This specification relates to a membrane biofilm device and reactor, and to processes for water treatment using a membrane-supported biofilm.
In a membrane biofilm reactor (MBfR) for water or wastewater treatment, a membrane is used to both support the growth of a biofilm on a wall of the membrane and to transport a gas to the biofilm through the wall of the membrane. Membrane biofilm reactors were reviewed by Martin and Nerenberg in “The membrane biofilm reactor (MBfR) for water and wastewater treatment: Principles, applications, and recent developments” (Bioresour. Technol. 2012). Membrane-aerated biofilm reactors (MABR) are a subset of MBfRs in which an oxygen containing gas is used. MABRs were reviewed by Syron and Casey in “Membrane-Aerated Biofilms for High Rate Biotreatment: Performance Appraisal, Engineering Principles, Scale-up, and Development Requirements” (Environmental Science and Technology, 42(6): 1833-1844, 2008).
MBfR technology has existed on a laboratory scale for several years, but it has not been widely commercialized or scaled-up. The ZeeLung™ MABR developed by GE Water & Process Technologies uses cords, each cord containing multiple fine hollow fiber membranes. The cords are packaged into modules and cassettes in a way that resembles the packaging of hollow fiber ultrafiltration membranes into ZeeWeed™ modules and cassettes. The cords are potted into upper and lower headers to form modules. The modules are mounted to a frame to form a cassette. The cassette can be mounted on the floor of a process tank. MBfR units of this type are described in International Publication Number WO 2014/130043 A1, published on Aug. 28, 2014, which is incorporated herein by reference.
This specification describes a process in which a membrane supported biofilm unit is maintained at a generally constant depth of submergence in water to be treated. The unit could be mechanically lifted or lowered, but in a preferred embodiment the unit floats in the water. The unit may move horizontally as it rises or falls, or not. Optionally, the unit may be mounted such that it can be moved between multiple positions in the tank in plan view, for example depending on loading conditions, biofilm maturity or health, or change of season.
An exemplary floating unit has a frame and one or more floats. The frame holds modules or other structures with membranes. The floats may be secured to the frame before the frame is placed in a tank. Alternatively, the floats may be provided as part of a raft that is placed in the tank first, with the frames added later. The frame extends downwards from the floats, preferably such that the membranes are completely submerged. The floats may widen above the waterline to increase their righting moment. The frame may be part of a cassette as described in International Publication Number WO 2014/130043 A1.
Various processes for providing gas to the unit are also described. Process gas for use by the biofilm can be provided above the static head pressure of the water at the lowest depth of submergence continuously. Alternatively, process gas may be provided at a lower pressure but with intermittent increases in pressure sufficient to cause gas to also flow to an aerator. Non-process gas, such as gas for mixing the tank or scouring the membranes, can be provided periodically for example by valves, by an accumulator, or by a pulsing aerator. In one embodiment, a valve set is configured to provide a higher flow rate to a series of aerators sequentially.
The unit may be attached to one or more conduits to remove water or exhaust gas from the unit. The water removed can be monitored to check for leaks in the unit, for example by comparing the amount of water removed over a period of time to the expected amount of condensation in that period of time. Exhaust gas can be analyzed, for example to determine the amount of oxygen in it. This can be used to measure or monitor an oxygen transfer rate for the unit.
Keeping the unit at a generally constant depth of submergence enables a desired process gas pressure relative to water pressure without having to monitor and compensate for changes in the depth of the water in the tank. For example, the process gas pressure can be kept higher than the water head by a fixed amount to minimize or prevent water or gas entry into the membranes. In another process, a single gas feed is attached to the membranes and to an aerator, preferably in parallel. Varying the applied gas pressure can provide process air only, process air and bubbles from the aerator for mixing, or process air and bubbles from the aerator for scouring. Non-process air can be provided intermittently, or sequentially between multiple units in a tank or other group of units, by a cyclic aeration system valve unit. A pressure reducing by pass around the valve unit can be provided such that each unit receives process air, or process air and mixing air, continuously at a lower rate.
In a hybrid MABR application for municipal wastewater treatment, membrane supported fixed-film biomass and suspended biomass are complementary. The fixed-film biomass is at least partially aerobic while the suspended biomass is at least partially anoxic or anaerobic. Floating membrane units as described herein may be added to an existing process tank in a wastewater treatment plant. For example, one or more units may be added to a tank, optionally with suspended biomass, to reduce aeration energy consumption, to increase capacity, or to reduce nitrogen concentration in the effluent.
Rigid anchoring of cassettes is standard for filtration membranes. However, MBfR units are more likely to be installed into existing plants. The ideal location for the units for the treatment process may have limited mounting points due to existing equipment or structures. In some cases, it may be desirable to add the units without stopping the plant. It may also be desirable to change the position of a unit to adapt to conditions that change over time. These factors can make it advantageous to provide a floating unit. A floating unit also locates the membranes at a generally fixed and predetermined depth of submergence regardless of the tank design or water level in the tank. In some processes, the generally constant depth of submergence assists in the operation of the membranes or aerators that are part of the unit. Providing a floating unit with its own aerators also helps when retrofitting the unit in a tank by removing the need to adapt the unit to mixing or aerating equipment already present in a plant.
Gas permeable membranes suitable for supporting the growth of a biofilm on their surface may be provided in various forms including flat-sheets and hollow fibers. One preferred structure is a “cord” as described in International Publication Number WO 2014/130043. The cord is made up of a plurality of filaments. Some of the filaments are hollow fiber gas transfer membranes. Other filaments are reinforcing filaments, or provided to space out the gas transfer membranes.
Referring to
In the unit 30 shown, each float 32 is a hollow tube with two sealed ends defining an airtight cavity. The floats 32 are made of stainless steel. The floats 32 are located on the sides of the cassettes 16. The unit 30 is approximately 5 m long and 2.6 m wide. The floats 32 are 400 mm in outside diameter and provide about 2,900 N of buoyancy each. The required buoyancy is determined based on the weight of the cassettes 16 but accounting for the buoyancy of the hollow fiber membranes, headers 14, 15 and other hollow parts of the cassettes 16. Dynamic forces exerted by bubbles rising from the aerators 20 should also be considered. In other alternatives, the floats 30 may be of other shapes, materials or structures that float. The floats 30 may be placed in other locations relative to the cassettes 30. There may be other numbers of cassettes 16 or floats.
The center of gravity of the cassettes 16 is below the expected waterline 34. The floats 32 preferably widen above the expected waterline 34. In the example shown, the expected waterline 34 is below the horizontal centerline of the cylindrical floats 32. In this way the righting moment of the unit 30 is increased to make the unit 30 more stable when subject to non-centered loads such as wind, obstructed aerators, or variations in airflow among the aerators 20.
After being lowered by cranes into the tank 52, each unit 40 is attached to tethers 54 to position the unit 40 in the tank 52. The other ends of the tethers 54 are attached, for example, to the sides of the tank 52 as shown or to a deck or the ground around the tank 52. The tethers 54 allow the units 40 to rise and fall in the tank 52 as the water level rises and falls in the tank 52. In this way, the immersion depths of the cords 12 and aerators 20 remain generally constant. Alternatively, the units 40 may be raised or lowered mechanically in response to changes in water level, but the floating units 40 provide this adjustment simply and automatically. Having the cords 12 and aerators 20 at a constant and predetermined depth of submergence helps enable some of the processes that will be described further below. However, the processes described herein may also be used or adapted for use with modules 10 fixed in place in a tank 52.
It is acceptable, but not preferred, for the units 40 to move horizontally to some extent as they rise and fall. The simplest tether 54 is a rigid cable provided with some excess length. In another alternative, the tether 54 is taut but includes a resilient member. For example, the tether 54 may have a section of rubber, coiled spring or other resilient material. In other alternatives, devices used to attach boats or other marine structures to docks or pilings may be adapted. For example, a tether 54 may include a bent whip or pole, a vertical rod that slides within a ring, or a spring biased lever. Since gas distribution to the cords 12 and aerators 20 improves when the unit 40 is level, it is preferable to use tethers 54 such that they tend to stabilize or level the unit 40.
A temporary walkway may be dropped into place across the walls of the tank 52 to facilitate hooking up one or more hoses 56 to the units 40. The hoses 56 are preferably flexible so that they move with the units 40. The hoses 56 may be connected to rigid pipes where they reach the ground or the walls of the tank 52. Since the hoses 56 primarily transport gasses, they typically float on the surface of the water in the tank 52 and do not need to be supported. One hose 56 is connected to each unit 40 in
When a unit 40 is used for water treatment, for example in a MABR, the membranes are typically provided with gas for transfer to the biofilm supported on the membranes and gas to produce bubbles outside of the membranes. The first gas may be called “process gas” and is pumped into the inside of the gas transfer membranes. Optionally, process gas that is not transferred to the biofilm may be removed from the the inside of the membranes. Gas used to produce bubbles may be called non-process gas, mixing gas, scouring gas, or mixing/scouring gas. This gas is fed to an aerator 20, preferably below or near the bottom of the module 10. The process gas contains a component, such as oxygen, that supports a biochemical reaction in the biofilm. The non-process gas may contain the same component for convenience, but it is not required. In an MABR, air may be used for process gas and non-process gas. Optionally, module exhaust gas may be used as non-process gas. Non-process gas may be used to mix the water around a module 10 to promote transfer of aqueous reactants into the biofilm. Non-process gas can also be used, typically when provided at a higher rate than for mixing, to periodically scour the membranes to remove excess biofilm or to control the thickness of the biofilm.
A floating unit 40 can be used in a variety of membrane biofilm reactors. Depending on the type of a gas supplied into it, the unit 40 can be used for, among others, aerobic treatment of wastewater. In this case, the process gas is an oxygen-containing gas such as air. In another example, the unit 40 can be used for fully or partially anaerobic biochemical reactions where the process gas can be hydrogen, carbon monoxide, syngas or methane. For example, hydrogen containing process gas can be used to denitrify groundwater or to produce methane. Syngas or methane containing process gas can be used to produce ethanol. In this specification, references to “air” may be used for convenience but should be understood to include other gasses where appropriate.
In another alternative, a floating unit 40 can be used without process air to support a fixed biofilm. In this case, cords 12 may be provided without hollow fiber membranes, or the hollow fiber membranes can be used without supplying air to them, to support an anoxic or anaerobic biofilm. For example, a floating unit 40 may be added into a tank in a conventional activated sludge plant to provide an integrated fixed-film activated sludge (IFAS) reactor.
A floating unit 40 may be used in an essentially fixed film reactor such as an MABR where most of the active biomass in a tank 52 is fixed on the surface of the cords 12. Alternatively, a floating unit 40 may be used in a hybrid configuration where there is also biologically active suspended growth (planktonic biomass) in the tank. One application for a hybrid configuration is to add a floating unit 40 to a tank 52 in an existing activated sludge plant to enhance the removal of nitrogen.
The process air in this example is supplied at a pressure that is the sum of all pressure losses between the blower and the discharge point. This is composed of i) membrane losses, ii) discharge pressure and iii) conduit losses. The relationship between air flow and membrane losses for two sample cassettes 16 with smaller and larger hollow fibers is presented in
The exhaust discharge pressure is a design choice. An increased exhaust discharge pressure can be provided using an orifice in the exhaust discharge hose 56. The increased pressure provides additional driving force for gas permeation and can also ensure that the pressure inside the membranes is higher than the water static pressure outside the membranes at the lowest submergence depth of the membranes. This prevents water from entering the membranes should there be a leak. For example, with the lowest part of a membrane submerged 2.4 m below the water surface, static head pressure is about 25 kPa. The exhaust discharge pressure, optionally reduced by pressure loss in the exhaust hose 56, may be equal to or more than this static head pressure. The composition of the exhaust air is a function of the transport conditions at the membrane surface and the activity of the biofilm. In general, the flow rate of exhaust gas is 80-95% of the feed flow rate and the exhaust gas is low in oxygen.
In the example of a four cassette unit 40, hose 56 sizes can be selected to limit conduit losses to about 5 kPa. The process air is supplied at a total pressure of 55 kPa (25+25+5), which is within the operating range of typical centrifugal or positive displacement blowers used in biological wastewater treatment.
Still referring to
In one example, a plant has 24 units 40 with four cassettes 16 each for a total of 96 cassettes. Each unit 40 has an automatic valve 60. The units 40 are divided into six mixing groups, each mixing group having four units 40 and four automatic valves 60 that open and close simultaneously. Each mixing group receives mixing air in turn for 20 seconds out of a total cycle time of 120 seconds. While a cassette 16 receives mixing air, the mixing air flow rate is 80 Nm3/h/cassette. The total mixing air flow rate is 80 Nm3/h/cassette×96/6, or 1,280 Nm3/h.
In another example, a plant has 24 units 40 with four cassettes 16 each for a total of 96 cassettes. There is one automatic valve 60 for every three units 40, or a total of eight automatic valves 60. The units 40 are divided into eight mixing groups, each mixing group having three units 40 and one automatic valve 60. Each mixing group receives mixing air in turn for 20 seconds out of a total cycle time of 160 seconds. While a cassette receives mixing air, the mixing air flow rate is 80 Nm3/h/cassette. The total mixing air flow rate is 80 Nm3/h/cassette×96/8, or 960 Nm3/h.
The air flow rate required for scouring ranges between 160-320 Nm3/h/cassette, with a preferred value of about 240 Nm3/h/cassette. The frequency for scouring may be, for example, 1-14 scours per week, with a preferred value of about 7 scours per week. If the number of automatic valves in a system is larger than the number of mixing groups, the flow rate used for mixing may be used for scouring. In the first example above, if only two automatic valves 60 are opened at the same time (rather than four), the scouring flow rate is 1280/2/4 or 160 Nm3/h/cassette. If only one valve is opened, the scouring flow rate is 1280/1/4 or 320 Nm3/h/cassette. In the second example, because there is only one automatic valve per mixing group, the blower is ramped up, or an additional blower is turned on, to achieve the desired scouring flow rate. To accommodate the scouring flow rate, a non-process air hose 56 for a four cassette unit 40 may be about 100 mm (4 inches) in diameter.
Another hose 56 may be used for one or more ancillary functions such as removing liquid from a module 10, monitoring gasses exhausted from the module 10, or both. This ancillary function hose 56 may be a small tube, for example about 5 mm for a four-cassette unit 40. In the example shown in
At the monitoring station 70, each ancillary hose 56 is equipped with a valve 72, for example an on/off isolation valve. The valve 72 allows liquid to be removed, or exhaust monitored, from each unit 40 separately. For example, each unit may be treated once per hour or once per day in sequence. The monitoring station 70 has a vacuum pump 74, a liquid reservoir 76 on a load cell 78 and a liquid discharge line 80.
When monitoring or testing a unit 40, the associated isolation valve 72 is opened (as shown for the top ancillary hose 56 in
Liquid may collect in a unit 40 due to condensation of water vapor in the process air or due to leaks. The liquid is removed to allow for continued operation of the unit 40. Measuring the amount of liquid collected can be used, for example, to check for leaks in a unit. An expected amount of condensate can be calculated from data such as process air flow rate, relative humidity of process air, and the temperature of water in the tank 52. Comparing the amount of liquid collected to this estimate gives an indication of whether there are leaks and their significance. Alternatively, the amount of liquid removed over time can be monitored, optionally adjusted for seasonal or other factors, and used as a baseline. Significant departures from the baseline indicate a leak.
Exhaust gas monitoring can be used, for example, to determine the oxygen transfer rate of the unit 40. Using an appropriate calculation, for example using the difference in oxygen concentration between input process air and exhaust air and the process air flow rate, the rate of oxygen transferred through the unit 40 can be estimated. This rate gives an indication of the health of the biofilm and the rate of reaction in the biofilm. Although all of the exhaust air could be collected, it is more convenient to have an exhaust hose 56 extending from the lower header 14 to above the water around the module 10 without extending to the sides of the tank 52. Most of the exhaust air is simply vented, optionally through a restriction to cause the process air to be at higher pressure while in the module 10. Only a small amount of the exhaust air is required for exhaust gas monitoring, and this small amount can be withdrawn through the ancillary hose 56 to reduce the length of large diameter hose 56 required.
As shown in
Air supplied through the hose 56 flows either only to the modules 10 (process air) or both to the modules 10 and the aerators 20 depending on flow rate and pressure losses as illustrated in
Mixing and scouring air flow rates and frequencies can be similar to those described in relation to
Floating units 40 can be installed into existing tank 52 without interrupting operation of a plant or emptying the tank 52. Existing aeration diffusers and piping or other equipment in the tank 52 often does not need to be removed or relocated. The tethers 54 can be arranged to locate a unit 40 in a desired part of the tank 52, for example to improve mixing or biological conversion efficiency. If treatment objectives evolve over time, a unit 40 can be moved by reconfiguring or relocating its tethers 54. Optionally, a tank may have a set of tether attachment points available to allow a unit 40 to be relocated repeatedly, for example seasonally. The floating units 40 are generally self leveling which helps distribute process and non-process air equally among the modules. The aerators 20 are always under the same hydrostatic head despite changes in water level in the tank 52 so desired mixing and scouring air flow rates can be accurately achieved by controlled the applied gas pressure. Floating units 40 can be added, for example, to a suspended growth tank in a wastewater treatment plant. The suspended growth may be maintained under aerobic, anoxic or anaerobic conditions. In some circumstances, adding one or more floating units 40 might provide one or more advantages such as reducing energy consumption, accommodating a higher feed flow rate or pollutant loading, increasing nitrification capacity, increasing or implementing total nitrogen removal, or implementing biological phosphorous removal.
This written description uses examples to disclose the invention and also to enable any person skilled in the art to practice the invention, including making and using any devices or systems and performing any incorporated methods. The patentable scope of the invention is defined by the claims, and may include other examples that occur to those skilled in the art. Numerical parameters given above are intended as non-limiting examples and might be increased or decreased, for example by 50% of a single value or the end points of a range.
Filing Document | Filing Date | Country | Kind |
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PCT/US2015/037649 | 6/25/2015 | WO | 00 |