Fire-protection composition

Abstract

A fire-protection composition has browsing-resistant metal fibers.

Description

FIELD OF INVENTION

[0001] The invention relates to a fire-protection composition, such as a sealing composition, which is difficult to ignite or is capable of intumescing.

BACKGROUND INFORMATION AND THE PRIOR ART

[0002] Fire-protection compositions with intumescing materials, which expand when overheated, are customarily used as fire-protection products in kneadable or dimensionally stable form or as composite structures especially in dry-wall constructions, for example, to close off openings in partitions, wall feed-throughs and back-ventilated facades fire-tight and smoke-tight in the event of a fire.

[0003] Long-term stability is a particularly important criterion for fire-protection products. A problem arises in this regard if small animals, such as rats and mice, which destroy, for example, fire-protection products reinforced with fiberglass, by simply biting through the glass fibers; browse on the fire-protection products.

[0004] According to the DE10024421, an intumescing fire-protection composition consists essentially of a polymer matrix, expandable graphic, fillers and additives. According to U.S. Pat. No. 6,153,674, the structural phase is reinforced by adding a fiber mixture of tough organic fibers and high-strength inorganic fibers in an amount of 0.01% to 15% of the total weight, the inorganic fibers, including metal fibers having a length of 1 mm to 25 mm and a diameter of 0.05 μm to 5 μm. Such fiber mixtures are not resistant to browsing.

[0005] Moreover, the EP492248 discloses a fire protection product, which is constructed as a fabric and has grainy intumescing materials, such as expandable graphite, which is disposed in sandwich fashion between two textile fabrics of any fiber materials, which are sewn together or needle-punched. For reinforcement, glass, mineral or metal fibers 5 mm to 20 mm in length, as components of a fiber mixture, are mixed with these textile fabrics.

[0006] Moreover, according to WO0188301, it is known that concrete may be reinforced with steel wire fibers, 10 mm to 70 mm in length.

OBJECT OF THE INVENTION

[0007] It is an object of the invention to realize a fire-protection composition with a high long-term stability.

SUMMARY OF THE INVENTION

[0008] This objective is accomplished essentially by the distinguishing features of the independent claims. Advantageous further developments arise out of the dependent claims.

[0009] Essentially, a fire-protection composition contains a proportion of browsing-resistant metal fibers.

[0010] By means of the browsing-resistant barriers, which small animals cannot bite through or break and which are not decomposed biologically over time, as are organic fibers, a permanent protection of the fire-protection product against browsing by small animals is provided, as a result of which the long-term stability is increased.

[0011] Advantageously, the proportion of browsing-resistant metal fibers is 1% to 5% of the total weight. As a result, provided that the long-term stability is adequate, the remaining 95% remain available for essential, conventional components of a fire-protection composition.

[0012] Advantageously, the browsing-resistant metal fibers have a length of more than 20 mm, so that they are embedded over a greater length and the work, required to pull them out, is greater than that required to pull out conventional fibers and is beyond the capabilities of small animals.

[0013] Advantageously, the browsing-resistant metal fibers have a diameter of 20 μm to 200 μm, so that the bending resistance is greater than that of conventional fibers and cannot be overcome by small animals. The browsing-resistant metal fibers, with a fiber diameter of 20 μm and a, length of 20 mm act like needles and, during browsing, become hooked in the flesh of rodents.

[0014] Advantageously, the browsing-resistant metal fibers have a diameter of less than 600 μm and a length of less than 30 mm, because, beyond this, the effect through injury decreases significantly.

[0015] Advantageously, the browsing-resistant metal fibers are standardized steel wire fibers for use in reinforced concrete and are available technologically in large numbers.

[0016] Advantageously, the browsing-resistant metal fibers consist of a corrosion-resistant material such as stainless steel or brass, so that the long-term stability is increased further.

[0017] Advantageously, the fire-protection composition has material capable of intumescing, so that it expands when overheated.

[0018] Advantageously, the browsing-resistant metal fibers are a component of a composite structure, such as an intumescing fabric, as a result of which the textile fabric itself, which is disposed on the outside, is protected against browsing by small animals.

[0019] Advantageously, the intumescing fabrics with the browsing-resistant metal fibers are needle-punched at least partly, which, moreover, contribute to the internal bonding of the composite structure.

[0020] The invention is described in greater detail with respect to three advantageous examples with a formulation for each:

[0021] A: a silicone polymer composition, which is difficult to ignite

[0022] B: and intumescing sealing composition

[0023] C: and intumescing tape/wrap for plastic pipes

A		Amount	Tolerances	Chemical Name
1	Silicone polymer	38.0%	±10%	α, ω-polydimethylsiloxane glycol
2	Silicone plasticizer	14.0%	±7%	α, ω-trimethylpolydimethylsiloxane
3	Catalyst	0.5%	±0.3%	Dibutyl tin dilaurate
4	Fillers, pigments	12.5%	±10%	Chalk, talcum, clay, shear spar, iron
				oxide pigments, titanium dioxide,
				carbon black
5	Cross-linking	4.7%	±2%	Butanone oxime-vinyl silane
	agent			(alternatively alkoxysilanes,
				methoxysilanes, ethoxysilanes or
				mixtures)
6	Adhesion	0.8%	±0.5%	(3-aminopropyl) triethoxysilane
	promoter
7	Thickener	4.0%	±3%	Aerosil
8	Ablative filler	23.0%	±10%	Aluminum trihydrate (ATH)
9	Metal fibers	2.5%	±2%	Stainless steel fibers or brass,
				diameter 200μ; length 20 mm
B		Amount	Tolerances	Example
1	Acrylate dispersion	35.0%	±10%	Acronal 81D
2	Plasticizer	10.0%	±7%	Dioctyl phthalate
3	Dispersant	0.5%	±0.3%	Emulphor
4	Fillers	35%	±15%	Chalk, talcum, clay
5	Expanded graphite (or an	15%	±7%	Nordmin
	intumescing mixture of
	ammonium poly-phosphate,
	melamine and penta-
	erythritol)
6	Thickener	2.0%	±1.5%	Aerosil, cellulose ether
7	Steel wire fibers	2.5%	±2%	Steel fibers, diam. 300μ,
				length 20 mm Harex GSF
				20
8	Additives for stabilizing ash	5.0%	±2%	Zinc borate, powdered glass
	crust
C		Amount	Tolerances	Example
1	Polyvinyl acetate dispersion	35.0%	±10%	Makrovil D 3630
2	Dispersant	0.5%	±0.3%	Emulphor
3	Ash crust stabilizer	15.0%	±10%	Ammonium polyphosphate,
				zinc borate
4	Expanded graphite	35%	±15%	Nordmin
5	Thickener	2.0%	±1.5%	Aerosil, cellulose ether
6	Steel wire fibers	2.5%	±2%	Harex GSF 20
7	Fillers	10%	±10%	Chalk, talcum, clay, shear
				spar,

[0024] The mixture can be extruded and dried. However, panels can also be pressed, dried and cut to size. The formulations generally have very wide tolerances, so that a broad spectrum of viscosities, tensile strengths and intumescences can be formulated. For producing panels, the mixture, before it is dried and cured, can be applied on a textile backing material or on a fiberglass fabric and pressed, so that, during drying, there is bonding to form a fabric.

Claims

1. A fire-protection composition containing metal fibers, wherein browsing-resistant metal fibers are present.

2. The fire-protection composition of claim 1, wherein the proportion of browsing-resistant metal fibers is between 1 percent and 5 percent of the total weight.

3. The fire-protection composition of claim 1, wherein the browsing-resistant metal fibers have a length of at least 20 mm.

4. The fire-protection composition of claim 1, wherein browsing-resistant metal fibers have a length of not more than 30 mm.

5. The fire-protection composition of claim 1, wherein the browsing-resistant metal fibers have a fiber diameter of 20 μm to 600 μm.

6. The fire-protection composition of claim 1, wherein the browsing-resistant metal fibers are conventional steel wire fibers for concrete.

7. The fire-protection composition of claim 1, wherein the browsing-resistant metal fibers consists of a corrosion-resistant material such as stainless steel or brass.

8. The fire-protection composition of claim 1, wherein the browsing-resistant metal fibers are a component of a composite structure.

9. The fire-protection composition of claim 8, wherein the composite structure with the browsing-resistant metal fibers is needle-punched at least partly.

10. The fire-protection composition of claim 1, wherein said composition has an intumescing material.