This application relates generally to designs and transfers and specifically to a flocked stretchable design or transfer.
It is often desirable to decorate clothing or other articles with designs that have various surfaces, such as designs that have a flocked surface such that the surface is fuzzy. Using flocked designs works well with clothes or other articles that are not meant to be stretched. To date, flocked designs have not been used with stretchable articles since the flock adhesive layer and, thus, the design, tends to permanently splits or cracks, sometimes without recovery, as the material is stretched. This is undesirable since the design becomes severely deformed. It is also undesirable since the flock fibers may become detached from the transfer or design, leaving permanent holes, voids, or gaps in the design. Another undesirable aspect of using flocked designs on stretchable articles is that the stretchable article may not reform to its original size and shape near the flocked design due to the adhesive used to keep the flocked design on the clothing or article.
Today's fashions are often characterized by stretchable materials, whether the stretchable material is a knitted material, nylon, polyester, elastic or other material. Thus, a wide market of clothing does not use flocked designs because of the undesirable characteristics associated therewith. What is needed is a flocked stretchable design or transfer that can be stretched with the clothing or other article that will reform to its original design without loss of design quality or adhesion or integrity of the image.
These and other needs are addressed by the various embodiments and configurations of the present invention. The present invention is directly generally to flocked elastic and/or elastomeric films.
In one embodiment of the present invention, flock fibers are embedded in an elastic or elastomeric film by heating the film to a temperature above its softening temperature but below its melting temperature and applying pressure to the fibers. When the film is cooled to a temperature below its softening temperature, the fibers are firmly and permanently held by the film in the absence of an adhesive. The resulting flocked interface between the flock fibers and the elastomeric film can thus be adhesive-free. The film may be contacted with flock by either direct flocking or flocked transfer techniques.
In another embodiment, an article is provided including:
(a) an elastomeric film having a modulus of elasticity of less than about 11.25 lbf, an elongation of at least about 200%, and/or a recovery from elongation of at least about 75%; and
(b) a plurality of flock fibers in contact with the elastomeric film.
The interface between the flock fibers and elastomeric film is free of an adhesive other than the elastomeric film.
The article can have a number of advantages relative to the current design articles. For example, the article can be adhesive-free, thereby saving material and labor costs. The elastomeric film itself acts as the adhesive. The flock is forced into the softened and tacky elastomeric film under pressure, such as during lamination. When cooled below the softening point, the flock is held firmly by the film. When a flock transfer is used, misoriented fibers are not received by the softened elastomeric film and stay on the sacrificial carrier. The article, however, may be manufactured using techniques less expensive than flock transfers. The elastomeric film may be coated with a release adhesive, for example, the release adhesive contacted with flock, and the flock later pressed into the elastomeric film when the film is thermally softened. Alternatively, the flock may be applied to the elastomeric film while the film is in the softened state. The electrostatic force may itself be sufficient to embed the fibers in the film. Finally, the unsoftened elastomeric film, may be electrostatically flocked. The residual electrostatic force will hold the flock in position on the film until the film is heated and the fibers pressed into the film.
These and other advantages will be apparent from the disclosure of the invention(s) contained herein.
As used herein, “at least one”, “one or more”, and “and/or” are open-ended expressions that are both conjunctive and disjunctive in operation. For example, each of the expressions “at least one of A, B and C”, “at least one of A, B, or C”, “one or more of A, B, and C”, “one or more of A, B, or C” and “A, B, and/or C” means A alone, B alone, C alone, A and B together, A and C together, B and C together, or A, B and C together.
The above-described embodiments and configurations are neither complete nor exhaustive. As will be appreciated, other embodiments of the invention are possible utilizing, alone or in combination, one or more of the features set forth above or described in detail below.
As shown in
The elastomeric film 204 should be durable, thermally stable, and able to resist the various treatments including but not limited to flocking and/or lamination process, applying chemicals, washing, heating, drying, both during the flocking process and after the design or transfer has been heat applied to the article. The elastomeric material can be of any suitable composition, such as rubber, polyurethane, and other elastomers. Particularly preferred elastomers include natural vulcanized rubber and other elastomers, such as styrene-butadiene copolymer, polychloroprene (neoprene), nitrile rubber, butyl rubber, polysulfide rubber (Thiokol), cis-1,4-polyisoprene, ethylene-propylene terpolymers (EPDM rubber), silicone rubber, (thermoplastic) polyurethane such as Spandex, and polyurethane rubber. As will be appreciated, “elastomers” refer to synthetic thermosetting (typically high) polymers having properties similar to those of vulcanized natural rubber, namely the ability to be stretched to at least twice their original length and to retract quickly to approximately their original length when released and to un-cross-linked polyolefins that are thermoplastic. “Thermosetting” materials are high polymers that solidify or set irreversibly when heated. This property is typically associated with a cross-linking reaction of the molecular constituents induced by heat or radiation. The material may include curing agents, such as organic peroxides or sulfur. Common thermosetting materials include rubber, (linear) polyethylene, phenolics, alkyds, amino resins, polyesters, epoxides, and silicones. Thermosetting materials have a thermoplastic (reversible or un-cross-linked) temperature regime and a thermosetting (irreversible or cross-linked) temperature regime. “Thermoplastic” materials high polymers that soften when exposed to heat and return to their original condition when cooled to room temperature. Examples of thermoplastic materials include crude rubber, waxes, polyvinyl chloride, nylons, fluorocarbons, (linear) polyethylene, polyurethane, polypropylene, and cellulosic and acrylic resins.
The elastomeric material is preferably elastic. The term “elastic” as used herein means those materials that have the ability to regain, at least substantially, their original shape after a load is removed. The elastic film preferably has a modulus of elasticity of less than about 11.25 pounds per foot (“lbf”) (50 N). The modulus of elasticity for the material selected is preferably above about 0.5 lbf (2.22 N) (where the modulus is defined as the force required to pull a ¼ inch sample from 3 inches to 6 inches). As the modulus of elasticity (Young's Modulus) is a fundamental material constant, the modulus is an index of the stiffness of the material. A higher value of the modulus indicates a more brittle material (i.e. glass, ceramics). A very low value represents a elastomeric material (i.e. rubber). The elastic film preferably has an elongation of at least about 200% and more preferably at least about 300% and a recovery of at least about 75% and more preferably at least about 95%. The recovery is the percent of the film's shape retained after the film is stretched to 100% of its original length at a rate of 30 inches per minute and the stretched film allowed to retract freely for 1 minute. The film preferably has an ultimate tensile strength of at least about 1,000, more preferably at least about 2,000, and even more preferably from about 2,000 to about 10,000 psi, and a tear strength of at least about 200, more preferably at least about 250, and even more preferably from about 250 to about 700 PLI.
Preferably, the elastomeric material is a substantially transparent, nonwoven, cast or extended thermoplastic polyester film, with (poly)urethane films being preferred. Even more preferably, the material is Clarense® by Bemis Associates Inc., Lycra® from Du Pont de Nemours Company, and Dorlastan® from Bayer and Dureflex® from Deerfield Urethane.
The elastomeric film 204 preferably is self-supporting and has a thickness ranging from about 1 mil to 25 mils and more preferably, from about 1 mil to 15 mils.
The flock 208 used in any of the processes discussed herein can be any electrostatically chargeable fiber, such as fibers made from rayon, nylon, cotton, acrylic, and polyester. Preferably, the flock preferably has a melting and/or softening point that is greater than and is resilient under the temperatures and pressures experienced in design manufacturing and later application processes to resist softening, deformation, and melting. Due to its low melt point, acrylic flock is undesirable in many applications. Resilient flock, such as rayon, nylon, and terephthalate (e.g., poly(cyclohexylene-dimethylene terephthalate) polymer flock, is particularly preferred. In most applications, the flock orientation is at least substantially orthogonal (perpendicular) to the first side of the elastic film.
A method to manufacture the design 200 will now be discussed with reference to
While the direct flocked embodiments can be less expensive than the heat transfer embodiment, the heat transfer embodiment has the advantage of removing fibers that are misoriented (i.e., are not normal or perpendicular to the film surface) as they remain on the carrier sheet/release adhesive assembly after removal.
In another embodiment shown in
In one configuration, the film 500 is a self-supporting, solid adhesive film 500, such as described in copending U.S. patent application Ser. Nos. 09/621,830, filed Jul. 24, 2000; 10/670,091, filed Sep. 23, 2003; 10/455,541, filed Jun. 4, 2003; 09/735,721, filed Dec. 13, 2000; and 10/455,575, filed Jun. 4, 2003, each of which is incorporated herein by this reference. The adhesive film 500 is formed before application to the elastomeric film 204, such as solvent casting the film on a sacrificial carrier 504. When the article is manufactured, the lower roll 104 of transfer 108 is replaced by a roll of the adhesive film 500 and carrier 504, with the free (exposed) surface of the adhesive film 500 facing upwards to adhesively engage the film 204. Thus, the transfer and adhesive film 500 are adhered to the carrier 504 at the same time during lamination. The sacrificial carrier 504 supports the solidified film and is removed after application to the film 204 and before application to the substrate 508. The removal of the carrier 504 is shown in
In another configuration, no permanent adhesive film 500 is required to apply the elastomeric film 204 to a desired substrate. This article configuration is formed by replacing the lower roll 104 of transfer 108 with a roll of the substrate 508. Thus, both the flock 208 and substrate 508 are adhered to the film 204 at the same time during lamination. In this configuration, the upper interface between the flock and film 204 and lower interface between the film 204 and substrate 508 are free of an intervening permanent adhesive.
To adhere to a substrate without a further adhesive, the elastomeric film is heated to a temperature sufficient to cause the film to become tacky (which is typically above the softening point) but to a temperature that is less than the temperature used to embed the flock fibers in the film. This maintains desired flock fiber orientation and prevents the flock fibers from being dislodged and/or matted down in the film.
A number of variations and modifications of the invention can be used. It would be possible to provide for some features of the invention without providing others.
For example in one alternative embodiment, only one surface of the film 208 is flocked and the unflocked opposing surface is free of an adhesive. This embodiment may be used to produce a patch.
The present invention, in various embodiments, includes components, methods, processes, systems and/or apparatus substantially as depicted and described herein, including various embodiments, subcombinations, and subsets thereof. Those of skill in the art will understand how to make and use the present invention after understanding the present disclosure. The present invention, in various embodiments, includes providing devices and processes in the absence of items not depicted and/or described herein or in various embodiments hereof, including in the absence of such items as may have been used in previous devices or processes, e.g., for improving performance, achieving ease and/or reducing cost of implementation.
The foregoing discussion of the invention has been presented for purposes of illustration and description. The foregoing is not intended to limit the invention to the form or forms disclosed herein. In the foregoing Detailed Description for example, various features of the invention are grouped together in one or more embodiments for the purpose of streamlining the disclosure. This method of disclosure is not to be interpreted as reflecting an intention that the claimed invention requires more features than are expressly recited in each claim. Rather, as the following claims reflect, inventive aspects lie in less than all features of a single foregoing disclosed embodiment. Thus, the following claims are hereby incorporated into this Detailed Description, with each claim standing on its own as a separate preferred embodiment of the invention.
Moreover, though the description of the invention has included description of one or more embodiments and certain variations and modifications, other variations and modifications are within the scope of the invention, e.g., as may be within the skill and knowledge of those in the art, after understanding the present disclosure. It is intended to obtain rights which include alternative embodiments to the extent permitted, including alternate, interchangeable and/or equivalent structures, functions, ranges or steps to those claimed, whether or not such alternate, interchangeable and/or equivalent structures, functions, ranges or steps are disclosed herein, and without intending to publicly dedicate any patentable subject matter.
The present application claims the benefits of U.S. Provisional Patent Application Ser. No. 60/719,098, filed Sep. 20, 2005, which is incorporated herein by this reference.
Number | Name | Date | Kind |
---|---|---|---|
1580717 | Flick | Apr 1926 | A |
1975542 | Forsdale | Oct 1934 | A |
1992676 | Schwarz | Feb 1935 | A |
2047978 | Maclaurin | Jul 1936 | A |
2275617 | Duerr et al. | Mar 1942 | A |
2278227 | Thackeray et al. | Mar 1942 | A |
2477912 | Vallandigham | Aug 1949 | A |
2592602 | Saks | Apr 1952 | A |
2636837 | Summers | Apr 1953 | A |
2835576 | Ensink | May 1958 | A |
2981588 | Hyman | Apr 1961 | A |
2999763 | Sommer | Sep 1961 | A |
3099514 | Haber | Jul 1963 | A |
3215584 | McConnell et al. | Nov 1965 | A |
3314845 | Perri | Apr 1967 | A |
3351479 | Fairchild | Nov 1967 | A |
3377232 | Mencock et al. | Apr 1968 | A |
3432446 | Coppeta | Mar 1969 | A |
3459579 | Newman | Aug 1969 | A |
3496054 | Baigas | Feb 1970 | A |
3529986 | Kappas et al. | Sep 1970 | A |
3565742 | Stephens et al. | Feb 1971 | A |
3591401 | Snyder et al. | Jul 1971 | A |
3630990 | Neal | Dec 1971 | A |
3644267 | Jackson, Jr. et al. | Feb 1972 | A |
3660200 | Anderson et al. | May 1972 | A |
3674611 | Petry et al. | Jul 1972 | A |
3772132 | Dulin, Jr. | Nov 1973 | A |
3775205 | Hermann et al. | Nov 1973 | A |
3803453 | Hull | Apr 1974 | A |
3837946 | Gribbin | Sep 1974 | A |
3887737 | Baxter et al. | Jun 1975 | A |
3900676 | Alderson | Aug 1975 | A |
3903331 | Klein | Sep 1975 | A |
3917883 | Jepson | Nov 1975 | A |
3918895 | Mizuno | Nov 1975 | A |
3928706 | Gibbons | Dec 1975 | A |
3936554 | Squier | Feb 1976 | A |
3956552 | Geary | May 1976 | A |
3961116 | Klein | Jun 1976 | A |
3969559 | Boe | Jul 1976 | A |
3979538 | Gilman et al. | Sep 1976 | A |
4018956 | Casey | Apr 1977 | A |
4025678 | Frank | May 1977 | A |
4031281 | Keeling | Jun 1977 | A |
4034134 | Gregorian et al. | Jul 1977 | A |
4035532 | Gregorian et al. | Jul 1977 | A |
4062992 | Power et al. | Dec 1977 | A |
4088708 | Riew | May 1978 | A |
4142929 | Otomine et al. | Mar 1979 | A |
4160851 | Lienert et al. | Jul 1979 | A |
4201810 | Higashiguchi | May 1980 | A |
4218501 | Kameya et al. | Aug 1980 | A |
4238190 | Rejto | Dec 1980 | A |
4263373 | McCaskey et al. | Apr 1981 | A |
4273817 | Matsuo et al. | Jun 1981 | A |
4282278 | Higashiguchi | Aug 1981 | A |
4292100 | Higashiguchi | Sep 1981 | A |
4294577 | Bernard | Oct 1981 | A |
4308296 | Chitouras | Dec 1981 | A |
4314813 | Masaki | Feb 1982 | A |
4319942 | Brenner | Mar 1982 | A |
4340632 | Wells et al. | Jul 1982 | A |
4352924 | Wooten et al. | Oct 1982 | A |
4362773 | Shikinami | Dec 1982 | A |
4387214 | Passmore et al. | Jun 1983 | A |
4390387 | Mahn | Jun 1983 | A |
4396662 | Higashiguchi | Aug 1983 | A |
4413019 | Brenner | Nov 1983 | A |
4423106 | Mahn | Dec 1983 | A |
4430372 | Knoke et al. | Feb 1984 | A |
4438533 | Hefele | Mar 1984 | A |
4465723 | Knoke et al. | Aug 1984 | A |
4588629 | Taylor | May 1986 | A |
4652478 | Mau | Mar 1987 | A |
4668323 | Lenards et al. | May 1987 | A |
4687527 | Higashiguchi | Aug 1987 | A |
4741791 | Howard et al. | May 1988 | A |
4810549 | Abrams et al. | Mar 1989 | A |
4861644 | Young et al. | Aug 1989 | A |
4895748 | Squires | Jan 1990 | A |
4923848 | Akada et al. | May 1990 | A |
4931125 | Volkmann et al. | Jun 1990 | A |
4980216 | Rompp | Dec 1990 | A |
5008130 | Lenards | Apr 1991 | A |
5041104 | Seal | Aug 1991 | A |
5047103 | Abrams et al. | Sep 1991 | A |
5059452 | Squires | Oct 1991 | A |
5077116 | Lefkowitz | Dec 1991 | A |
5115104 | Bunyan | May 1992 | A |
5126182 | Lumb et al. | Jun 1992 | A |
5155163 | Abeywardena et al. | Oct 1992 | A |
5207851 | Abrams | May 1993 | A |
5298031 | Gabay et al. | Mar 1994 | A |
5346746 | Abrams | Sep 1994 | A |
5403884 | Perlinski | Apr 1995 | A |
5480506 | Mahn, Sr. et al. | Jan 1996 | A |
5529650 | Bowers et al. | Jun 1996 | A |
D372403 | Jensen | Aug 1996 | S |
5543195 | Squires et al. | Aug 1996 | A |
5597633 | Mecke et al. | Jan 1997 | A |
5597637 | Abrams et al. | Jan 1997 | A |
5681420 | Yamane | Oct 1997 | A |
5685223 | Vermuelen et al. | Nov 1997 | A |
5756180 | Squires et al. | May 1998 | A |
5771796 | Morrison et al. | Jun 1998 | A |
5858156 | Abrams et al. | Jan 1999 | A |
5863633 | Squires et al. | Jan 1999 | A |
6010764 | Abrams | Jan 2000 | A |
6025068 | Pekala | Feb 2000 | A |
6083332 | Abrams | Jul 2000 | A |
6110560 | Abrams | Aug 2000 | A |
6114023 | Schwarz et al. | Sep 2000 | A |
6178680 | Sloot | Jan 2001 | B1 |
6224707 | Lion | May 2001 | B1 |
6247215 | Van Alboom et al. | Jun 2001 | B1 |
6249297 | Lion | Jun 2001 | B1 |
6350504 | Alboom et al. | Feb 2002 | B1 |
6361855 | Mahn, Jr. et al. | Mar 2002 | B2 |
6376041 | Morrison et al. | Apr 2002 | B1 |
6436506 | Pinter et al. | Aug 2002 | B1 |
6676796 | Pinter et al. | Jan 2004 | B2 |
6774067 | Demott et al. | Aug 2004 | B2 |
6924000 | Tallmadge | Aug 2005 | B2 |
7135518 | Bandou et al. | Nov 2006 | B2 |
7229680 | Crompton | Jun 2007 | B1 |
7344759 | Penttinen et al. | Mar 2008 | B2 |
7393516 | Seo et al. | Jul 2008 | B2 |
7410682 | Abrams | Aug 2008 | B2 |
7461444 | Deaett et al. | Dec 2008 | B2 |
20010008039 | Alboom et al. | Jul 2001 | A1 |
20010008672 | Norvell et al. | Jul 2001 | A1 |
20020009571 | Abrams | Jan 2002 | A1 |
20020098329 | Abrams | Jul 2002 | A1 |
20030129353 | Abrams | Jul 2003 | A1 |
20030176567 | Tallmadge | Sep 2003 | A1 |
20030186019 | Abrams | Oct 2003 | A1 |
20030207072 | Abrams | Nov 2003 | A1 |
20030211279 | Abrams | Nov 2003 | A1 |
20040010093 | Wefringhaus et al. | Jan 2004 | A1 |
20040033334 | Merovitz | Feb 2004 | A1 |
20040050482 | Abrams | Mar 2004 | A1 |
20040053001 | Abrams | Mar 2004 | A1 |
20040055692 | Abrams | Mar 2004 | A1 |
20040058120 | Abrams | Mar 2004 | A1 |
20040081791 | Abrams | Apr 2004 | A1 |
20040170799 | Carr et al. | Sep 2004 | A1 |
20050081985 | Abrams | Apr 2005 | A1 |
20050158508 | Abrams | Jul 2005 | A1 |
20050260378 | Bernabeu | Nov 2005 | A1 |
20050266204 | Abrams | Dec 2005 | A1 |
20050268407 | Abrams | Dec 2005 | A1 |
20060026778 | Lion | Feb 2006 | A1 |
20060029767 | Lion | Feb 2006 | A1 |
20060142405 | Kijima | Jun 2006 | A1 |
20060251852 | Abrams | Nov 2006 | A1 |
20060257618 | Bernabeu | Nov 2006 | A1 |
20070003761 | Miyazono et al. | Jan 2007 | A1 |
20070022548 | Abrams | Feb 2007 | A1 |
20070026189 | Abrams | Feb 2007 | A1 |
20070110949 | Abrams | May 2007 | A1 |
20070148397 | Abrams | Jun 2007 | A1 |
20070289688 | Abrams | Dec 2007 | A1 |
20080003399 | Abrams | Jan 2008 | A1 |
20080006968 | Abrams | Jan 2008 | A1 |
20080050548 | Abrams | Feb 2008 | A1 |
20080095973 | Abrams | Apr 2008 | A1 |
20080102239 | Abrams | May 2008 | A1 |
20080111047 | Abrams | May 2008 | A1 |
20080113144 | Abrams | May 2008 | A1 |
20080124503 | Abrams | May 2008 | A1 |
20080145585 | Abrams | Jun 2008 | A1 |
20080150186 | Abrams | Jun 2008 | A1 |
20080187706 | Lion et al. | Aug 2008 | A1 |
Number | Date | Country |
---|---|---|
606651 | Feb 1991 | AU |
653994 | Oct 1994 | AU |
757595 | Apr 1967 | CA |
2010076 | Aug 1990 | CA |
1306411 | Aug 1992 | CA |
2064300 | Sep 1992 | CA |
3004560 | Aug 1981 | DE |
19707381 | Aug 1998 | DE |
19734316 | Feb 1999 | DE |
0122656 | Oct 1984 | EP |
0210304 | Feb 1987 | EP |
0280296 | Aug 1988 | EP |
0506601 | Sep 1992 | EP |
0685014 | Dec 1995 | EP |
0913271 | Oct 1998 | EP |
0989227 | Mar 2000 | EP |
1072712 | Jan 2001 | EP |
1598463 | Nov 2005 | EP |
2543984 | Oct 1984 | FR |
2659094 | Sep 1991 | FR |
2881149 | Jul 2006 | FR |
1171296 | Nov 1969 | GB |
1466271 | Mar 1977 | GB |
2065031 | Jun 1981 | GB |
2101932 | Jan 1983 | GB |
2126951 | Apr 1984 | GB |
2214869 | Sep 1989 | GB |
0506601 | Sep 1992 | GB |
71007184 | Jun 1965 | JP |
55079143 | Jun 1980 | JP |
56107080 | Aug 1981 | JP |
56108565 | Aug 1981 | JP |
56141877 | Nov 1981 | JP |
58062027 | Apr 1983 | JP |
S61-146368 | Jul 1986 | JP |
62-033576 | Feb 1987 | JP |
63118544 | May 1988 | JP |
64-014021 | Jan 1989 | JP |
S64-068582 | Mar 1989 | JP |
01192538 | Aug 1989 | JP |
01-266284 | Oct 1989 | JP |
01-310947 | Dec 1989 | JP |
02048076 | Feb 1990 | JP |
04-126221 | Apr 1992 | JP |
04-169297 | Jun 1992 | JP |
5-201196 | Aug 1993 | JP |
08-267625 | Oct 1996 | JP |
11256484 | Sep 1999 | JP |
2000263673 | Sep 2000 | JP |
2001270019 | Oct 2001 | JP |
2003063833 | Jul 2003 | KR |
WO 8901829 | Mar 1989 | WO |
WO 9009289 | Aug 1990 | WO |
WO 9204502 | Mar 1992 | WO |
WO 9312283 | Jun 1993 | WO |
WO 9419530 | Sep 1994 | WO |
WO 9734507 | Sep 1997 | WO |
WO 0207959 | Jan 2002 | WO |
WO 0209925 | Feb 2002 | WO |
WO 02058854 | Aug 2002 | WO |
WO 03031083 | Apr 2003 | WO |
WO 2004005023 | Jan 2004 | WO |
WO 2004005600 | Jan 2004 | WO |
WO 2005035235 | Apr 2005 | WO |
WO 2005118948 | Dec 2005 | WO |
Number | Date | Country | |
---|---|---|---|
20070102093 A1 | May 2007 | US |
Number | Date | Country | |
---|---|---|---|
60719098 | Sep 2005 | US |