1. Field of the Invention
The invention relates to filtration, and in particular, to a filtration device using photocatalyst to purify water.
2. Description of the Related Art
Photocatalyst has the ability to purify environments, with TiO2 is the most used phtocatalyst. When water exists on the surface of photocatalyst (TiO2) with sufficient light, Hydroxyl Radical (OH.) can be produced, then decomposing organic matter that attach to photocatalyst surface.
When utilizing photocatalyst in processing polluted water, the photocatalyst could be usually used in powder form, or fixed to carriers. A slurry photocatalyst reactor is used for powdered photocatalyst. The photocatalyst is suspended in the water. After the completion of the reaction using the powdered photocatalyst, the photocatalyst is recycled. But a carrier photocatalystic reactor is used for photocatalyst fixed to carriers. The selection of carrier material and the method of fixing photocatalyst are factors required.
Conventional recycling of photocatalyst uses ultra-filtration membrane or micro-filtration membrane, although both membranes of ultra-filtration or micro-filtration are microporous, resulting in high fabrication cost, high operating pressure, and complicated maintainance.
The invention provides a filtration device comprising a tank, photocatalyst, a light source and a non-woven membrane module. The tank comprises a reacting section and a separating section. The photocatalyst is added to water. The light source, disposed in the reacting section, provides light to react with the photocatalyst, decomposing pollutants in the water. The non-woven membrane module, disposed in the separating section, intercepts the photocatalyst in the water, purifying water.
The filtration device further comprises an inflow pump, communicating with the reacting section and pumping water into the tank, a first blower, providing air to the reacting section, and a first air distributor, disposed in the reacting section, communicating with the first blower. Air is diffused in the water by the first air distributor, uniformly suspending the photocatalyst.
The first blower comprises a manifold.
The filtration device further comprises a second air distributor, disposed in the separating section, communicating with the manifold, whereby air is diffused in the water, maintaining filtrating flux of the non-woven membrane module.
The filtration device further comprises a mixer, disposed in the reacting section, uniformly suspending the photocatalyst.
The filtration device further comprises a second blower, providing air to the separating section.
The filtration device further comprises a second air distributor, disposed in the separating section, communicating with the second blower or a manifold of the first blower, whereby air is diffused in the water, maintaining filtrating flux of the non-woven membrane module.
The photocatalyst is TiO2 and is powdered.
The filtration device further comprises an outflow pump, communicated with the non-woven membrane module, removing out purified water, carriers, added to the reacting section and intercepting the photocatalyst.
The carriers are made of non-woven material.
The photocatalyst is pre-fixed in the carriers, and added to the reacting section.
The carriers are pervious to light.
The filtration device further comprises a sieve, disposed between the reacting section and the separating section, preventing the carriers from entering the separating section.
The diameter of the carriers is between 2 mm and 20 mm.
The carriers are of polymethyl methacrylate (PMMA), polystyrene (PS), polycarbonate (PC), polyethylene terephthalate (PET), polypropylene (PP), polyethylene (PE), 4-methylpentene (TPX), or a combination thereof.
The light has a wavelength between 250 nm and 450 nm.
The non-woven membrane module comprises a plurality of non-woven membrane, with pore size of diameter between 0.03 μm and 30 μm.
The non-woven membrane module comprises a plurality of non-woven membrane, and the non-woven membrane are of polymethyl methacrylate, polystyrene, polycarbonate, polyethylene terephthalate, polypropylene, polyethylene, 4-methylpentene, or a combination thereof.
The invention provides a variant filtration device, for purifying water, comprising a first tank, photocatalyst, a light source, a second tank, and a non-woven membrane module. The photocatalyst is added to the first tank. The light source, disposed in the first tank, provides light to react with the photocatalyst, decomposing pollutants in the water. The second tank, communicating with the first tank, receives water from the first tank. The non-woven membrane module, disposed in the second tank, intercepts the photocatalyst in the water, producing purified water.
The invention provides another variant filtration device, for purifying water, comprising a tank, photocatalyst, a light source, and a non-woven membrane module. The tank receives water to process water purification. The photocatalyst is added to the tank. The light source provides light to react with the photocatalyst, decomposing pollutant in the water. The non-woven membrane module, disposed under a waterline of the tank, intercepts the photocatalyst in the water, producing purified water.
A detailed description is given in the following embodiments with reference to the accompanying drawings.
The invention can be more fully understood by reading the subsequent detailed description and examples with references made to the accompanying drawings, wherein:
The invention provides a filtration device, used after secondary or tertiary treatment, removing pollutant and sterilizing. The filtration device can further be used before processing raw water pretreatment, removing micro-contaminants, or in surface water and groundwater treatment, removing organic matter and nitrogen pollutants.
The tank 11 is divided into a reacting section R and a separating section S by a divider D. A passage at the lower portion of the divider D communicates the reacting section R to the separating section S. The inflow pump P1 communicates with the reacting section R of the tank 11, pumping water to the tank 11.
The photocatalyst 12 is powdered TiO2, added to the tank 11 and mixed with water. It should be noted that since the photocatalyst 12 of the embodiment is of extremely small particles, the photocatalyst 12 in all figures is not in proportion.
The fluorescent tubes 13 are disposed in the reacting section R, providing light to react with the photocatalyst 12, wherein the wavelength of light is between 250 and 450 nm. It should be noted that while there are two fluorescent tubes in the embodiment, it is not limited thereto.
The non-woven membrane module 14, comprised of a plurality of non woven membrane, is disposed in the separating section S and connects with the outflow pump P2. The non-woven membrane are of polymethyl methacrylate, polystyrene, polycarbonate, polyethylene terephthalate, polypropylene, polyethylene, 4-methylpentene, or a combination thereof. Additionally, the non-woven membrane have pore size with diameter between 0.03 and 30 μm.
The first air distributor 15 is disposed at the bottom of the reacting section R, communicating with the first blower B1. The first blower B1 provides air to the reacting section R, and air is diffused in the water by the first air distributor 15.
The second air distributor 16 is disposed at the bottom of the separating section S, communicating with the second blower B2. The second blower B2 provides air to the separating section S, and air is diffused in the water by the second air distributor 16.
In this embodiment, the second air distributor 16 communicates with the second blower B2, but it is not limited thereto. The first blower B1 can further comprise a manifold L (as shown in
When the filtration device 10 is in operation, the first air distributor 15 diffuses air in the water, uniformly suspending the photocatalyst 12 in the water, such that the photocatalyst 12 can effectively contact pollutant in the water. The fluorescent tubes 13 provide light to react with the photocatalyst 12, and initiate oxidation and decompose pollutant thereto. The second air distributor 16 diffuses air in the water, producing shear force from cross-flow over the surface of the non-woven membrane. As a result, the photocatalyst 12 does not remain and clog the non-woven membrane, stablizing filtrating flux of the non-woven membrane module 14. Finally, the outflow pump P2 removes purified water through the non-woven membrane module 14. Because the non-woven membrane module 14 filters the photocatalyst 12, the photocatalyst 12 returns to the reacting section R to continue purifying water. Thus, the amount of photocatalyst 12 in the tank 11 remains stable.
Although purification rate increases with concentration of suspended photocatalyst, higher concentrations of suspended photocatalyst reduce the filtrating flux of the non-woven membrane module. Therefore, the invention provides another filtration device.
It should be noted that the bottom sieve BS can be disposed in any position between the reacting section R and the separating section S, preventing the carriers C from flowing to the separating section S.
Non-woven material is porous and of fiber, so the carriers C, of non-woven material, can intercept and fix the suspended photocatalyst 12 therein, decreasing concentration of the suspended photocatalyst 12, and raising the filtration efficiency of the non-woven membrane module 14. Thus, filtrating flux is improved, and the operating pressure is lowered.
In this embodiment, the photocatalyst 12 can also be prefixed in the carriers C by chemical or physical means, and added to the reacting section R.
The filtration device utilizes non-woven membrane to filter the photocatalyst. Solid particles in the water are removed by fabric filtration captured by lower pressure drop, improving filtration efficiency. Compared to micro-filtration membrane, fibers of the non-woven membrane interlace with each other, forming irregular but curved paths and holes. Not only is sieve mechanism provided, but also interception, inertial impaction, and Brownian diffusion are activated. The utilization of non-woven membrane in the filtration module allows the filtration device to operate at lower pressure, to effectively intercept solid particles, and lower material costs. In addition, the surface of the non-woven membrane can be backwashed, whereby fouling of the non-woven membrane is successfully controlled.
While the invention has been described by way of example and in terms of preferred embodiment, it is to be understood that the invention is not limited thereto. To the contrary, it is intended to cover various modifications and similar arrangements (as would be apparent to those skilled in the art). Therefore, the scope of the appended claims should be accorded the broadest interpretation so as to encompass all such modifications and similar arrangements.
Number | Date | Country | Kind |
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TW094142048 | Nov 2005 | TW | national |