Patent Application
20240181745
This disclosure relates to a flat lightweight member (fiber reinforced plastics) including a skin layer on a surface and a core layer inside that can be used as a propeller blade, and a method of manufacturing the flat lightweight member. Specifically, the disclosure relates to a flat lightweight member made from a fiber reinforced resin that is favorable in appearance quality and also excellent in productivity while being excellent in mechanical property at the ends and adhesiveness between a core layer and a skin layer, and a method of manufacturing the flat lightweight member.
Fiber reinforced resins are used in a wide range of industrial fields because of having light weight, high strength, and high rigidity. In particular, molded articles are suitably used, which are obtained by using a prepreg that is an intermediate material where a fiber reinforced material made from long fibers such as reinforcing fibers is impregnated with a resin. In addition, a sandwich structure material that has a skin layer of a fiber reinforced resin and a porous core layer is, because of being lightweight and tough, effectively used in transportation facilities such as aircrafts, automobiles, and ships, and in the fields of sports and leisure. Known as fiber reinforced plastics that have such a sandwich structure are flat lightweight members that include: a skin layer including a fiber reinforced material; and a core layer including lightweight particles and a matrix resin. In this regard, the flat lightweight member refers to a structure that varies in periphery length and in cross-sectional shape in the longitudinal direction, and means a member that can be used mainly as a propeller blade.
Known as such a flat lightweight member is a propeller blade that has an upper surface prepreg and a lower surface prepreg stacked and bonded in the thickness direction at the ends. That flat lightweight member is obtained by stacking the upper surface prepreg and the lower surface prepreg respectively in one and the other split dies, and disposing a foaming agent in the space formed by the both prepregs when the dies are combined (for example, Japanese Patent Laid-open Publication No. 2020-151876).
In addition, known as a similar flat lightweight member is a flat lightweight member that has a main part composed of a skin layer, a core layer, and a separation layer, a peripheral edge (an outer peripheral part of the flat lightweight member, when the flat lightweight member is viewed from the direction in which the largest projected area is obtained) composed of a skin layer and a core layer, and reinforcing fibers for reinforcement additionally disposed at sites corresponding to a leading edge and a trailing edge when the flat lightweight member is used as a propeller blade. In that flat lightweight member, the separation layer that suppresses passage of lightweight particles is disposed between the core layer and the skin layer, and the separation layer separates the lightweight particles from the mixture of lightweight particles and matrix resin constituting the core layer, and causes a dry reinforcing fiber material constituting the skin layer to be impregnated with only the matrix resin, thereby forming the skin layer (for example, Japanese Patent Laid-open Publication No. 8-276441).
Furthermore, techniques of using a prepreg that has incisions provided in a regular distribution over the entire in-plane area, or a preform obtained by laminating the prepregs are known for obtaining the uniform dynamic characteristics and excellent dimensional stability of flat lightweight members (for example, JP Patent No. 5272418).
The flat lightweight member where the upper surface prepreg and the lower surface prepreg are stacked and bonded in the thickness direction at the ends as mentioned above, however, requires a region for stacking and bonding the both prepregs at the ends. Thus, the flat lightweight member creates a need to dispose a prepreg that has a high specific gravity even for a region that should be originally formed from a lightweight core layer, and has the problem of increasing the weight of the flat lightweight member. In addition, for the same reason, the shapes of flat lightweight members to which such a configuration can be applied may be limited in some instances. Moreover, the employment of a structure with ends of prepregs simply butted with each other has the problem of decreasing the joint strength, and causing lightweight particles and a matrix resin that form the core layer to leak to the outside of the flat lightweight member, thereby impairing the appearance quality.
In addition, the conventional flat lightweight member where the main part is composed of the skin layer, the core layer, and the separation layer, the peripheral edge is composed of the skin layer and the core layer, and reinforcing fibers for reinforcement are further disposed at sites corresponding to the leading edge and the trailing edge as mentioned above possibly causes peeling in the vicinity of the separation layer when the member is used over a long period of time, and has the problem of failing to integrate the core layer and the skin layer firmly, if the position of the separation layer disposed is not appropriate.
Furthermore, the conventional method of manufacturing a flat lightweight member, stacking the upper surface prepreg and the lower surface prepreg respectively in one and the other split dies, and disposing the foaming agent in the space formed by the both prepregs when the dies are combined, requires heating the dies to cure the prepregs after stacking the prepregs on the surface of the dies that have three-dimensional shapes at room temperature, and requires not only a huge amount of labor and a special technique and device for the stacking step, but also a large amount of time for raising and lowering the temperatures of the dies, and thus has a problem with productivity.
In addition, the conventional method of manufacturing the flat lightweight member, in which the skin layer is formed by allowing a portion of the matrix resin for constituting the core layer to pass through the separation layer and then impregnating and curing the dry reinforcing fiber material, has difficulty in obtaining a flat lightweight member with high accuracy and small variations because individually disposed upper and lower separation layers are displaced or deviated at the time of molding when the flat lightweight member has a three-dimensional shape instead of a simple flat-plate shape. In addition, positioning is difficult in disposing the reinforcing fibers for reinforcement, and the reinforcing fibers are also likely to be displaced during fiber reinforced resin molding, and thus, the center of gravity of the flat lightweight member may be changed in some instances. Furthermore, in the process of impregnating the reinforcing fibers with the matrix resin, air bubbles referred to as voids are generated at the ends, and may degrade the mechanical property or impair the appearance quality in some instances.
As described above, such conventional technique as mentioned above have extreme difficulty in providing a flat lightweight member excellent in mechanical property at the ends and adhesiveness between a core layer and a skin layer, and is favorable in appearance quality.
Accordingly, it could be helpful to provide a flat lightweight member that is favorable in appearance quality and also excellent in productivity while being excellent in mechanical property at the ends and adhesiveness between a core layer and a skin layer, and a method of manufacturing the flat lightweight member.
We thus provide:
(1) A flat lightweight member including: skin layers disposed on both surfaces of the flat lightweight member; an end reinforcing layer disposed to have contact with both inner surfaces of the skin layers on the both surfaces at an end of the flat lightweight member; and a core layer disposed in a space surrounded by the skin layers and the end reinforcing layer to have direct contact with the inner surfaces of the skin layers, characterized in that the skin layer includes one or more layers including reinforcing fibers aligned in one direction and a first matrix resin, the end reinforcing layer includes a fiber reinforced resin sheet, and the core layer includes thermally expandable particles and a second matrix resin.
(2) The flat lightweight member according to (1), characterized in that the fiber reinforced resin sheet includes reinforcing fibers aligned in one direction and a first matrix resin.
(3) The flat lightweight member according to (1), characterized in that the fiber reinforced resin sheet is a fiber reinforced foam including reinforcing fibers.
(4) The flat lightweight member according to any one of (1) to (3), characterized in that the reinforcing fibers raised from the skin layers are in the core layer.
(5) The flat lightweight member according to any one of (1) to (4), characterized in that the reinforcing fibers raised from the end reinforcing layer are in the core layer.
(6) The flat lightweight member according to any one of (1) to (5), characterized in that the space surrounded by the skin layers and the end reinforcing layer is a closed space.
(7) The flat lightweight member according to any one of (1) to (6), characterized in that in the end reinforcing layer, the fiber reinforced resin sheet has a wound structure or a folded structure.
(8) A method of manufacturing a flat lightweight member with the use of a double-sided die including an upper die and a lower die, the method characterized by including:
(9) A method of manufacturing a flat lightweight member with the use of a double-sided die including an upper die and a lower die, the method characterized by including:
(10) The method of manufacturing a flat lightweight member according to (8) or (9), characterized in that the reinforcing fiber resin sheet is a prepreg including reinforcing fibers aligned in one direction and a first matrix resin.
(11) The method of manufacturing a flat lightweight member according to (8) or (9), characterized in that the reinforcing fiber resin sheet is a fiber reinforced foam including reinforcing fibers.
(12) The method of manufacturing a flat lightweight member according to any one of (8) to (11), characterized in that an incised prepreg is used as the prepreg.
(13) The method of manufacturing a flat lightweight member according to any one of (8) to (12), characterized in that a site of at least the one skin layer corresponding to an inner surface of the flat lightweight member is raised before completing the die closing step.
(14) The method of manufacturing a flat lightweight member according to any one of (8) to (13), characterized in that a site of the end reinforcing layer corresponding to an inner surface of the flat lightweight member is raised before completing the die closing step.
Our flat lightweight members and methods of manufacturing the flat lightweight members can provide a flat lightweight member favorable in appearance quality and also excellent in productivity while being excellent in mechanical property at the ends and adhesiveness between a core layer and a skin layer.
1: Flat lightweight member
21, 22, 23: Skin layer
200: Raised reinforcing fibers of skin layer
30: Core layer
300: Fiber reinforced part of core layer partially including raised reinforcing fibers of skin layer
40, 41: End reinforcing layer
50: Closed space
500: Outline of closed space
81: Upper die
82: Lower die
90: Mixture
Hereinafter, our members and methods will be described in detail with reference to the drawings together with examples.
Our flat lightweight member includes: skin layers disposed on both surfaces, end reinforcing layers disposed to have contact with both inner surfaces of the skin layers on the both surfaces at the ends of the flat lightweight member; and a core layer disposed in the space surrounded by the skin layers and the end reinforcing layers to have direct contact with the inner surfaces of the skin layers. The skin layer is formed with the use of one or more prepregs including reinforcing fibers aligned in one direction and a first matrix resin, and includes one or more layers including the reinforcing fibers and the first matrix resin. In addition, the end reinforcing layer includes a fiber reinforced resin sheet, and the core layer includes thermally expandable particles as lightweight particles and a second matrix resin.
The skin layer is formed mainly with the use of a prepreg including reinforcing fibers aligned in one direction and a first matrix resin, and includes one or more layers containing the reinforcing fibers and the first matrix resin.
In this regard, the inner surface of the skin layer is a surface of the skin layer, located on the inner surface side of the flat lightweight member. The “surface” means the outer surface of the flat lightweight member, unless otherwise noted.
The thickest part of the skin layer constituting one surface of the flat lightweight member is preferably formed from two or more layers of prepregs, and more preferably has four or more layers of prepregs. More specifically, the part preferably has two or more layers, more preferably four or more layers including the reinforcing fibers and the first matrix resin.
The thickness of the skin layer is preferably 0.1 mm or more and 10 mm or less, more preferably 0.2 mm or more and 5 mm or less, still more preferably 0.4 mm or more and 2 mm or less. The thickness falls within the preferred range mentioned above, thereby making it easy to transfer heat uniformly even to the inside of the laminate at the time of molding, and thus providing a flat lightweight member that is excellent in appearance.
The skin layer is also preferably formed with the use of a prepreg that has two or more orientation directions, more preferably a prepreg that has three or more orientation directions. Thus, the skin layer has two or more, more preferably three or more orientation directions. Such a prepreg is obtained by preparing multiple prepregs that have reinforcing fibers aligned in one direction, and laminating the prepregs such that the orientation directions of the reinforcing fibers are shifted. When the longitudinal direction of the flat lightweight member is regarded as a 0 degree direction, for example, examples of preferred aspects of the laminated configuration include a laminated configuration including two types of 0 degrees and 90 degrees, a laminated configuration including three types of 0 degrees and ±45 degrees, a laminated configuration including three types of 0 degrees and ±30 degrees, and a laminated configuration including four types of 0 degrees, ±45 degrees, and 90 degrees.
In addition, from the viewpoint of achieving a balance between impact property and rigidity, it is preferable for the skin layer to use one or more unidirectional prepregs that are prepregs with reinforcing fibers aligned in one direction, and further use one or more woven fabric prepregs that are prepregs with continuous fibers woven. In particular, it is preferred that a woven fabric prepreg is disposed on the outermost surface of the flat lightweight member, whereas a unidirectional prepreg is disposed inside the woven fabric prepreg such that the fiber direction corresponds to the longitudinal direction of the flat lightweight member, thereby providing a flat lightweight member including a skin layer with a woven fabric substrate of reinforcing fibers at the outermost surface and with reinforcing fibers arranged in one direction inside. Such a configuration allows, when the flat lightweight member is used as a propeller blade, the reinforcing fibers derived from unidirectional prepreg to take charge of tensile stress applied in the longitudinal direction of the flat lightweight member, while the woven fabric substrate derived from the woven fabric prepreg keeps the flat lightweight member from being broken by the collision of a flying object.
The end reinforcing layer is disposed at peripheral edges of the flat lightweight member. The peripheral edge of the flat lightweight member means a peripheral part, when the flat lightweight member is projected from above (that is, an outer peripheral part of the flat lightweight member, when the flat lightweight member is viewed from the direction in which the largest projected area is obtained). In addition, the inner surface of the end reinforcing layer is a surface of the end reinforcing layer, located on the inner surface side of the flat lightweight member.
The end reinforcing layer includes a fiber reinforced resin sheet.
The fiber reinforced resin sheet preferably includes a prepreg including reinforcing fibers aligned in one direction and a first matrix resin. The fiber reinforced resin sheet preferably includes two or more layers of prepregs, and more preferably four or more layers of prepregs. Such a fiber reinforced resin sheet causes the end reinforcing layer to include one or more layers including the reinforcing fibers aligned in one direction and the first matrix resin.
In contrast, the fiber reinforced resin sheet of the end reinforcing layer is also preferably a fiber reinforced foam (porous body) including reinforcing fibers. Examples of such a fiber reinforced foam can include a sandwich structure (for example, described in WO 14/162873 A) and a nonwoven fabric (for example, described in Japanese Patent Laid-open Publication No. 2014-172201) where one surface is impregnated with a thermoplastic resin, and reinforcing fibers are exposed from the other surface.
Depending on the dimensions of the flat lightweight member, in a cross section orthogonal to the outline direction of the peripheral edge, the cross-sectional area of the end reinforcing layer is preferably 1 mm2 or more and 1200 mm2 or less, more preferably 5 mm2 or more and 500 mm2 or less. Setting the thickness to have such a cross-sectional area makes it easy to transfer heat uniformly even to the inside of the laminate (that is, over the overall thickness of the end reinforcing layer), and thus provides a flat lightweight member that is excellent in appearance.
The end reinforcing layer preferably has a fiber orientation in a direction along the outline of the peripheral edge. For example, after preparing an elongated laminate that has reinforcing fibers oriented in the longitudinal direction with the use of the fiber reinforced resin sheet, the laminate is disposed along the outline of the peripheral edge of the flat lightweight member as desired, thereby allowing the fiber orientation in the direction along the outline of the peripheral edge of the flat lightweight member.
The core layer has direct contact with the skin layer, unlike a conventional flat lightweight member including a separation layer between a skin layer and a core layer. The employment of such a configuration allows the core layer and the skin layer to be firmly integrated, thus making peeling less likely to be caused in the vicinity of the separation layer even in use over a long period of time.
The core layer is formed from a lightweight resin and a second matrix resin. The ratio by weight between the lightweight particles (thermally expandable particles) and the second matrix in the core layer preferably is 5% or more and 100% or less, more preferably 10% or more and 40% or less, when the weight of the second matrix resin is regarded as 100%. When the weight of the lightweight particles is 5% or more, the reduced specific gravity of the core layer makes a lightweight property more likely to be exhibited. In addition, when the weight is 10% or more, the partial “resin rich” can be reduced, which is generated by the second matrix resin separated from the lightweight particles, and thus, the core layer has a more homogeneous structure, thereby allowing variations in the center of gravity to be reduced. In contrast, when the weight is 100% or less, the second matrix resin can be made present between the lightweight particles to crosslink the lightweight particles with each other, thereby making the core layer rigid and then maintaining the shape thereof. When the weight average molecular weight is more than 100%, crosslinking between the lightweight particles becomes insufficient so that the core layer becomes brittle and the shape easily collapses. Furthermore, when the weight is 40% or less, the periphery of the lightweight particles can be covered with the second matrix resin, thus, the generation of cracks in the core layer is suppressed, and the mechanical property of the core layer can be kept favorable over a long period of time.
The fiber reinforced resin sheet mainly includes reinforcing fibers and a first matrix resin.
The reinforcing fibers of the fiber reinforced resin sheet may be continuous fibers or discontinuous fibers. The form of the fiber reinforced resin sheet is not particularly limited, but from the viewpoint of mechanical property, it is preferable to use a prepreg as the fiber reinforced resin sheet. In addition, from the viewpoint of lightweight property, it is preferable to use a fiber reinforced resin foam as the fiber reinforced resin sheet.
The prepreg mainly includes reinforcing fibers and a first matrix resin.
The reinforcing-fiber volume fraction preferred for the prepreg is preferably 40% or more and 80% or less, more preferably 45% or more and 75% or less, still more preferably 50% or more and 70% or less.
The amount of the reinforcing fibers included in the prepreg is preferably 50 g/m2 or more and 1000 g/m2 or less in terms of the basis weight of the reinforcing fiber in a sheet-shaped material. If the basis weight is excessively small, holes without reinforcing fibers therein may be produced in the surface of the prepreg. The basis weight is equal to or more than the lower limit of the above-mentioned preferred range, thereby allowing the elimination of holes that are breaking origins. In addition, the basis weight is equal to or less than the upper limit of the above- mentioned preferred range, thereby allowing heat to be transferred uniformly to the inside in preheating for molding. The basis weight is more preferably 100 g/m2 or more and 600 g/m2 or less, still more preferably 150 g/m2 or more and 400 g/m2 or less for achieving a balance between the uniformity of the structure and the uniformity of the heat transfer.
The basis weight of the reinforcing fibers is measured by cutting out a 10-cm square region from a sheet-shaped material of the reinforcing fibers, measuring the mass of the cut region, and dividing the mass by the area of the region. The measurement is performed ten times at different sites of the sheet-shaped material of the reinforcing fiber, and the average of the measured values is employed as the basis weight of the reinforcing fibers.
Examples of the reinforcing fibers for use in the fiber reinforced resin sheet, the prepreg, and the fiber reinforced foam include organic fibers such as aramid fibers, polyethylene fibers, and polyparaphenylene benzoxazole (PBO) fibers; inorganic fibers such as glass fibers, carbon fibers, silicon carbide fibers, alumina fibers, tyranno fibers, basalt fibers, and ceramic fibers; metal fibers such as stainless steel fibers and steel fibers; and boron fibers, natural fibers, and modified natural fibers. In particular, the carbon fibers are lightweight among these reinforcing fibers, moreover have particularly excellent properties in specific strength and specific modulus, and are also excellent in heat resistance and chemical resistance, and thus are suitable for members such as automobile panels and blades for aircraft propulsion devices for which weight reduction is desired. In particular, PAN based carbon fibers from which high-strength carbon fibers are easily obtained are preferred.
The first matrix resin and the second matrix resin are cured in the flat lightweight member.
Examples of the first matrix resin for use in the prepreg include thermosetting resins such as epoxy resins, unsaturated polyester resins, vinyl ester resins, phenol resins, epoxy acrylate resins, urethane acrylate resins, phenoxy resins, alkyd resins, urethane resins, maleimide resins, and cyanate resins; and thermoplastic resins such as polyamide resins, polyacetal resins, polyacrylate resins, polysulfone resins, acrylic butadiene styrene (ABS) resins, polyester resins, acrylic resins, polybutylene terephthalate (PBT) resins, polyethylene terephthalate (PET) resins, polyethylene resins, polypropylene resins, polyphenylene sulfide (PPS) resins, polyether ether ketone (PEEK) resins, liquid crystal polymers, vinyl chloride, fluorine-based resins such as polytetrafluoroethylene, and silicones. It is preferable to use the thermosetting resins, in particular. The first matrix resin is a thermosetting resin, thereby causing the prepreg to have tackiness at room temperature, and thus even when the skin layer is composed of multiple prepregs, the layers are integrated by adhesion, and can be molded while maintaining the intended laminated configuration.
Examples of the second matrix resin for use in the core layer include thermosetting resins such as epoxy resins, unsaturated polyester resins, vinyl ester resins, phenol resins, epoxy acrylate resins, urethane acrylate resins, phenoxy resins, alkyd resins, urethane resins, maleimide resins, and cyanate resins; and thermoplastic resins such as polyamide resins, polyacetal resins, polyacrylate resins, polysulfone resins, acrylic butadiene styrene (ABS) resins, polyester resins, acrylic resins, polybutylene terephthalate (PBT) resins, polyethylene terephthalate (PET) resins, polyethylene resins, polypropylene resins, polyphenylene sulfide (PPS) resins, polyether ether ketone (PEEK) resins, liquid crystal polymers, vinyl chloride, fluorine-based resins such as polytetrafluoroethylene, and silicones. In addition, it is preferable to use the thermosetting resins, in particular. The second matrix resin is a thermosetting resin, thereby causing the cured matrix resin to cover the periphery of the lightweight particles of the core layer to form a porous structure, and thus, even when heat is applied to the flat lightweight member, the core layer can be prevented from being deformed or expanded.
In the first matrix resin and the second matrix resin, the glass transition temperature of the first matrix resin is preferably higher than the glass transition temperature of the second matrix resin.
The lightweight particles in the flat lightweight member mean thermally expandable resin particles that cause a volume expansion with increase in temperature by heating at the time of molding, and thermally expandable particles that are already thermally expanded but can be compressed by pressurization.
The thermally expandable particles causes a volume expansion when the particles are mixed with the second matrix resin and heated, and when the second matrix resin is a thermosetting resin, the thermosetting resin is subjected to curing to form a core layer that has a lightweight porous structure. Alternatively, when the second matrix resin is a thermoplastic resin, the molten thermoplastic resin is solidified at the time of cooling, or the softened thermoplastic resin is bound to form a core layer that has a lightweight porous structure.
The volume expansion coefficient α (%) of the mixture of the thermally expandable particles and the second matrix resin is expressed by formula (1), where the volume of the mixture before being expanded is denoted by V1 (cm3), and the volume thereof after being expanded is denoted by V2 (cm3).
α=100×(V2−V1)÷V1 (1)
In the core layer, the volume expansion coefficient α preferably is 30% or more and 2000% or less, although the volume expansion coefficient α varies depending on the ratio by weight between the thermally expandable particles and the second matrix resin and the heating conditions at the time of molding.
Examples of the thermally expandable particles include a polyacrylonitrile-based copolymer, a polymethacrylonitrile-based copolymer, a polyvinylidene chloride-based copolymer, a polystyrene or polystyrene-based copolymer, a polyolefin, and a polyphenylene oxide-based copolymer, and the thermally expandable particles are preferably capsule-shaped particles including therein a thermally expandable gas. In particular, thermally expandable particles that have a hydrocarbon with a low boiling point as a thermally expandable gas are preferred, because the thermally expandable particles are large in volume expansion coefficient and capable of forming a lightweight core layer.
The sizes of the thermally expandable particles are preferably adapted such that the average particle diameter before undergoing the volume expansion is 1 μm to 1 mm. Setting the average particle diameter to be 1 μm or more allows the thermally expandable particles to be kept from leaking out to the surface of the flat lightweight member due to resin flow at the time of molding. In addition, setting the diameter to be 1 mm or less causes the thermally expandable particles to enter even the thin part of the core layer, thus allowing the core layer to be made lightweight, and allowing the density unevenness of the thermally expandable particles and second matrix resin in the core layer to be reduced.
Examples of such thermally expandable particles include “MATSUMOTO MICROSPHERE” (registered trademark) manufactured by Matsumoto Yushi-Seiyaku Co., Ltd., “EXPANCEL” (registered trademark) manufactured by Nobel Corporation, and “ESLEN Beads” manufactured by SEKISUI CHEMICAL CO., LTD., but this disclosure is not to be considered limited to these products.
As the lightweight particles, only one type of thermally expandable particles may be used, or multiple types of thermally expandable particles may be used in mixture. In addition, the thermally expandable particles may be used alone, or may be used in mixture with particles that are not thermally expanded such as glass beads.
In the flat lightweight member, the reinforcing fibers raised from the skin layer are preferably in the core layer.
In this regard, the state of the reinforcing fibers raised means a state with one or more reinforcing fibers protruding in an out-of-plane direction from the surface (the surface with the largest surface area) of the fiber reinforced resin sheet, prepreg, or fiber reinforced foam. The lower limit of the lengths of the protruding reinforcing fibers is preferably 0.1 mm or more, more preferably 0.5 mm or more, still more preferably 1 mm or more. If the lengths fall below the lower limit, there is concern that the reinforcing fibers entered into the core layer may come off. In addition, the upper limit of the lengths of the protruding reinforcing fibers is preferably 100 mm or less, more preferably 50 mm or less, still more preferably 10 mm or less. If the lengths exceed the upper limit, there is a possibility that the reinforcing fibers may be broken at the time of raising. In this regard, the length of the raised reinforcing fiber is determined by embedding and polishing a region including a boundary part between the skin layer and the core layer as in
In addition, in the flat lightweight member, the reinforcing fibers raised from the end reinforcing layer are preferably in the core layer.
The raised reinforcing fibers are continuously connected from the end reinforcing layer to the core layer, and the employment of such a configuration allows the adhesion between the end reinforcing layer and the core layer to be strengthened.
The method of raising the reinforcing fibers as described above will be described later.
In the flat lightweight member, the space surrounded by the skin layer and the end reinforcing layer is preferably a closed space. More specifically, the periphery of the core layer is preferably covered with the skin layer and the end reinforcing layer.
For the flat lightweight member, the end reinforcing layer is preferably disposed on the entire peripheral edge. The employment of such a configuration improves the mechanical property at the ends of the flat lightweight member, and allows the lightweight particles and second matrix that form the core layer to be kept from leaking to the surface of the flat lightweight member.
The flat lightweight member preferably has a form with the core layer including the reinforcing fibers raised from the skin layers or the end reinforcing layers, as mentioned above. To obtain such a form, it is preferable to use an incised prepreg as at least a part of the prepreg used to constitute the skin layer or the end reinforcing layer. In particular, the form is suitable when the flat lightweight member has variations in thickness or a complicated three-dimensional shape.
The incised prepreg is a prepreg that has incisions regularly distributed over the entire in-plane area, and continuous reinforcing fibers constituting the prepreg are cut at sites with the incisions present. Such regularly distributed incisions can be provided, for example, by the method described in JP Patent No. 5272418 described above.
The incised prepreg can be used for the skin layers or the end reinforcing layers in combination with a normal prepreg that merely has continuous fibers for the reinforcing fibers and has no incision.
Such an incised prepreg makes incised sites more likely to have openings or deviations generated, and improves the stretchability of the prepreg in the reinforcing fiber direction. In addition, the flow at the time of compression molding opens the incised sites to separate the fiber strands of the reinforcing fibers from each other, thereby causing the prepreg to exhibit flexibility and improving the fluidity. Employing a configuration such that the prepreg can flow in this manner causes the reinforcing fibers to reach even the ends to reduce the region where the resin is excessive, thereby allowing a flat lightweight member that is excellent in mechanical property and appearance to be obtained. From the viewpoint of fluidity, incisions are preferably made over the entire area in the thickness direction of the prepreg.
The use of the incised prepreg for the skin layer is preferred, because the reinforcing fibers are likely to be raised, and can be in the core layer to form a strong adhesive surface. In addition, the use allows the ends of the raised reinforcing fibers to be in the core layer, thus allowing the raised reinforcing fibers to be deep in the core layer, and allowing the adhesion between the core layer and the skin layer to be enhanced.
As the skin layer, an integrated laminate of a non-incised prepreg and an incised prepreg may be used. In this example, it is preferable to dispose the incised prepreg at the surface of contact with the core layer. Such an aspect is a preferred aspect in which the incised prepreg allows the adhesion between the core layer and the skin layer to be strengthened, while the non- incised prepreg exhibits an excellent mechanical property.
The use of the incised prepreg for the end reinforcing layer is preferred in that tightness in the fiber directions can be suppressed, when the end reinforcing layer is pressed against the end outline of the flat lightweight member and then deformed with the expansion of the core layer, thus suppressing the “resin rich” and the generation of voids, and easily improving the appearance quality and mechanical property at the ends. The fiber directions of the reinforcing fibers in the end reinforcing layer are preferably directions along the end outline of the flat lightweight member.
For the flat lightweight member, the fiber reinforced resin sheet preferably has a wound structure or a folded structure in the end reinforcing layer.
Our method of manufacturing the flat lightweight member is a method of manufacturing a flat lightweight member with the use of a double-sided die including an upper die and a lower die, the method characterized by including: a preparing step of preparing one skin layer and the other skin layer with the use of a prepreg including reinforcing fibers aligned in one direction and a first matrix resin, and preparing an end reinforcing layer with the use of a fiber reinforced resin sheet; a first disposing step of disposing the one skin layer in the lower die heated to a molding temperature, and placing the end reinforcing layer on at least a part of a peripheral edge of the one skin layer; an introducing step of placing a mixture of lightweight particles (thermally expandable particles) and a second matrix resin on the inner surface of the one skin layer (the inner-side surface of the skin layer, in flat lightweight member finally obtained); a second disposing step of further disposing the other skin layer on the upper surface of the one skin layer, and then bringing the end reinforcing layer into contact with at least a part of a peripheral edge of the other skin layer; and a die closing step of closing the upper die heated to the molding temperature, and further including a step of expanding the volume of the lightweight particles to form a core layer.
The skin layers 21 and 22 can be prepared, for example, by cutting, from a sheet-shaped prepreg, cut prepregs that have a desired shape and a desired fiber orientation, and then laminating the cut prepregs, if necessary. In addition, for example, sheet-shaped prepregs can be laminated in a desired fiber orientation, and then cut into a desired shape to prepare the skin layers.
The end reinforcing layers can be prepared, for example, by laminating fiber reinforced resin sheets until reaching a predetermined thickness and then cutting the laminate into a predetermined width, or can be prepared as elongated strip-shaped members by pultrusion molding or extrusion molding.
When the end reinforcing layer has a wound structure, the end reinforcing layer is obtained by, for example, preparation of winding one fiber reinforced resin sheet in order from the end. Furthermore, for example, one fiber reinforced resin sheet can be also folded and then wound to prepare the end reinforcing layer. In addition, also from a plurality of fiber reinforced resin sheets laminated, a wound structure can be obtained in accordance with the same procedure.
When the end reinforcing layer has a folded structure, for example, one fiber reinforced resin sheet is folded in two or three, and the folded fiber reinforced resin sheet is further folded to prepare the end reinforcing layer. Furthermore, for example, a thin wound structure that has a flat cross-sectional shape can be prepared from one fiber reinforced resin sheet, and then folded to prepare the end reinforcing layer. In addition, also from a plurality of fiber reinforced resin sheets laminated, a folded structure can be obtained in accordance with the same procedure.
When using a prepreg as the fiber reinforced sheet, the prepreg can be prepared by laminating a sheet-shaped prepreg cut into an elongated form, or a tape-shaped prepreg slit tape. When using a fiber reinforced foam as the fiber reinforced sheet, the fiber reinforced foam can be prepared by cutting a sheet-shaped fiber reinforced foam into an elongated form.
Next,
In the first disposing step, the one skin layer may be disposed in the planar form in the lower die, or may be shaped into a three-dimensional shape in advance and then disposed in the lower die. In addition, the linear end reinforcing layer may be disposed while being bent along the peripheral edge of the one skin layer, or may be bent in advance along the shape of the peripheral edge and disposed. In particular, when using a thermosetting resin as the first matrix resin, the skin layer and the end reinforcing layers are integrated by the tackiness of the prepreg, thus facilitating the positioning of the end reinforcing layers, which is preferred.
Subsequently,
In the introducing step, the mixture of lightweight particles and second matrix resin is preferably preheated. The use of such a method decreases the viscosity of the mixture of the lightweight particles and second matrix resin, thus allowing the charging time to be shortened and facilitating the introducing amount. The mixture of the lightweight particles and second matrix resin can be preheated with the use of an oven or a microwave oven.
Furthermore,
As shown in
Our method of manufacturing the flat lightweight member is a method of manufacturing a flat lightweight member with the use of a double-sided die including an upper die and a lower die, the method characterized by including: a preparing step of preparing a skin layer with an end reinforcing layer, where the end reinforcing layer is bonded to a peripheral edge of one skin layer, and the other skin layer, with the use of a prepreg including reinforcing fibers aligned in one direction and a first matrix resin; a first disposing step of disposing the skin layer with the end reinforcing layer in the lower die heated to a molding temperature; an introducing step of placing a mixture of lightweight particles and a second matrix resin the inner surface of the one skin layer; and a second disposing step of further disposing the other skin layer in the lower die to bring the end reinforcing layer into contact with the peripheral edge of the one skin layer; and a die closing step of closing the upper die heated to the molding temperature, and further expanding the volume of the lightweight particles to form a core layer.
The skin layers and the end reinforcing layers can each be prepared by the method described above. The skin layer with the end reinforcing layers can be produced by bonding the end reinforcing layers to the peripheral edge of the one skin layer. When a thermosetting resin is used as the first matrix resin, the skin layer and the end reinforcing layers can be bonded to each other by the tackiness of the prepreg. Alternatively, when a thermoplastic resin is used as the first matrix resin, the end reinforcing layers and the one skin layer can be heated to the melting temperature of the thermoplastic resin, pressed, and cooled to bond the end reinforcing layers and the one skin layer to each other. In addition, the end reinforcing layers can be bonded to the one skin layer with the use of a resin adhesive or a resin adhesive film.
Further,
In the method of manufacturing a flat lightweight member, an incised prepreg is preferably used as the prepreg. The use of the incised prepreg for the skin layer is preferred, because the reinforcing fibers are likely to be raised, and the raised reinforcing fibers can be deep in the core layer to form a strong adhesive surface. As the skin layer, an integrated laminate of a non-incised prepreg and an incised prepreg may be used. In this example, it is preferable to dispose the incised prepreg on the side close to the surface of contact with the core layer. Such an aspect is a preferred aspect, because the incised prepreg allows the adhesion between the core layer and the skin layer to be strengthened, while the non-incised prepreg exhibits an excellent mechanical property.
The use of the incised prepreg for the end reinforcing layer is preferred in that tightness in the fiber directions can be suppressed, when the end reinforcing layer is pressed against the end outline of the flat lightweight member and then deformed with the expansion of the core layer, thus suppressing the “resin rich” and the generation of voids, and allowing improvements in the appearance quality and mechanical property at the ends. The fiber directions of the reinforcing fibers in the end reinforcing layer are preferably directions along the end outline of the flat lightweight member.
In the method of manufacturing a flat lightweight member, it is preferable to raise the inner surface of at least one skin layer before the completion of the die closing step. In particular, in the introducing step, raising the reinforcing fibers at the inner surface of at least one skin layer is a preferred aspect. The reinforcing fibers at the inner surface of the one skin layer can be raised by introducing the mixture of the lightweight particles and second matrix resin with the use of a spatula or the like to be applied to the entire inner surface of the skin layer. In addition, the reinforcing fibers at the inner surface of the one skin layer can be raised by applying the mixture of the lightweight particles and second matrix resin while allowing the mixture to flow from a higher part of the skin layer to a low part thereof by gravity. Preheating the mixture of the lightweight particles and second matrix resin is preferred because the flow by gravity can be effectively utilized. The preheating temperature depends on the molding temperature and the expansion start temperature of the lightweight particles, and is preferably 40° ° C.or higher and 180° C. or lower, more preferably 70° C. or higher and 130° C. or lower. Setting the preheating temperature to be equal to or higher than the lower limit of the preferred range decreases the viscosity of the second matrix resin to allow the resin to flow, whereas setting the temperature to be equal to or lower than the upper limit suppresses the thermal expansion of the lightweight particles, thus allowing the resin to be applied over a sufficient period of time in the introducing step.
In the method of manufacturing a flat lightweight member, it is preferable to raise the reinforcing fibers at the inner surfaces of the end reinforcing layers before the completion of the die closing step. In particular, when a fiber reinforced foam is used as the end reinforcing layers, the fiber reinforced foam is heated in the die, thereby causing the reinforcing fibers included in the fiber reinforced foam to spring back to raise the reinforcing fibers, and the reinforcing fibers are in the core layer, thereby firmly integrating the core layer and the end reinforcing layers.
Our method of manufacturing a flat lightweight member can be applied to the manufacture of any flat lightweight member, and the obtained flat lightweight member is suitably used as a propeller blade structure, for example, in a transportation facility such as an aircraft, an automobile, or a ship, or in the field of sports or leisure.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2021-056515 | Mar 2021 | JP | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/JP2022/007537 | 2/24/2022 | WO |
