The present invention relate to an FePt magnetic thin film having perpendicular magnetic anisotropy and a method for manufacturing the same.
In the recent advancement of highly information-oriented society, there is an urgent need for ultrahigh-density magnetic recording media that process and store a vast amount of information. Desirably, the magnetic-recording media have a magnetically isolated fine particle structure and the fine particles therein overcome thermal disturbance and are oriented in one direction. In particular for increase in the density of the magnetic recording media, it is necessary to reduce the size of ferromagnetic particles. However, when the size of ferromagnetic fine particles is reduced, the magnetic recording becomes unstable at room temperature because there is a criticality particle diameter below which the thermal disturbance becomes predominant. From this viewpoint, L10-structured ordered FePt alloys, which have great uniaxial crystalline magnetic anisotropy (Ku: 7.0×107 erg/cc) and retain their ferromagnetism as superfine nanometer-sized particles, are attracting attention as materials for next-generation ultrahigh-density magnetic recording media.
The ordered FePt alloys also have an application as magnet because of their high uniaxial magnetic anisotropy. FePt alloys are superior in corrosion and oxidation resistances, compared to rare-earth magnets such as Nd- and Sm-based magnets. Some elements are added to the rare earth magnets for improvement in resistance to corrosion or oxidation, but the elements thus added deteriorate the magnetic properties. However, there is no need for addition of other elements to FePt alloys and the magnetic properties of FePt per se are reflected in the characteristics of magnet, and thus, use of FePt alloys is extremely advantageous. If realized, such thin film magnets superior in corrosion resistance, would be applied to ultra-small electromagnetic parts, ultra-small magnets for micromachines, dental attachments, medical therapy applying magnetic field locally, for example, to nerves, pumps for drug delivery systems delivering a trace amount of chemicals into the body, and the like.
However, the L10 structure is thermodynamically stable at room temperature, but FePt thin films prepared by sputtering cannot be converted (oriented) into an ordered structure because they are not exposed to the order-disorder transformation temperature present in a high temperature range during the manufacturing process. For the reason, it is necessary to use a high-temperature process, for example a process of forming a film on a heated substrate or heat-treating an ordered alloy thin film once formed, normally at a temperature of higher than 500° C. for obtaining an L10 ordered structure. However, materials currently used for hard disk devices do not have the resistance at a high temperature, and such a high-temperature process represents a great difficulty, from the practical point of view.
Although there are many manufacturing methods proposed recently aimed at decreasing the processing temperature, these low-temperature manufacturing methods often result in problems such as deterioration in magnetic properties, difficulty in controlling crystal orientation, and complication of manufacturing process due to addition of third element. Fe50Pt50 in the stoichiometric composition and the alloys in the Fe-rich composition were used in many of these manufacturing methods (Non-Patent document 1).
Recently, Takahashi et al. have succeeded in preparing a thin FePt film having the L10 structure at a low temperature by forming the film by sputtering on a substrate heated to 300° C. (Non-Patent document 2 and Patent document 1), but the film prepared at a low temperature was found to be dependent on film thickness in the subsequent studies and the ordering proceeded only when the film thickness is 100 nm or more.
Non-Patent document 1: M. Watanabe, M. Homma and T. Masumoto, Trans. J. Magn. Magn. Mater. 177, 1231 (1998)
Non-Patent document 2: T. K. Takahashi, M. Ohnuma, and K. Hono, Jpn. J. Appl. Phys. 40, L367 (2001)
Patent document 1: Japanese Patent Application Laid-Open No. 203-99920
Accordingly, it is an object of this invention to provide a new FePt magnetic thin film that overcomes the problems of the traditional methods described above, can be formed at a lower temperature and has perpendicular magnetic anisotropy, and a method for manufacturing the same.
To solve the problems above, this invention provides firstly an FePt magnetic thin film characterized by having an atomic composition represented by the following formula:
FexPt100-x
(19<x<52).
Secondly, this invention provides the Fe magnetic thin film characterized by having a film thickness of less than 100 nm and an L10 structure.
Thirdly, the FePt magnetic thin film characterized by being formed on a single crystalline substrate or an oxide undercoat layer on the surface thereof; fourthly, the FePt magnetic thin film formed via a thin layer of one or more of transition and noble metals formed as the undercoat layer; fifthly, the FePt magnetic thin film wherein the thin layer is a single layer or multiple layers; and sixthly, the FePt magnetic thin film wherein the thin film has a layer of one or more metals of Fe, Ag, Ni, Co and Cr and a layer of one or more metals of Au, Pt, and Cu, are provided
This invention additionally provides seventhly, a method for manufacturing any one of the FePt magnetic thin films above, characterized by forming the FePt magnetic thin film by sputtering on a single crystalline substrate, a substrate having an oxide undercoat layer formed thereon, or a substrate having a thin film of one or more of transition and noble metals as undercoat layer at a temperature in the range of 240° C. to 500° C., and eighthly, the method for manufacturing the FePt magnetic thin film wherein the FePt magnetic thin film is formed by sputtering at a temperature of 300° C. or lower.
This invention described above is completed based on the new findings obtained by various studies conducted by the inventors. That is, it is possible to prepare an ordered FePt-alloy thin film oriented in the direction perpendicular to the film and higher in crystalline magnetic anisotropy at a low temperature, by shifting the composition from the stoichiometric composition of Fe50Pt50 (at. %) to the Pt-rich side during preparation of the thin FePt film by sputtering.
In other words, this invention, which is developed based on the dependence of FePt orientation on composition at a low temperature, allows formation of thin FePt films in a wide range of compositions that are independent of film thickness and have the L10 structure even at a thickness of 10 nm or less, by sputtering at a practically feasible substrate temperature. In addition, an L10-structured FePt thin film having uniaxial magnetic anisotropy in the direction perpendicular to the film is formed successfully by epitaxial growth thereof on the substrate. The manufacturing method according to this invention differs significantly from conventional low-temperature manufacturing methods, in that it is possible to form an orientation-controlled L10structured ordered FePt-alloy thin film at a low temperature only by a simple method of changing the composition of the FePt phase. Further, the simple method allows generation of significantly higher crystalline magnetic anisotropy.
This invention is characterized by the description above, and hereinafter, the embodiments thereof will be described
Firstly, the FePt magnetic thin film according to this invention should have a compositional region showing high uniaxial magnetic anisotropy. Thus, the FePt phase should have an alloy composition (atomic ratio) of FexPt100-x, where 19<x<52.
In addition, the film thickness is preferably as thin as possible, considering industrial application, for example, to ultra-small electronic parts. Different from conventional methods, it is possible to form a thin film having the L10 structure having a thickness of not as thick as 100 mm, specifically in the range of 2 to 100 nm, by this invention.
It is necessary to control crystallization direction for providing an FePt thin film formed on a substrate with magnetic anisotropy, and it can be accomplished easily by selecting a single crystalline substrate properly. In order to control perpendicular orientation of an easy axis of magnetization, favorable are single crystalline substrates of MgO (001), NaCl (001), GaAs (001), and the like. Even when a non-single crystalline substrate such as glass plate is used, it becomes easier to control orientation by constructing an undercoat layer of an oxide such as MgO or ZnO on the surface of the substrate.
In this invention, it is quite important to select a favorable substrate and a favorable undercoat layer, for example of oxide or other substance, formed on the surface thereof in forming the FePt thin film.
In selecting the substrate and the undercoat layer for a FePt phase for the purpose of obtaining an ordered phase, important are the viewpoints of control and acceleration of the orientation of FePt phase. From the viewpoints above, it is also possible to form an FePt magnetic thin film via a thin layer of one or more of transition and noble metals as the undercoat layer on a substrate (favorably, single crystalline substrate or substrate having an oxide undercoat layer) in this invention.
In such a case, the thin layer may be a single layer or multiple layers, but in a more favorable embodiment, the thin layer preferably has a layer of one or more metals of Fe, Ag, Ni, Co and Cr (which may be called a seed layer) and a layer of one or more metals of Au, Pt, and Cu (which may be called a buffer layer). The seed layer preferably has a thickness of 0.2 to 2 nm, while the buffer layer a thickness of 5 to 50 nm.
In selecting the undercoat layer of the transition and noble metals, considered is a fact that it is possible to obtain a higher degree of ordering and a larger perpendicular magnetic anisotropy in the Pt-rich composition region, by selecting an undercoat layer larger in lattice mismatching with the FePt layer. It is also possible to control the anisotropy by the undercoat layer selected.
It is of course not always necessary to form the undercoat layer described above. By deciding the composition and the film-forming condition from the viewpoint of FePt phase ordering, it is possible to control the orientation of the FePt thin film. For example, as shown in the Examples below, it is possible to control the orientation of the FePt layer on a single crystalline MgO (001) substrate even without use of an undercoat layer such as the seed or buffer layer, and the ordering proceeds in the Pt-rich composition region at a temperature in the range of 240° C. to 500° C. For orientational control at the time, it would be favorable, for example, to form a film by sputtering under an Ar (argon) gas pressure in the range of 3 to 40 mTorr.
The FePt magnetic thin film according to this invention is prepared by sputtering at a temperature lower than that traditionally used, however, a substrate temperature higher to some extent is needed during FePt film deposition, for obtaining an ordered phase and a larger uniaxial magnetic anisotropy. On the other hand, the processing temperature is desirably lower, from the practical viewpoint. For that purpose, the film should be formed at a substrate temperature in the range of 240° C. to 500° C., and the most important feature of this invention is that it is possible to form a film at a lower temperature of 300° C. or lower.
When a material having a high coercive force is used as a recording medium, a high magnetic field is needed for writing information (magnetization curling). Thus, a heat-assisted magnetic recording method was proposed. Magnetization (information) is partially disappeared by heating a recording medium locally, for example with a laser beam, and thus raising the temperature of the magnetic material dose to the Curie temperature. By applying a magnetic field from outside at the time, it becomes possible to magnetize the recording medium in the direction of the magnetic field after cooling. Considering the trend of such an information-recording method, it is important to control the Curie temperature, in application of the heat-assisted method to magnetic recording and others. It is where the advantageous effects of the FePt thin film according to this invention are used. That is, it is possible to form a thin film of ordered FePt alloy having a Curie temperature Tc lower than that of a bulk in the Pt-rich composition region at a low temperature. It is also possible to control the Tc arbitrarily by adjusting the composition.
Hereinafter, this invention will be described in more detail with reference to Examples, but it should be understood that this invention is not restricted by the following Examples.
By using a UHV-compatible magnetron-sputtering apparatus having an ultimate vacuum of 1×10−9 Torr or less, Fe seed layer of 1 nm and Pt buffer layer of 40 nm in thickness were formed on a single crystaline MgO (001) substrate at room temperature under an Ar gas pressure of 1 mTorr, and then, FePt thin film of 18 nm in thickness was formed by sputtering at a substrate temperature of 300° C. under an Ar gas pressure of 5 mTorr.
Fe seed layer of 1 nm and Pt buffer layer of 40 nm in thickness were formed on a single crystalline (001) substrate at room temperature in a similar manner to Example 1, and then, FePt layer of 18 nm in thickness was formed at a substrate temperature of 300° C.
Fe seed layer of 1 mm and Pt buffer layer of 40 nm in thickness were formed on a single crystalline MgO (001) substrate at room temperature in a similar manner to Example 1, and then, FePt film of 18 nm in thickness was formed at a substrate temperature of 300° C.; and
Fe seed layer of 1 nm and several metal-alloy buffer layers of 40 nm in thickness were formed on a single crystalline MgO (001) substrate in a similar manner to Example 1 at room temperature and then, FePt film of 18 nm in thickness was formed at a substrate temperature of 300° C.; and
Fe seed layer of 1 nm and a buffer layer of 40 nm in thickness were formed on a single crystalline MgO (001) substrate at room temperature in a ar manner to Example 1, and then, FePt thin film of 18 mm in thickness was formed at a substrate temperature of 300° C.; and
Fe seed layer of 1 nm and Pt buffer layer of 40 nm in thickness were formed on a MgO (001) single crystal substrate at room temperature in a similar manner to Example 1, and then, Fe thin films having varying thickness t were formed at a substrate temperature of 300° C.; and
Fe seed layer of 1 nm and Pt buffer layer of 40 nm in thickness were formed on a single crystalline MgO (001) substrate at room temperature in a similar manner to Example 1 and then, Fe38Pt62 thin films were prepared at a substrate temperature of 300° C. while the film thickness t is altered; and
Fe seed layer of 1 nm and Au buffer layer of 40 nm in thickness were formed on a single crystalline MgO (001) substrate at room temperature in a similar manner to Example 1 and then, Fe38Pt62 thin films of 18 nm in thickness were formed at substrate temperatures of 240° C. and 300° C.; and
FePt thin film of 18 mm in thickness were formed on a single crystalline MgO (001) substrate directly by UHV magnetron sputtering under the conditions of an Ar gas pressure of 5 mTorr and a temperature of 300° C.
Only FePt (00n) diffraction peaks were observable in the results obtained from the FePt thin films formed on the MgO (001) substrate, which indicates that the sample thin film is (001) oriented. Distinct FePt (001) and (003) superlattice-reflected lines were not observed from the Fe52Pt48 thin film that has an almost stoichiometric composition, indicating that no ordering proceeded. However, the Fe38Pt62 thin film in the Pt-rich side composition region showed distinct superlattice-reflection lines, demonstrating that the L10 ordered structure was formed.
The results above indicate that for example the orientation proceeds even without use of a seed layer and a buffer layer in the Pt-rich composition region of FexPt100-x (in at. %) 19<x<52 and in a temperature range of 240 to 500° C. by controlling the ordering of the FePt layer on MgO (001) single crystal substrate. It was also confirmed that it is preferable to control the Ar gas pressure in 3 to 40 mTorr during film deposition for the orientational control at the time.
FePt thin films having various undercoat layers were prepared in a similar manner to Example 1. Influences of lattice mismatching on these thin films were analyzed. The results shown in
Fe seed layer (1 mm) and Pt buffer layer (40 nm) and FePt thin film (18 mm) were formed on a MgO (001) substrate by UHV-magnetron sputtering under the conditions of an Ar gas pressure of 5 mTorr and a temperature of 300° C. The following six kinds of compositions were used then, and the dependence of magnetization on temperature in each case was determined.
FexPt100-x: x=30, 34, 38, 45, 52, and 62.
As described above in detail, this invention provides a FePt thin film having a greater uniaxial magnetic anisotropy that is prepared in a simpler process at a lower temperature. It provides a technology significantly more advantageous than that traditionally practiced, concerning the thin film used as a magnetic recording medium.
Hard disk drive is particularly important among many information storage devices and there is an established market demanding large-capacity magnetic recording media, and this invention is extremely valuable in this market.
Number | Date | Country | Kind |
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2003-87789 | Mar 2003 | JP | national |
2003-313158 | Sep 2003 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP04/04152 | 3/25/2004 | WO | 12/15/2005 |