The invention relates to a fiber quality sensor such as a hair damage sensor, and to a hair care device comprising such a hair damage sensor.
The chapter 7 “Surface Potential Studies of Human Hair Using Kelvin Probe Microscopy”, by Bhushan in: Biophysics of Human Hair: Structural, Nanomechanical, and Nanotribological Studies, pp. 153-169 (2010), discloses that virgin hair has a better charge mobility and can therefore dissipate charge more readily than chemically damaged hair.
U.S. Pat. No. 6,518,765 describes using an array of triboelectric sensors for testing electrostatic properties of a remote environment. A method of determining the triboelectric properties of a material comprises selecting a plurality of insulators; simultaneously rubbing the plurality of insulators against the material; measuring a change in a magnitude and polarity of an electrical charge on each of a plurality of the insulators over time; and determining a triboelectric property of the material in response to results from said measuring. The insulating materials may be selected so their triboelectric properties cover a desired range.
US 2003/226397 describes a directional coupler sensor for measuring the moisture content of a substrate, such as hair. The sensor incorporates a high frequency directional coupler having a pair of generally parallel plates defining a coupling gap therebetween. A high frequency signal generator generates an electromagnetic field across the gap with the substrate placed across the coupling gap. The coupled power relates to the moisture content of the substrate. A pressure sensor is provided to ensure that the desired compactness of the substrate across the coupling gap is achieved to obtain accurate, reliable and consistent results.
US 2016/0028327 describes a method of producing a triboelectric generator element comprising a material based on rough dielectric polymer intended, in order to create electrical charges, to be placed in contact with another material having different triboelectric properties to those of the dielectric polymer material, the method including forming on a support a layer based on a material formed of a given dielectric polymer.
US 2016/0011233 describes a sensor for measuring static charge of fibers, comprising: a sensor handle which is insulated; a metal sensor head connecting to the sensor handle; an electrometer and a capacitor, both inside of the insulated sensor handle (whereby the isolated handle is not in direct contact with the fiber and does not result in an electrical signal); and a display on the handle, and wherein the static charge generated during a contact between the fiber and the sensor head is transferred from the sensor head to the capacitor, measured by the electrometer connected to the capacitor, and shown on the display. The sensor head is preferably in the shape of a brush or comb, and the static charge is generated during combing. Measuring electrostatics of fibers, especially when combing fibers is one of common ways to assess keratinaceous fiber conditions. Generally speaking, more electrostatics on fibers cause more fly-away of fibers. More damaged and/or curled keratinaceous fibers may cause more electrostatic charging when combing because of more friction and/or detangling between fibers when combing.
U.S. Pat. No. 6,504,375 describes an electrostatic voltmeter modulator for measuring an electrostatic field between the electrostatic voltmeter modulator and a surface includes a shield, a sensing electrode, and a layer disposed between the shield and sensing electrode.
It is, inter alia, an object of the invention to provide a fiber quality sensor. The invention is defined by the independent claims. Advantageous embodiments are defined in the dependent claims.
Embodiments of the invention provide a hair based triboelectric sensor device with self-generating sensor signal to detect hair health or damage, and in particular a sensor device that measures and analyses the signal shape, magnitude of hair surface potential and rate of hair surface discharging (charge retention/dissipation) during a hair treatment with a hair care device, such as a straightener. The sensor technology is based on the analysis of electrostatic and/or triboelectric surface charging characteristics of hair fibers. The hair based sensing technology with self-generating signal offers potential for both a stand-alone consumer and/or professional device and an integrated module into existing hair styling devices (e.g. hair straightener, styler). The hair based sensor is based on but not limited to a sliding triboelectric generator being used as a sensor for measuring a charge (voltage or surface potential change) which is dependent on the surface property (topography, chemistry) of hair. The sensor principle makes use of the triboelectric effect, in-plane charge separation and electrostatic induction. The rubbing of a hair against a counter-surface (e.g. of a care device) causes an electrical charge build-up and charge induction in a specific sensor electrode array, made out of a conductive and dielectric electrode allows to monitor the time-dependent and spatial, macroscopic discharge behavior. The charge leaks away through the hair and/or sensor specific induction electrode materials/configurations. The rate of this process depends on the structural (integrity of cuticles, number of cuticle layers removed) and physico-chemical surface properties of the hair fiber (presence of lipids, moisture level). By comparing the voltage signature with reference shapes and analyzing the signal in the time and frequency domain, the level of hair damaged can be assessed and quantified (if a calibration curve is available), or a baseline measurement done.
These and other aspects of the invention will be apparent from and elucidated with reference to the embodiments described hereinafter.
Embodiments of the invention provide a hair based triboelectric sensor with self-generating sensor signal to detect hair health or damage. In particular, embodiments provide a sensor device that measures and analyses the signal shape, magnitude of hair surface potential and rate of hair surface discharging (charge retention/dissipation) during a hair treatment with a hair care device, such as a straightener. The sensor is based on a hair based sliding triboelectric generators for generating charge in response to movement of the hair care device over the hair; and this hair based triboelectric generator being used as a sensor for measuring a parameter which is dependent on the surface property (topography, chemistry), the sensor signal being the charge (voltage) generated by the triboelectric generator. The sensor principle makes use of the triboelectric effect, in-plane charge separation and electrostatic induction. The rubbing of a hair against a counter-surface (e.g. of a hair care device) causes an electrical charge build-up and charge induction in a specific sensor electrode array, made out of a conductive and dielectric electrode allows to monitor the time-dependent and spatial, macroscopic discharge behavior. The charge leaks away through the hair and/or sensor specific induction electrode materials/configurations. The rate of this process depends on the structural (integrity of cuticles, number of cuticle layers removed) and physico-chemical surface properties of the hair fiber (presence of lipids, moisture level). By comparing the voltage signature with reference shapes and analyzing the signal in the time and frequency domain, the level of hair damaged can be assessed and quantified (if a calibration curve is available), or a baseline measurement done.
To be able to use this invention in a handheld device, an electrode pair or grating structure—together with the hair forming a sliding triboelectric generator—is integrated in the hair care device and responds to the surface charge build-up by means of triboelectric charging and electrostatic induction. Suitable electronics to capture the signal/charge build up is an amplifier with large input resistance (typically >1012Ω).
In a first embodiment of this invention, a specific hybrid electrode design made out of conductive and dielectric electrodes allows to monitor the time-dependent and spatial, macroscopic discharge behavior. The conductive part is made of a conductive material such as copper (Cu), aluminum (Al) or a transparent conductor such as indium tin oxide (ITO), poly(3,4-ethylenedioxythiophene) polystyrene sulfonate (PEDOT-PSS), or graphene. The dielectric part is made of a dielectric material such as polyester (PET) or fluorinated ethylene propylene (FEP). This invention is not limited to the listed materials. Combinations of many other suitable materials could also be used; a person skilled in the art knows how to combine them correctly based on their tribo-electric properties. An in-plane induction electrode pair or multiple interdigitated electrodes made out of one metallized dielectric (metal is on the back side) and one conductive material enable to measure large flat hair bundles and assess the hair damage state based on controlled discharge through the conductive electrode(s). Hair rubbed over these electrode arrays result in multiple in-plane charge separation and induction events but also ‘forced’ discharge events due to conductive metal electrode allowing one to study the dynamic discharge behavior of hair.
If the unique signal signature deviates, this allows a statement on the charging state/characteristics and surface condition of the hair (see embodiment 4).
All the herein described in-plane electrode pairs/arrays can, for example, be integrated in a plate of a hair straightener.
In a second embodiment of this invention, various geometries of hybrid electrodes are used to compensate for angular deviation and avoid signal noise at the hair tip during use of a hair care device. These geometries are aimed to improve the sensor signal. To fully exploit the sensor signal, in the ideal case the hair should be rubbed substantially perpendicularly relative to the orientation of the electrodes pairs. In many hair care applications it may be difficult to maintain or control such a substantially perpendicular orientation, or the device is used under a certain angle relative to the length of the hair bundle or root-tip direction. Therefore, specific electrode design configurations are needed making straightening robust to DC noise burst which would be generated instead of an alternating voltage signal during sliding at the hair tip. By using specific arrangements and modifications of the above described hybrid electrode (embodiment 1), such a noise burst can be avoided and clear signals extracted. For compensating angular deviation from a perfect 90 degree angle or angular misalignment, and improve the sensor signal (signal-to-noise ratio), dedicated geometries can include the following electrode geometries or combinations thereof:
In a third embodiment, similar to embodiments 1 and 2, an in-plane electrode configuration of alternating electrodes materials is used. In this embodiment there is one additional material, and thus in total three types of materials, viz. (1) an electrically conductive material, such as a metal like copper (Cu), (2) a material which is lower than the chosen electrically conductive material in the triboelectric series compared to hair, for example fluorinated ethylene propylene (FEP) or Teflon types, and (3) a third material which is ranked above the chosen electrically conductive material (e.g. copper Cu) in the triboelectric series. Ideally, this third material should also be ranked above hair, e.g. polyurethane or negatively charged β-P(VDF-TrFE). See e.g. https://www.trifield.com/content/tribo-electric-series/, http://www.regentsprep.org/regents/physics/phys03/atribo/default.htm, or http://www.rfcafe.com/references/electrical/triboelectric-series.htm for a table listing various materials according to their respective affinities for negative charge.
The electrode configuration shown in
When hair strands are rubbed over the surface or vice versa, starting on the nonconductive segments and moving into the conductive segments, two electrical signals are generated. The usage of two triboelectric charge generating materials, one higher and one lower in the triboelectric series compared to copper, results in two electrical signals which are mainly in opposite direction of each other (respectively positively and negatively).
This additional signal and the ratio between these signals can be used to gain additional spatial information on the surface chemical state of hair (e.g. relative presence of polar and non-polar groups varying over the full hair length (from root to tip) or the individual cuticle length (typical 3-5 μm, i.e. suggested width of 3rd electrode material is 1 to 3 μm). To compensate for or nullify the misalignment (un-parallelism of active tribo areas in respect to cuticle direction), the electrode should have multiple small segments of e.g. 10 by 10 μm in length and/or width, preferably lengths and widths in the order of 1 to 5 μm. These dimensions of the active tribo area are not limited to the third material and can be used for one or more of the other used materials. The relatively uniform potential on the cuticle when measured far away from the cell borders increases close to the edge of the cuticle cells, indicating that these regions are more polar due to protein exposure.
Furthermore it can be used to distinguish between combing direction, from tip to root or from root to tip, as this difference in combing direction results in different electrical output signals.
By changing the electrode dimensions denoted in
Furthermore multiple segments and combinations of these segments can used. For example, the configuration of
In a fourth embodiment of this invention, the analysis of a modulated charge dissipating signal (which is dependent on the hair surface topography/chemistry properties and the electrode design such as width of electrode segments) allows to conclude on the hair damage state. As mentioned in relation to embodiment 2, the electrode layout dictates the shape of the generated triboelectric voltage. The signal is modulated and results in a distinctive pattern of repeated pulses. Damage detection of hair by signal analysis of distinctive triboelectric surface potential patterns is possible by means of a suitably programmed microprocessor through:
Embodiments of the invention thus provide a new sensor technology with self-generating signal based on triboelectric effect and electrostatic charge induction. A specific electrode configuration is provided, with an array of two in-plane electrodes with alternating conductive and dielectric coated segments: alternating conductive (charge dissipation electrode) and dielectric covered induction electrodes. A main advantage of this feature is that it allows monitoring charge build up and discharge behavior/events of hair. This configuration fundamentally differs from a conventional triboelectric generator in that in such a conventional triboelectric generator a conductive discharge electrode would not be placed directly next to a dielectric electrode as this would negatively affect power generation/sensor signal magnitude as charges leak away. The controlled or forced sequential discharge monitoring of hair allows discriminating healthy from damaged hair based on charge leakage/dissipation behavior as shown in
An embodiment provides a (preferably in-plane) electrode array with alternating dielectric (polymer insulator) coated and conductive (metallic) electrode segments. The triboelectric charge generated during movement of a third material (fiber, hair) over the electrodes (or vice versa) results in a surface potential difference measured between both electrodes. Other types of triboelectric generators are alternatively possible, e.g. a vertical contact separation (tapping mode) generator. Alternatively, by just consecutively tapping the fibers a unique charge-discharge signature can be obtained. Any form of contact electrification or triboelectric charging that produces an electrical signal that can be measured can be employed in the present invention. The conductive electrode induces controlled repeated discharge events during rubbing and functions mainly as a charge dissipation electrode. The combination of triboelectric/electrostatic charging and controlled discharging during the rubbing produces a unique signature of the fiber that can be used by a microprocessor to determine surface electrochemical and topographical properties (such as damage, surface integrity, electro-chemical surface state).
An embodiment provides a sensor that allows to measure both the build-up and discharge of electrostatic charges simultaneously during rubbing using specific alternating dielectric and conductive electrode segment configurations, whereafter the generated charges are converted into a voltage using a high-ohmic electrometer.
An embodiment provides a fiber sensor system comprising a pair or an array of alternating conductive and dielectric coated segments (insulators), a third fiber-like material and an amplifier connected to the pair of alternating electrodes and having an input impedance in the range 1-200 TOhm. The triboelectric charge generated during movement of the third material over the electrodes (or vice versa) results in a surface potential difference measured between both electrodes. The conductive electrode induces controlled repeated discharge events during rubbing and functions mainly as a charge dissipation electrode to characterize the electrochemical and topographical surface state of the fiber.
An embodiment of the invention comprises an electrode array with alternating dielectric (insulator) coated and conductive (metallic) electrode segments, differential measurement of surface potential changes, special sensor electronics with input resistance being at least 1 TOhm, and measurement of combined electrostatic charge and discharge (rate) behavior to provide a unique triboelectric fiber signature.
Aspects of the invention include:
The invention is advantageously used in a hair care device, comprising a fiber quality sensor S according to the invention, and a microprocessor coupled to receive output signals from the fiber quality sensor. The hair care device could, for example, provide an indication (e.g. optical or acoustic alarm) to the user that he/she should stop the treatment in order to avoid overheating. Settings (e.g. temperature) could also be adapted.
The invention can be applied not only in hair care applications, but also in textile (fiber) applications, e.g. monitoring quality and durability of textile finishing during production, or in garment care, e.g. monitoring quality and durability of textiles during use or after laundering.
It should be noted that the above-mentioned embodiments illustrate rather than limit the invention, and that those skilled in the art will be able to design many alternative embodiments without departing from the scope of the appended claims. In the claims, any items placed between parentheses are just reference signs referring to examples in the drawings that shall not be construed as limiting the claim. In particular, the scope of the claims is not limited by materials matching the reference signs, so that instead of copper (Cu) any suitable conductive materials may be used, while instead of FEP and PU other suitable dielectric materials may be used. The word “comprising” does not exclude the presence of elements or steps other than those listed in a claim. The word “a” or “an” preceding an element does not exclude the presence of a plurality of such elements. The notion “a pair” thus includes a plurality of pairs, and the notion “a pair of mutually adjacent electrodes” includes interdigitated electrode arrays or multiple interdigitated electrodes. The mere fact that certain measures are recited in mutually different dependent claims does not indicate that a combination of these measures cannot be used to advantage.
Number | Date | Country | Kind |
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16164516.3 | Apr 2016 | EP | regional |
Filing Document | Filing Date | Country | Kind |
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PCT/EP2017/057144 | 3/27/2017 | WO | 00 |