Patent Grant
7963124
1. Field of the Invention
The present invention relates to methods and apparatus for forming optical fiber and more particularly, to methods and apparatus for forming optical fiber having improved characteristics.
2. Technical Background
Optical fibers have acquired an increasingly important role in the field of communications, frequently replacing existing copper wires. This form of transmission is done by sending a beam of light through an optically clear fiber. Because interference with the light beam or its partial loss during the transmission must be at a minimum to make the use of optical fibers a successful communications technology, the optical fibers must be protected from any environment which will cause loss of signal or distortion of the signal. Coating the fibers is one such technique. The optical fibers are coated to protect the fiber surface from damage which can result from abrasion or water, to maintain the fiber strength, and to prevent transmission loss resulting from fiber bending.
Optical fibers typically contain a glass core, a glass cladding, and at least two coatings, i.e., a primary (or inner) coating and a secondary (or outer) coating. The primary coating which is applied immediately after the fiber is formed serves as a buffer to cushion and protect the glass fiber core when the fiber is bent, cabled, or spooled. The secondary coating is applied over the primary coating and functions as a tough, protective outer layer that prevents damage to the glass fiber during processing and use. Both coatings typically need to be cured (e.g., by irradiation with UV light) to harden and to maintain structural integrity through the fiber life time.
Conventional techniques and manufacturing processes for producing optical fibers generally include drawing an optical fiber downwardly along a linear pathway through the stages of production. However, this technique provides significant impediments to improving and modifying production of the optical fiber. For example, the equipment associated with linear production of optical fibers is usually aligned in a top to bottom fashion thereby making it difficult to add or modify the process without adding height to the overall system. In some cases, addition to the linear production system requires additional construction to add height to a building housing (e.g., where the draw tower is at or near the ceiling of an existing building). Such impediments cause significant costs in order to provide modifications or updates to optical fiber production systems and facilities.
For example, it is difficult to increase the draw speed of the fiber, because the fiber spends less time in UV irradiators that cure fiber coating. However, adding more irradiators or larger irradiators to the linear production system is difficult. There is typically little space available for adding additional irradiators (to accommodate a fiber that travels faster through the irradiator), without adding height to the overall system. Because adding height to an existing system can add significant cost to the system, fiber draw systems in which space is available for additional irradiators without necessitating an increase in overall system height are desired.
One aspect of the invention includes a method for producing an optical fiber, said method comprising:
(i) drawing a bare optical fiber from a preform along a first pathway; (ii) contacting said bare optical fiber with a region of fluid in a fluid bearing and redirecting said bare optical fiber along a second pathway as said bare optical fiber is drawn across said region of fluid cushion; (iii) coating the bare optical fiber; and (iv) irradiating said coated fiber in at least one irradiation zone to at least partially cure said coating, while subjecting the optical fiber to UV light. Preferably, the bare optical fiber is drawn at a rate of at least 10 m/sec.
Additional features and advantages of the invention will be set forth in the detailed description which follows, and in part will be readily apparent to those skilled in the art from that description or recognized by practicing the invention as described herein, including the detailed description which follows, the claims, as well as the appended drawings.
It is to be understood that both the foregoing general description and the following detailed description present embodiments of the invention, and are intended to provide an overview or framework for understanding the nature and character of the invention as it is claimed. The accompanying drawings are included to provide a further understanding of the invention, and are incorporated into and constitute a part of this specification. The drawings illustrate various embodiments of the invention, and together with the description serve to explain the principles and operations of the invention.
Reference will now be made in detail to the present preferred embodiment(s) of the invention, examples of which are illustrated in the accompanying drawings.
The invention provides new system(s) and method(s) for producing optical fibers along nonlinear paths through the use of fluid bearings. Embodiments of the present invention are herein described in detail in connection with the drawings of
Higher draw rates reduce the cost of manufacturing optical fiber. When coating an optical fiber it is important to produce, at high draw rates, uniform, strong coatings that can protect the fiber core. However, when a freshly coated fiber is not provided with a sufficient dwell time inside irradiators (for example, when the fiber is drawn too fast through the irradiation devices), the fiber coating may not cure sufficiently and the fiber will suffer from defects such as delaminating coatings, non-uniform coatings, weaker coatings, or undesirable changes in fiber's optical parameters. To combat these defects, the optical fiber is irradiated in accordance with the invention by maintaining the optical fiber within an irradiation zone for a sufficient time to be cured. One advantage of the present invention is that it enables a faster draw speed and provides a longer irradiation zone(s) to sufficiently cure the fiber coating(s).
The present invention includes improved methods for irradiating drawn optical fibers, to reduce defects that are associated insufficient coating cure. As used herein, “irradiating” exposing a coated fiber is moved to irradiation, preferably with UV light, which at least partially cures the coating. As will be better understood from the description that follows, the methods and apparatus of the present invention may allow for relatively high speed, high tension formation of drawn, doped, optical glass fibers having well cured coating as compared to prior art methods for making fibers.
To achieve the foregoing, an embodiment of the present invention includes a system and a method for producing an optical fiber including drawing the fiber from a heated glass source, and contacting the bare optical fiber with a region of fluid cushion of a fluid bearing and redirecting the bare optical fiber along at least a second pathway as the bare optical fiber is drawn across the region of fluid cushion.
According to further embodiments of the invention, a method of manufacturing an optical fiber at high speed is provided that comprises the steps of drawing the optical fiber from a heated glass supply, such as optical fiber preform, at a draw rate of greater than or equal to 10 m/s, preferably greater than or equal to 20 m/s, and even more preferably greater than or equal to 30 m/s, followed by cooling step wherein the optical fiber is preferably cooled to 200° C. or less, more preferably to less than 100° C., and even more preferably to less than 80° C.
As used herein, the term “irradiation zone” refers to an area downstream from a draw furnace where coated optical fiber is irradiated to at least partially cure the fiber coating(s), for example by UV light. In a preferred embodiment, the average irradiation rate (also referred as average power herein) of the fiber in the irradiation zone may be less than 400 W/cm, including less than 300 W/cm, preferably more than 80 W/cm, for example 110 W/cm to 280 W/cm. For example, the average power may be 300 W/in (about 118 W/cm) or 500 W/in (about 195 W/cm), or 600 W/in (about 240 W/cm). The term “UV light” refers to light having a wavelength of from about 150 nm to about 420 nm.
The phrase “bare optical fiber” as used herein means an optical fiber directly drawn from a preform and prior to applying a protective coating layer to its outer surface (e.g., prior to the bare optical fiber being coated with a polymeric based material). The present invention provides flexibility by allowing the bare optical fiber to be transported along nonlinear pathways through stages of production prior to a protective coating being applied theret thus providing more vertical space for additional (or longer) irradiators. In addition, as discussed later herein, systems and methods of the embodiments of the present invention not only provide nonlinear pathways, but can also assist in cooling and further processing of the optical fiber during production.
Referring to
If desired, optional additional fluid bearing(s) can be used to transport the bare optical fiber 114 from the substantially horizontal pathway (Z) generated by the alignment of the first and second bearings 116 back to the substantially vertical pathway (Y) (or any other third pathway). In the embodiment illustrated in
The method of curing the compositions of primary and secondary coatings of the present invention can be thermal, chemical or radiation induced depending upon the nature of the coating composition(s) and the optional polymerization initiator being employed. Radiation for purposes of this application means the application of infrared, visible light, atomic radiation, actinic radiation and ultraviolet rays, as well as ionized rays such as X-rays, electron beam, alpha-rays, beta-rays, gamma-rays and the like. “Cure”, “curable”, and “cured” for purposes of this application includes partially, substantially or totally cured coatings and compositions for coatings which can be partially, substantially or totally cured. The primary and secondary coating compositions are preferably cured with radiation, and more preferably ultraviolet radiation (although it is understood that both the primary and secondary coatings can be cured at once after application of both of the coatings). If ultraviolet (UV) radiation is used, preferably the coatings are is cured at a dose level of at least about 0.2 J/cm2, more preferably from about 0.5 to about 1.0 J/cm2.
A coating material commonly used in the manufacture of optical fibers is a urethane acrylate-based composition which is curable by exposure to ultraviolet (UV) light. This material is applied to the surface of the fiber in a liquid state and is subsequently exposed to UV light for curing. The coating material may be applied in one or more layers, with a two-layer coating system being a preferred embodiment. The primary coating is usually applied directly to the surface of the fiber, and the secondary coating is applied over the primary coating. It the embodiment of
The fiber can go through a variety of other processing stages within the system (not shown). Drawing mechanisms 128 (also referred to as tensioning system herein) are used to provide the necessary tension on the optical fiber as it is drawn throughout the entire system as shown in
Additional conventional process steps may be included, such as non-contact diameter measurement apparatus, further fiber cooling apparatus, and spool winding apparatus. Such additional process steps are conventional and not shown for clarity.
As the optical fiber 114 is transported over the fluid bearings 116 (described later herein), the region of fluid cushion on each fluid bearing 116 cools the bare optical fiber 114. For example, referring to
In addition to providing cooling, the arrangement of
Heretofore, systems and methods for producing optical fibers in nonlinear pathways have been described. As described herein, such systems and methods can include incorporation of one or more bearing assemblies.
In the embodiment illustrated, the arcuate outer surfaces 238, 239 of the first plate 230 and the second plate 232 are preferably substantially aligned and form a region between the outer surfaces 238, 239 of both the first plate 230 and the second plate 232. This region is configured to receive an optical fiber so that optical fiber can travel along this region without rotation of the bearing assembly. This fiber support channel 250 is more clearly illustrated in the embodiment shown in
In addition, as shown in the embodiment of
As shown in
In the embodiment illustrated in
Preferably, the fiber is located in an area of the channel 250 that is between about 1 and 2 times the fiber diameter, more preferably between about 1 and 1.75 times the fiber diameter, most preferably between about 1 and 1.5 times the fiber diameter. By locating the fiber in such a relatively narrow region in channel 250, the fiber will center itself during operation due to the Bernoulli effect. For example as the fiber gets closer to either opposing surface of channel 250, the velocity of the air will increase nearest one surface and decrease nearest the other. According to the Bernoulli effect, an increase in fluid velocity occurs simultaneously with a decrease in pressure. As a result, the greater pressure caused by the decreased fluid flow near one surface will force the fiber back into the center of channel 250. Thus, in the preferred embodiments, the fiber is centered within the fiber support channel 250 at least substantially via the Bernoulli effect due to a fluid stream which is passing around the fiber and out of the fiber support channel 250 while the fiber is being drawn. Notably, such centering occurs without having to utilize any flow of fluid which would impinge upon the fiber from the side thereof, e.g., there are no jets of fluid flow employed which emanate from sidewalls of channel 250. The velocity of the fluid stream traveling through the slot is preferably adjusted to maintain the fiber so that the fiber is located entirely within a tapered region of the slot 250. In the presently described embodiment, because the fiber is located in an area of the channel 250 that is between about 1 and 2 times the fiber diameter, the fiber is supported by a pressure difference that exists below the fiber 214 (rather and as opposed to aerodynamic drag which might also be used to support a fiber, if one so chose). By supporting or levitating the fiber within channel 250 via a fluid pressure differential, much lower fluid flows can be employed than if aerodynamic drag was used to levitate the fiber.
In the embodiment illustrated, the fluid stream is preferably provided by a single fluid stream which enters fiber support channel 250 via the narrower inner portion of fiber support channel 250 and exits via the wider outer region of fiber support channel 250. In this way, the fiber can be positioned entirely within the slot formed by fiber support channel 250 such that the fiber floats between the narrowest and widest portion of the slot. By employing a tapered fiber support channel 250 and injecting the fluid flow through the region 250 in this manner, it is possible to retain the fiber in a region of said slot formed by fiber support channel 250 wherein the slot has a width which is between 10 to 150, more preferably 15 and 100, and most preferably between about 24-70 microns greater than the diameter of the fiber being directed through the fiber support channel 250. During the fiber draw process, the fiber is also preferably retained within a region of the channel such that the distance between the outer fiber and each wall is between 0.05 and 0.5 times the fiber diameter.
In some preferred embodiments, fiber support channel 250 is provided with a means for reducing pressure under the fiber as the fiber moves outwardly away from the source of the fluid flow. Such a means for releasing pressure can be achieved in the form of a tapered channel design, as described above. Additional means for reducing pressure are disclosed in U.S. Patent Application Ser. No. 60/861,587, the entire disclosure of which is hereby incorporated by reference in its entirety.
The fluid bearings described herein enable the optical fiber to travel along the region of fluid cushion so as to prevent or substantially prevent actual mechanical contact between the optical fiber and the bearing assembly, e.g., the fiber travels within fiber support channel 250 without contacting either of plates 230 or 232. In addition, because of the size and configuration of the region, the fluid bearing is capable of maintaining the fiber within the region without mechanical contact through a range of draw tensions without active control of the fluid flow.
Referring to
Other factors influencing fiber position within fiber support channel 250 include the draw tension. For example, fiber pulled with 200 g of tension will float lower within fiber support channel 250 than fiber pulled with a tension of 100 g given the same fluid flow. As such, it is important that the fluid exiting the region of the fluid bearing be sufficient to maintain the optical fiber at the desired location for the particular fiber draw speed and draw tension employed.
For example, in an embodiment that utilizes a fiber support channel 250 having a width of about 127 microns at the innermost section between plates 230 and 232 and approximately 380 microns at the outermost section, the fluid flow rate can be from about 0.5 L/sec to more than 5 L/sec. Such a configuration and fluid flow can result in local fluid velocities around the optical fiber as high as 800 km/hour or even higher. Thus, in some embodiments the maximum fluid velocities around the fiber employed in the fiber support channel 250 are higher than 100, higher than 200, higher than 400, and possibly even higher than 600 km/hour. In some embodiments, maximum fluid velocities around the fiber employed in the fiber support channel 250 have been higher than 900 km/hour. For example, applicants have successfully employed 1000 km/hour fluid flow around the fiber in the fiber support channel 250. However, the methods disclosed herein are certainly not limited to these fluid velocities, and in fact the fluid velocity preferably can be chosen to result in the fiber being located at a desired location within fiber support channel 250, depending on draw conditions (e.g. draw speed, draw tension, etc.) and fluid bearing design. In another embodiment, the fluid flow rate can be from about 3 L/sec to about 4 L/sec. Of course, any fluid rate sufficient to maintain the optical fiber at the desired location at a given draw tension can be utilized. The use of such high fluid flow velocities can greatly facilitate cooling of the optical fiber. The larger the difference between the temperature of the fiber and the temperature of the fluid being emitted through the fluid bearing, and the higher the fluid flow velocity, the greater the amount of cooling that can be achieved. In some embodiments, the temperature of the fiber entering the fluid bearing can be greater than 100° C., greater than 500° C., greater than 1000° C., and even greater than 1500° C. higher than the temperature of the fluid being emitted through and supporting the fiber within the fluid bearing. Employing such temperature differentials in the embodiment discussed above, with an optical fiber draw speed of greater than 10 meters per second, and preferably greater than 20 meters per second, a fiber having a temperature upon entry into the fluid bearing of 1100° C. may be cooled as much as 1000° C., i.e., to about 100° C. using a room temperature (i.e., about 20° C.) fluid (preferably air) by passing the fiber through the fluid bearing to make the fiber achieve a 180 degree turn in direction. This very significant amount of cooling illustrates the capability of using fluid bearings such as are disclosed herein to cool the fiber greater than 50° C., 200° C., 500° C., 700° C., and even greater than 900° C. Perhaps even more significant is that such fiber cooling amounts can be achieved over fiber distance (i.e. the circumferential distance over which the fiber is exposed to the fluid cushion of the fluid bearing) of less than 3, more preferably less than 2, and most preferably less than 1 meter. However, greater or lesser distances of fiber/fluid cushion contact can be employed, depending on desired results and the layout of the manufacturing area. The significant cooling capability of the fluid bearings disclosed herein enables the potential elimination of helium cooling devices from the optical fiber draw process altogether.
The radius of the fluid bearings 116 is not critical. In some embodiments, fluid bearing is constructed to result in a fiber turn radius of from about 8 to 16 cm. Larger or smaller radius fluid bearings can be employed, or additional fluid bearings can be employed, for example, depending on whether greater cooling is desired (in which case larger radius fluid bearing may be preferred) or the constraints of the fiber draw process.
The glass preform 110 is preferably formed of a doped silica glass. The preform 110 may be formed such that either the core or the cladding (if present) of the drawn fiber is doped, or such that both the core and the cladding of the drawn fiber are doped. The silica glass may be doped with one or more of germanium, fluorine, phosphorous or chlorine, or combinations thereof, for example. Other suitable dopants may be used as well. Germanium doped fibers, were found by the inventors to exhibit heat aging under most manufacturing conditions. Methods and apparatus for forming the preform 110 are well known and are readily appreciated by those of skill in the art. Such methods include IVD, VAD, MCVD, OVD, PCVD and the like.
Examples of suitable primary and optional secondary coating compositions of the present invention are described and produced as follows. The primary coating composition comprises an oligomer wherein the oligomer is formed from a reaction comprising a polyol having “m” hydroxyl functional groups, wherein “n” hydroxyl groups of said polyol are terminated in forming the oligomer and “m” is greater than “n” such as acrylate or a methacrylate, for example. Preferably, the primary coating composition also includes at least one monomer, and at least one photoinitiator. Additionally, the primary coating composition of the present invention can optionally include any number of additives, for example, adhesion promoters, anti-oxidants, catalysts, lubricants, co-monomers, low-molecular weight non-crosslinking resins, and stabilizers. Some additives (e.g., chain transfer agents) can operate to control the polymerization process, thereby affecting the physical properties (e.g., modulus, glass transition temperature) of the polymerization product formed from the primary coating composition. Other additives can affect the integrity of the polymerization product of the primary coating composition (e.g., protect against de-polymerization or oxidative degradation).
The secondary coating composition typically contains urethane acrylate liquids whose molecules become cross-linked when polymerized. Other suitable materials for use in secondary coating materials, as well as considerations related to selection of these materials, are well known in the art and are described in U.S. Pat. Nos. 4,962,992 and 5,104,433 to Chapin, the specifications of which are hereby incorporated by reference.
Preferably, a photoinitiator is used in the primary and secondary coating compositions. The photoinitiator should be suitable to cause polymerization (i.e., curing) of the composition after its application to a glass fiber. For most acrylate-based coating formulations, photoinitiators, such as the ketonic photoinitiating and/or phosphine oxide additives, are preferred. When used in the compositions of the present invention, the photoinitiator is present in an amount sufficient (e.g., 0.5 to 10 wt %) to provide rapid ultraviolet curing.
The photoinitiator provides reasonable cure speed without causing premature gelation of the coating composition. A desirable cure speed is any speed sufficient to cause substantial curing of the coating materials (i.e., greater than 85%, preferably greater than 90%, more preferably 95%) of the coating composition. As measured in a dose versus modulus curve, a cure speed for coating thicknesses of about 25 to about 100 μm is preferably less than about 1.0 J/cm2, and more preferably less than about 0.5 J/cm2.
Suitable photoinitiators for the primary and secondary coating compositions include by way of example 1-hydroxycyclohexylphenyl ketone (e.g., Irgacure 184 available from Ciba Specialty Chemical (Hawthorne, N.Y.), bis(2,6-dimethoxybenzoyl)-2,4,4-trimethylpentyl phosphine oxide (e.g., commercial blends Irgacure 1800, 1850, and 1700 available from Ciba Specialty Chemical), 2,2-dimethoxyl-2-phenyl acetophenone (e.g., Irgacure 651, available from Ciba Specialty Chemical), bis(2,4,6-trimethyl benzoyl)phenyl-phosphine oxide (Irgacure 819), (2,4,6-trimethylbenzoyl)diphenyl phosphine oxide (Lucerin TPO, available from BASF (Munich, Germany)), ethoxy (2,4,6-trimethylbenzoyl) phenyl phosphine oxide (Lucerin TPO-L from BASF), and combinations thereof.
The irradiators 122A, 122B preferably include a housing 322 surrounding the fiber and having an aperture 323 situated and serving as the exit port of fiber 114. An cylindrical sleeve-like walls 326 (which may be, for example, formed of a reflective material) extends through the irradiator 122A, 122B and defines a passage 330 therein. The walls 326 of each irradiator surrounding passage 330 include one or more UV sources 332 (not shown) that provide the desired radiation within at the irradiation zone. Several irradiators may be utilized after each coating step to provide the irradiation zone of the desired length. The irradiators are adapted to receive and guide the optical fiber 114. However, it will be appreciated that other housing configurations and components may also be employed.
The passage 330 preferably has a diameter dimension D of greater than 15 mm at all places along its length, and preferably between about 15 mm and 30 mm, to allow the drawn fiber to readily drop therethrough. The term the “length L” of irradiation zone is defined as the length of total irradiation zone, i.e., L=Lp+Ls=Σli, where LP is the length of the primary irradiation zone, Ls is the length of the secondary irradiation zone, li is length of the irradiation zone provided by each individual irradiator device 122i, and i is the number of irradiating devices utilised. For example, li may be 10 to 50 cm long, for example 25 cm. If the system utilizes a total of 4 irradiating devises (2 in irradiation zone and 2 in the secondary irradiation zone), each 25 cm long, than L=100 cm. Similarly, if the system utilizes a total of 6 irradiating devises, each 25 cm long, than L=150 cm. Assuming that the UV power incident on the fiber does not change, the faster the drawing speed, the faster is the fiber moving through each irradiating device, thus either more, or longer irradiating devices are needed to provide the same cure to a faster moving fiber. The length L of the total irradiation zone is preferably between about 1 m and 10 m, and more preferably between about 1.5 m and 8 m, for example between about 3 m and 7 m. The preferred length L will depend on the draw speed of the fiber 114 and examples of ranges of a draw speed are from about 10 m/s to about 100 m/s, such as from about 10 m/s to 75 m/s, including from about 20 m/s to 50 m/s. The presence of fluid bearings 116 (as shown in
Preferably, the overall system for forming the optical fiber is housed in an area protected from outside elements, such as a building or factory having a roof height of between about 10 and 30 meters. Preferably the vertical distance h between the a furnace 112 and the coating unit 120A is less than 6 m, more preferably less than 5 m, even more preferably less than 4 m (for example, less than or equal to: 3 m, 2.5 m, 2 m, 1.5 m, 1 m, 0.75 m, or 0.5 m). In at least one embodiment, the total length L of the (total) irradiation zone can extend at least 10% of the vertical height of the overall system, including at least 20% of the vertical height of the overall system. In addition, the length L of the irradiation zone can extend at least 25% of the vertical distance between the roof and the floor of a building or factory in which the overall system is housed, including at least 30% of the vertical distance between the roof and the floor of a building or factory in which the overall system is housed.
The tensioning station 128 may be any suitable device for controlling the tension in the drawn fiber 114. Preferably, the tensioning device includes a microprocessor which continuously receives input from one or more fiber tension and/or diameter sensors (not shown) and is operative to apply the tension of the fiber 114 as needed. In a preferred embodiment, the tension commanded is based upon controlling the fiber diameter to equal a set diameter stored in memory.
Also, as the fiber 114 passes through the passage 330, the fiber 114 is maintained inside irradiator(s) at a selected tension FT. Preferably, the tension FT is between about 25 and 200 grams. More preferably, the tension FT is between about 60 and 180 grams. Most preferably, the tension FT is between about 90 and 150 grams. The total length L of the primary and secondary irradiation zones is selected such that primary and secondary coatings are sufficiently cured (i.e., greater than 85%, preferably greater than 90%, more preferably 95%) of the coating composition is cured. The fiber remains within the irradiators for a selected resident irradiation time tT, which, as stated above is preferably less than 0.5 sec. Preferably, the resident time within the primary irradiation zone is less than 0.2 sec, and the resident time within the primary irradiation zone is also less than 0.2 sec. More preferably, the resident time within the primary irradiation zone is less than 0.1 sec, and the resident time within the primary irradiation zone is also less than 0.1 sec.
The presence of fluid bearings 116 (as shown in
Drawing at high speed (more than 20 m/sec) enables production of large volumes of the optical fiber which is then coated and irradiated in accordance with aspects of the present invention to produce a high quality coated fiber.
Examples 1-14, representing various embodiments of the present invention, are set forth in Table 2. These examples correspond to a coating cure of 85%-95%, incident UV radiation on fiber with power of 118 W/cm, and show the treatment of optical fiber through a primary and a secondary irradiation zone having the corresponding indicated length Lp, Ls in meters and a total length L=Lp+Ls, as well as the indicated draw speed of the optical fiber in meters per second. It s noted that although in these examples the irradiation time in primary coating irradiation zone is the same as the irradiation time in secondary, coating irradiation zone, irradiation time for the coatings will depend on specific coating compositions and does not have to be the same.
It will be apparent to those skilled in the art that various modifications and variations can be made to the present invention without departing from the spirit and scope of the invention. Thus it is intended that the present invention cover the modifications and variations of this invention provided they come within the scope of the appended claims and their equivalents.
This application claims the benefit of priority under 35 U.S.C. §119 (e) of U.S. Provisional Application Ser. No. 61/004,676 filed on Nov. 29, 2007.
| Number | Name | Date | Kind |
|---|---|---|---|
| 4962992 | Chapin et al. | Oct 1990 | A |
| 5104433 | Chapin et al. | Apr 1992 | A |
| 20030059188 | Baker et al. | Mar 2003 | A1 |
| 20030126890 | Orita et al. | Jul 2003 | A1 |
| 20030159283 | White | Aug 2003 | A1 |
| 20060051040 | Baker et al. | Mar 2006 | A1 |
| Number | Date | Country |
|---|---|---|
| 3-12912 | Jun 1989 | JP |
| 2008066661 | Jun 2008 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 20090139269 A1 | Jun 2009 | US |
| Number | Date | Country | |
|---|---|---|---|
| 61004676 | Nov 2007 | US |
