This invention relates generally to composite structures. More particularly, the invention relates to a fiber reinforced core panel having a series of strips containing a series of cuts wrapped with a fibrous reinforcement sheet and the composite structures made there from.
It is common practice in the industry to score foam panels and balsa wood in order to allow it to curve around complex shapes. Scoring consists of cutting slits partially through the panel on each side, or cutting slits completely through the panel and securing the individual pieces with a scrim. This may result in significant resin absorption during infusion, and the cut foam panels and balsa wood may end up being more flexible than is really useful.
There is a need to have composite structures formed from low density strips able to be contoured in the direction of the composite along the length of the strips and able to be contoured in both directions along the strip length and perpendicular to the strip length for such complex shapes such as a dome or saddle shape.
A fiber reinforced core panel contains a series of adjacent, substantially parallel low density strips and a continuous fibrous reinforcement sheet threaded through the low density strips. The low density strips have at least three faces (a major face, a first edge face, a second edge face, and optionally a minor face) where the major face of each strip is disposed within the first or second side of the core panel. At least a portion of the low density strips comprise a series of cuts, where the cuts originate in the major or minor face and the cuts extend through only a portion of the thickness of the strips. The process for forming the fiber reinforced core panel is also disclosed.
The present invention will now be described by way of example only, with reference to the accompanying drawings which constitute a part of the specification herein and in which:
Referring now to the Figures, and in particular, to
Referring now to
Referring now to
In one embodiment, the strips 100 in the core panel 11 are arranged such that they form a relatively flat panel. The strips 100 are flipped relative to the adjacent strips 100 (strips 100a compared to strips 100b) making the major face 105 of a particular strip 100a, b on the opposing side of the core panel 11 compared to the major face 105 of the adjacent strip 100a, b. If the strips are four sided, as shown in the trapezoid profile shaped strips 100 in
Referring to
In one embodiment, the composite 10 contains curvature along the X direction, the direction perpendicular to the length of the strips (the “X” direction is shown, for example, in
In another embodiment of gaining curvature in the X direction, the strips 100 and the reinforcing sheet 200 are secured to form a fiber reinforcement core panel 11 in a manner that can allow the core panel 11 to bend in either the direction of the first side 11a or the second side 11b such as shown in
The low density strips 100 may be formed from any suitable materials including but not limited to foam (closed-cell or open-cell), balsa wood, and sealed plastic bottles. The foam may be, for example, polyurethane foam, expanded polystyrene foam, expanded polyethylene foam, expanded polypropylene foam, or a copolymer thereof. The strips may be formed of a rigid foam such as PVC, styrene acrylonitrile (SAN), or polymethacrylimide (PMI); a fire resistant foam such as phenolic; or hollow tubes made of plastic, metal, paper, or the like. In a potentially preferred embodiment, the strips 100 are composed of closed-cell foam. The type of closed-cell foam may be selected on the basis of processing parameters such as pressure, temperature, or chemical resistance or other desired panel properties, such as water or fire resistance, thermal insulation or light transmission.
The strips 100 preferably have resin absorption of less than about 250 g/m2 under vacuum pressure as measured by weight change and a deformation of less than 10% under a vacuum of 101 kPa as measured by thickness change. The strips 100 may also have a film or coating on at least one of the surfaces to reduce resin absorption or improve bonding between foam strips and reinforcement. The film or coating may be applied in any known manner and may include PVC, polyolefins, polyurethanes, and other polymers. Low composite structure 10 density is one of the key performance parameters for composite sandwich panels. Resin pickup by foam or other core materials can be significant. Closed cell foams have moderate resin absorption at the surface. Since the amount of foam surface area is increased by 100% to 200% when using elongated foam strips, there is a need in these structures to reduce the surface absorption of resin (polymeric matrix 500). One method by which this can be achieved is by sealing off the foam strips from the resin supply using a PVC shrink wrap film. Covering the foam strips with an impermeable layer of film serves to reduce the resin pickup in the foam and also serves to minimize the resin content in the resultant structure. Preferably, the surface coating on at least one face of the strips 100 is impervious to resin. Some films and coatings may interfere with adhesion between the foam surface of the strips 100 and the reinforcement sheet 200. Some covering films and coatings may reduce the bonding between the foam and reinforcement, but the mechanical properties are mainly developed by the reinforcement. Alternatively, the impermeable layer could be chosen to enhance the bond between the low density strips 100 and the reinforcement sheet 200, improving the mechanical properties of the composite structure 10.
The strips 100 can be a unitary material, a collection of pieces, and/or reinforced material. In the embodiment where the strips are a collection of pieces, the pieces can be individual free pieces, or pieces held together such as with an adhesive.
The core panel 11 may contain curvature or contour in the Y direction (and optionally curvature in the X direction also). The Y direction, for example shown in
The series of cuts may be formed in the strips in a number of ways. In one preferred embodiment, a sheet of closed cell polyurethane foam is sliced, creating cuts all the way across the sheet. This is shown, for example, in
In one embodiment, the strips 100 only have cuts on the major face or the minor face such as shown, for example, in
The series of cuts 150 form planes in the low density strips 100. The planes may be perpendicular to the cut face (major or minor) or non-perpendicular to the cut face. The planes formed by the cuts may change in angle comparing the major to the minor face, from one low density strip to an adjacent strip, or along the length of one strip.
The line formed on the surface of the face that is cut (also referred to as the cut face) is either perpendicular to the sides of the cut face or non-perpendicular to the edges of the cut face.
The depth of the cuts is selected for the desired properties in the final product with greater depth cuts generally resulting in the ability to curve to a tighter radius. In one embodiment, the cuts on average have a depth of between about 10 and 90% of the thickness of the low density strips 100, more preferably between about 20 and 75%.
The frequency of the cuts is selected for the desired properties in the final product with greater frequency of cuts generally resulting in the ability to curve to a tighter radius. In one embodiment, the cuts on average have an average frequency of between about 1 cut per 10 inches and 5 cuts per inch.
The cuts 150 in the low density strips 100 may have any suitable width (width of the space removed from the strip by the cut in the direction along the length of the strip). The cut width, in one embodiment, is minimized so as to minimize extra resin pick-up during infusion. In one embodiment, the width of the cut is approximately constant throughout the depth of the cut, while in another embodiment, the width of the cut decreases through the depth of the cut forming a tapered cut. This is shown in
In one embodiment, the cuts are filled with a plurality of fibers or fabric. If the cuts are filled with fibers, the fibers may be introduced during any suitable manufacturing step, including incorporating the fibers into the cuts before the strips are formed into the core panel, or during infusion where the resin infused contains fibers.
The cuts 150 in the low density strips 100 may be arranged such that when the low density strips 100 are formed into the core panel 10, the cuts are aligned or are staggered as illustrated in
In addition to providing curvature, the series of cuts 150 may also contain additional structural benefits. When resin is impregnated into the panel 11, the cuts fill with resin and may contribute to the structural strength of the panel. The infused cuts form reinforcement ribs in the transverse direction thus reducing the truss buckling. The cuts 150 may also add in ensuring complete resin penetration and quicker resin penetration.
Referring back to one embodiment shown in
The continuous fibrous reinforcing sheet 200 may be a woven, knit, bonded textile, nonwoven (such as a chopped strand mat), or sheet of strands. The fibrous reinforcing sheet 200 can be unidirectional strands such as rovings and may be held together by bonding, knitting a securing yarn across the rovings, or weaving a securing yarn across the rovings. In the case of woven, knit, warp knit/weft insertion, nonwoven, or bonded the textile can have yarns or tape elements that are disposed in a multi- (bi- or tri-) axial direction. The yarns or fibers of the reinforcing sheet 200 may be, for example, fiberglass, carbon, polyester, aramid, nylon, natural fibers, and mixtures thereof. Preferably, the continuous fibrous reinforcement sheet 200 is a multi-axial knit. A multi-axial knit has high modulus, non-crimp fibers that can be oriented to suit a combination of shear and compression requirements. The fibers may be monofilament, multifilament, staple, tape elements, or a mixture thereof. Glass rovings are preferred due to their low cost, relatively high modulus, and good compatibility with a variety of resins. The fibers used in the reinforcement sheet 200 have a high strength to weight ratio. Preferably the fibers have strength to weight ratio of at least 1 GPa/g/cm3 as measured by standard fiber properties at 23° C. and a modulus of at least 70 GPa.
The reinforcing sheet 200 can also be combined with thermoset or thermoplastic resin before being combined with the foam strips. The resin can either be impregnated in the fibers (prepreg), layered in a film form next to the fiber sheets (such as SPRINT® by Gurit), or intermingled with the reinforcement fibers (TVVINTEX® by Saint Gobain). Pre-combining the resin and reinforcement has the advantage of being used in dry processes with similar skins. These processes typically have higher control over fiber resin ratios and thus the potential for lower weight structures. The process is also more controlled with fewer voids or defects. The downside of these prepreg processes is higher material acquisition costs, controlled storage is often needed, and processing typically requires higher capital outlay (heating, autoclave, etc.).
Referring now to the embodiment shown in
One important element of some of the embodiments is the angle between the point in which the reinforcing fiber sheet 200 begins traveling between the strips 100a and 100b until it reaches its exit point at the opposite side of the panel 11. To illustrate this angle, the first imaginary line 151 is drawn from the second major face edge 104 of strip 100b and the first major face edge 102 of the strip 100a. A second imaginary line 152 is drawn from the second major face edge 104 of strip 100b and the first major face edge 102 of the strip 100b. The angle between the first imaginary line 151 and the major face 105 of the strip 100a is Θa, and the angle between the major face 105 of strip 100a to the second imaginary line 152 is Φa the angle between the major face 105 of strip 100b and the second imaginary line 152 is Θb, and the angle between the major face 105 of strip 100b and the first imaginary line 151 is Φb. In one embodiment, angles Θb and Θa are chosen such that they add up to less than 180 degrees. Likewise, in one embodiment, the angles Φa and Φb are selected to add up less than 180. This configuration is also facilitated when the angels Θa and Φa add up to be less than 180 degrees and when the angles Θb and Φb also add up to be less than 180 degrees. In order to design a panel 11 that curves about the first surface 11a, and angles Θa and Φa add up to be less than the sum of angles Θb and Φb. In order to accomplish a curve of the panel 11 above the second surface 11b, the angles Θb and Φb add to be greater than the sum of angle Θa and Φa.
To form the wrapped configuration of the panel 11, the reinforcing sheet 200 is positioned across the edge face 101, moves across the major face 105, then the edge face 103 of a first strip (which is also the edge face 101 of the adjacent strip). The reinforcement fabric 200 continues around the major face 105 of the adjacent strip and then the edge face 103 (which is also the edge face 101 of the next strip). This progression is repeated along the length of the fiber reinforcing core panel 11 to create a situation where the fiber reinforcing sheet 200 covers the surfaces 101, 105, 103 of the strips 100. In one embodiment, the reinforcement sheet forms at least about sixty five percent (65%) of the surface area of the first side 11a and the second side 11b of the core panel 11 and provides angular support between the first surface 11a and the second surface 11b. Additionally, the surface area of the major faces 105 covered by the reinforcing sheet 200 will be greater than the surface area of the minor faces 107, if there are minor surfaces. In a second embodiment, the fibrous reinforcing sheet 200 covers at least about eighty percent (80%), or preferably at least about ninety percent (90%), of the surface area of the first 11a and second 11b side of the panel 11.
The strips 100 and reinforcing sheet 200 of fiber reinforcing core panel 11 at times may need to be secured prior to assembly with the other components of the composite structure 10. Referring now to
In another embodiment, the integrity of the fiber reinforced core panel 11 is created by bonding the reinforcing sheet 200 to the strips 100 prior to disposing the polymeric matrix in the composite structure 10. In such an embodiment, the reinforcement sheet can be secured to the strips 100 with an adhesive, and the adhesive can be disposed in a pattern such as stripes or dots to leave a portion of the reinforcing fabric 200 open. In another embodiment, the reinforcement sheet can be secured to the strips through the inclusion of a nonwoven adhesive web.
Referring back to
The outer skin layers 300, 400 may contain layers of woven, knit, bonded textile, nonwoven fibers, or sheet of strands such as rovings. The fibrous reinforcing sheet can be unidirectional strands such as rovings, and the unidirectional strands can be held together by bonding, knitting a securing yarn across the rovings, or weaving a securing yarn across the rovings. In the case of woven, knit, warp knit/weft insertion, nonwoven, or bonded the textile can have yarns or tape elements that are disposed in a multi- (bi- or tri-) axial direction. The yarns or fibers of the reinforcing sheet can be fiberglass, carbon, polyester, aramid, natural fibers, and mixtures thereof. Preferably, the continuous fibrous reinforcement sheets are a multi-axial knit. A multi-axial knit has high modulus, non-crimp fibers that can be oriented to suit a combination of shear and compression requirements. The fibers may be monofilament, multifilament, staple, tape elements, or a mixture thereof.
The composite panel may be contoured or bent at any point during the manufacture. In one embodiment, the composite panel is contoured in a mold during the resin infusion and curing process. In another embodiment, the panel is contoured before the skin layers are applied (when it is a fiber reinforced core panel).
In one embodiment, a composite panel 10 can be made from two or more adjacent reinforced core panels 11. The reinforced core panels 11 can be arranged with the strips 100 in each panel 11 parallel to one another or turned at 90 degrees to one another. An additional layer of reinforcement like as used in the outer skins 300, 400 may be added between the reinforced core panels 11. Outer skin layers 300 and 400 are then added to the top and bottom of the reinforced core panels 11.
The composite structure 10 is impregnated or infused with a polymeric matrix 500 of resin which flows, preferably under differential pressure, through at least a portion of (the reinforcing sheet 200, the outer skins 300, 400, and optional stabilizing layers 600, 700). Preferably, the resin flows throughout all of the reinforcing materials (the reinforcing sheet 200, the outer skins 300, 400, and optional stabilizing layers 600, 700) and cures to form a rigid, load bearing structure. Resin such as a polyester, a vinylester, an epoxy resin, a bismaleimide resin, a phenol resin, a melamine resin, a silicone resin, or thermoplastic monomers of PBT or Nylon etc. may be used. Vinylester is preferred due to its moderate cost, good mechanical properties, good working time, and cure characteristics. The reinforcement fabric can also be combined with resin before wrapping around the foam strips. Resins include b-staged thermosets as in thermoset prepregs or thermoplastic resins as in tape yarns, commingled yarns, or unidirectional sheets.
Infusing the resin throughout the porous reinforcing fibers under differential pressure may be accomplished by processes such as vacuum bag molding, resin transfer molding or vacuum assisted resin transfer molding (VARTM). In VARTM molding, the core and skins are sealed in an airtight mold commonly having one flexible mold face, and air is evacuated from the mold, which applies atmospheric pressure through the flexible face to conform the composite structure 10 to the mold. Catalyzed resin is drawn by the vacuum into the mold, generally through a resin distribution medium or network of channels provided on the surface of the panel, and is allowed to cure. The composite structure 10 may have flow enhancing means such as, but not limited to: grooves or channels cut into the major and minor surfaces of the strips; a network of grooves on all sides of the strips; additional elements in the reinforcement fabric such as voids or flow enhancing yarns. Additional fibers or layers such as surface flow media can also be added to the composite structure to help facilitate the infusion of resin. A series of thick yarns such as heavy rovings or monofilaments can be spaced equally apart in one or more axis of the reinforcement to tune the resin infusion rate of the composite panel. In one example polyester monofilaments were spaced about 20 mm apart along the length of the reinforcement sheet. The sheet was then wrapped around the foam strips and infused with resin in the direction of the foam strips. The infusion rate was noticeably faster than when using reinforcement without the added monofilaments.
A process for forming the fiber reinforced core panel and composite structure began with a sheet of closed cell polyurethane foam. The one inch thick sheet of foam was then then sliced creating cuts about 0.0625 in wide and about 0.625 in deep every two inches. The cuts were created in the top and bottom of the panel, and the top and bottom slots were offset one half of the interval distance so that each bottom slot was in the middle of two top slots and vice versa. A drawing of the sliced panel is illustrated as
Next, the sheet of foam was cut into sixteen (16) inch long strips having 1 inch height, 1.28 inch width major side, 0.125 inch minor side and a trapezoid shape. The angles of the trapezoid were 60 degrees from the base to the adjacent sides. A drawing of the low density strip formed with the series of cuts is illustrated as
The strips were laid side by side with their longitudinal axes aligned such that the major face alternated between facing upwards and downwards every other strip. The edge faces of the strips were next to the edge faces of strips adjacent to that strip.
A continuous fibrous reinforcing sheet made of E-glass rovings in a 12 oz/yd2 double bias (+/−45 degree) construction (EBX1200® from Vectorply Corporation) was threaded through the strips. The reinforcing sheet was threaded such that the reinforcing sheet was adjacent to the edge faces and the major face such as shown in
Stabilizing layers were added to either side of the panel to hold the strips and reinforcing sheet in place until the next operation. The stabilizing layers were lightweight fiberglass scrims (STABILON® from Milliken & Company). The stabilizing layers were applied using a lightweight hot-melt nonwoven adhesive (PA1541A/1® from Spunfab).
The panel including the stabilizing layers, under its own weight, resulted in a radius of curvature of approximately 1.7 m. Creating a panel without creating a series of cuts in the strips resulted in a panel with little or no measurable curve.
Next, outer skin layers comprised of 4 layers of E-glass rovings in a 12 oz/yd2 double bias (+/−45 degree) construction (EBX1200® from Vectorply Corporation) were laid on either side of the panel.
Finally, the panel with the outer skins was placed in a mold and secured under a vacuum bag. The air was evacuated and a catalyzed vinyl ester resin (CCP ARMORSTAR IVE-XC400® available from Composites One, LLC) was infused throughout the core panel and outer skins until there were no obvious air voids.
The mold was released from the composite structure. The resultant sandwich structure would be useful in applications such as wind turbine blades, boat decks, train floors or other structures were high stiffness and low weight are valued.
All references, including publications, patent applications, and patents, cited herein are hereby incorporated by reference to the same extent as if each reference were individually and specifically indicated to be incorporated by reference and were set forth in its entirety herein.
The use of the terms “a” and “an” and “the” and similar referents in the context of describing the invention (especially in the context of the following claims) are to be construed to cover both the singular and the plural, unless otherwise indicated herein or clearly contradicted by context. The terms “comprising,” “having,” “including,” and “containing” are to be construed as open-ended terms (i.e., meaning “including, but not limited to,”) unless otherwise noted. Recitation of ranges of values herein are merely intended to serve as a shorthand method of referring individually to each separate value falling within the range, unless otherwise indicated herein, and each separate value is incorporated into the specification as if it were individually recited herein. All methods described herein can be performed in any suitable order unless otherwise indicated herein or otherwise clearly contradicted by context. The use of any and all examples, or exemplary language (e.g., “such as”) provided herein, is intended merely to better illuminate the invention and does not pose a limitation on the scope of the invention unless otherwise claimed. No language in the specification should be construed as indicating any non-claimed element as essential to the practice of the invention.
Preferred embodiments of this invention are described herein, including the best mode known to the inventors for carrying out the invention. Variations of those preferred embodiments may become apparent to those of ordinary skill in the art upon reading the foregoing description. The inventors expect skilled artisans to employ such variations as appropriate, and the inventors intend for the invention to be practiced otherwise than as specifically described herein. Accordingly, this invention includes all modifications and equivalents of the subject matter recited in the claims appended hereto as permitted by applicable law. Moreover, any combination of the above-described elements in all possible variations thereof is encompassed by the invention unless otherwise indicated herein or otherwise clearly contradicted by context.