1. Field of the Invention
The present invention relates to a fixing device for use in fixing unfixed toner particles onto a recording medium, and an image forming apparatus using the fixing device.
2. Discussion of the Background
Image forming apparatuses using electrophotography include a fixing device to fix an unfixed toner image transferred onto a recording medium. Such a fixing device typically adopts a heat roller system.
A fixing device adopting a heat roller system includes a fixing roller containing a heat source such as a halogen heater therein and a pressure roller. The pressure roller is in contact under pressure with the fixing roller, thereby forming a nip therebetween. The fixing device adopting a heat roller system fixes unfixed toner images onto a recording medium while the recording medium is passing through the nip. The fixing roller used in the fixing device adopting a heat roller system is formed of a core made of, for example, metals, on which an elastic layer (i.e., a heat insulating layer) and a release layer are formed. This type of fixing device has a relatively large thermal capacity. It naturally takes a long time to raise the temperature of such a roller by heat from room temperature to a predetermined temperature.
Reduction in the time needed to be taken to raise the temperature (hereinafter referred to as rise time) is essential for energy saving. By reducing the thickness of the core and the elastic layer of such a roller applying heat to unfixed toner, a relatively low thermal capacity can be imparted to the roller, resulting in shortening the rise time of the roller. The roller applying heat to unfixed toner refers to a roller directly heated by a heater. However, a background roller applying heat to unfixed toner typically contains a heat source therein. Therefore it takes a long time before the heat is conveyed to the surface of the roller. Especially, when the roller is used for fixing color images, the elastic layer thereof has to be sufficiently thick to obtain quality images. Therefore, such a roller has a long rise time. In addition, it also takes a long time to raise the temperature of such a roller to a predetermined temperature again after the roller is deprived of heat by a recording medium passing through the nip. Therefore, when recording media consecutively pass through the nip, the fixing ability of a fixing device using such a roller deteriorates because the temperature of the heat roller falls.
Published unexamined Japanese Patent Application No. JP 2002-40855 discloses a fixing device including a system in which a heat source is disposed outside the fixing member to directly apply heat to the surface thereof. In this system, the fixing roller has a substantially short rise time because heat is applied only to the surface layer to be heated and in addition has a quick response to the temperature fall caused by recording media passing through the nip. However, the heat conveyed to the surface layer in fact diffuses into a portion not to be heated such as the inside of the fixing roller and the pressure roller. Thus, the actual rise time of the fixing roller is longer than its theoretical time.
It is possible to shorten the rise time of a fixing roller by forming a heat insulating layer under the surface layer of the heating roller to improve thermal insulation properties thereof. As materials having good thermal insulation properties, there are materials containing a gas such as air having a low specific thermal conductivity therein. As disclosed in JP 2000-206815, foamed silicone rubber is widely used. Foamed silicone has a low specific thermal conductivity and good thermal insulation properties because of air contained therein. However, the air contained in the foamed silicone is compressed at the nip, resulting in reduction in the content ratio of the air. Thereby, the specific thermal conductivity of the foamed silicone becomes high. In addition, foamed silicone is easily transformed by compression. Thus, it is unsuitable to apply a high plane pressure to foamed silicone. Further, foamed silicone tends to deteriorate over time with repetitive transformation. Furthermore, foamed silicone has another drawback in that, since the rotation radius of a foamed silicone roller varies under compression, such a roller is not suitable as a driving roller to convey recording media, etc., at a constant speed.
JP 2002-40855 exemplifies porous ceramics and porous resin as a thermal insulation material having a high rigidity with little transformation. JP 2000-275996 and JP 2001-65544 disclose a binder mixed with hollow particles. However, these materials have insufficient thermal insulation properties.
Further, JP 2001-343850 discloses a fixing roller including a heat insulating layer formed of accumulated layers including resin films having holes. However, this structure has a drawback in that it is difficult to appropriately position the holes in adjacent film layers and to form a heat insulating layer having a large void ratio.
In view of these reasons, the present investors recognized a need exists for a fixing device that can avoid heat diffusion into a portion not to be heated, to thereby shorten waiting time and save energy.
Accordingly, an object of the present invention is to provide a fixing device comprising a member for fixing and other members such as a cleaning member to remove toner adhered to the member for fixing that have good thermal insulation properties to avoid heat diffusion to a portion not to be heated for shortening waiting time and saving energy. The member for fixing represents a fixing member, a pressure member, etc., which form a nip.
Another object of the present invention is to provide an image forming apparatus comprising the fixing device.
Briefly, these objects and other objects of the present invention as hereinafter will become more readily apparent can be attained by a fixing device comprising at least one fixing member configured to fix a toner image on a transfer material, comprising a first substrate, a pressing member configured to form a nip with the at least one fixing member, comprising a second substrate, and a heater. At least one of the at least one fixing member and the pressing member further comprises a heat insulating layer overlying the first or second substrate.
It may be preferred that the heat insulating layer comprises accumulated film layers and a filler dispersed between the accumulated film layers to form a space therebetween.
It may be preferred that the filler is a particulate material.
It may be preferred that the filler is a particulate hollow material.
It may be preferred that the filler has a fiber.
It may be preferred that the filler has a hollow fiber.
It may be preferred that the accumulated film layers are adhered to each other or the film layers and the filler are adhered to each other.
It may be preferred that, in the fixing device mentioned above, at least one of the at least one fixing member and the pressing member comprises a roller substrate and the accumulated film layers comprises a film sheet that is spirally wound around the roller substrate in such a way that the winding direction of the film sheet is opposed to the rotation direction of the roller substrate.
It may be preferred that the heat insulating layer further comprises accumulated film layers and each of the accumulated film layers has a concavo-convex surface to form a space therebetween.
It may be preferred that the heat insulating layer further comprises a filler dispersed between the accumulated film layers having a concavo-convex surface.
It may be preferred that the heat insulating layer further comprises a flat film alternately disposed with the film layer having concavo-convex surface.
It may be preferred that the at least one fixing member is a heat induction roller comprising a heat generating layer located overlying the heat insulating layer.
It may be preferred that the fixing device mentioned above further comprises a fixing belt that is rotated while being sandwiched by the at least one fixing member and the pressing member.
It may be preferred that the fixing device mentioned above further comprises a heat roller heated by the heater and a fixing belt that receives heat of the heat roller. The fixing belt is rotated while supported by the at least one fixing member and the heat roller and is sandwiched by the at least one fixing member and the pressing member to apply heat to unfixed toner image.
It may be preferred that, in the fixing device mentioned above, the heater is located inside the at least one fixing member.
It may be preferred that, in the fixing device mentioned above, the heater is disposed in the vicinity of the at least one fixing member to apply heat thereto.
It may be preferred that the heater disposed in the vicinity of the at least one fixing member to apply heat thereto directly applies heat to the toner image on the transfer sheet.
It may be preferred that the heat insulating layer comprises accumulated thermoplastic resin film layers and a particulate hollow material dispersed therebetween while fixed thereto by a thermoplastic resin.
It may be preferred that the fixing device mentioned above further comprises at least one cleaning member comprising a substrate and a second heat insulating layer. The at least one cleaning member cleans the surface of at least one of the at least one fixing member and the pressing member.
It may be preferred that the second heat insulating layer comprises accumulated film layers each of which has a concavo-convex surface to form a space therebetween.
As another aspect of the present invention, a fixing device is provided that comprises a fixing member configured to fix a toner image, a pressing member configured to form a nip with the fixing member, a heater, and a cleaning member configured to clean the surface of at least one of the fixing member and the pressing member. The cleaning member comprises a substrate and a heat insulating layer.
As another aspect of the present invention, an image forming apparatus is provided that comprises a photoreceptor, an irradiator configured to irradiate the photoreceptor to form a latent image on the photoreceptor, a developing device configured to develop the latent image on the photoreceptor with a toner to form a toner image on the photoreceptor, a cleaner configured to remove toner remaining on the photoreceptor, a discharging device configured to discharge the photoreceptor, a transferring device configured to transfer the toner image to a recording medium, and the fixing device mentioned above.
As another aspect of the present invention, a heat insulating member is provided that comprises a support and a heat insulating layer located overlying the support. The heat insulating layer comprises accumulated film layers and a filler dispersed between the accumulated film layers to form a space therebetween. As another aspect of the present invention, a heat insulating member is provided that comprises a support and a heat insulating layer located overlying the support. The heat insulating layer comprises accumulated film layers and each layer has a concavo-convex surface to form a space therebetween.
These and other objects, features, and advantages of the present invention will become apparent upon consideration of the following description of the preferred embodiments of the present invention taken in conjunction with the accompanying drawings.
Various other objects, features, and attendant advantages of the present invention will be more fully appreciated as the same becomes better understood from the detailed description when considered in connection with the accompanying drawings in which like reference characters designate like corresponding parts throughout and wherein:
The present invention is now described below in detail with reference to several embodiments and accompanying drawings.
Members for fixing represent a fixing member and a pressure member. Rollers for fixing represent a fixing roller and a pressure roller.
The image forming apparatus illustrated in
In this structured printer, writing signals are transmitted from a host machine (not shown), for example a computer. An irradiating device 8 is driven according to received image signals and light is emitted from a laser beam source of the irradiating device 8. The light is scanned by a polygon mirror rotationally driven by a motor and irradiated by mirrors, etc. to the photoreceptor drum 1 uniformly charged by the charging device 2. Then, a latent image corresponding to the writing information is formed on the photoreceptor drum 1. The latent image formed on the photoreceptor drum 1 is developed with toner by the developing device 3 and the developed toner image is borne on the surface of the photoreceptor drum 1.
The paper set at the top of the bunch of paper set in the paper feeder cassette 9 is fed by the paper feeder roller 26 and is sent out by a register roller 27 at an appropriate timing of the toner image borne on the photoreceptor drum 1.
The toner image on the photoreceptor drum 1 is transferred onto a paper by the transfer device 4. The toner remaining on the surface of the photoreceptor drum 1 after this transfer is removed by the cleaning device 5. Then the photoreceptor drum 1 is discharged by the discharging device 6 for the next cycle.
The paper onto which the toner image is transferred is sent to the fixing device 10 by the conveyer belt 7. The toner image is fixed on the paper by application of heat and pressure. The paper on which the toner image is fixed is output to a tray 29 by a paper discharging roller 28.
Next, an embodiment of the fixing device is described.
The fixing device 10 illustrated in
A temperature detection device (not shown) is attached to the fixing roller 11. Electric current to the halogen heater is controlled according to the output of the temperature detection device such that the temperature of the fixing roller 11 is maintained at a predetermined temperature. The fixing roller 11 in this embodiment includes a metal core 14 having a diameter of 30 mm and a TEFLON® layer 15 functioning as a release layer having a thickness of 10 μm coated thereon, as examples. The pressure roller 12 is a thermal insulation roller having an outer diameter of 30 mm that includes a metal core 16 and a heat insulating layer 17 having a thickness of 1 mm thereon, as examples. On the heat insulating layer 17, an elastic layer 18 (i.e., a silicone rubber layer) having a thickness of, e.g., 0.3 mm is formed. As a release layer 19 (i.e., a surface layer), PFA tube having a thickness of 15 μm is coated on the elastic layer 18, as an example. The elastic layer 18 is provided to the pressure roller 12 when the fixing roller 11 forming a nip under pressure with the pressure roller 12 is hard. However, the pressure roller 12 can dispense with the elastic layer 18 when the fixing roller 11 has an elastic layer or this thermal insulation roller (i.e., the pressure roller 12) is used as a supporting roller for a fixing belt.
In
Each concavo-convex film 20 can be formed by embossing a flat film. For example, as in
As illustrated in
The embodiment illustrated in
The embodiment illustrated in
In addition, spaces K in the heat insulating layers 17A to 17D are preferably formed as open spaces.
When the spaces are closed in the heat insulating layer 17, the roller diameter may become large by the internal air inflated by heat, resulting in fluctuation in conveying speed. Therefore, the ends of the heat insulating layer in the direction of the roller axis are preferably not sealed to let the internal air in the heat insulating layer escape from the ends of the roller through the continuous space. It is thus possible to prevent the fluctuation in the roller diameter even when the internal air in the heat insulating layer is inflated by heat.
Any materials workable to thin film forms can be used to form the heat insulating layers 17A to 17D. Specific examples of such materials include polyesters, polyimides, polyamide-imides, polybenzo imidazoles, polybenzo bisoxazoles, polyphenylene sulfides. In the embodiments of the present invention, polyimides and polyphenylene sulfides are adopted considering thermal resistance, specific thermal conductivity, and strength of the material. Adiathermancy and strength of the heat insulating layer can be controlled by adjusting the thickness of the film and the dimensions of concavity and convexity (i.e., dimensions of the spaces K). In the embodiments of the present invention, when a polyphenylene sulfide film is used, the polyphenylene sulfide film may have a thickness of 15 μm, and a concavity and convexity height difference of 70 μm. When the heat insulating layer 17 has about 10 film layers, adiathermancy thereof is sufficient. When the thickness of the entire heat insulating layer 17 is 0.5 mm, and preferably about 1 mm, it is possible to shorten the rise time.
Specific examples of the hollow particles 23 for use in the structure examples illustrated in
In addition, as illustrated in
The structures of the heat insulating layers 17A to 17D illustrated in
Therefore, in the structure illustrated in
Next, a second example of a fixing device of the present invention is described with reference to
A fixing device 30 illustrated in
In the fixing device 30 of this example, the radiation heat from the halogen heater 33 is supplied to the surface of the fixing roller 31 and is not conveyed much to the internal portion (the metal core 34) thereof. Thus, the fixing device can effectively apply heat to the toner and the recording medium. Similar to the pressure roller 32 (and the pressure roller 12 illustrated in
Next, a third example of a fixing device of the present invention is described with reference to
A fixing device 50 illustrated in
The fixing nip of the fixing device 50 of this embodiment is formed when the pressure roller 32 is in contact under pressure with the second fixing member 52 and the fixing roller 51 with the fixing belt 53 therebetween. The second fixing member 52 located on the upstream side in the fixing nip forms the first nip and the fixing roller 51 located on the downstream side in the fixing nip forms the second nip. The fixing nip is formed in a manner in which the fixing belt 53 is rolled around the pressure roller 32 by the second fixing member 52 and the fixing roller 51. A recording medium P is conveyed into the fixing nip from right to left in this figure and receives the heat of the fixing belt 53 such that the toner T is fixed onto the recording medium P. The fixing belt 53 of this embodiment is formed of a substrate including a polyimide on which a silicone rubber layer having a thickness of, e.g., 0.2 mm as an elastic layer and a PFA coating layer having a thickness of, e.g., 10 μm as a release layer are formed.
The fixing roller 51 is the same as the fixing roller 31 illustrated in
The heat insulating layer 57 of the fixing roller 51 and the heat insulating member 52b of the second fixing member 52 can adopt the same structure as any one of the heat insulating layers 17A to 17D described with reference to
In the fixing device 50 of this embodiment, a heat source (i.e., the halogen heater 33) is disposed on the upstream side of the fixing nip and applies heat to the fixing belt 53 from a surface thereof (i.e., the surface that contacts unfixed toner). In addition, each of the first and the second fixing members (i.e., the fixing roller 51 and the second fixing member 52) and the pressure roller 32 serving to form the fixing nip has a heat insulating layer. Therefore, the heat held in the fixing belt 53 is not easily transferred to the substrates (i.e., the roller metal cores 54 and 36 and the supporting member 52a) of the members forming the fixing nip. Thus, the heating belt 53 can effectively apply heat to toner and recording media.
In addition, the heat insulating layers in the members of forming the fixing nip have a good rigidity so that the formed fixing nip is uniform.
In this example, each of the second fixing member 52 serving as a member for fixing, the fixing roller 51 serving as a roller for fixing, and the pressure roller 32 includes a heat insulating layer. The adiathermancy of the member for fixing, the roller for fixing, and the pressure roller is improved by adopting for the heat insulting layer thereof the same structure as any one of the heat insulating layers 17A to 17D described with reference to
Next, two examples of a fourth embodiment of a fixing device of the present invention are described with reference to
A fixing device 60A illustrated in
The fixing roller 61 includes a roller substrate 62 on which a heat insulating layer 63, an electric conductive layer (i.e., a heat generating layer) 64, an elastic layer 65, and a release layer 66 are formed. The roller substrate 62 is made of a resin since this roller adopts a heat induction system. The roller substrate is not limited to a resin roller and another roller such as a glass roller is also suitable in light of heat resistance and rigidity. The heat insulating layer 63 can adopt the same structure as any one of the heat insulating layers 17A to 17D described with reference to
In the fixing devices 60A and 60B of these examples, the rise time can be shortened by using this heat induction system. In addition, the heat induction device 67 is disposed inside the heat insulating layer 63. Thereby, the heat of the electric conductive layer (i.e., heat generating layer) 64 is effectively blocked so that the heating efficiency does not become low. Namely, efficiency of the induction coil 69 tends to become low as its temperature rises, but the heat of the electric conductive layer 64 is not easily transferred to the induction coil 69 due to the existence of the heat insulating layer 63. Thus, deterioration of the efficiency of the induction coil 69 can be restrained. The electric conductive layer (i.e., heat generating layer) 64 is not limited to a nickel sleeve and can be formed by an electric conductive polymer, plated metal, material containing carbon, and their combination formed on the outermost film layer in the heat insulating layer 63. The rise time properties are good by using these electric conductive layers.
A fixing device 60B illustrated in
In this example, a heat insulating layer is provided to each of the fixing roller 61 and the pressure roller 32 functioning as rollers for fixing and the heat insulating layer adopts the same structure as any one of the heat insulating layers 17A to 17D described with reference to
Next, an example of a fifth embodiment of a fixing device of the present invention is described with reference to
A fixing device 70 illustrated in
Since the fixing member 74 is abrasively in contact with the fixing belt 71, the fixing member 74 can adopt the same structure as that of the second fixing member 52 in the fixing device 50 illustrated in
In the fixing device 70, the fixing member 74 fixedly disposed inside the fixing belt 71 is in contact under pressure with the pressing member 32 to form a nip. To form a uniform nip without a bending, a supporting member 75 forming the fixing member 74 is preferred to be a rigid metal or a substance having an equivalent rigidity thereto. When the supporting member 75 is made of a metal frame or the like, its heat capacity is large. Thus, when the supporting member 75, which is not involved in fixing is heated, the heating efficiency deteriorates. To prevent this deterioration, a reflection board 73 is provided between the fixing member 74 and the halogen heater 72. Also, the fixing member 74 receives the heat from the fixing nip. However, in this example, the heat from the fixing belt 71 is not easily transferred to the supporting member 75 because the heat insulating material 76 is used for directly forming the nip. Thereby, the heat from the fixing belt 71 is not easily transferred to the supporting member 75 and deterioration of heating efficiency can be prevented. The heat insulating member 76 of the fixing member 74 can adopt the same structure as any structure of the heat insulating layers 17A to 17D described with the reference to
In this embodiment, a heat insulating layer is provided to each of the fixing member 74 functioning as a member for fixing and the pressure roller 32 functioning as a roller for fixing and the heat insulating layers adopt the same structure as any structure of the heat insulating layer 17A to 17D described with reference to
Next, a sixth embodiment of a fixing device of the present invention is described with reference to
A fixing device 90 illustrated in
The fixing roller 91 is a heat insulating roller and includes a metal core 94 and a heat insulating layer 97, an elastic layer 96, and a release layer 95 that are formed on the metal core 94. Thus, the heat from the fixing belt 93 is not easily transferred to the internal portion of the fixing roller 91. Thereby, unnecessary diffusion of the heat of the fixing belt 93 can be prevented, resulting in restraint of a fall in the temperature thereof. The heat insulating layer 97 can adopt the same structure as any structure of the heat insulating layer 17A to 17D described with reference to
In the fixing device 90 of this embodiment, the heat of the fixing belt 93 heated by the heating roller 92 is not easily transferred to the metal core of the fixing roller 91 because the fixing roller 91 has the heat insulating layer 97 Therefore, the fixing device 90 of this embodiment has good heating efficiency and can shorten the rise time. In addition, the number of members for use in the fixing device 90 is fewer than that of the fixing device 50 illustrated in
For a fixing device, there is also a toner offset problem other than the issues for the rise time and the temperature fall at the time of continuous paper feeding. Toner offset is a phenomenon in which toner on a recording medium is not fixed thereon and a portion of the unfixed toner is transferred to the fixing roller. This unfixed toner may remain on the fixing roller or is transferred back to a recording medium, resulting in deterioration of image quality. As countermeasures to this toner offset problem, there is provided a fixing device including a cleaning roller contacting a fixing roller and/or a pressure roller. A typical cleaning roller is poorer in releasability of its surface relative to that of the surface of a fixing roller and a pressure roller. Such a cleaning roller can scrape toner remaining on the surface of a fixing roller and a pressure roller by utilizing this difference in releasability. However, when such a cleaning roller is in contact with a fixing roller or a pressure roller, the cleaning roller deprives the fixing roller or the pressure roller of heat and thus the rise time becomes longer.
Therefore, the present inventors recognized the heat absorbed by a cleaning roller can be minimized by providing the same heat insulating layer as any layer of the heat insulating layers 17A to 17D described with reference to
In
Any material can be used for the surface layer of a cleaning roller as long as its releasability is poorer relative to that of the surface layer of a fixing roller or a pressure roller. Specific examples of such materials include metals such as aluminum and non-woven fabric.
The cleaning roller 100 illustrated here can also be provided to the fixing rollers or the pressure rollers in the fixing devices of each embodiment other than the fixing device 30 described with reference to
When each fixing device mentioned above was set in the image forming apparatus illustrated in
Next, another embodiment of an image forming apparatus of the present invention is described with reference to
The image forming apparatus illustrated in this
A fixing device 80 attached to the image forming apparatus of the present invention has the same structure as that of the fixing device 30 described with reference to
In the image forming apparatus having the structure mentioned above, an unfixed toner image overlapped on the intermediate transfer belt 85 from each photoreceptor 1, or an unfixed toner image on the intermediate transfer belt 85 from the photoreceptor 1K in the case of a monochrome print, is transferred onto the fixing roller 81 by the function of the opposing roller 88. The unfixed toner borne on the fixing roller 81 is conveyed by the rotation thereof to the fixing nip where the fixing roller 81 and the pressure roller 82 are in contact under pressure with each other and fixed onto a recording medium P upon application of heat and pressure.
The fixing roller 81 includes a metal core on which a heat insulating layer including a plurality of film layers having a thickness of, e.g., 0.5 mm are accumulated. On the heat insulating layer, a PFA tube having a thickness of, e.g., 15 μm is coated as a release layer.
In the fixing device 80 of this embodiment, unfixed toner transferred onto the fixing roller 81 is directly heated by a halogen heater 83, meaning that it is unnecessary to heat the members for fixing (i.e., the fixing roller 81 in this case) and the fixing device can be ready in action for operation instantly. The heat of the toner heated does not diffuse much to the metal core of the fixing roller by the effect of the heat insulating layer, meaning that the heat is conveyed efficiently.
In this embodiment, a heat insulating layer is provided to each of the fixing roller 81 and the pressure roller 82 functioning as a roller for fixing and the heat insulating layer adopts the same structure as any structure of the heat insulating layer 17A to 17D described with reference to
In
In this embodiment, a heat insulating layer is also provided to each of the fixing roller 81 and the pressure roller 82 to restrain the amount of heat reaching the metal core of both rollers, and thus the fixing belt 112 can be heated efficiently. The heat insulating layer can adopt the same structure as any structure of the heat insulating layers 17A to 17D described with reference to
Having now fully described the present invention with reference to the figures, it will be apparent to one of ordinary skill in the art that many changes and modifications can be made thereto without departing from the spirit and scope of the present invention as set forth therein. For example, in a fixing device having a suitable structure, the effect of the present invention can be obtained by providing the heat insulating layer described with reference to
This document claims priority and contains subject matter related to Japanese Patent Applications Nos. 2003-378196 and 2004-269840, filed on Nov. 7, 2003 and Sep. 16, 2004, respectively, the entire contents of each of which are hereby incorporated herein by reference.
Number | Date | Country | Kind |
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2003-378196 | Nov 2003 | JP | national |
2004-269840 | Sep 2004 | JP | national |
Number | Name | Date | Kind |
---|---|---|---|
3868744 | Thettu | Mar 1975 | A |
6122479 | Fujita et al. | Sep 2000 | A |
6501935 | Hirai et al. | Dec 2002 | B2 |
6542705 | Fujita et al. | Apr 2003 | B2 |
6559421 | Yura et al. | May 2003 | B1 |
6577817 | Harris | Jun 2003 | B2 |
6795678 | Yura et al. | Sep 2004 | B2 |
6871041 | Takagi et al. | Mar 2005 | B2 |
7006781 | Imai et al. | Feb 2006 | B2 |
Number | Date | Country |
---|---|---|
05-069515 | Mar 1993 | JP |
3069476 | Mar 2000 | JP |
2000-206815 | Jul 2000 | JP |
2000-275996 | Oct 2000 | JP |
2001-065544 | Mar 2001 | JP |
2001-343850 | Dec 2001 | JP |
2002-040855 | Feb 2002 | JP |
Number | Date | Country | |
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20050152721 A1 | Jul 2005 | US |