Patent Application
20250116110
This invention relates to a gypsum wallboard construction that retards thermal transmission from one side of the gypsum wallboard to the other when one side is exposed to flames.
Fire resistance of a wallboard is measured according to ASTM E119, where a series of wallboard panels are exposed to a furnace. A number of thermocouples are affixed to predetermined locations on the opposite side of the wall that is not exposed to direct fire from the furnace. To be certified as having passed this ASTM E119 fire test, none of the thermocouples should exceed readings of 325° F. plus ambient temperature in less than 60 minutes, or the average value of the thermocouples should remain less than 250° F. plus ambient temperature for a minimum of 60 minutes.
When gypsum wallboard is exposed to a high temperature, the gypsum (calcium sulfate dihydrate) that makes up the wallboard's core undergoes a dehydration reaction which first converts gypsum to calcium sulfate hemihydrate and then to calcium sulfate. This series of reactions involve the release of water molecules which help to temporarily insulate the wallboard and slow the transfer of heat from the fire-exposed side to the other, unexposed side. At the same time that these reactions are taking place and water is being evolved, the gypsum wallboard is shrinking to compensate for the loss of water. In turn, this internal shrinkage of the wallboard panels eventually creates gaps at the joints, exposing the mounting studs to direct contact with the furnace fire. These studs, whether wood or metal, burn or significantly accelerate the transmission of heat to the unexposed side of the wallboard panels and eventually result in failure of the test. So, being able to pass the fire test involves mitigating heat transfer across the wallboard and minimizing or eliminating board shrinkage. This shrinkage has conventionally been achieved by incorporating and distributing vermiculite into the gypsum core. Vermiculite is comprised of an insulating surface but more importantly, it expands when heated. After heating for one hour, high expansion vermiculite particles could expand to about 300% or more of their original volume. In any case, the expansion of vermiculite particles that have been distributed within a gypsum wallboard core helps to retain the structural integrity of the wallboard structure when the board is exposed to intense heat. As the gypsum core contracts in response to loss of water molecules, the vermiculite expands to achieve a counterbalance.
Li et al. U.S. Pat. No. 10,604,929 provides an example of the use of vermiculite within the gypsum core to increase fire resistance.
In the present invention, a combination of expandable graphite and carbon black is used in a gypsum wallboard construction to mitigate heat transfer from a fire-exposed side of the wallboard panel to the unexposed side. In the current invention, a small quantity of carbon black is dispersed in the layer of gypsum just below the face paper of the gypsum wallboard. A small quantity of expandable graphite is dispersed in the rest of the gypsum core of the wallboard. When heated, the expandable graphite particles expand as much as 1000-fold. In this inventive construction, the combination of the thermal insulation provided by the carbon black layer and the shrinkage mitigation provided by the expansion of expandable graphite has shown results that are superior to traditional systems containing vermiculite alone.
Shrinkage is determined by cutting a 2″×5″ piece of the wallboard and then measuring the thickness at four locations on the piece of board. The board is then placed in a furnace at 538° C. for a duration of 30 minutes after which thickness measurements of the same four spots on the board are taken again. The difference between the average thickness before placing in the oven and the average thickness after placing in the oven is recorded as the shrinkage. The higher that the number is, the higher the shrinkage. A negative number would indicate a net expansion.
Further objects, features and advantages will become apparent upon consideration of the following detailed description of the invention when taken in conjunction with the appended claims.
The front cover sheet 12 and the back cover sheet 20 are conventional paper cover sheets used in conventional wallboard construction.
The front carbon black layer 14 is formed of carbon black. The front carbon black layer 14 is between 8 mil (0.008 inch, 0.2032 mm) and 15 mil (0.015 inch, 0.381 mm) thick. The carbon black layer 14 extends over the full length and width of the wallboard 10. The front carbon black layer 14 is Thermax N991, manufactured by CanCarb of Medicine Hat, Alberta, Canada. As shown in Table 1, Thermax in 991 has the following characteristics.
In the process of manufacturing the wallboard of the present invention, the carbon black layer is deposited on the front cover sheet 12 before being married to the gypsum+expandable graphite core 16.
The gypsum+expandable graphite core 16 comprises a mixture of a conventional gypsum core and expandable graphite evenly distributed throughout the core 16. The core 16 comprises approximately 16 pounds per MSF (thousand square feet) of the finished core 16. Two different grades of expandable graphite, 3494 and 3570 manufactured by Asbury Graphite of North Carolina, Inc. of Lumberton North Carolina, can be used for the core 16. Specifications for expandable graphite 3494 and expandable graphite 3570 are shown in Table 2 and Table 3 below.
A control formula for a gypsum core wallboard contains 60 lbs./MSF of vermiculite VCX 204 supplied by Specialty Vermiculite Corp. of Enoree, South Carolina. The specification for the vermiculite is shown in Tables 4, 5, and 6.
(b)Elements are expressed as oxide
A small-scale fire test that is reflective of full furnace ASTM E119 tests involves cutting out a 7.5 inch×7.5 inch size of the test wallboard 10, locating the exact center point of the front cover sheet 12 of wallboard 10, and then affixing a thermocouple to the back (unexposed) cover sheet 20 at the center point location. A blowtorch flame is directed to the center point on the front cover sheet 12 (at a predetermined distance from the front cover sheet 12), and the temperature readings of the thermocouple located on the back cover sheet 20 of the side opposite of the flame are monitored.
The control wallboard containing vermiculite experienced a net shrinkage of 5/1000 inch, and when heated by way of the blow torch fire test, the back cover sheet of this control wallboard required about 60 minutes to reach 670° F. Table 7 shows these results, along with results for various levels of expandable graphite being added to the paper/core slurry and separately, to the gypsum core slurry. Table 7 shows that a mixture of 1.3 lbs./MSF of expandable graphite Grade 3538 (supplied by Asbury Graphite) in the paper/core layer and 9.3 lbs./MSF in the core displayed both lower shrinkage and a longer time to get to 670° F. than the control wallboard. The dosage range of expandable graphite in the core is 3.0 to 30.0 lbs/MSF (based on total dosage of gypsum in the wallboard)
Table 8 shows results of gypsum wallboards which were made by dosing the paper/core slurry and the core with various levels of carbon black and expandable graphite. The dosage range of carbon black in the carbon black layer is 0.5 to 5.0 lbs/MSF (based on total dosage of gypsum in the wallboard).
Table 8 shows that the mixture of 2.6 lbs./MSF of Thermax N991 carbon black in the paper/core slurry along with 16 lbs./MSF of expandable graphite Grade 3494 had superior performance in both shrinkage and thermal transmission than the control vermiculite wallboard.
Turning to
While this invention has been described with reference to preferred embodiments thereof, it is to be understood that variations and modifications can be affected within the spirit and scope of the invention as described herein and as described in the appended claims.
This invention claims priority from U.S. Provisional Patent Application No. 63/588,837, filed Oct. 9, 2023, and U.S. Provisional Patent Application No. 63/590,567, filed Oct. 16, 2023, which are hereby incorporated by reference.
| Number | Date | Country | |
|---|---|---|---|
| 63588837 | Oct 2023 | US | |
| 63590567 | Oct 2023 | US |
