Patent Grant
7557300
The present invention relates to flexible electrical conductor cables suitable for high temperature installations.
Solid oxide fuel cells, along with other high temperature fuel cells, typically operate at temperatures well in excess of 500° C., and often in the range of 800° C. or higher. It is a challenge to find electrical conducting cables for use in such a high temperature environment which have an adequately low electrical resistance, resist thermal degradation at such elevated temperatures, and which may survive repeated thermal cycling from ambient temperatures to operating temperatures.
Several commercially available high temperature cables do not perform satisfactorily. For example, Radix MCS™ Furnace Cables comprise a solid or stranded nickel core which is sheathed with an insulator and protective cover. The insulator comprises a braided mica layer and a braided ceramic fibre layer. The protective cover comprises a braided stainless steel layer. These cables are suitable for high temperature AC application but when used with a DC power source such as a fuel cell, they demonstrate unacceptably high voltage drops. Other combinations of conducting cores and braided or smooth stainless steel sheaths have been similarly unsuccessful.
Therefore, there is a need in the art for a high temperature electrical conductor cable which mitigates the difficulties of the prior art.
An electrical conducting cable comprising:
(a) a conductive core having terminal lugs at each end;
(b) a flexible, gas impermeable sheath which is hermetically sealed to each of the terminal lugs.
In one embodiment, the cable consists essentially of the conductive core and sheath as described above.
The invention will now be described by way of an exemplary embodiment with reference to the accompanying simplified, diagrammatic, not-to-scale drawings. In the drawings:
The present invention provides for an electrical conducting cable suitable for use in high temperature environments such as with high temperature fuel cell stacks, and solid oxide fuel cell stacks in particular. When describing the present invention, all terms not defined herein have their common art-recognized meanings.
As seen in
In one embodiment, the conducting core (12) comprises a highly conductive metal or metal alloy which may comprise copper, nickel, or silver, or alloys thereof. Aluminum may be used as an alloying element in smaller quantities, however, it cannot be used in pure form because of its relatively low melting temperature. In one preferred embodiment, the core comprises substantially pure copper. The corrugated sheathing (14) preferably but not necessarily comprises a stainless steel or any other oxidation resistant alloy. The corrugated sheathing must be gas-impermeable at all intended operating temperatures. High temperature alloys such as Inconel□ are suitable but may not provide added benefits commensurate with their additional expense. The terminal lug (16) may be formed from any conductive metal but is preferably formed from a stainless steel or Inconel□ or the like. The corrugations in the sheathing (14) enhances the flexibility of the cable (10).
In one embodiment, the cable (10) does not require an insulating layer between the outer sheath (14) and the conducting core (12). The cable (10) is robust enough to perform satisfactorily at high temperatures without such an insulating layer.
The electrical capacity of the cable is related to the diameter and length of the conductive core. Those skilled in the art, with minimal and routine experimentation, will be able to determine the optimum and minimum satisfactory settings in each instance.
One method of ensuring a hermetic seal between the conducting core (12), the sheathing (14) and the terminal lug (16) is to join them by vacuum brazing. A paste of Ni-braze alloy BNi-3 is inserted into the terminal lug cavity, coating the internal surfaces to which the conducting core and the sheathing will be bonded to. The conducting core is inserted in the corrugated sheathing which is cut slightly shorter than the length of the core. The end of the conducting core and corrugated sheathing is inserted into the terminal lug cavity already coated with braze alloy paste. The assembly is put on fixtures designed to keep the braze alloy paste from flowing out of the terminal lug, heated in a vacuum furnace to a brazing temperature of 1040° C. and held for an hour before cooling.
The method of joining must of course provide adequate electrical contact between the terminal lugs and the core.
As will be apparent to those skilled in the art, various modifications, adaptations and variations of the foregoing specific disclosure can be made without departing from the scope of the invention claimed herein. The various features and elements of the described invention may be combined in a manner different from the combinations described or claimed herein, without departing from the scope of the invention.
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| Number | Date | Country | |
|---|---|---|---|
| 20060000632 A1 | Jan 2006 | US |
