The present disclosure falls within the technical field of sensors, and particularly relates to a flexible strain sensor based on the same conductive material and a preparation method thereof.
A strain sensor is a device that converts an external mechanical signal into an electrical signal, and the device is deformed under the action of an external force, thereby causing the change of the electrical properties of the internal sensing material to achieve sensing. Traditional strain sensors are mostly made of metal and semiconductor materials, which are difficult to apply to complex interfaces due to their narrow tensile strain range and inflexibility. Flexible strain sensors, due to their advantages of ultra-thinness, low modulus, high flexibility, and high ductility, can be attached to complex curved surfaces, and can be used in wider and more complex application conditions than traditional metal sensors. The flexible strain sensors have attracted extensive attention from researchers. Currently, the flexible strain sensors are often integrated into wearable devices and have important applications in medical health, human motion detection, soft robots, and human-computer interaction.
Resistive strain sensors have become the mainstream of the flexible strain sensors because of their simple manufacture, low cost, and strong stability. A classical resistive strain sensor should consist of a sensing area and a connection area in series, and a resistance change ΔR and an initial resistance R0 of the sensor are determined by the sensing area and the connection area. Various materials and shape structures are designed to construct the sensing area and the connection area of the sensor to increase the sensitivity and measurement range of the sensing area and minimize the resistive contribution of the connection area. However, to ensure local sensitivity and durability, the material of the connection area should have high conductivity and stable mechanical properties. The traditional design method uses carbon nanomaterials as the sensing area and metal films as the connection area. The metal films have ultra-high conductivity and stable mechanical properties, but the metal material is generally expensive. In order to use a carbon-based material instead of a metal material as the connection area to reduce costs and to have comparable performance of metal connection, researchers have also used carbon black doped polydimethylsiloxane as the sensing area because of its high resistivity and strong dependence on strain, and carbon nanotube doped polydimethylsiloxane as the connection area because of its relatively low resistivity and weak dependence on strain.
However, the above methods all require multi-step operation, are expensive to manufacture, and different materials require multiple drying and curing, which increases the complexity of the process and is not conducive to mass production of the flexible strain sensors. Therefore, how to facilitate easy and low-cost fabrication of the flexible strain sensors is a technical barrier to mass production of sensors.
In view of the state of the related art, the present disclosure provides a flexible strain sensor based on the same conductive material and a preparation method thereof, aiming to solve the problems that the manufacturing process of the flexible strain sensor is complicated and mass production is difficult.
In an aspect, the technical solution adopted by a sensor of the present disclosure is as follows. A flexible strain sensor based on the same conductive material, where the flexible strain sensor is of a layered structure and includes a flexible substrate, a sensing area and a connection area located on the flexible substrate, and an encapsulation layer for protecting the sensing area.
The sensing area and the connection area are made of the same conductive material, and sizes and shape structures of the sensing area and the connection area satisfy that when the flexible strain sensor is deformed, a resistance value change of the flexible strain sensor is determined by the sensing area, a resistance value of the connection area is ignored, and the connection area is only used for connecting the sensing area and an external device.
In a preferred embodiment, the sensing area is connected by a plurality of elongated rectangles circuitously, the connection area is a large rectangle, and the strain degree of the sensing area is more than the strain degree of the connection area when the sensor is deformed.
In another aspect, the preparation method of the present disclosure adopts the following technical scheme. A method for preparing the flexible strain sensor based on the same conductive material includes the following steps.
At S1, the same composite conductive material is used to design the sensing area and the connection area, where the design rule is that when the sensor is deformed, the resistance value change of the sensor is determined by the sensing area, the resistance value of the connection area is ignored, and the connection area only serves to connect the sensing area and the external device.
At S2, the sensing area and the connection area of the sensor are prepared by printing in one step with the same composite conductive material, the silicone rubber is coated on the sensing area as the encapsulation layer for protection, and accessories connected to the external device are mounted on the connection area.
In a preferred embodiment, the resistance change of the sensor is characterized in step S1 as:
where ΔR is the resistance change value of the sensor, R0 is an initial resistance value of the sensor, Rs0 represents an initial resistance value of the sensing area, Rc0 represents an initial resistance value of the connection area, εs is a strain value of the sensing area, εc is a strain value of the connection area, GFs is the sensitivity of the sensing area, and GFc is the sensitivity of the connection area.
Parameters of the sensor are designed to meet three conditions: Rs0»Rc0, GFs≥GFc, and εs≥εc.
Advantageous effects of the present disclosure compared to the prior art are as follows.
In the drawings, 1—flexible substrate, 2—sensing area, 3—connection area, 4—encapsulation layer, 5—metal snap button, and 6—wire.
Hereinafter, the present disclosure will be described in detail with reference to the drawings and specific embodiments, but embodiments of the present disclosure are not limited thereto.
With reference to
The sensing area and the connection area are both made of the same conductive material, and the preparation of the sensor based on the same conductive material may be done in one step by means of a screen printing process without the need for a step-by-step process. That is, the sensing area and the connection area are prepared using the same conductive material, and the design rule of the sensor based on the same conductive material may be satisfied by adjusting sizes and shape structures of the sensing area and the connection area.
In one embodiment, the flexible substrate 1 uses high elasticity fabric, i.e., a soft fabric substrate, and the encapsulation layer 4 uses silicone rubber. The sensing area 2 is designed to be connected by a plurality of elongated rectangles circuitously and the connection area 3 is designed as a large rectangle to ensure that strain degrees of the sensing area and the connection area are consistent during deformation and also increase an effective length-width ratio of the sensing area. The sensing area 2 has an effective length of 220 mm and an effective width of 2 mm; the connection area 3 has an effective length of 20 mm and an effective width of 20 mm. The conductive material used in both the sensing area and the connection area is a carbon black-silicone rubber composite conductive material with a volume fraction of 9%, namely, the conductive material is a composite conductive paste mixed by the carbon black and the silicone rubber. Since a length-width ratio of the sensor is not only proportional to an initial value of a resistance but also related to the sensitivity, increasing the length-width ratio may increase the sensitivity of the sensor. It is known that the length-width ratio of the sensing area is greater than that of the connection area, and therefore the initial resistance Rs0»Rc0 and sensitivity GFs>GFc; Rs0 is an initial resistance value of the sensing area, Rc0 is an initial resistance value of the connection area, GFs is the sensitivity of the sensing area, and GFc is the sensitivity of the connection area.
The performance test for a fully printed flexible strain sensor is as follows.
A method for preparing a flexible strain sensor in this embodiment includes the following steps.
At S1, the same composite conductive material is used to design the sensing area and the connection area, where the design rule is that when the sensor is deformed, the resistance value change of the sensor is determined by the sensing area, the resistance value of the connection area may be ignored, and the connection area only serves to connect the sensing area and the external device.
The implementation is as follows.
where ΔR is a resistance change value of the sensor, R0 is an initial resistance value of the sensor, Rs represents a resistance value of the sensing area, and Rc represents a resistance value of the connection area.
where GF is the sensitivity of the sensor, & is a strain value of the sensor, and the formula is transformed to obtain: ΔR=GFεR0.
In one specific embodiment, GFsεsRs0»GFcεcRc0 is required to satisfy that the resistance change of the sensor under strain depends on the sensing area, among these three variables, R0 is the easiest variable to control, so long as Rs0»Rc0, and GFs≥GFc, εs≥εc are guaranteed. Rs0 represents the initial resistance value of the sensing area, Rc0 represents the initial resistance value of the connection area, εs is a strain value of the sensing area, and εc is a strain value of the connection area.
The flexible strain sensor of the present disclosure satisfies Ohm's Law, i.e.,
where ρ represents the resistivity of the composite material, L, W, and t represent the length, the width, and the thickness of the sensor, respectively. It may be seen that the length-width ratio of the sensor is directly proportional to the resistance value, and the same composite conductive material is used for the sensing area and the connection area to ensure ρs=ρc, and the thickness ts=tc, and therefore Rs0»Rc0 is needed, at least
is ensured, namely,
Theoretically, the larger the length-width ratio of the sensing area, the higher the resistance contribution of the sensing area in the sensor, and the more the influence of the resistance of the connection area may be ignored. However, increasing the length-width ratio of the sensing area requires increasing the size of the sensor at the same time, which is not conducive to miniaturization of the sensor. Therefore, the maximum specification of the flexible strain sensor is considered, limiting conditions are given:
where Ws and Wc are the widths of the sensing area and the connection area, respectively, and Ls and Lc are the lengths of the sensing area and the connection area, respectively.
The sensing area is designed to be connected by a plurality of elongated rectangles circuitously, and the connection area is designed as a large rectangle, where a circuitous elongated-rectangle structure is more likely to cause stress concentration when subjected to a force, so as to ensure that the strain degree of the sensing area is greater than that of the connection area when the sensor is deformed, namely εs>εc, a condition εs≥εc is satisfied.
In a preferred embodiment, the sensing area has the effective length of 220 mm and the effective width of 2 mm; the connection area has the effective length of 20 mm and the effective width of 20 mm. The length-width ratio of the sensing area is 110 times that of the connection area, satisfying the design rule.
The conductive material used in the sensing area and the connection area is the carbon black-silicone rubber composite conductive materials with a volume fraction of 9%. Because the length-width ratio of the sensor is not only directly proportional to the initial value of the resistance but also related to the sensitivity, increasing the length-width ratio of the sensor may increase the sensitivity of the sensor. The sizes of the sensing area and connection area have been designed to meet the design requirement GFs≥GFc.
In general, the design rules for the sensing area and the connection area satisfy that the resistance change of the sensor under strain depends on the sensing area and neglects the resistance contribution of the connection area, and parameters of the sensor need to meet three conditions: Rs0»Rc0, GFs≥GFc, and εs≥εc.
At S2, the sensing area and the connection area of the sensor are prepared by printing in one step with the same conductive material through the screen printing process, then a layer of the silicone rubber is coated on the sensing area as the encapsulation layer for protection, and the metal snap buttons are mounted on the connection area through the conductive gel as accessories connected to the external device, so that the whole sensor may be prepared.
In one embodiment, the sensor is prepared by performing one-step printing of the carbon black-silicone rubber composite conductive paste on the fabric substrate on the basis of the screen printing process.
While the above embodiments are preferable embodiments of the present disclosure, the implementation of the present disclosure is not limited by the above embodiments. Any other changes, modifications, substitutions, combinations, and simplifications without departing from the spirit essence and principles of the present disclosure shall be equivalent replacement modes and shall be included in the scope of the present disclosure.
Number | Date | Country | Kind |
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202110300119.0 | Mar 2021 | CN | national |
Filing Document | Filing Date | Country | Kind |
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PCT/CN2021/124326 | 10/18/2021 | WO |