The present invention relates generally to ceramic filter elements.
Filtration is a widely used process whereby a slurry or solid liquid mixture is forced through a media, with the solids retained on the media and the liquid phase passing through. This process is generally well understood in the industry. Examples of filtration types include depth filtration, pressure and vacuum filtration, and magnetic, gravity and centrifugal filtration.
Both pressure and vacuum filters are used in the dewatering of mineral concentrates. The principal difference between pressure and vacuum filters is the way the driving force for filtration is generated. In pressure filtration, overpressure within the filtration chamber is generated with the help of e.g. a diaphragm, a piston, or external devices, e.g. a feed pump. Consequently, solids are deposited onto the filter medium and filtrate flows through into the filtrate channels. Pressure filters often operate in batch mode because continuous cake discharge is more difficult to achieve.
The cake formation in vacuum filtration is based on generating suction within the filtrate channels. Several types of vacuum filters exist, ranging from belt filters to rotary vacuum drum filters and rotary vacuum disc filters.
Rotary vacuum disc filters are used for the filtration of suspensions on a large scale, such as the dewatering of mineral concentrates. The dewatering of mineral concentrates requires large capacity in addition to producing a cake with low moisture content. Such large processes are commonly energy intensive and means to lower the specific energy consumption are needed. The vacuum disc filter may comprise a plurality of filter discs arranged in line co-axially around a central pipe or shaft. Each filter disc may be formed of a number of individual filter sectors, called filter plates, that are mounted circumferentially in a radial plane around the central pipe or shaft to form the filter disc, and as the shaft is fitted so as to revolve, each filter plate or sector is, in its turn, displaced into a slurry basin and further, as the shaft of rotation revolves, rises out of the basin. When the filter medium is submerged in the slurry basin where, under the influence of the vacuum, the cake forms onto the medium. Once the filter sector or plate comes out of the basin, the pores are emptied as the cake is deliquored for a predetermined time which is essentially limited by the rotation speed of the disc. The cake can be discharged by a back-pulse of air or by scraping, after which the cycle begins again.
In a rotary vacuum drum filter, filter elements, e.g. filter plates, are arranged to form an essentially continuous cylindrical shell or envelope surface, i.e a filter drum. The drum rotates through a slurry basin and the vacuum sucks liquid and solids onto the drum surface, the liquid portion is “sucked” by the vacuum through the filter media to the internal portion of the drum, and the filtrate is pumped away. The solids adhere to the outside of the drum and form a cake. As the drum rotates, the filter elements with the filter cakes rise out of the basin, the cakes are dried and removed from the surface of the drum.
The most commonly used filter media for vacuum filters are polymeric filter cloths and ceramic filter media. Whereas the use of a cloth filter medium requires heavy duty vacuum pumps, due to vacuum losses through the cloth during cake deliquoring, the ceramic filter medium, when wetted, does not allow air to pass through which does not allow air to pass through, which further decreases the necessary vacuum level, enables the use of smaller vacuum pumps and, consequently, yields significant energy savings.
The magnetic separation technology was initially aimed the processing of strongly magnetic ores but today magnetic separation is applied in the treatment of waste waters, in biotechnologies, pharmaceutical applications etc. Stolarski et al., Magnetic field enhanced press-filtration, Chemical Engineering Science 61 (2006), p. 6395-6403, discloses an experimental magnetically enhanced press filtration using a press filter cell which consists of a filtration chamber built by a cake building ring and two filter plates. The used filter media was placed between the cake building ring and the filter plate, and a magnetic field was attached to one side of the press filtration cell. Hence, the filtration cell consists of a magnet side and a non-magnet side. The applied feed slurry was a suspension of ferromagnetic iron oxide. According to Stolarski et al. the presence of a magnetic field results in an increase of filtrate flow especially at the beginning of the filtration process, and it has a positive effect on the filtration kinetics (permeability and cake resistance). As a negative side effect of the filtration with superposed permanent magnetic field is that the capacity of the filter chamber is much lower due to the structuring of the filter cake. Similar experimental press filtration cell is disclosed in Eichholz et al., Magnetic field enhanced cake filtration of superparamagnetic PVAc-particles, Chemical Engineering Science 63 (2008), p. 3193-3200.
U.S. Pat. No. 8,075,771 and U.S. Pat. No. 8,066,877 discloses magnetic field gradient enhanced cake filters. The magnetic pressure cake filter includes a container containing a solid-liquid mixture and a filter media. A pressure is applied to to the solid-liquid mixture so that the pressure at the top of the mixture exceeds that of the filter media. The container is placed within a solenoidal magnet so that the solid-liquid mixture in the container is subjected to a magnetic field provided by the magnet. U.S. Pat. No. 8,066,877 mentions also that in addition to a conventional cake-filtration configuration, the apparatus for solid-liquid separation may take the form of a drum filter, as disc filter, a candle filter, a cross-flow filter or any other type of apparatus that relies on cake-filteration for separation. However, U.S. Pat. No. 8,066,877 discloses construction examples only for a cross-flow filter and a candle filter. The cross-flow filter disclosed is in form of a tube of a filter membrane and single magnetic wire in proximity to, or along, the axis of the tube. The tube and the magnetic wire are subjected to a magnetic field. The solid-liquid mixture is fed into one end of the tube. the magnetic particles in the mixture are attracted to and adhere to the magnetic wire as a result of the gradient magnetic forces in the vicinity of the wire in the magnetic field. The liquid passes through the filter membrane of the tube along the length of the tube and is collected as a filtrate. Periodically the magnetic wire is removed from the tube and the magnetic particles are cleaned from the wire. A plurality of similar tubes with one open end may be arranged to form a candle filter.
An aspect of the present invention is to increase filtration capacity of ceramic filter elements used in removal of liquid from solids containing material to be dried in a capillary suction dryer. Aspects of the invention are a filter plate, an apparatus and method according to the independent claims. Embodiments of the invention are disclosed in the dependent claims.
An aspect of the invention is a filter element to be used in removal of liquid from solids containing material in a capillary suction dryer, the filter element comprising:
a ceramic substrate having a first surface and a second opposite surface,
a ceramic microporous layer covering at least one of the first and the second surfaces of the ceramic substrate,
filtrate channels provided within the ceramic porous substrate, whereby a negative pressure can be maintained within the filtrate channels directing liquid from the outer surface of the ceramic microporous layer by capillary action through the microporous layer and further through the ceramic substrate into the filtrate channels and further out of the filter element.
The filter element is characterized in that it comprises further magnetic material within the ceramic substrate or on an opposite surface of the ceramic substrate in relation to the microporous layer in the case the microporous layer is positioned on only one of the first and second surfaces of the ceramic substrate.
In an embodiment, the magnetic material is provided in or between the filtrate channels.
In an embodiment, in combination with any preceding embodiment, the magnetic material is provided in the ceramic substrate zones which define the filtrated channels between themselves.
In an embodiment, in combination with any preceding embodiment, the magnetic material comprises magnetic elements located in cavities provided in the ceramic substrate zones which define the filtrated channels between themselves.
In an embodiment, in combination with any preceding embodiment, the ceramic substrate comprises two half-plates glued together, and wherein the magnetic material comprises magnetic particles mixed into glue gluing the half-plates together.
In an embodiment, in combination with any preceding embodiment, a core of the ceramic substrate and thereby the filtrate channels is formed by a granular core material, and wherein the granular core material contains magnetic particles or elements.
In an embodiment, in combination with any preceding embodiment, the magnetic material comprises magnetic sheet material provided in the ceramic substrate to form zones which define the filtrate channels between themselves.
In an embodiment, in combination with any preceding embodiment, the ceramic substrate comprises two half-plates fixed together, and wherein the magnetic material comprises a magnetic sheet provided between the half-plates, the magnetic sheet comprising an opening pattern that matches to the filtrate channels within the ceramic substrate.
In an embodiment, in combination with any preceding embodiment, the ceramic substrate comprises two half-plates fixed together, each of the half-plates having filtrate channels on the opposing surfaces, and wherein the magnetic material comprises a magnetic sheet provided between the half-plates.
In an embodiment, in combination with any preceding embodiment, the ceramic microporous layer covers only one of the first and the second surfaces of the ceramic substrate, and the magnetic material is provided on the other of the first and the second surfaces of the ceramic substrate.
In an embodiment, in combination with any preceding embodiment, the ceramic microporous layer covers only one of the first and the second surfaces of the ceramic substrate, and the magnetic material is within the ceramic substrate close to the other of the first and the second surfaces of the ceramic substrate between the filtrate channels and the said other of the first and the second surfaces of the ceramic substrate.
In an embodiment, in combination with any preceding embodiment, the ceramic filter element is made of magnetic material.
In an embodiment, in combination with any preceding embodiment, the magnetic material comprises permanent magnets or electromagnets.
A further aspect of the invention is a filter apparatus comprising one or more filter elements according to any combination of preceding embodiments.
A still further aspect of the invention is a method for manufacturing a filter element to be used in removal of liquid from solids solids containing material in a capillary suction dryer, wherein the method comprises the steps of:
providing a ceramic substrate with filtrate channels within the ceramic substrate, said ceramic substrate having a first surface and a second opposite surface,
coating at least one of the first and the second surface of the ceramic substrate with a ceramic microporous material layer,
whereby a negative pressure can be maintained within the filtrate channels directing liquid from the outer surface of the ceramic microporous layer by capillary action through the microporous layer and further through the ceramic substrate into the filtrate channels and further out of the filter element.
The method is characterized by the step of:
providing magnetic material within the ceramic substrate.
In an embodiment, the method comprises making the filter element or the ceramic substrate of a magnetic material.
In the following the invention will be described in greater detail by means of example embodiments with reference to the accompanying drawings, in which
Principles of the invention can be applied for drying or de-watering fluid materials in any industrial processes, particularly in mineral and mining industries. In embodiments described herein, a material to be filtered is referred to as slurry, but embodiments of the invention are not intended to be restricted to this type of fluid material. The slurry may have high solids concentration, e.g. base metal concentrates, iron ore, chromite, ferrochrome, copper, gold, cobalt, nickel, zinc, lead and pyrite. In the following, example embodiments of filter plates for rotary vacuum disc filters are illustrated but the principles of the invention can be applied also for filter media of other types of vacuum filters, such as rotary vacuum drum filters.
Each filter disc 21 may be formed of a number of individual sector-shaped ceramic filter elements, called filter plates, mounted in a radial planar array around the central axis of the drum to form an essentially continuous and planar disc surface. The number of the filter plates may be 12 or 15, for example.
In exemplary embodiments the filter plates 22 of the consecutive discs are disposed in rows, each row establishing a sector or zone of the disc 21. As the row of the filter discs 21 rotate, the plates 22 of the each disc 22 move into and through the basin 9. Thus, each filter plate 22 goes through four different process phases or sectors during one rotation of the disc 21. In a cake forming phase, a partial vacuum is transmitted to the filter plates 22 and filtrate is drawn through the ceramic plate 22 as it is immersed into the slurry basin 9, and a cake 35 forms on the surface of the plate 22. The liquid or filtrate in the central interior space 33 is then transferred into the collecting pipe and further out of the drum 20. The plate 22 enters the cake drying phase (illustrated in
An aspect of the invention is enhancing filtration capacity in ceramic filters in ceramic filters utilizing magnetism. Embodiments of the invention are especially suitable for enhancing filtration of magnetite slurry.
According to an aspect of the invention a filter plate of any material having at least one magnetic element inside for creating a magnetic field, is provided. The filter plate can be used for increasing filtration capacity particularly in magnetite applications. The magnetic field causes an attractive force on the magnetic particles and thus increases the amount of material forming on the filter plate in a vacuum filter, such as a capillary action filter, conventional rotary vacuum filter or drum filter or capillary action drum filter. The magnetic field also has an impact on the orientation of particles in the cake increasing filtration capacity.
In embodiments of the invention the filter element comprises a ceramic substrate, a ceramic microporous layer covering the ceramic substrate, filtrate channels within the ceramic substrate, and magnetic material provided in and/or between or behind the filtrate channels within the ceramic substrate.
In some embodiments, the magnetic material is provided in the ceramic substrate zones which define the filtrated channels between themselves.
In some embodiments, the magnetic material comprises magnetic elements located in cavities provided in the ceramic substrate zones which define the filtrated channels between themselves. An exemplary embodiment is illustrated in
In embodiments, the interior space of the ceramic substrate 32, and thereby the filtrate channel 33 may be formed by a granular core material, and the magnetic material or elements 51 may installed in the core material such that the filtrate can flow between the magnetic elements 51, as illustrated in in
In an embodiment, magnetic material may comprise magnetic particles 51 mixed into the granular core material which provide the filtrate channels 33 within the ceramic substrate 32, as illustrated in
In an embodiment, the magnetic material comprises a thin magnetic sheet 61 provided in the ceramic substrate 32 to form zones which define the filtrate channels 33 between themselves. In an embodiment, the magnetic sheet comprises an opening pattern (channel pattern) that matches to the desired filtrate channels within the ceramic substrate 32 as illustrated in
In an embodiment, each of the half-plates 32A and 32B of the ceramic substrate have filtrate channels 33 on their opposing surfaces, and a magnetic sheet 61 located between the half-plates is uniform and does not contain a cut-off channel pattern, as illustrated in
In an embodiment, magnetic material comprises magnetic particles 71 mixed into glue 72 gluing the half-plates 32A and 32B of the ceramic substrate 32 together, as illustrated in
In an embodiment, the filter plate may be made of magnetic material. For example, the ceramic substrate may be entirely made of magnetic material, or both the ceramic substrate and the microporous membrane may be entirely made of magnetic material. This means that the ceramic material used contains also magnetic particles.
Although not shown in
In embodiments, a ceramic microporous layer 31 may cover only one major surface of the ceramic substrate 32 so that the filtering operation is carried out only through that surface, as illustrated in
The magnetic plate principle was tested with magnetite slurry. It was concluded that the cake thickness was significantly larger when using magnetic field. The test work also surprisingly indicated that a higher hydraulic capacity was obtained with magnetic field, which further enhanced the filtering capacity. It is possible that the magnetic field rearranges the particles in the magnetic field such a way that it has a positive effect on the hydraulic flow. It may also be possible that water molecules are arranged in such a way by the magnetic field that the hydraulic flow is affected. This feature of the magnetic filter plate allows an enhanced filtering effect also in filtering other than magnetite slurry.
An example of a magnetic material suitable for the magnetic elements according to the invention is neodymium-iron-boron (NdFeB) permanent magnet. Size and strength of individual magnets depend on the application and filter element in question. Permanent magnet blocks are commercially available from Webcraft GmbH, Germany, http://www.supermagnete.de, for example. As an alternative to permanent magnets, electromagnets may be used in some applications. For example, in exemplary embodiments shown in
Upon reading the present application, it will be obvious to a person skilled in the art that the inventive concept can be implemented in various ways. The invention and its embodiments are not limited to the examples described above but may vary within the scope of the claims.
Number | Date | Country | Kind |
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20135607 | May 2013 | FI | national |
Filing Document | Filing Date | Country | Kind |
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PCT/FI2014/050438 | 5/30/2014 | WO | 00 |