The present disclosure relates generally to battery electrodes. More specifically, the present disclosure relates to increasing a volumetric energy density of a battery employing the battery electrodes.
A battery may be formed by electrodes, one or more separators, electrolyte, a housing, terminals, and other possible componentry. The battery may be employed as a source of power for an electronic device. In certain batteries, such as secondary (e.g., rechargeable) batteries having stacked electrodes, a first electrode (e.g., an anode) may be larger than a second electrode (e.g., a cathode). Indeed, a sufficient size difference between the anode and the cathode, and proper placement of the anode relative to the cathode, may ensure that the battery functions and operates properly.
However, due at least in part to limitations in traditional manufacturing systems and processes for producing traditional batteries, a size difference between the anode and the cathode may be relatively large to account for relatively large deviations from nominal or design sizes of the anode and the cathode. For example, the nominal or design size of the cathode may be relatively small with respect to the nominal or design size of the anode, such that a sufficient size difference between the anode and the cathode will exist even if a size of the anode deviates from the nominal or design size and/or a size of the cathode deviates from the nominal or design size. Unfortunately, the relatively large size difference between the anode and the cathode may contribute to wasted space within the battery and reduce a volumetric energy density thereof. For at least these reasons, among others, improved batteries and battery manufacturing are desired.
A summary of certain embodiments disclosed herein is set forth below. It should be understood that these aspects are presented merely to provide the reader with a brief summary of these certain embodiments and that these aspects are not intended to limit the scope of this disclosure. Indeed, this disclosure may encompass a variety of aspects that may not be set forth below.
In an embodiment, a battery includes a separator having a first side and a second side opposing the first side. The battery also includes an anode having an anode face that faces the first side of the separator, where the anode face includes an anode face surface area. The battery also includes a cathode having a cathode face that faces the second side of the separator, where the cathode face includes a cathode face surface area. A surface area ratio between the anode face surface area and the cathode face surface area is between 1.030 and 1.038.
In another embodiment, a battery includes an anode having an anode face with an anode width dimension and an anode height dimension. The battery also includes a cathode having a cathode face with a cathode width dimension and a cathode height dimension. The battery also includes a width ratio between the anode width dimension and the cathode width dimension within a first range of 1.006 to 1.009. The battery also includes a height ratio between the anode height dimension and the cathode height dimension within a second range of 1.022 to 1.024.
In yet another embodiment, a battery assembly includes an anode having an anode face, where the anode face includes an anode face surface area. The battery also includes a cathode having a cathode face, where the cathode face includes a cathode face surface area. A surface area ratio between the anode face surface area and the cathode face surface area is between 1.030 and 1.038. The battery also includes a portion of the anode forming an anode/cathode overhang that extends beyond a perimeter of the cathode.
Various refinements of the features noted above may exist in relation to various aspects of the present disclosure. Further features may also be incorporated in these various aspects as well. These refinements and additional features may exist individually or in any combination. For instance, various features discussed below in relation to one or more of the illustrated embodiments may be incorporated into any of the above-described aspects of the present disclosure alone or in any combination. The brief summary presented above is intended only to familiarize the reader with certain aspects and contexts of embodiments of the present disclosure without limitation to the claimed subject matter.
Various aspects of this disclosure may be better understood upon reading the following detailed description and upon reference to the drawings described below in which like numerals refer to like parts.
One or more specific embodiments will be described below. In an effort to provide a concise description of these embodiments, not all features of an actual implementation are described in the specification. It should be appreciated that in the development of any such actual implementation, as in any engineering or design project, numerous implementation-specific decisions must be made to achieve the developers' specific goals, such as compliance with system-related and business-related constraints, which may vary from one implementation to another. Moreover, it should be appreciated that such a development effort might be complex and time consuming, but would nevertheless be a routine undertaking of design, fabrication, and manufacture for those of ordinary skill having the benefit of this disclosure.
When introducing elements of various embodiments of the present disclosure, the articles “a,” “an,” and “the” are intended to mean that there are one or more of the elements. The terms “comprising,” “including,” and “having” are intended to be inclusive and mean that there may be additional elements other than the listed elements. Additionally, it should be understood that references to “one embodiment” or “an embodiment” of the present disclosure are not intended to be interpreted as excluding the existence of additional embodiments that also incorporate the recited features. Furthermore, the particular features, structures, or characteristics may be combined in any suitable manner in one or more embodiments. Use of the terms “approximately,” “near,” “about,” “close to,” and/or “substantially” should be understood to mean including close to a target (e.g., design, value, amount), such as within a margin of any suitable or contemplatable error (e.g., within 0.1% of a target, within 1% of a target, within 5% of a target, within 10% of a target, within 25% of a target, and so on). Moreover, it should be understood that any exact values, numbers, measurements, and so on, provided herein, are contemplated to include approximations (e.g., within a margin of suitable or contemplatable error) of the exact values, numbers, measurements, and so on).
The present disclosure relates generally to fine blanking of battery electrodes in a battery. More specifically, the present disclosure relates to battery electrodes produced via a fine blanking technique that generates battery electrodes having more consistent and/or precise sizes, which enables an improvement in volumetric energy density of the battery relative to traditional embodiments.
In accordance with the present disclosure, a battery (e.g., a secondary or rechargeable battery, such as a lithium-ion battery) may include electrodes, electrode tabs extending from bodies of the electrodes, electrolyte, one or more separators configured to separate the electrodes, a housing, battery terminal tabs, and other possible componentry. For example, the housing may define a housing interior configured to receive the electrodes (e.g., at least one anode and at least one cathode), the one or more separators, and the electrolyte. Each electrode tab may be electrically coupled with a positive battery terminal tab or a negative battery terminal tab, which may extend outside of the housing interior and are configured to be coupled to a load (e.g., an electric device powered by the battery).
In certain types of batteries, each anode may be larger than each cathode. For example, while the anode and the cathode may otherwise include the same or similar shape, the anode may be larger than the cathode. Further, the anode and the cathode may be stacked (e.g., with a separator therebetween) such that a perimeter of the anode is disposed outward from a perimeter of the cathode. In this way, the perimeter of the anode may substantially surround or encircle the perimeter of the cathode. Put differently, the anode may overhang the cathode along the perimeter of the cathode. This feature may be referred to by the present disclosure as an anode/cathode overhang and may contribute to safe operation of the battery. Indeed, a sufficient size of the anode/cathode overhang may be needed to ensure regulatory compliance and/or safe operation of the battery.
Due at least in part to manufacturing limitations in traditional embodiments, an actual size of an electrode in a traditional battery may substantially deviate from a nominal or design size of the electrode. Accordingly, in traditional batteries, the nominal or design size of the anode is relatively large compared to the nominal or design size of the cathode, thereby ensuring that, even if the actual sizes of the electrodes substantially deviate from the nominal or design sizes, the traditional battery will still include a sufficiently sized anode/cathode overhang. However, this may come at the cost of volumetric energy density of the battery. Indeed, while including a relatively large size disparity between the anode and the cathode ensures that the anode/cathode overhang is sufficiently sized despite the manufacturing limitations and deviations in traditional embodiments described above, the relatively large size disparity between the anode and the cathode contributes to wasted space within the housing interior defined by the housing of the battery.
In accordance with the present disclosure, a fine blanking technique is employed to produce anodes and cathodes such that deviations from the nominal or design sizes of the anode and the cathode are reduced. By reducing deviations from the nominal or design sizes of the anode and the cathode, a size of the cathode can be more closely aligned with a size of the anode while still ensuring a sufficient size of the anode/cathode overhang. In general, the fine blanking technique may include a single cutting step in which one or more electrodes is cut from a layered material, which may differ from traditional embodiments in which multiple cutting steps are employed, thus reducing manufacturing complexity, time, and cost. These and other features of the fine blanking technique contribute to more precise electrode sizes, namely, by reducing deviations from the nominal or design sizes. By reducing deviations from the nominal or design sizes, a size of the cathode may be increased relative to a size of the anode, while still ensuring a sufficient size of the anode/cathode overhang.
Another aspect of the present disclosure includes a growth of the size of the anode relative to the size of the housing. Indeed, in traditional embodiments, the size of the anode may be constrained by the above-described deviations from nominal or design size and a need to fit the anode within boundaries of the housing of the battery. By employing the fine blanking technique referenced above, the size of the anode and the size of the cathode may be increased (and the size of the cathode may be more closely aligned with the size of the anode) while ensuring a sufficiently sized anode/cathode overhang, and without substantially contributing to a footprint of the battery. Accordingly, a volumetric energy density of the present disclosed battery is improved over traditional embodiments. For example, the presently disclosed battery may include an approximately 1% increase in volumetric energy density. These and other features are described in detail below.
By way of example, the electronic device 10 may include any suitable computing device, including a desktop or notebook computer (e.g., in the form of a MacBook®, MacBook® Pro, MacBook Air®, iMac®, Mac® mini, or Mac Pro® available from Apple Inc. of Cupertino, California), a portable electronic or handheld electronic device such as a wireless electronic device or smartphone (e.g., in the form of a model of an iPhone® available from Apple Inc. of Cupertino, California), a tablet (e.g., in the form of a model of an iPad® available from Apple Inc. of Cupertino, California), a wearable electronic device (e.g., in the form of an Apple Watch® by Apple Inc. of Cupertino, California), and other similar devices. It should be noted that the processor 12 and other related items in
In the electronic device 10 of
In certain embodiments, the display 18 may facilitate users to view images generated on the electronic device 10. In some embodiments, the display 18 may include a touch screen, which may facilitate user interaction with a user interface of the electronic device 10. Furthermore, it should be appreciated that, in some embodiments, the display 18 may include one or more liquid crystal displays (LCDs), light-emitting diode (LED) displays, organic light-emitting diode (OLED) displays, active-matrix organic light-emitting diode (AMOLED) displays, or some combination of these and/or other display technologies.
The input structures 22 of the electronic device 10 may enable a user to interact with the electronic device 10 (e.g., pressing a button to increase or decrease a volume level). The I/O interface 24 may enable electronic device 10 to interface with various other electronic devices, as may the network interface 26. In some embodiments, the I/O interface 24 may include an I/O port for a hardwired connection for charging and/or content manipulation using a standard connector and protocol, such as the Lightning connector provided by Apple Inc. of Cupertino, California, a universal serial bus (USB), or other similar connector and protocol. The network interface 26 may include, for example, one or more interfaces for a personal area network (PAN), such as an ultra-wideband (UWB) or a BLUETOOTH® network, a local area network (LAN) or wireless local area network (WLAN), such as a network employing one of the IEEE 802.11x family of protocols (e.g., WI-FI®), and/or a wide area network (WAN), such as any standards related to the Third Generation Partnership Project (3GPP), including, for example, a 3rd generation (3G) cellular network, universal mobile telecommunication system (UMTS), 4th generation (4G) cellular network, long term evolution (LTE®) cellular network, long term evolution license assisted access (LTE-LAA) cellular network, 5th generation (5G) cellular network, and/or New Radio (NR) cellular network, a 6th generation (6G) or greater than 6G cellular network, a satellite network, a non-terrestrial network, and so on. In particular, the network interface 26 may include, for example, one or more interfaces for using a cellular communication standard of the 5G specifications that include the millimeter wave (mmWave) frequency range (e.g., 24.25-300 gigahertz (GHz)) that defines and/or enables frequency ranges used for wireless communication. The network interface 26 of the electronic device 10 may allow communication over the aforementioned networks (e.g., 5G, Wi-Fi, LTE-LAA, and so forth). The power source 29 of the electronic device 10 may include any suitable source of power, such as a rechargeable lithium polymer (Li-poly) battery and/or an alternating current (AC) power converter.
In accordance with the present disclosure, and as described in detail below with reference to later drawings, a battery (e.g., corresponding to the power source 29) of the electronic device 10 may include a housing, at least one anode disposed in the housing, and at least one cathode disposed in the housing, among other features. The anodes and/or the cathodes may be produced via a fine blanking technique in which actual sizes of the anodes and/or the cathodes are more closely aligned with nominal or design sizes of the anodes and/or the cathodes. That is, the fine blanking technique may reduce error margins in production of the anodes and/or the cathodes. As will be appreciated in view of the description below, more precise and/or consistent sizes of the anodes and/or the cathodes enable improved volumetric energy density of the battery relative to traditional embodiments.
Electrodes (e.g., one or more anodes and one or more cathodes), one or more separators, and electrolyte of the battery 40 may be disposed in a housing interior defined by the housing 42. In certain embodiments, the electrodes and the one or more separators may be arranged via a stacking (e.g., zig-zag stacking) procedure before they are disposed in the housing interior defined by the housing 42. The electrodes, described in detail below with reference to later drawings, may be produced, extracted, created, or cut from a layered material via a fine blanking technique. The layered material of the anode may include, for example, a copper layer disposed between a first layer of graphite and a second layer of graphite. The layered material of the cathode may include, for example, an aluminum layer disposed between a first layer of lithium cobalt oxide and a second layer of lithium cobalt oxide. Other layered materials are also contemplated.
As previously described, and as can be seen with respect to
In some embodiments, multiple instances of the anode 80 and the cathode 86 may be stacked in an alternating order, and the separator 90 may zig-zag (e.g., be applied in an alternating and/or back-and-forth manner) between the various anodes 80 and cathodes 86 (or multiple instances of the separator 90 may be employed, each being disposed between adjacent instances of the anode 80 and the cathode 86). With reference again to
While the anode/cathode overhang 102 may need to be sufficiently sized in order to ensure proper and safe functionality of the corresponding battery, a relatively large size of the anode/cathode overhang 102 reduces a volumetric energy density of the corresponding battery. As previously described, traditional techniques for electrode production may include a nominal or design anode size that is relatively large compared to a nominal or design cathode size, which allows for relatively large deviations from the nominal or design sizes while still ensuring a sufficient anode/cathode overhang size. In accordance with the present disclosure, a fine blanking technique is employed to produce the cathode 86, the anode 80, and the anode/cathode overhang 102 illustrated in
In
In
For example, a width ratio (e.g., maximum width ratio) between the width 144 in
Due at least in part to the above-described features, a surface area of the cathode face 110 in
An actuation assembly 206 (e.g., including one or more servomotors) of the fine blanking system 170 may be employed to exert a force 207 against the upper portion 172, namely, the upper shoe 174 of the upper portion 172 and/or the lower portion 186 of the fine blanking system 170. The actuation assembly 206 may additionally or alternatively exert a force 209 against the lower portion 186 of the fine blanking system 170. In some embodiments, the force 209 may be exerted against the lower portion 186 of the fine blanking system 170 via a platform, surface, or mount on which the fine blanking system 170 is disposed. In other embodiments, one motor (e.g., servomotor) of the actuation assembly 206 may exert the force 207 against the upper shoe 174 of the upper portion 172 of the fine blanking system 170, and another motor (e.g., servomotor) of the actuation assembly 206 may exert the force 209 against the lower portion 186 of the fine blanking system 170. Other actuation mechanisms employing the actuation assembly 206 are also contemplated by the present disclosure.
A controller 208 of the fine blanking system 170 may include processing circuitry 210 and memory circuitry 212 storing instructions thereon that, when executed by the processing circuitry 210, cause the controller 208 to perform various functions. The processing circuitry 210 and/or the memory circuitry 212 may be similar to that of the processor 12 and/or the memory 14 described with reference to
The first punch 176 and the first suction pad 190 may sandwich (e.g., squeeze or hold in place) a first portion of the layered material therebetween, and the second punch 178 and the second suction pad 192 may sandwich a second portion of the layered material therebetween. The force 207 from the actuation assembly 206, controlled by the controller 208, may continue to press the upper shoe 174, the first punch 176, and the second punch 178 in the downwards direction 214. The first suction pad 190 and the second suction pad 192 may also be forced in the downwards direction 214 (e.g., via the first punch 176 and the second punch 178, respectively) and relative to the die 194. In this way, the first punch 176 may be forced into the first die opening 196, and the second punch 178 may be forced into the second die opening 198.
As the first punch 176, the second punch 178, the first suction pad 190, and the second suction pad 192 continue to be forced in the downwards direction 214 (e.g., through the first and second die openings 196, 198), a first electrode may be cut from the layered material (e.g., corresponding to the first die opening 196), and a second electrode may be cut from the layered material (e.g., corresponding to the second die opening 198). That is, the first electrode may take the shape of the first opening 196 formed in the die, and the second electrode may take the shape of the second opening 198 in the die 194. It should be noted that the first electrode and the second electrode may both correspond to anodes, the first electrode and the second electrode may both correspond to cathodes, or the first electrode may correspond to an anode and the second electrode may correspond to a cathode.
As described above, the controller 208 may control the force 207 exerted by the actuation assembly 206 on the upper shoe 174 and, in some embodiments, the force 209 exerted on the lower portion 186 of the fine blanking system 170. In some embodiments, the controller 208 may control aspects of the fine blanking system 170 based on data feedback received from the spring assembly 204. For example, in the illustrated embodiment, the spring assembly 204 includes a first gas spring 216 coupled to the first connector 200 via a first extension 217, a first pressure sensor 218 corresponding to the first gas spring 216 (e.g., configured to detect a pressure in the first gas spring 216), a second gas spring 220 coupled to the second connector 202 via a second extension 219, and a second pressure sensor 222 corresponding to the second gas spring 220 (e.g., configured to detect a pressure in the second gas spring 220). The first gas spring 216 and the second gas spring 220 may be, for example, nitro gas springs. As the suction pads 190, 192 are forced in the downward direction 214 as described above, the connectors 200, 202 extending from the suction pads 190, 192 may exert respective forces on the gas springs 216, 220 (e.g., via the extensions 217, 219). Accordingly, a first pressure in the first gas spring 216 and a second pressure in the second gas spring 220 may increase during the cutting process.
The controller 208 may receive data feedback from the first pressure sensor 218 and the second pressure sensor 222 and control the actuation assembly 206 based on the data feedback. As an example, due to ambient conditions, wear on certain parts of the fine blanking system 170, and/or other conditions, a correspondence between the spring pressure (e.g., in the first gas spring 216 and/or the second gas spring 220) and the force(s) 207 and/or 209 may change over time. Indeed, the controller 208 may determine, based on the data feedback from the pressure sensors 218, 222, that an increase or reduction in the force(s) 207 and/or 209 to properly cut the electrode from the layered material is needed. Accordingly, the controller 208 may periodically adjust the force(s) 207 and/or 209 in response to the data feedback from the pressure sensors 218, 222. Additionally or alternatively, the controller 208 may control an aspect of the first gas spring 216, the second gas spring 220, or both to increase or reduce spring forces within the first and/or second gas springs 216, 220. Based on the above-described controls, the fine blanking system 170 may precisely cut the first and second electrodes from the layered material while reducing or negating burring and/or cracking in the electrodes, among other technical benefits. Other aspects of the fine blanking system 170, described in detail below, may also contribute to reducing or negating burring and/or cracking in the electrodes.
As shown, the punch 176 is forced in the downwards direction 214 into the die opening 196. The cathode 86 is cut from the layered material 60 as the punch 176 is forced in the downwards direction 214. Indeed, a portion 260 of the end piece 240 of the layered material 60 and an additional portion 266 of the layered material 60 is removed such that the cathode 86 is formed from the layered material 60. The portion 260 of the end piece 240 of the layered material 60 and the additional portion 266 of the layered material 60 may be referred to as stock material or waste material. After the cathode 86 is cut from the layered material 60, the punch 176 and the suction pad 190 may be returned to the positions illustrated in
It should be noted that other fine blanking system and techniques are also possible. For example,
In general, embodiments of the present disclosure are directed toward batteries including electrodes generated via fine blanking techniques. Presently disclosed fine blanking techniques reduce deviations of actual sizes of battery electrodes from nominal sizes of battery electrodes. In doing so, a sufficiently sized anode/cathode overhang is provided without an unnecessarily large size different between the anode and the cathode. These and other features contribute to an improved volumetric energy density relative to traditional embodiments.
It is well understood that the use of personally identifiable information should follow privacy policies and practices that are generally recognized as meeting or exceeding industry or governmental requirements for maintaining the privacy of users. In particular, personally identifiable information data should be managed and handled so as to minimize risks of unintentional or unauthorized access or use, and the nature of authorized use should be clearly indicated to users.
The specific embodiments described above have been shown by way of example, and it should be understood that these embodiments may be susceptible to various modifications and alternative forms. It should be further understood that the claims are not intended to be limited to the particular forms disclosed, but rather to cover all modifications, equivalents, and alternatives falling within the spirit and scope of this disclosure.
The techniques presented and claimed herein are referenced and applied to material objects and concrete examples of a practical nature that demonstrably improve the present technical field and, as such, are not abstract, intangible or purely theoretical. Further, if any claims appended to the end of this specification contain one or more elements designated as “means for [perform]ing [a function] . . . ” or “step for [perform]ing [a function] . . . ,” it is intended that such elements are to be interpreted under 35 U.S.C. 112(f). However, for any claims containing elements designated in any other manner, it is intended that such elements are not to be interpreted under 35 U.S.C. 112(f).
This application claims priority to U.S. Provisional Application No. 63/357,893, filed Jul. 1, 2022, entitled “FINE BLANKED BATTERY ELECTRODES,” the disclosure of which is incorporated by reference in its entirety for all purposes.
Number | Date | Country | |
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63357893 | Jul 2022 | US |