Claims
- 1. Acid-dyeable textile fibers or filaments of polyester containing a minor proportion, sufficient to provide at least 0.02 weight percent nitrogen, of 2,2,6,6-tetramethylpiperidine groups attached through oxyalkylene linkages to carboxylate units at the ends of polyester chains, said linkages being through the 1 or 4 positions of the tetramethylpiperidine ring, the oxyalkylene linkages consisting of oxyethylene or oxyethylene and oxypropylene, and there being an average of at least about 10 oxyalkylene units per tetramethylpiperidine group of which at least 5 are oxyethylene units.
- 2. Fibers or filaments as defined in claim 1 wherein the polyester comprises at least 85 mole percent ethylene terephthalate units.
- 3. Fibers or filaments as defined in claim 2 wherein said polyester contains alkylene oxide condensates of a 1-alkyl-2,2,6,6-tetramethyl-4-hydroxypiperidine, linked to terephthalate units at the ends of polyester chains, said 1-alkyl group having 1 to 4 carbon atoms.
- 4. Fibers or filaments as defined in claim 2 wherein said polyester contains alkylene oxide condensates of a 1-hydroxyalkyl-2,2,6,6-tetramethylpiperidine, linked to terephthalate units at the ends of polyester chains, said 1-hydroxyalkyl group having 1 to 4 carbon atoms.
- 5. Fibers or filaments as defined in claim 2 wherein the polyester comprises 2 to 10 weight percent ethylene adipate units.
- 6. Fibers of filaments as defined in claim 1 wherein the 2,2,6,6-tetramethylpiperidine groups provide 0.02 to 0.25 weight percent nitrogen, based on the weight of the modified polyester.
- 7. Fibers or filaments as defined in claim 1 wherein there are an average of 10 to 80 oxyalkylene units per tetramethylpiperidine group.
- 8. Fibers or filaments as defined in claim 1 wherein there are an average of 10 to 40 oxyalkylene units per tetramethylpiperidine group.
- 9. Fibers or filaments as defined in claim 1 wherein 2,2,6,6-tetramethylpiperidine groups are attached to said carboxylate units through the 4-position of the tetramethylpiperidine ring.
- 10. Fibers or filaments as defined in claim 1 wherein the polyester comprises at least 85 mole percent ethylene terephthalate units and contains oxyethylene condensates of 1,2,2,6,6-pentamethyl-4-hydroxypiperidine linked to terephthalate units at the ends of polyester chains, there being an average of about 20 oxyethylene units per pentamethylpiperidine group.
Priority Claims (1)
Number |
Date |
Country |
Kind |
2346734 |
Sep 1973 |
DT |
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REFERENCE TO RELATED APPLICATION
This is a continuation-in-part of application Ser. No. 505,953 filed Sept. 13, 1974, now abandoned.
US Referenced Citations (5)
Foreign Referenced Citations (1)
Number |
Date |
Country |
32,434 |
Aug 1972 |
JA |
Continuation in Parts (1)
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Number |
Date |
Country |
Parent |
505953 |
Sep 1974 |
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