical parts. A degree of play means a tolerance that permits relative movement between parts without disengagement. A reference to “back” means left on a drawing or drawings and a reference to “forward” means right on the drawing or drawings.
Features of the invention will become apparent from the drawings and following detailed discussion, which by way of example without limitation describe preferred embodiments of the invention.
A preferred invention embodiment shown in the drawings illustrates the invention as a process to compound silicone gum into a base for forming articles. In the drawings,
The MEA 16 serves to express the viscous material from a container to the compounding system 14. In typical operations, 55-gallon steel drums from a pallet are dumped into totes and the totes (approx. 80 pounds each) are dumped into a Banbury mixer. However, manually maneuvering drums from pallets can cause back and shoulder strains and injuries. In a preferred compounding operation of the invention with respect to
The material in the drums 42 may be identical or it may be of a variety of physical properties such as viscosity. The drums 42 are removed from the pallet 40 one by one by drum hauler 44 such as from Easy Lift Equipment Co., Inc., 2 Mill Park Court, Newark, Delaware 19713. The lid of each of three drums 42 is removed and each of the drums 42 is loaded by the hauler 44 into a respective container evacuator 42, which may be a Schwerdtel S 6-F drum press. Use of the drum hauler 44 eliminates ergonomic risks associated with lifting and handling the heavy drums 42. The silicone gum is then forced from each drum in measured aliquots by the MEA 16 into the conveyor 18. In the drawings embodiment, the MEA 16 comprises a container evacuator 22, feed tube 24 and cutting apparatus 26. The container evacuator 22 can be a drum press, which is a device that evacuates viscous or compacted contents from a drum. As illustrated in
The operation of feed system 12 can be described with reference to
Misalignment coupling 116 serves to transmit mechanical power from one rotating shaft to another where the shafts are not in exact alignment. In
Back couple half 134 interior passageway 140 has an inner cylindrical splined surface 170 adapted to receive a complementary splined surface 172 of drive shaft 114 and forward couple half 136 has a splined surface 174 adapted to receive the complementary splined surface of reduced diameter back section 158 of threaded shaft 122. The 172, 158 splined surfaces are configured and oriented to nestle within respective spline surfaces 170, 174 in an interdigitated manner. The term interdigitated means that the splines are interlaced as fingers of two hands can be joined in parallel.
Coupler section 138 interior passageway 140 portion has a smooth wall and this portion of the passageway 140 has a larger diameter than back couple half or forward couple half diameters defined by grooves of the splined surfaces 170 and 174. The coupler section 138 connects the halves 134, 136 so that the spline configurations of the halves 134, 136 are misaligned to trap the drive shaft 114 and threaded shaft 122 to one another. The keys 142 and 144 are held by rings 154 and 156 with some degree of axial play and are placed 900 out of phase to one another to provide a slackened tolerance to both axial and angular misalignment between drive shaft 114 and threaded shaft 122. The misalignment coupling 116 configuration transmits drive shaft torque while accommodating axial and angular misalignment.
An overrun backoff mechanism is another embodiment illustrated in
Another embodiment of the invention relates to hydraulic control of the fastener 110. In
In other terms, as hydraulic fluid flows into port B and out of port A of hydraulic motor 112 causing Lead Screw 122 to rotate unscrewing itself from Clamp Block 132. This causes clamp Block 132 to extend. Once Clamp Block 132 has extended to the point that Clamp Block 132 comes into contact with Lug 128, as illustrated in
In an overrun situation, hydraulic fluid flows into port A and out of port B of hydraulic motor 112 causing rotation of Lead Screw 122 in its tightening direction. Restart Spring 119 presses on Lead screw 122 pushing its threads into the Threaded bore of Clamp Block 132 causing the threads to reengage. Once the threads of Clamp Block 132 and Lead Screw 122 have reengaged Lead Screw 122 will travel toward Lug 128. Lead Screw 122 will come in contact with Lug 128 (
In a fastener unlocking cycle, a solenoid of the spool valve 230 directs fluid flow from port P to port B and from port A to port T resulting in hydraulic flow from port B to port A in each motor 224, 226 and 228. Flow from port B to port A actives each motor 224, 226 and 228 to open each fastener 110. When an open situation is determined by PLC timing, the PLC returns the valve 230 to neutral. In an event that a motor fails to operate when hydraulically activated, a relief valve 232 prevents pressure from increasing above a “burst pressure.”
Each MEA 16 includes the container evacuator 22, feed tube 24 and cutting apparatus 26 and each is set on a respective floor scale 28. In each MEA 16, the feed tube 24 is connected through the disc shaped platen 56 to communicate with the press cavity 60. The platen 56 is driven by hydraulic plunger 72. When a batch is set up by loading each chamber 50 of the feed system 12 battery, an operator can initiate a system cycle by controller 30 touch screen located at a work station. The controller 30 can be a microprocessor or computer or the like for controlling the MEA 16 as hereinafter described.
The operator can commence system operation at controller 30. When a cycle is activated by an operator, a plunger 72 of each container evacuator 22 of the battery shown in
The material is cut into small pieces by cutting apparatus 26 as it exits from the discharge port 70 to the conveyor 18 to charge to compounding system 14. Cutting can be accomplished by various cutting mechanisms, including a cutting head disposed at an outlet end of the feed tube. For example, Brandl, U.S. Pat. No. 5,797,516, incorporated hereto in its entirety discloses a cutting head formed by a knife that is detachably mounted in an axial direction and radial and tangential to the axial direction. The cutting head is situated relative to a feed tube about a common central longitudinal axis.
In the
The controller 30 of
The controller 30 also controls operation of cutting apparatus 26 according to the calculated charged material weight. Initially, the cutting apparatus 26 can be programmed to make cuts of about “football” sized material, for example to fit in a 14″ inner diameter screw conveyor 18. Once a piece of material is cut from the feed tube discharge port 70, floor scale 28 senses a contemporaneous weight and feeds this signal back to the controller 30. When the controller 30 senses a contemporaneous weight signal and calculates that a total charged weight is within a specified range of total material to be charged (for example within 15 pounds of “set point”) to the compounding system 14, the controller can signal the cutting apparatus 26 via lines 84 to increase cut frequently to produce smaller “diced” pieces. The smaller diced pieces at approach to set point permit improved control of feed to attain a charged material weight within a prescribed tolerance range, for example +/−2 pounds for a batch.
As the drum 42 evacuation process is completed, door fasteners of the hinged closures 52 and 56 open and a controller 30 Run Screen displays “NEW DRUM.” A beacon light mounted on the container evacuator 22 turns yellow, indicating the drum 42 is ready to be changed. The chamber 50 hinged closures 52 and 56 open the hydraulic unit motor terminates. The door fasteners are opened and the empty drum is removed, typically with the drum hauler. The press is reloaded with a drum the process repeated.
As material is charged from the presses to the screw conveyor, the conveyor is turning at low rpms to feed the material to the mixer. The screw is programmed to stop turning 90 seconds after the last press makes its last cut. We have determined this time to be adequate to clear all material from the conveyor.
Conveyor 18 transports and drops the silicone gum to chute 20, which drops the material into a material compounding system 14. In one silicone compounding process, a heat cured rubber (HCR) composition can be produced by kneading a high-viscosity polydiorganosiloxane, an inorganic filler and additives by means of a batch kneading machine such as the high intensity Banbury mixer 32 or a low intensity double arm dough mixer. In this process, silicone gum, inorganic filler, treating agents and additives are batch mixed until desired properties are obtained. In Kasahara et al., U.S. Pat. No. 5,198,171, a preconcentrate of silicone gum, inorganic filler and treating agents is formed by a high speed mechanical shearing mixer. The resulting premix is further compounded in a same-direction double screw extruder. A premix is formed in a first step wherein a silicone gum having a viscosity at 25° C. of 1×105 cP or more, an inorganic filler and a treating agent are mixed in a high speed mechanical shearing machine to provide a flowable particulate mixture in which each ingredient is present in a substantially uniform, finely dispersed state. The flowable particulate mixture is then fed at a constant feed rate into a kneading and extruding machine that has two screws rotating in the same direction.
As the material exits from the end of the conveyor, it falls into a chute. It tumbles down the chute directly into the mixing chamber of a Banbury mixer where feed is mixed with filler and additives. In the
In the mixer 32 such as a Bepex Turbolizer, fumed silica, the silicone gum and a treating agent can be added to form a densified polymer/filler mass. After the gum feed is mixed it is dropped into the nip 46 of roll mill 34 where the material is rolled into a strip form. After a drop, a programmed logic controller (PLC) verifies that the mixer drop door has opened, then reclosed and is ready for feed. For any residual material that hangs in the chute, the “pusher” is programmed to sweep a few seconds after the conveyor stops. This serves to scrape down the chute, and ensure all material gets into the mixer to correctly formulate the batch.
The mill imparts a final mix to fully incorporate filler and to cool material. Then, the material is stripped from the mill a strip form. The strip form is fed by means of conveyor belt 36 into compounder 38, which may be an extruder. The compounder 38 serves to clean and form the material for packaging. The material can be packaged and boxed through an automated cut, weigh and packaging system.
The feed system and method of the invention can be used in conjunction with a process to compound a silicone rubber into a base for sealing compounds with additives such as pigments dosed to the rubber in appropriate quantities and mixed in large mixers or extruders.
A heat cured rubber (HCR) comprises a high viscosity silicone polymer, an inorganic filler and various additives that aid processing or impart desired final properties to the composition. A vulcanizing agent or catalyst can be added and the composition heat cured to fabricate silicone rubber moldings such as gaskets, medical tubing and computer keypads. An HCR composition can be produced by kneading a high-viscosity polydiorganosiloxane, the inorganic filler and additives by means of a batch kneading machine such as a high intensity Banbury mixer or a low intensity double arm dough mixer. In this process, polydiorganosiloxane, inorganic filler, treating agents and additives are batch mixed until desired properties are obtained. In Kasahara et al., U.S. Pat. No. 5,198,171, a preconcentrate of polydiorganosiloxane, inorganic filler and treating agents is formed by a high speed mechanical shearing mixer. The resulting premix is further compounded in a same-direction double screw extruder. The premix is formed in a first step wherein a diorganopolysiloxane having a viscosity at 25° C. of 1×105 cP or more, an inorganic filler and a treating agent are mixed in a high speed mechanical shearing machine to provide a flowable particulate mixture in which each ingredient is present in a substantially uniform, finely dispersed state. The flowable particulate mixture is then fed at a constant feed rate into a kneading and extruding machine that has two screws rotating in the same direction.
The following Example is illustrative and should not be construed as a limitation on the scope of the claims.
This EXAMPLE is a combined description of press experiments at Schwerdtel US headquarters (New Jersey), ProSys Corporation (Missouri), and at GE Silicones Waterford, N.Y. Experiments on the shaftless screw conveyor were conducted at GE Silicones Waterford using Martin Sprocket equipment.
A viscous material feed system as schematically illustrated in the drawings included a Schwerdtel S 6-F drum press mounted to Vishay BLH floor scale that measured material flow according to loss of weight. The Schwerdtel S 6-F press included a hydraulic pressure driven cylinder and platen that drives a platen into the 55 gallon drum.
The feed system included a feed tube to receive material expressed from a drum by the press and a pneumatic solenoid operated cutting system that metered material from the feed tube to a 12″×24′ shaftless screw conveyor according to loss of weight sensed by the scale. The screw conveyor interfaced to a chute. The chute permitted material to fall via gravity directly to a Banbury mixer. Material remaining in the chute was cleared by a pneumatic pusher prior to each mix (GE design and fabrication). The system was controlled by operators at two (2) QuickPanel LM90 touch screens.
In operation, an operator first entered set points into a system controller. One set point represented a target batch of silicone gum to be charged to a Banbury mixer, which was part of a silicone gum compounding system. A pallet of four (4) fifty-five (55) gallon drums of polymer (Viscosity Range 150,000 to 900,000 Poise) was placed on the drum carousel. The 55-gallon straight-sided steel drums were delivered by the carousel and one drum was loaded into the Schwerdtel S 6-F drum press using an Easy Lift Equipment Drum Hauler unit. The Schwerdtel S 6-F drum press was controlled by a GE Fanuc 90/30 PLC. Material was displaced, from the drum to the feed tube by the hydraulic Schwerdtel gum press.
The operator pressed a START OR RESTRT BATCH button of the controller to commence operation. The press doors were secured by hydraulically driven fasteners. Then, as the screw conveyor started turning, the hydraulically driven press platen commenced traveling down into the drum. As platen traversed the drum, drum contents were squeezed upward into the feed tube. As the platen completed traversing the drum axis, all material was forced upward into the feed tube. As material exited the feed tube, a pneumatic solenoid operated cutting system diced the material into pieces that then fell into a 12″×24′ shaftless screw conveyor to charge to a Banbury mixer.
A batch of material flow from conveyor to the Banbury mixer was measured by loss of weight detected by the Vishay BLH load cells. A combined weight of presses, feed tubes, cutting mechanisms and material-containing drums was registered by the control system as a first weight. The control system monitored a charged weight of silicone gum to the Banbury by registering progressing weight as silicone gum was pressed from the drums and expelled through the feed tubes and cutting systems. The control system displayed a differential between the first weight and registered progressive weights that represented a charged silicone gum weight.
A system operator observed the differential weight and terminated the batch operation when the differential weight registered within a ±2 pound range of the set point, the pneumatic solenoid operated cutting system rate was increased to dice smaller aliquots of exiting material. The batch feed operation was terminated by the operator when the control system registered a charged silicone gum weight with 2 pounds of the set point.
The EXAMPLE illustrates control of material charge to a compounding system according to a feed system of the invention.
The invention includes changes and alterations that fall within the purview of the following claims. The foregoing examples are merely illustrative of the invention, serving to illustrate only some of the features of the present invention. For example, the invention includes a controller with a set of instructions: to refer to a look-up data base to determine a set point for a material to be charged to a compounding system; sensing an initial combined weight of a material extracting apparatus and a container with material; signaling commencement of the material extracting apparatus operation to evacuate the material from the container; sensing a progressing combined weight of the material extracting apparatus and the container with material; calculating a charged material weight according to a difference between the initial combined weight and the sensed progressing combined weight; and terminating the material extracting apparatus operation when a calculated charged material weight is within a specified range of the set point.
The appended claims are intended to claim the invention as broadly as it has been conceived and the examples herein presented are illustrative of selected embodiments from a manifold of all possible embodiments. Accordingly it is Applicants' intention that the appended claims are not to be limited by the choice of examples utilized to illustrate features of the present invention.
As used in the claims, the word “comprises” and its grammatical variants logically also subtend and include phrases of varying and differing extent such as for example, but not limited thereto, “consisting essentially of” and “consisting of.”
Where necessary, ranges have been Supplied, those ranges are inclusive of all sub-ranges there between. Such ranges may be viewed as a Markush group or groups consisting of differing pairwise numerical limitations which group or groups is or are fully defined by its lower and upper bounds, increasing in a regular fashion numerically from lower bounds to upper bounds. It is to be expected that variations in these ranges will suggest themselves to a practitioner having ordinary skill in the art and where not already dedicated to the public, those variations should where possible be construed to be covered by the appended claims.
It is also anticipated that advances in science and technology will make equivalents and substitutions possible that are not now contemplated by reason of the imprecision of language and these variations should also be construed where possible to be covered by the appended claims.
All United States patents (and patent applications) referenced herein are herewith and hereby specifically incorporated by reference in their entirety as though set forth in full.
The invention includes changes and alterations that fall within the purview of the following claims.
This application is a continuation in part of Stanton et al., Viscous Material Feed System and Method, Ser. No. 11/532,334, filed 15 Sep. 2006.
Number | Name | Date | Kind |
---|---|---|---|
2105990 | Pelouch | Jan 1938 | A |
2922360 | Monk, Jr. | Jan 1960 | A |
3113705 | Weitzel | Dec 1963 | A |
3546430 | Kane | Dec 1970 | A |
3637111 | McCreary | Jan 1972 | A |
3731616 | Ligh | May 1973 | A |
4067483 | Mucke | Jan 1978 | A |
4071168 | Stone | Jan 1978 | A |
4154044 | Lang | May 1979 | A |
4166221 | McGaha | Aug 1979 | A |
4221102 | Lang | Sep 1980 | A |
4284597 | Stein | Aug 1981 | A |
4285643 | White | Aug 1981 | A |
4402428 | Lang | Sep 1983 | A |
4448272 | Keller et al. | May 1984 | A |
4448736 | Emery et al. | May 1984 | A |
4534493 | Sedran | Aug 1985 | A |
4539864 | Wiebe | Sep 1985 | A |
4548446 | Warshawsky | Oct 1985 | A |
4559870 | Krummacher et al. | Dec 1985 | A |
4693397 | Lang | Sep 1987 | A |
4874022 | Schwerdtel | Oct 1989 | A |
4955769 | Crankshaw | Sep 1990 | A |
4986717 | Cummins | Jan 1991 | A |
5078304 | Schneider | Jan 1992 | A |
5105736 | Morris | Apr 1992 | A |
5137368 | Kistner | Aug 1992 | A |
5335185 | Pitts et al. | Aug 1994 | A |
5360146 | Ikushima | Nov 1994 | A |
5361692 | Zimmer | Nov 1994 | A |
5377815 | Vetter | Jan 1995 | A |
5417169 | Carpenter | May 1995 | A |
5460209 | Jandur et al. | Oct 1995 | A |
5671873 | Hammerl | Sep 1997 | A |
5797516 | Brandl | Aug 1998 | A |
5846042 | Iannuzzi | Dec 1998 | A |
5851049 | Squire | Dec 1998 | A |
5941539 | Pratt | Aug 1999 | A |
6035957 | Place | Mar 2000 | A |
6061608 | Moldavsky | May 2000 | A |
6155808 | White | Dec 2000 | A |
6211267 | Suto | Apr 2001 | B1 |
6250123 | Killop | Jun 2001 | B1 |
6348001 | Killop | Feb 2002 | B2 |
6391234 | Silvi | May 2002 | B1 |
6414054 | Boffard | Jul 2002 | B1 |
6444154 | Boudreau | Sep 2002 | B1 |
6474971 | Dong | Nov 2002 | B1 |
6524191 | Tennies | Feb 2003 | B1 |
6572253 | Silvi | Jun 2003 | B2 |
6592000 | Owens et al. | Jul 2003 | B1 |
6604559 | Rubin | Aug 2003 | B2 |
6619898 | Cosenza | Sep 2003 | B1 |
6682105 | Latham | Jan 2004 | B2 |
6749786 | Boudreau | Jun 2004 | B2 |
6789302 | Preta | Sep 2004 | B1 |
6951101 | Nitsche | Oct 2005 | B2 |
7032499 | Domann | Apr 2006 | B2 |
7089818 | Daigre | Aug 2006 | B2 |
20020039523 | Hartmann | Apr 2002 | A1 |
20030185647 | Cosenza | Oct 2003 | A1 |
20050173137 | Buchl | Aug 2005 | A1 |
20050241774 | Hart | Nov 2005 | A1 |
20060110237 | Belinda | May 2006 | A1 |
Number | Date | Country |
---|---|---|
1530480 | Jun 1968 | FR |
Number | Date | Country | |
---|---|---|---|
20080067198 A1 | Mar 2008 | US |
Number | Date | Country | |
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Parent | 11532334 | Sep 2006 | US |
Child | 11536826 | US |