Patent Application
20180204687
This invention relates generally to electrodes, and more particularly to supercapacitor electrodes.
As the world population is increasing, the number of vehicles is expected to increase from 1.2 billion to 2 billion by 2035. This results in the production of nearly 1.5 billion tires per year, which inevitably turn into waste. These discarded tires pose serious environmental and health issues such as: 1) piles of the waste tires generate vermin and insect infestation, which pose a severe health issue; 2) if piles of waste tires catch fire, it is hard to extinguish and moreover burning tires generate hazardous gases, heavy metals and oil which severely contaminate soil, environment and groundwater; and 3) waste tires require large landfills and increasing number of discarded tires may lead to landfill maintenance issues.
Owing to their cross-linked structure and presence of various additives, waste tires do not decompose easily and resist degradation in most of the chemically and physically harsh conditions. As a result, they are generally disposed of and accumulate in landfills, which is an unsustainable solution. The best solution economically and ecologically would be to recycle waste tires and use them as a raw material for value-added products. A typical tire contains natural rubber and polybutadiene, styrene butadiene rubber, butyl rubber and fractional amounts of organic and inorganic fillers/additives. Carbon black is the major constituent of the tire (˜30-35% by weight), which provides an avenue to recover this carbon for energy related applications. A method of recovering carbon black from waste tires is disclosed in U.S. patent application Ser. No. 13/945,239, “Pyrolytic Carbon Black Composite and Method of Making the Same,” filed Jul. 18, 2013, the disclosure of which is incorporated fully by reference.
In spite of the significant efforts to develop carbon-based materials for supercapacitors, such as reduced graphene oxide (rGO), multiwall carbon nanotubes (MWCNT), carbide derived carbons (CDC), and onion-like carbons (OLC), activated carbon (AC) still remains the material of choice for commercial supercapacitors due to its moderate cost, high specific surface area (SSA), good conductivity, high electrochemical performance and compatibility with other materials, for example, conducting polymers. Therefore, inexpensive synthesis of AC with developed porosity using biomass, waste products or other low cost and environmentally benign precursors has been explored for the development of next generation supercapacitor technology.
Towards this goal, synthesis of the AC from biomass and waste products has gained significant interest recently. For example, Wang et al produced high surface area (up to 2287 m2/g) nanosheets from hemp bast fibers, which demonstrated high charge storage capacity of 106 F/g at 0° C., at current density of 10 A/g in ionic liquids. Elmira et al. derived low surface area carbon from banana peels. When tested as a lithium-ion battery anode, the recovered carbon showed high gravimetric capacity of 1090 mAh/g at 50 mA/g. Jian et al. reported the recovery of carbon fibers from disposable bamboo chopsticks, which have abundant natural cellulose fibers. These carbon fibers in combination with manganese oxide yielded a capacity of 710 mAh/g for 300 cycles, when tested as lithium-ion battery anode. Li-Feng et al. pyrolyzed nitrogen doped bacterial cellulose to synthesize nitrogen rich carbon, which demonstrated 195 F/g capacitance at 1 A/g. Mandakini et al. pyrolyzed dead leaves to recover carbon (SSA 1230 m2/g), which yielded 88 F/g capacitance in organic electrolytes. Ping et al. used plant derived nitrogen rich carbon as a catalyst for the oxygen reduction reaction. Wenjing et al. derived heteroatom doped porous carbon by carbonizing human hairs, which exhibited a capacitance of 340 F/g at a current density of 1 A/g. Jia et al. synthesized carbon from the peanut shell for sodium-ion capacitor with a high rate capability of 72% after 10,000 cycles. Other waste materials used as carbon source include agricultural waste, rice husk, newspapers, wood and coffee.
A major limitation of AC materials is their poor energy density. To enhance the energy density, various approaches have been explored such as use of the pseudocapacitive materials (e.g., metal oxides or organic redox polymers) on conductive substrates, use of asymmetric configuration with expanded voltage windows, among others. Organic redox polymers, such as polyaniline (PANI), are promising pseudocapacitive materials because they are highly conductive, offer enhanced capacitance, and are environmental friendly and low cost materials. However, its large volume expansion and shrinkage during the doping/dedoping process leads to structural breakdown and limited lifetime performances. Most organic conducting redox-active polymers based electrodes lose more than 50% of their capacitance after 1000 cycles. One common strategy to improve the lifetime of organic-systems is to create composite materials based on strong conducting substrates such as carbon. Various attempts have been made to synthesize composites of PANI with various conductive substrates such as CNTs, rGO, metal oxides, GO (non-conductive), CDC, OLC, to benefit from the synergistic effects of both polymers and carbon materials. However, some of them rely on tedious synthesis methods and use toxic/explosive chemicals during the synthesis process.
A method of making a supercapacitor from waste tires, includes the steps of providing rubber pieces and contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the sulfonated rubber to produce tire-derived carbon composite comprising carbon black embedded in carbon matrix derived from sulfonated rubber and thus depending on the temperature of carbonization carbon composite comprising graphitized interface portions; activating the tire-derived carbon composite by contacting the tire-derived carbon composite with a specific surface area-increasing composition to increase the specific surface area of the carbon composite to provide activated tire-derived carbon composite; mixing the activated tire-derived carbon composite with a monomer and polymerizing the monomer to produce a redox-active polymer coated, activated tire-derived carbon composite; and forming the redox-active polymer coated, activated tire-derived carbon composite into a film.
The method can further comprise the step of forming the redox-active polymer coated, activated tire-derived carbon film into an electrode. The method can include the step of forming a supercapacitor comprising the electrode. The supercapacitor can be a pseudocapacitor.
The graphitized interface portions can comprise 10%-40% of the tire-derived carbon composite, by weight. The temperature of the sulfonation bath can be between −20° C. to 200° C. The rubber pieces can be contacted with the sulfonation bath for between 30 minutes and 5 days. The pyrolizing can include heating to at least 200° C. to 2400° C. The pyrolizing can include at least two stage heating. A first stage heating can include heating to between room temperature and 400° C. at 1° C./min, and a second stage heating comprises heating to between 400 and 2400° C. at 2° C./min. The heating rates in both stages can be as high as 50° C./min. The pyrolizing time can be between 1 min and 24 hours. The pyrolizing can be conducted in an inert atmosphere. The graphitized portion can have a layer spacing of between 3.5-4.7 angstroms.
The activating step can include contacting the tire-derived carbon with at least one selected from the group consisting of KOH, CO2 or ZnCl2. The KOH can be mixed with the tire-derived carbon at a weight ratio of between 1:2 and 1:10.
The pore size after the activating step can include micropores of less than 2 nm, and mesopores of 2-10 nm. The mesopores can be 3-5 nm. The pores can be between 70%-90% micropores and between 10%-30% mesopores. The specific surface area after the activating step can be between 1000-2000 m2/g.
The tire-derived carbon can be mixed with monomer and oxidant at a ratio of (x) Monomer: (y) Oxidant: (z) tire-carbon where x=20-40%, y=20-40%, and z=30-50%. The oxidant can be at least one selected from the group consisting of ammonium persulfate, iron chloride, and potassium dichromate. The redox-active polymer can include at least one selected from the group consisting of polyaniline, polypyrrole, and polythiophene. The polymer can comprise 50%-90% of the redox-active polymer coated, activated tire-derived carbon composite, by weight.
The tire rubber pieces can be between 100 nm and 2 inches. The tire rubber pieces can include particles of between 100 nm and 0.5 mm and rubber crumbs of between 0.5 mm to 2 inches.
The electrode can have capacitance retention of over 95% after 10,000 cycles. The electrode can have a capacitance of over 450 F/g at a scan rate of 1 mV/s, of over 200 F/g at a scan rate of 10 mV/s, and over 150 F/g at a scan rate of 100 mV/s.
The film-forming step can include mixing the redox-active polymer coated, activated tire-derived carbon, carbon black, and a binder in a solvent, evaporating the solvent to produce a film-forming mixture, and applying pressure to the film-forming mixture to form the film.
The conductivity of the films can be between 50-200 S/m. The films can be bent to 180°.
An electrode can include a tire-derived carbon composite comprising carbon black embedded in carbon matrix from sulfonated rubber, the matrix carbon comprising temperature-dependent partially graphitized interface portions on the carbon black particles and being activated, and coated with a redox-active polymer to provide a redox-active polymer coated, activated tire-derived carbon composite. The redox-active polymer coated, activated tire-derived carbon composite can be provided as a film, the film further including carbon black and a binder.
The graphitized interface portions can be 10%-40% of the tire-derived carbon composite, by weight. The polymer can include 50%-90%, by weight, of the redox-active polymer coated, activated tire-derived carbon composite. The pore size after the activating step can include micropores of less than 2 nm, and mesopores of 2-10 nm. The mesopores can be 3-5 nm. The pores can be between 70%-90% micropores and between 10%-30% mesopores.
A supercapacitor can include an electrode, the electrode comprising a redox-active polymer coated, tire-derived carbon composite comprising carbon black embedded in sulfonated rubber-based carbon matrix, the carbon composite comprising graphitized interface portions and being activated and coated with the redox-active polymer to provide a redox-active polymer coated, activated tire-derived carbon composite electrode.
The supercapacitor can have capacitance retention of over 95% after 10,000 cycles. The supercapacitor can have a capacitance of over 450 F/g at a scan rate of 1 mV/s, of over 200 F/g at a scan rate of 10 mV/s, and over 150 F/g at a scan rate of 100 mV/s.
A method of making a supercapacitor from rubber, comprising the steps of providing rubber pieces; contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber; pyrolyzing the sulfonated rubber to produce carbon composite comprising graphitized interface portions; activating the carbon composite by contacting the carbon composite with a specific surface area-increasing composition to increase the specific surface area of the carbon composite to provide an activated carbon composite; mixing the activated carbon composite with a monomer and polymerizing the monomer to produce a redox-active polymer coated, activated carbon composite; and forming the redox-active polymer coated, activated carbon composite into a film. The rubber can include carbon black as filler and thereby it can produce carbon black embedded carbon matrix with graphitized interfaces of different degrees depending on the pyrolysis temperature.
There are shown in the drawings embodiments that are presently preferred it being understood that the invention is not limited to the arrangements and instrumentalities shown, wherein:
A method of making a supercapacitor from waste tires or other rubber sources begins with providing rubber pieces and contacting the rubber pieces with a sulfonation bath to produce sulfonated rubber. The rubber pieces can include carbon black filled crosslinked rubber chunks. Carbon black is amorphous or noncrystalline.
The process is shown schematically in
The method of sulfonating the rubber can vary. In one aspect, the temperature of the sulfonation bath can be between −20° C. to 200° C. The rubber pieces can be contacted with the sulfonation bath for between 30 minutes and 5 days. The sulfonation bath can include a concentration of sulfuric acid, or fuming sulfuric acid, or chlorosulfonic acid, or SO3 gas containing fluid that is suited to the rubber composition and the conditions of the sulfonation.
The rubber pieces can be any suitable size, such as between 100 nm and 2 inches. The rubber pieces can comprise rubber particles of between 100 nm and 0.5 mm and rubber crumbs of between 0.5 mm to 2 inches.
The sulfonated tire rubber is pyrolyzed to produce a tire-derived carbon composite comprising carbon black embedded in carbon matrix with graphitized interface portions. The graphitized interface portions can comprise 10%-40% of the tire-derived carbon composite, by weight. The graphitized portion can comprise a layer spacing of between 3.5-4.7 angstroms. The presence of the outer graphitized shell preserves the carbon black within and raises yield and provides the correct pore volume characteristics.
The pyrolysis can be conducted by any suitable process. The pyrolizing can comprise heating to at least 200° C. to 2400° C., or 900° C. to 1100° C. A temperature of about 1000° C. was found to produce favorable results. The pyrolizing can comprise at least two-stage heating. A first stage heating can comprise heating to between room temperature and 400° C. at 1° C./min, and a second stage heating can comprise heating to between 400 and 2400° C. at 2° C./min. The heating rates in both stages can be as high as 50° C./min. The pyrolizing time can be between 1 min and 24 hours. The pyrolizing can be conducted in an inert atmosphere.
The tire-derived carbon composite is then activated by contacting the tire-derived carbon composite with a specific surface area-increasing composition or process to increase the specific surface area of the carbon to provide an activated tire-derived carbon composite. Many processes for activating carbon are known, and any suitable activation composition or method can be utilized. The activating step can comprise contacting the tire-derived carbon with at least one selected from the group consisting of KOH, CO2, or ZnCl2. The KOH can be mixed with the tire-derived carbon at a weight ratio of between 1:2 and 1:10.
The pore size after the activating step has a mixed meso-microporosity between 1-10 nm or between about 1-5 nm, with both micropores of less than 2 nm, and mesopores of preferably 3-5 nm, or 2-10 nm. There are preferably no pores of greater than 5 nm, or 6 nm, 7 nm, 8 nm 9 nm or 10 nm. The pores can have between 70%-90% micropores and between 10%-30% mesopores. The specific surface area after the activating step is between 1000-2000 m2/g.
The activated tire-derived carbon composite is mixed with a monomer for preparing the redox-active polymer. The monomer is polymerized to produce a redox-active polymer coated, activated tire-derived carbon composite. Redox-active polymers are polymers bearing redox centers or groups. They are a group of polymers with non-conjugated backbone and redox-active centers localized in pendant groups. The redox centers, not the polymer chain generally govern the redox behavior. The reaction rate can be controlled by the applied potential or current. Conducting redox-active polymers such as polyaniline (PANI), polypyrrole (PPy) and polythiophene (PTh) have been extensively used in electrochemical supercapacitors, although other redox-active polymers can be used. The redox-active polymer can comprise 50%-90% of the redox-active polymer coated, activated tire-derived carbon composite, by weight.
The aniline, pyrrole, thiophene, or other monomer can be mixed with a suitable oxidant to polymerize the monomer. Suitable oxidants include ammonium persulfate, iron chloride, and potassium dichromate. Any suitable polymerization process and oxidant for the monomer can be used. The tire-derived carbon composite is mixed with monomer and oxidant at a ratio of (x) monomer: (y) oxidant: (z) tire-derived carbon composite of for example x=1-4 μl, y=1-4 mg, and z=1-10 mg. The proportions can be monomer 20-40%, oxidant 20-40%, and tire-derived carbon composite 30-50%, by weight.
The redox-active polymer coated, activated tire-derived carbon composite can be formed into a film. The film-forming step can include mixing the redox-active polymer coated, activated tire-derived carbon composite (80-90%), carbon black (5-10%), and a binder in a solvent (5-10%), evaporating the solvent to produce a film-forming mixture, and applying pressure to the film-forming mixture to form the film.
The redox-active polymer coated, activated tire-derived carbon film can be formed into an electrode with any suitable construction and by any suitable process. An electrode according to the invention comprises a tire-derived carbon composite comprising carbon black embedded in sulfonated rubber-based carbon matrix with graphitized interface portions and being activated, and coated with a redox-active polymer to provide a redox-active polymer coated, activated tire-derived carbon composite.
The electrode can be used to form a supercapacitor comprising the electrode. The supercapacitor can be made in two or three electrode configurations and/or can be a flexible supercapacitor. In the two-electrode setup, activated carbon can serve as a counter electrode and the composite film of the invention as a working electrode, while in a three-electrode setup, an Ag/AgCl counter electrode can be used. In a flexible supercapacitor, gel-type electrolytes can be employed.
A supercapacitor according to the invention includes an electrode, the electrode comprising a redox-active polymer coated, tire-derived carbon composite comprising carbon black embedded in sulfonated rubber-based carbon matrix with graphitized interface portions and being activated and coated with the redox-active polymer to provide a redox-active polymer coated, activated tire-derived carbon composite electrode. The supercapacitor can be formed into any suitable supercapacitor construction and by any suitable process.
The supercapacitor has capacitance retention of over 95% after 10,000 cycles. The supercapacitor supercapacitor has a capacitance of over 450 F/g at a scan rate of 1 mV/s, of over 200 F/g at a scan rate of 10 mV/s, and over 150 F/g at a scan rate of 100 mV/s. The electrodes are also highly flexible and conducting. The conductivity of the as-synthesized films varies between 50-200 S/m depending on the desired composition. The films can easily be bent to 180° position or beyond.
An experimental crumb tire rubber of irregular shapes (0.3-1 cm size) was used to derive carbon by soaking in concentrated sulfuric acid bath and subsequent washing. The washed sulfonated tire rubber was then pyrolyzed in a tubular furnace under a flowing nitrogen gas atmosphere. The temperature of the furnace was ramped up in two stages, from room temperature to 400° C. at 1° C./min and 400° C. to 1100° C. at 2° C./min followed by cooling to room temperature. The pyrolyzed residue yields up to 50% carbon by weight. To increase the SSA, as-produced carbon was mixed with potassium hydroxide, KOH pellets (Sigma-Aldrich) at a 1:4 weight ratio using a mortar and pestle followed by heating at 800° C. for 1 h under nitrogen flow. The activated tire-derived carbon (TC) was then washed with 10 wt. % HCl to remove the remaining salts and ashes, followed by thorough washing with the deionized water until the pH of the supernatant became neutral. TC was then oven-dried at 100° C. for 24 h.
A rapid mixing polymerization route was utilized to synthesize PANI/TC composites because it hampers the secondary growth of the PANI by diffusing away the polymerized carbon and provides more active sites for uniform polymerization. Aniline (>99.5%; Sigma-Aldrich) was polymerized at room temperature using ammonium peroxydisulfate (APS) (>98%; Fischer Scientific) as an oxidizing agent, with and without the presence of TC. Various compositions of the PANI and TC were tested for optimal electrochemical performance. Typically, 60 μl of aniline was dissolved in 10 ml of 1 M HCl solution and 60 mg of APS was dissolved in the same amount of HCl. 60 mg of TC was sonicated in 1 M HCl for 30 minutes prior to start of the synthesis followed by the rapid addition of aniline and APS solutions to the TC suspension. The whole mixture was vigorously stirred during the synthesis to ensure well mixing of both solutions before the start of polymerization. The change of the solution color from black to green (emeraldine salt) confirmed the start of the polymerization process. The reaction was carried out overnight and the resulting product was washed with ethanol/water and filtered until the solution reached a neutral pH value. A similar protocol was adopted to synthesize PANI without TC. The as-synthesized PANI/TC composite film is highly flexible and can be used directly in flexible energy storage devices. The whole process is scalable for the synthesis of PANI/TC composites for portable energy storage devices to large scale energy storage systems (e.g., flowable electrodes for grid energy storage).
Transmission electron microscopy (TEM) was performed with JEM-2100 (JEOL, Japan) using an accelerating voltage of 200 kV. Samples were sonicated in ethanol for 5 minutes prior to dropping 1-2 drops on copper grid for imaging. Gas sorption measurements were performed on Quadrasorb instrument (Quantachrome, USA) using nitrogen at −196° C. Brunauer-Emmett-Teller (BET) method and Density Functional Theory (DFT) models were used to determine SSA of all the investigated samples, using the adsorption data taken at relative pressure (P/Po) range of 0.05-0.2. Quench-solid density functional theory (QSDFT) was used to derive PSD by considering the slit-shaped pore geometry, while total pore volumes were calculated at P/Po=0.99. Renishaw inVia Spectrometer with a 632 nm laser as the excitation source using 5% laser power was used during all the measurements. Fourier transform infrared spectroscopy (FTIR) was carried out on FTIR spectrometer (Perkin-Elmer) with a resolution of 4 (1/cm).
Film electrodes were prepared by mixing 90 wt. % active material with 5 wt. % carbon black (100% compressed; Alfa Aesar, USA) and 5 wt. % polytetrafluoroethylene (PTFE) binder (Sigma-Aldrich) in ethanol. After evaporation of ethanol, powder was rolled using a roller mill to prepare ˜100 μm thick films. The AC (YP-50, Kuraray, Japan) electrodes having a thickness between 100-150 μm were prepared by mixing 95 wt. % AC and 5 wt. % PTFE binder. All electrochemical tests were performed in a three-electrode Swagelok® cell. TC or PANI/TC composite electrodes were used as the working, over-capacitive activated carbon films were used as the counter and Ag/AgCl was used as the reference electrode. Clegard membranes served as a separator and 1 M H2SO4 as the electrolyte. Electrochemical measurements were performed with cyclic voltammetry (CV), galvanostatic charging/discharging potential limiting (GCPL), and electrochemical impedance spectroscopy (EIS). Impedance measurements were performed at a sine wave signal amplitude of 10 mV in the frequency range of 200 kHz to 10 MHz. Capacitance and energy density values were calculated similar to our previous report.
The morphology of the tire-derived activated carbon (TC) and PANI/TC was investigated with TEM. TC exhibited a three-dimensional, interconnected and random morphology (
The sorption isotherms before and after the activation of tire-derived carbon are shown in
Raman spectra (
Cyclic voltammetry was performed on the TC electrodes in 1 M H2SO4 at various scan rates between 1-100 mV/s in the voltage range of 0.6 to −0.15 V, to assess the charge storage capacity. A nearly rectangular shape CV was observed at all the sweep rates without any distortion/redox peaks, a characteristics of the capacitive (double layer formation) charge storage (
GCPL curves of TC electrodes (
Despite numerous physical and electrochemical advantages of the activated carbons, one major limitation is their poor energy density. The invention enhances the energy density by depositing organic conducting redox-active molecules on the subsurface and inner pores of the high surface area carbons to add faradic charge storage to the total capacitance of the electrodes. Organic redox-active molecules/polymers are favored due to their moderate cost, scalability, flexibility, organic nature and facile tailoring of their properties at molecular level. Unfortunately, they have poor stability upon charging/discharging, which hinders their application in energy storage devices. The major challenge for the development of conducting polymer/carbon composites is therefore to synthesize inexpensive, environmentally benign and high performance pseudocapacitive materials that offer longer cycling stability.
CV curves of the PANI/TC electrodes at various sweep rates between 5-100 mV/s in the potential range of −0.2 to 0.8 V are shown in
Across all the sweep rates, CVs of the PANI/TC composite remained rectangular with clear redox peaks confirming higher activity and stability of the PANI even at high scan rates, which is in sharp contrast to many published reports, where CVs were distorted at moderate scan rates. The high capacitance of the composite can be attributed to the uniform and thin coating of the PANI. Moreover, the 3D porous architecture of the composite offers higher conductivity (for good rate performance) and higher accessibility and shorter pathways for fast ion and charge transport. Poor accessibility of the electrolyte ions led to decline in capacitance at higher scan rates, a common characteristic of the electrochemical energy storage devices. Nevertheless, PANI/TC composite demonstrated the synergistic impact of both TC and PANI showing high capacitance, outperforming many previous reports.
GCPL of PANI/TC electrodes (
The rate performance of the TC and PANI/TC at various scan rates between 1-200 mV/s is shown in
Poor cycle life because of the degradation of the PANI upon cycling is the key issue of PANI-containing pseudocapacitive electrodes. Table 1 summarizes and compares the capacitance retentions of various PANI based composites with different types of carbons (e.g., CNTs, rGO, commercial carbons, etc.) and various metal oxides. All PANI based composites (Table 1) with various carbons/metal oxides exhibited decay in capacitance after moderate cycling.
The invention utilizes high surface area conducting carbons derived from the solid waste tires as a substrate for an organic-based supercapacitor. This carbon material is abundant, inexpensive and environmentally benign. Sulfuric acid treatment followed by pyrolysis of the shredded tire was carried out at 1100° C.; recovered carbon was subsequently chemically activated to develop the porosity. The activated TC exhibited mixed 3D meso-microporous network with a high surface area of 1625 m2/g. When tested as a supercapacitor electrode, it showed a high charge storage capacity of 135 F/g at 1 mV/s, comparable to the commercial carbons. The PANI/TC composite film was highly compatible, conductive, could be easily bent, rolled or used as a flat sheet in the devices. When tested as the pseudocapacitive electrode, PANI/TC film showed a capacitance of 480 F/g at 1 mV/s, a 256% higher capacitance than the activated TC. PANI/TC composite demonstrated excellent capacitance retention of up to 98%, outperforming all the PANI-based composites with activated carbons. The negligible capacitance loss was due to the tight confinement of the PANI within the inner pores of TC, which served as shallow traps for the PANI entrapment via τ-τ interactions, and led to the structural stability of PANI during charging/discharging. The waste tire-derived carbon of the invention shows promising results for capacitive charge storage as well as an excellent conductive 3D nano-scaffold for the deposition of the redox polymers for Faradic capacitance. The narrow pore size distribution (PSD) and high surface area lead to a good charge storage capacity, especially when used as three-dimensional nanoscaffold to polymerize polyaniline (PANI/TC) or other redox-active polymers. The high capacitance and long cycle life are, without wishing to be limited, ascribed to the short diffusional paths, uniform redox-active polymer coating and tight confinement of the redox-active polymer in the inner pores of the tire-derived carbon via τ-τ interactions, which minimize the degradation of the redox-active polymer such as PANI upon cycling.
Owing to PANI/TC high conductivity, facile synthesis procedure and flexibility, these composites can be used in various applications such as li-ion batteries, sensors and actuators. Moreover, as-developed PANI/TC or combination of TC with other redox-active polymers and/or metal oxides may find their application in the large scale energy storage systems such as electrochemical flow capacitors, where materials with moderate cost and higher energy density are critically required.
Ranges: throughout this disclosure, various aspects of the invention can be presented in a range format. It should be understood that the description in the range format is merely for convenience and brevity and should not be construed as an inflexible limitation on the scope of the invention. Accordingly, the description of a range should be considered to have specifically disclosed all the possible subranges as well as individual numerical values within that range. For example, description of a range such as from 1 to 6 should be considered to have specifically disclosed subranges such as from 1 to 3, from 1 to 4, from 1 to 5, from 2 to 4, from 2 to 6, from 3 to 6 etc., as well as individual numbers within that range for example, 1, 2, 2.7, 3, 4, 5, 5.3 and 6. This applies regardless of the bread of the range.
This invention can be embodied in other forms without departing from the spirit or essential attributes thereof, and accordingly, reference should be had to the following claims to determine the scope of the invention.
This application is a divisional application of U.S. patent Ser. No. 14/852,073, filed on Sep. 11, 2015, which claims priority to U.S. Provisional Patent Application No. 62/166,244, filed May 26, 2015, titled “HIGHLY FLEXIBLE AND CONDUCTIVE WASTE TIRE-DERIVED CARBON/POLYMER COMPOSITE PAPER AS ULTRA-LONG CYCLE LIFE PSEUDOCAPACITIVE ELECTRODE,” the contents of which are hereby incorporated herein by reference in their entireties.
This invention was made with government support under contract No. DE-AC05-00OR22725 awarded by the U.S. Department of Energy. The government has certain rights in this invention.
| Number | Date | Country | |
|---|---|---|---|
| 62166244 | May 2015 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 14852073 | Sep 2015 | US |
| Child | 15923691 | US |
