Flocked transfer and article of manufacture including the application of the transfer by thermoplastic polymer film

Information

  • Patent Grant
  • 7381284
  • Patent Number
    7,381,284
  • Date Filed
    Wednesday, June 4, 2003
    21 years ago
  • Date Issued
    Tuesday, June 3, 2008
    16 years ago
Abstract
A flocked transfer is produced by applying a release agent to a release sheet, and then applying the flocking to a release agent. Unlike the traditional method, a binder and thermoplastic hot melt film is applied to the back of the flock. The transfer, which is essentially release sheet, is then applied to a substrate, such as item of clothing, a rubber pad, etc., by positioning a sheet of thermoplastic hot melt film on the substrate; placing the transfer on the hot melt with the flock in contact with the hot melt film; and applying heat and pressure. The heat melts the thermoplastic hot melt film to bind the flock to the substrate and binds the flocking together. This method reduces the cost involved in producing flocked articles, especially for articles produced on a continuous basis.
Description
STATEMENT REGARDING FEDERALLY SPONSORED RESEARCH DEVELOPMENT

N/A


BACKGROUND OF THE INVENTION

This invention relates to flocked transfers, and, in particular to an improved method incorporating thermoplastic polymer film, in the making of the flocked transfer, which can reduce the cost and time required of producing transfers by a significant amount.


Heretofore, flocked transfers have generally been produced by applying a release agent to a release sheet. The flocking is applied to the release sheet in the desired pattern. A binder and a permanent hot melt adhesive are applied to the back of the flocking, and the transfer is allowed to dry. The binder is required to hold the flocking in the desired pattern. The hot melt adhesive, which is applied to the transfer as a powder, is used to adhere the transfer to a substrate, such as an article of clothing, a rubber pad, etc. The transfer is applied to the substrate by placing the transfer on the substrate with the dried hot melt adhesive in contact with the substrate. Heat, such as from an iron, is then applied to the release sheet. The heat melts the hot melt adhesive, to cause hot melt adhesive to flow into intimate contact with the substrate, forming a mechanical or physical adhesion with the substrate. The release agent then allows the release sheet to be removed from the transfer, leaving the flocking exposed on the substrate.


This traditional method has worked well for years. However, the method can be improved upon to reduce the cost of producing the transfer, and hence, the cost of the item containing the transfer.


In my co-pending application, I have described the usage of a thermoset film in lieu of the bond and powder for adhesion, which film, when subject to heat, adheres to the substrate, functions as an inherence for the flock. This current invention adds further enhancements to this process, by allowing the application and usage of a thermoplastic film, for adherence of the flock transfer.


BRIEF SUMMARY OF THE INVENTION

In accordance with the invention, generally stated, a flocked transfer of the present invention is produced by applying a release agent to a release sheet, and then applying the flocking to the release agent. Unlike the traditional method, a binder and adhesive are not applied to the ends of the flock, but rather, a thermoplastic polymer film is used in lieu thereof.


To form an article of manufacture with the flocked transfer, a hot melt film (in the form of a sheet are cut to shape) is positioned on the substrate to which the transfer is to be applied. The hot melt is preferably a blank or blank film, but can be any thermoplastic type of polymer film. The flock with the release adhesive and release sheet (i.e., the transfer) is then placed on the sheet of hot melt film with the release sheet up, so that the flocking is in contact with the hot melt film. Heat is then applied to the transfer. The heat melts the hot melt film, and secures the flock to the substrate. Because the film is thermoplastic, even if it is subsequently subjected to heat, below a particular temperature, it will not remelt, nor become tacky, and hence, there is no risk of the fibers becoming matted down in any of this type of adhesive, which could otherwise ruin the plush pile effect. It is known that there is a enhanced adhesion with thermoplastic materials, because the thermoplastic materials will cross-attach, and thereby adhere the flock fibers to it, which may become chemically attached thereto. Through the usage of this invention, the finished flock surface is more plush, soft, because more of the fiber is exposed and extends upwardly out of the adhesive, than with the screen-printed latex, as currently used. Also, this affords better soil release during washing or cleaning because of less fiber/adhesive entanglement occurs with the flock, during application.


The use of a thermoplastic type of film for achieving adherence of a transfer to a surface, can be done either before or after the heat transferring operation, or where the heat transfer is produced. The thermoplastic film can be brought into the process at either stage, with respect to the manufacture of the transfer. It is most practical to combine the hot melt film before the heat transfer is fabricated, so it is combined in a convenient and portable manner, which operation was not possible with the previous type of application, for the thermoset film, because once the thermoset film was heated, it sets, and cannot be reheated.


In addition, it is possible to use a two-part thermoplastic type of film, such as commonly available in the industry, having different properties on each side in terms of, for example, melting point, and viscosity of structure. In this way, one can use a higher melting point hot melt film, of thermoplastic material, on the side that attaches to the flock fibers, so that the transfer is initially put together with higher heat in order to set the fibers in place, and then subsequently during application of the transfer to a textile, it may be done at a lower temperature to activate the hot melt on the substrate side while not hot enough to remelt the film holding the flock in place. Also, the hot melt holding the flock can be a very high viscosity, that is, it will not flow much when melted, in order to keep the fibers in place and not mat them together, while the film on the substrate side could be a lower viscosity type of film, that will readily flow so it will penetrate and establish a good mechanical adhesion of the transfer or grid to any substrate upon which the transfer is applied.


Thus, it is an object of this invention to provide for the development of a flock, that may be temporarily adhered onto a release film carrier, fabricated of a thermoplastic film. And, it is a further object that the hot melt film may be used as an intermediate layer, to attach the fibers to the substrate, when developing the transfer initially.





BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS


FIG. 1 is a cross-sectional view of a prior art flock transfer;



FIG. 2 is a cross-sectional view of a flock transfer of the present invention;



FIG. 3 is an exploded view of the transfer, a hot melt sheet, and a substrate used to make an article of manufacture;



FIG. 4 is a cross-sectional view of an article of manufacture using the transfer of the present invention, showing a part of the transfer applied to part of the substrate and a part of the transfer and hot melt film spaced from the substrate; and



FIG. 5 is a schematic drawing of a process for continuously producing articles of manufacture, such as mouse pads, coasters, transfers for application to clothing, etc.





Corresponding reference numerals will used throughout the several views of the drawings.


DESCRIPTION OF THE PREFERRED EMBODIMENT

The following detailed description illustrates the invention by way of example, and not by way of limitation. This description will enable one skilled in the art to make and use the invention, including what is presently believed is the best mode of carrying out the invention.


A prior art flock transfer 101 is shown in FIG. 1. As is known, such transfers include a dimensionally stable release sheet 103, to which a conventional flock transfer release adhesive 105 is applied in a pattern which corresponds to the overall image to be flocked. The flock 107 is then electrostatically coated to the release sheet 105. A binder adhesive 109 is applied to the exposed ends of the flock to bind the flock together as a unit. Lastly, a hot melt adhesive 111 is applied. The transfer is then allowed to dry. The transfer is applied to a substrate, as is known, by positioning the transfer on a substrate, such as a shirt, coat, or other item of clothing, with the hot melt adhesive in contact with the substrate, and applying to the transfer. The heat activates the hot melt adhesive to adhere the transfer to the substrate. This process is described in my prior patent, U.S. Pat. No. 4,810,549, as well as in my co-pending application, Ser. No. 09/548,839, filed Apr. 13, 2000, both of which are incorporated herein by reference.


In addition, I have described a similar transfer to that of this current invention, utilizing a thermosetting film, in my application having Ser. No. 09/621,830, filed on Jul. 24, 2000. The contents of that application are incorporated herein by reference.


A flocked transfer 1 of the present invention is shown in FIG. 2. The transfer 1 of the present invention includes a release sheet 3, to which a conventional release agent 5, such as a wax, or other binder, has been applied. The release agent is applied to the sheet in the shape of a pattern of the flocking. Flocking 7 is then applied to the release agent, and hence, to the release sheet, to form the transfer. The flocking 7 is applied, for example, in the manner as described in my previous patent and applications, which are incorporated herein by reference. Unlike the prior art processes, the transfer 1 is made without the use of a binder adhesive or hot melt adhesive. As is discussed below, a thermoplastic film is used to adhere the transfer to a substrate.


An article of manufacture, such as an item of clothing having a transfer 1 applied thereto, a mouse pad, coaster, or any numerous items having a flocked surface, can be manufactured in accordance with this invention and is easily produced using the transfer 1. Referring to FIGS. 2-5, the article of manufacture 11 is produced by positioning a hot melt sheet 13 between a substrate 15 and the flocked release sheet. The hot melt sheet is, for example, a sheet of thermosetting polyester, available from Bostik, Inc. The hot melt sheet can also be made from a thermoplastic polymer, comprising polyesters, and which is available from Bostik. The hot melt sheet can also be made from a thermoplastic polyurethane. Any other thermoplastic film should also work well. The substrate 15 can be an item of clothing, a rubber pad (as for example, for producing a mouse pad or coaster), etc. The hot melt sheet can be precut to correspond to the shape of the transfer. The transfer 1 is then positioned on the hot melt sheet with the flock 7 against the hot melt sheet 13. Heat is applied to the transfer through the release sheet to activate the hot melt sheet. The hot melt sheet then acts to both bind the flock 7 together and to generally permanently adhere the flock 7 to the substrate 15. Preferably, to assemble the article, the flocked release sheet, the thermoplastic film, and the substrate are brought together and passed through a heat-laminating press where the three parts are subject to temperature of about 300° F. to about 350° F. (about 150° C.) and pressure (about 40-50 psi) for about 30 seconds. It has been found that medium-to-firm pressure has been most advantageous in providing for assembly of this type of plush flocked transfer. The pressure and heat will cause the hot melt film to adhere to the flock and the substrate. Additionally, the hot melt film will physically adhere or cure, to give a strong attachment of the flock to the substrate.


The basic premise of this application in utilizing a thermoplastic film which will semi-cure, after heat has been used to apply the transfer to a substrate, is that after heat application, if the temperature of the transfer does not rise to a particular heat level, it should not remelt again. In other words, the object is to use a hot melt film which has a melting point significantly high enough, so that when the transfer is applied through heat, it will adhere to the substrate, but that when the transfer and the substrate to which it is applied is not exposed to excessive heat, it will not remelt, even through the polymer film is thermoplastic, and for all practical purposes, in actual usage, the film will not remelt since it does not see those high temperatures again. In other words, if the melting point of the thermoplastic film is 350° F., and the top temperature that the flocked finished product will encounter, for example sunlight in a hot car, is only 250° F., then there is not a problem associated with the fact that the film is a thermoplastic and therefore can theoretically melt again, but only if it encounters those excessive temperatures.


Another attribute of the use of a thermoplastic film is that in the event one desires to remove the flocked transfer from, for example, an item of clothing, subjecting the transfer to those elevated temperatures, again, will allow the flock to be removed, if that is a need of the owner.


Articles, such as mouse pads or coasters, in which the entire top surface of the article is covered with the flocking can be produced on a continuous basis, as shown in FIGS. 3 and 5. Rolls 21, 23, and 25 of a flocked release sheet 1, the thermoplastic hot melt film 13, and the substrate 15, are provided. The three parts are brought together at a lamination station 33. Rollers can be provided in front of the station 33 so that the three elements are adjacent each other as they enter the lamination station. Rollers can be provided in front of the station 33 so that the three elements are adjacent as they enter the lamination station. In the lamination station, heat and pressure are applied to the three sheets (the flocked release sheet, the hot melt film, and the substrate) to melt the hot melt film. The melted hot melt film will then cure or cross-link, as noted above, to adhere the flock to the substrate. A web 35 exits the laminating station. The web 35 is then allowed to cool. The web 35 is ultimately directed to a cutting station where it is cut into individual articles. Once the web 35 is cooled, it can be directed immediately to a cutting station (after the sheet 35 cools), or can it can be wound up on an uptake roller to be cut into individual articles at a later time, or at a different location. At the cutting station, the release sheet 3 is removed from the flock and gathered on a take-up roll or is otherwise disposed of. After the release sheet has been removed from the flock, the substrate with the flock adhered thereto is cut to form the articles 11. It is also likely that one could remove the release liner either before or after the die cutting procedure. As shown in FIG. 3, a fringe material 50 can be applied to peripheral edges of the flocked release sheet 1 or substrate 15 during this manufacturing process.


Preferably the release sheet is flocked and supplied in roll form as shown in FIG. 5. However, the flocking of the release sheet could be made part of the process.


To produce flocked articles, such as shirts, jackets, sports bags, etc., which cannot be easily flocked on a continuous basis, the hot melt sheet can be applied to the transfer 1 prior to applying the transfer to the substrate. To do this, the thermoplastic hot melt film is placed in contact with the flock of the transfer, and the transfer and release sheet are heated to a temperature at which the thermoplastic hot melt film becomes tacky, but below the temperature at which the thermoplastic hot melt film begins to cure or physically adhere. This will adhere the thermoplastic hot melt film to the transfer 1 to form a transfer which can later be applied to an article by positioning the transfer with the hot melt film in position on the article (i.e., a piece of clothing) and applying heat and pressure to the transfer, for example, with an iron, sufficient to melt the hot melt film, to cause the hot melt film to somewhat cure or physically adhere, to adhere the flock, and secure to the clothing.


The method eliminates two steps from the prior art method: (1). Application of the binder adhesive, and (2) application, cleaning, sintering, and drying of the hot melt adhesive. In a continuous process, the present method also eliminates a station for applying the binder of hot melt adhesives as well as a station for drying the completed transfer. Because the station is not needed to apply (i.e., print) the binder and hot melt adhesives are applied to the flocking as part of the transfer, the machinery required to produce the article 11 is much less expensive (both in actual cost and in maintenance cost). Additionally, because the binder adhesive and hot melt adhesive is not used, the cost of the article of manufacture is reasonably reduced.


It is conceivable in the performance of the manufacture of the transfer of this invention, that the thermoplastic film may be a dual laminated type of film. For example, the upper surface may include a polyester type of film, that may have a melting point at a higher temperature. The lower film, laminated thereto, may be a polyethylene type of film, designed to have a lower temperature melting point. Hence, when the flock is applied to the upper surface of the laminated film, it will embed slightly into that film when heated, and the flock is electrostatically or otherwise applied, and while the bottom surface of the laminated film may likewise soften, once the transfer is cooled, all the films will become structurally sound, once again, in a film structure. Then, when a lower heat is applied to the transfer, for application of the transfer to a textile, rubber, or other surface, as when the transfer is being applied, the bottom polyethylene or EVA film will slightly soften, or melt, to function as an adhesive, for application of the entire transfer to its supporting substrate or surface. This is an example as to how the thermoplastic film(s) of this invention can be used not only for constructing of the transfer, but to function in a dual manner to allow for the application of the transfer to a shirt, bag, or other material, during its final application.


Another one of the advantages of utilization of thermoplastics, in the fabrication of flocked transfers, is that the binder adhesives previously used in the flocking process, typically contain an acrylic, or other materials, which may be flammable. Thermoplastics avoid that predicament. Furthermore, the thermoplastic type binder exhibits wash fastness, and will hold the flock in place even during severe washing conditions. Furthermore, thermoplastic films exhibit better elasticity, than can be obtained from the thermoset or other binder hot melt systems now in use. In addition, the use of the film provides a thinner profile for the finished product, providing a less bulky type of flock transfer, both visually and structural wise, when applied to a garment or other textiles. For example, flock transfers made in accordance with this invention can even be used upon sheer garment textiles. The usage of the thermoplastic film of this invention, avoids the necessity for application of binders, as previously used, and which contain formaldehyde or other undesirable chemicals, as used in previous adhesives to achieve cross linking for flocking purposes in the prior art. There are other miscellaneous film properties that are enhanced through the usage of thermoplastic films, versus the usage of the binder-hot melt powder combination, because there are films that have performance characteristics that cannot be obtained nor are they available for the binder-powder systems. For example, adhesions to leather, or other tough-to-stick-to-surfaces, that exhibit greater tensile strength, such as stretching that will not split, can be better accommodated through the usage of thermoplastic film.


Variations or modifications to the subject matter of this invention may occur to those skilled in the art upon reviewing the invention as described herein. Such variations, if within the scope of this invention, are intended to be encompassed within the claims to issue upon the invention of this application. The description of the preferred embodiment, as shown in the drawings, is set forth for illustrative purposes only.

Claims
  • 1. A method of producing a flocked transfer comprising: (a) supplying a flocked release sheet comprising a release sheet, a release adhesive adhered to the release sheet, and a plurality of flock fibers, with the flock fibers being adhered to the release sheet by the release adhesive;(b) supplying a pre-formed, solid, and self-supporting thermoplastic adhesive sheet;(c) thereafter contacting the flocked release sheet with the pre-formed, solid, and self-supporting thermoplastic adhesive sheet, with the flock fibers being substantially perpendicular to an adjacent surface of the thermoplastic adhesive sheet and the flock being positioned between the release sheet and release adhesive on the one hand and the thermoplastic adhesive sheet on the other; and(d) while the flocked release sheet is in contact with the thermoplastic adhesive sheet, heating and applying pressure to the pre-formed, solid, and self-supporting thermoplastic sheet to soften the thermoplastic adhesive and embed ends of the flock fibers in the thermoplastic adhesive sheet, thereby adhering the thermoplastic adhesive sheet to the flock of the flocked release sheet.
  • 2. The method of claim 1, wherein the step of heating the thermoplastic adhesive sheet comprises heating the thermoplastic adhesive sheet to a temperature at which the thermoplastic adhesive sheet becomes tacky, but below a temperature at which the thermoplastic adhesive sheet begins to soften or physically adhere and wherein the thermoplastic adhesive sheet is later adhered to a substrate.
  • 3. The method of claim 1, wherein the step of heating the thermoplastic adhesive sheet comprises heating the thermoplastic adhesive sheet to a temperature at which the thermoplastic adhesive sheet softens and wherein the thermoplastic adhesive sheet is in contact with a substrate during heating and is adhered permanently to the substrate after heating.
  • 4. The method of claim 3 wherein the thermoplastic adhesive sheet has upper and lower portions, wherein the upper portion is contacted with the substrate, wherein the lower portion is contacted with the flock and is positioned between the flock and upper portion, and wherein at least one of the melting point and viscosity of the upper portion is higher than the at least one of the melting point and viscosity of the lower portion.
  • 5. The method of claim 4, wherein the upper portion has a higher melting point than the lower portion.
  • 6. The method of claim 1, wherein the thermoplastic adhesive sheet is at least one of a thermoplastic polyurethane blank and a thermoplastic polyester blank having a substantially uniform thickness.
  • 7. The method of claim 1, wherein at least most of the flock is in direct contact with the thermoplastic adhesive sheet.
  • 8. The method of claim 1, wherein there is no binder adhesive in contact with the thermoplastic adhesive sheet.
  • 9. The method of claim 1, wherein the release sheet and thermoplastic adhesive sheet are on opposing surfaces of the flock.
  • 10. The method of claim 1, wherein the heating step is performed substantially in the absence of a binder adhesive positioned between the thermoplastic adhesive sheet and the flock.
  • 11. The method of claim 1, wherein, after step (d), an embedded length of a flock fiber is positioned in the adhesive and wherein, for most of the flock fibers, the embedded flock length used for the thermoplastic adhesive sheet is less than the embedded flock length used for a screen printed latex.
  • 12. The method of claim 1, further comprising: before step (d), precutting the thermoplastic adhesive sheet to a desired shape of a transfer formed in step (d).
  • 13. The method of claim 1, further comprising thereafter adhering the thermoplastic adhesive sheet to a substrate to adhere the flock to the substrate.
  • 14. The method of claim 13, wherein the step of heating the thermoplastic adhesive sheet and the step of adhering the thermoplastic adhesive sheet to the substrate are performed substantially simultaneously in a single operation.
  • 15. The method of claim 13, further including, before step (d), a step of cutting the thermoplastic adhesive sheet to a desired shape.
  • 16. The method of claim 12, wherein the interface between the thermoplastic adhesive sheet and the substrate is at least substantially free of a binder adhesive.
  • 17. The method of claim 1, wherein the flock comprises a plurality of fibers substantially perpendicular to the release sheet, and wherein at least substantially all of the flock fibers that are substantially perpendicular to the release sheet contact the thermoplastic adhesive sheet.
  • 18. The method of claim 1, in step (d), the pressure ranges from about 40 to about 50 psi.
  • 19. The method of claim 1, wherein the thermoplastic adhesive, after step (d), is free of a powdered hot melt adhesive.
  • 20. A method for continuously producing an article of manufacture having a flocked surface, the method comprising: (a) providing a flocked release sheet comprising a release sheet on the release sheet and a release agent and a plurality of flock fibers attached to the release agent, wherein the flock fibers are formed in a desired pattern on the release sheet and are substantially perpendicular to the release sheet;(b) providing a pre-formed, solid, and self-supporting thermoplastic adhesive sheet;(c) providing a substrate;(d) thereafter contacting the substrate, thermoplastic adhesive sheet, and flocked release sheet together, with the thermoplastic adhesive sheet being positioned between the flocked release sheet and the substrate and a free surface of the flock being in contact with the thermoplastic adhesive sheet, to produce a pre-assembly, wherein at least substantially all of the flock fibers that are substantially perpendicular to the release sheet contact the thermoplastic adhesive sheet; and(e) heating while applying pressure to the pre-assembly to tackify the thermoplastic adhesive and thereby adhere the free surface of the flock and the substrate to the thermoplastic adhesive sheet to form an article of manufacture, wherein at least substantially all of the flock fibers are embedded in the thermoplastic adhesive sheet.
  • 21. The method of claim 20, wherein the thermoplastic adhesive sheet has a substantially uniform thickness.
  • 22. The method of claim 20, wherein the thermoplastic adhesive sheet is a thermoplastic polyester and/or a thermoplastic polyurethane.
  • 23. The method of claim 20, wherein at least most of the flock fibers are in direct contact with the thermoplastic adhesive sheet.
  • 24. The method of claim 20, wherein there is no binder adhesive required to be in contact with the thermoplastic adhesive sheet.
  • 25. The method of claim 20, wherein the release sheet and thermoplastic adhesive sheet are on opposing surfaces of the flock.
  • 26. The method of claim 20, further comprising: applying heat to the pre-assembly to adhere the flock to the substrate; and removing the release sheet from the flock to produce a flocked substrate.
  • 27. The method of claim 20, wherein the thermoplastic adhesive sheet comprises upper and low portions, the upper portion being in contact with the flock, and wherein at least one of the following statements is true: (i) the upper portion has a higher melting point than the lower portion; and(ii) when melted, the upper portion has a higher viscosity than the lower portion.
  • 28. The method of 20, wherein the pressure applied to the pre-assembly ranges from about 40 to about 50 psi.
  • 29. The method of claim 20, wherein the article of manufacture is free of a powdered hot melt adhesive.
  • 30. A method for forming a transfer, comprising: (a) forming a flocked release sheet, the flocked release sheet comprising a release sheet, flock fibers, and a release agent positioned between the release sheet and flock, wherein the release agent adheres the flock to the release sheet;(b) contacting a pre-formed, solid, and self-supporting thermoplastic adhesive sheet to the exposed ends of the flock of the flocked release sheet, wherein the thermoplastic adhesive sheet is formed before step (b); and(c) while the thermoplastic adhesive sheet is in contact with the flock, heating and applying pressure to the flocked release sheet and thermoplastic adhesive sheet to render the thermoplastic adhesive sheet tacky and embed ends of the flock fibers in the thermoplastic adhesive sheet, thereby adhering the flocked release sheet to the thermoplastic adhesive sheet and providing a transfer comprising the thermoplastic adhesive sheet and flocked release sheet.
  • 31. The method of claim 30, wherein step (c) is performed substantially in the absence of a binder adhesive positioned between the thermoplastic adhesive sheet and the flock and wherein the thermoplastic adhesive sheet has a substantially uniform thickness before and after steps (b) and (c).
  • 32. The method of claim 30, further comprising: (d) thereafter contacting the thermoplastic adhesive sheet with a substrate; and(e) while the thermoplastic adhesive sheet is contacted with the substrate, heating and applying pressure to the transfer to adhere the transfer to the substrate, wherein, in the contacting step (d), the interface between the thermoplastic adhesive sheet and the substrate is at least substantially free of a binder adhesive.
  • 33. The method of claim 32, wherein, after step (c), an embedded length of a flock fiber is positioned in the thermoplastic adhesive sheet and wherein, for most of the flock fibers, the embedded flock length used for the thermoplastic adhesive sheet is less than the embedded flock length used for a screen-printed latex.
  • 34. The method of claim 32, wherein the thermoplastic adhesive sheet is partially melted in the heating step (e).
  • 35. The method of claim 32, wherein the thermoplastic adhesive sheet has upper and lower portions, wherein the upper portion is contacted with the substrate, wherein the lower portion is contacted with the flock and is positioned between the flock and upper portion, and wherein at least one of the melting point and viscosity of the upper portion is higher than the at least one of the melting point and viscosity of the lower portion.
  • 36. The method of claim 35 wherein the upper portion has a higher melting point than the lower portion, and wherein each of steps (d) and (e) occurs after each steps (b) and (c).
  • 37. The method of claim 30, further comprising: before step (b), precutting the thermoplastic adhesive sheet to a desired final shape of the transfer.
  • 38. The method of claim 30, wherein a first surface of the thermoplastic adhesive sheet in contact with the flock and a second opposing surface are each at least substantially free of a binder adhesive.
  • 39. The method of claim 30, wherein the flock comprises a plurality of fibers substantially perpendicular to the release sheet, and wherein at least substantially all of the flock fibers that are substantially perpendicular to the release sheet contact the thermoplastic adhesive sheet.
  • 40. The method of claim 30, wherein the pressure applied to the flocked release sheet and thermoplastic adhesive sheet ranges from about 40 to about 50 psi.
  • 41. The method of claim 30, wherein the transfer is free of a powdered hot melt adhesive.
  • 42. A method of producing a flocked transfer assembly, comprising: providing a release agent on the release sheet;flocking a plurality of flock fibers on the release agent in a desired pattern to form a flocked release sheet, having a free surface of the flock, wherein the release agent holds the flock to the release sheet, and wherein the flock fibers are substantially perpendicular to the upper and lower surfaces and to the release sheet;providing a pre-formed, solid and self-supporting thermoplastic adhesive sheet;contacting the free surface of the flock with the thermoplastic adhesive sheet such that at least most of a free surface of the flock is in direct physical contact with the thermoplastic adhesive sheet;heating and applying pressure to the flocked release sheet and thermoplastic adhesive sheet to render the thermoplastic adhesive tacky and embed at least most of the flock fibers in the thermoplastic adhesive, thereby adhering the thermoplastic adhesive sheet to the free surface of the flock to produce a flocked transfer assembly; andsubsequently adhering the flocked transfer assembly to a substrate.
  • 43. The method of claim 42, wherein the pressure applied to the flocked release and thermoplastic adhesive sheets ranges from about 40 to about 50 psi.
  • 44. The method of claim 42, wherein the flocked transfer assembly is free of a powdered hot melt adhesive.
  • 45. A method of producing an article of manufacture having a flocked surface, comprising: supplying a flocked surface comprising flock;supplying a pre-formed solid, and self-supporting thermoplastic adhesive sheet having a substantially uniform thickness and substantially flat upper and lower surfaces;thereafter contacting the thermoplastic adhesive sheet with the flock; andwhile the flocked surface is in contact with the thermoplastic adhesive sheet, heating and applying pressure to the thermoplastic adhesive sheet to soften the adhesive and embed at least most of the flock fibers in the thermoplastic adhesive, thereby binding the thermoplastic adhesive sheet to the flock of the flocked surface.
  • 46. The method of claim 45, wherein the flocked surface comprises a release sheet and a release agent in contact with a first side of the flocked surface, and wherein the thermoplastic adhesive sheet is in contact with an opposing second side of the flocked surface.
CROSS-REFERENCE TO RELATED APPLICATION

The present application is a divisional patent application of U.S. patent application Ser. No. 09/735,721, filed Dec. 13, 2000 of the same title, which is a continuation-in-part patent application of U.S. patent application Ser. No. 09/621,830, filed Jul. 24, 2000 entitled “FLOCKED TRANSFER AND ARTICLE OF MANUFACTURE INCLUDING THE FLOCKED TRANSFER”, each of which is incorporated in its entirety by this reference.

US Referenced Citations (202)
Number Name Date Kind
D66035 McIntosh Nov 1924 S
1905989 Safir et al. Apr 1933 A
D108581 Robinson Feb 1938 S
D114814 Hoos May 1939 S
D122192 De Moreau Aug 1940 S
D125860 Haas Mar 1941 S
D162533 Goldfarb Mar 1951 S
2592602 Saks Apr 1952 A
2636837 Summers Apr 1953 A
2916403 Calderwood Dec 1959 A
2999763 Sommer Sep 1961 A
D195245 Edesess May 1963 S
3215584 McConnell et al. Nov 1965 A
3314845 Perri Apr 1967 A
3377232 Mencock et al. Apr 1968 A
3459579 Newman Aug 1969 A
3496054 Baigas Feb 1970 A
3529986 Kappas et al. Sep 1970 A
3565742 Stephens et al. Feb 1971 A
3622434 Newman Nov 1971 A
3639149 Spalding Feb 1972 A
3644267 Jackson, Jr. et al. Feb 1972 A
3657060 Haigh Apr 1972 A
3660200 Anderson et al. May 1972 A
3674611 Petry et al. Jul 1972 A
3772132 Dulin, Jr. Nov 1973 A
3775205 Hermann et al. Nov 1973 A
3793050 Mumpower, Jr. Feb 1974 A
3803453 Hull Apr 1974 A
3816050 Koskolos Jun 1974 A
3816211 Haigh Jun 1974 A
3837946 Gribbin Sep 1974 A
3900676 Alderson Aug 1975 A
3903331 Klein Sep 1975 A
3917883 Jepson Nov 1975 A
3936554 Squier Feb 1976 A
3956552 Geary May 1976 A
3961116 Klein Jun 1976 A
3969559 Boe Jul 1976 A
3979538 Gilman et al. Sep 1976 A
3989869 Neumaier et al. Nov 1976 A
4018956 Casey Apr 1977 A
4025678 Frank May 1977 A
4031281 Keeling Jun 1977 A
4034134 Gregorian et al. Jul 1977 A
4035532 Gregorian et al. Jul 1977 A
4062992 Power et al. Dec 1977 A
4088708 Riew May 1978 A
4102562 Harper et al. Jul 1978 A
4120713 Jensen et al. Oct 1978 A
4142929 Otomine et al. Mar 1979 A
4160851 Lienert et al. Jul 1979 A
4201810 Higashiguchi May 1980 A
4218501 Kameya et al. Aug 1980 A
4269885 Mahn May 1981 A
4273817 Matsuo et al. Jun 1981 A
4282278 Higashiguchi Aug 1981 A
4292100 Higashiguchi Sep 1981 A
4294641 Reed et al. Oct 1981 A
4308296 Chitouras Dec 1981 A
4314813 Maskai Feb 1982 A
4314955 Boden et al. Feb 1982 A
4340623 Justus Jul 1982 A
4340632 Wells et al. Jul 1982 A
4352924 Wooten et al. Oct 1982 A
4362773 Shikinami Dec 1982 A
4369157 Conner Jan 1983 A
4370374 Raabe et al. Jan 1983 A
4385588 Bennetot May 1983 A
4387214 Passmore et al. Jun 1983 A
4388134 Long et al. Jun 1983 A
4390387 Mahn Jun 1983 A
4396662 Higashiguchi Aug 1983 A
4405401 Stahl Sep 1983 A
4418106 Landler et al. Nov 1983 A
4423106 Mahn Dec 1983 A
4430372 Knoke et al. Feb 1984 A
4438533 Hefele Mar 1984 A
4446274 Okazaki et al. May 1984 A
4465723 Knoke et al. Aug 1984 A
4510274 Okazaki et al. Apr 1985 A
4539166 Richartz et al. Sep 1985 A
4574018 Masuda et al. Mar 1986 A
4582658 Reichmann et al. Apr 1986 A
4588629 Taylor May 1986 A
4610904 Mahn et al. Sep 1986 A
4650533 Parker et al. Mar 1987 A
4652478 Maii Mar 1987 A
4668323 Lenards et al. May 1987 A
4670089 Hanson Jun 1987 A
4681791 Shibahashi et al. Jul 1987 A
4687527 Higashiguchi Aug 1987 A
4741791 Howard et al. May 1988 A
4790306 Braun et al. Dec 1988 A
4793884 Horikiri Dec 1988 A
4797320 Kopp et al. Jan 1989 A
4810321 Wank et al. Mar 1989 A
4810549 Abrams et al. Mar 1989 A
4812247 Fahner et al. Mar 1989 A
4834502 Bristol et al. May 1989 A
4895748 Squires Jan 1990 A
4931125 Volkmann et al. Jun 1990 A
4980216 Rompp Dec 1990 A
5008130 Lenards Apr 1991 A
5009950 Wagner et al. Apr 1991 A
5026591 Henn et al. Jun 1991 A
5041104 Seal Aug 1991 A
5043375 Henning et al. Aug 1991 A
5047103 Abrams et al. Sep 1991 A
5053179 Masui et al. Oct 1991 A
5059452 Squires Oct 1991 A
5077116 Lefkowitz Dec 1991 A
5108530 Niebling, Jr. et al. Apr 1992 A
5112423 Liebe, Jr. May 1992 A
5115104 Bunyan May 1992 A
5154871 Wagner et al. Oct 1992 A
5198277 Hamilton et al. Mar 1993 A
5207851 Abrams May 1993 A
5217563 Niebling et al. Jun 1993 A
5217781 Kuipers Jun 1993 A
5248536 Du Katz Sep 1993 A
5274039 Sirinyan et al. Dec 1993 A
5306567 Kuo et al. Apr 1994 A
5338603 Mahn et al. Aug 1994 A
5346746 Abrams Sep 1994 A
5350474 Yamane Sep 1994 A
5350830 Kuo et al. Sep 1994 A
5358789 Kuo et al. Oct 1994 A
5383996 Dressler Jan 1995 A
D365342 Evenson et al. Dec 1995 S
D366654 Lovegrove et al. Jan 1996 S
5489359 Yamane Feb 1996 A
5529650 Bowers et al. Jun 1996 A
5534099 Yamamoto Jul 1996 A
5564249 Borys et al. Oct 1996 A
5597637 Abrams et al. Jan 1997 A
5622587 Barthelman Apr 1997 A
5693400 Hamilton et al. Dec 1997 A
D391572 Lee Mar 1998 S
5762379 Salmon et al. Jun 1998 A
5766397 Jones Jun 1998 A
5771796 Morrison et al. Jun 1998 A
5804007 Asano Sep 1998 A
5858156 Abrams et al. Jan 1999 A
5900096 Zemel May 1999 A
5912065 Kukoff Jun 1999 A
5922436 Banfield et al. Jul 1999 A
5981009 Iacono et al. Nov 1999 A
6010764 Abrams Jan 2000 A
6083332 Abrams Jul 2000 A
6102686 Eschenfelder Aug 2000 A
6110560 Abrams Aug 2000 A
6113149 Dukatz Sep 2000 A
6146485 Iacono et al. Nov 2000 A
6170881 Salmon et al. Jan 2001 B1
6171678 Holeschovsky et al. Jan 2001 B1
6202549 Mitsam et al. Mar 2001 B1
6224707 Lion May 2001 B1
6247215 Van Alboom et al. Jun 2001 B1
6249297 Lion Jun 2001 B1
6257866 Fritz et al. Jul 2001 B1
6264775 Holeschovsky et al. Jul 2001 B1
6277312 Hansen et al. Aug 2001 B1
6296908 Reihs et al. Oct 2001 B1
6299715 Langsdorf et al. Oct 2001 B1
6350504 Alboom et al. Feb 2002 B1
6376041 Morrison et al. Apr 2002 B1
6387472 Reck et al. May 2002 B1
6428877 Suss et al. Aug 2002 B1
6436506 Pinter et al. Aug 2002 B1
6451148 Jenner Sep 2002 B1
6569538 Kaschel May 2003 B1
6660352 Hsu et al. Dec 2003 B2
6676796 Pinter et al. Jan 2004 B2
6887737 Woods et al. May 2005 B1
6929771 Abrams Aug 2005 B1
6977023 Abrams Dec 2005 B2
7229680 Crompton Jun 2007 B1
20010008039 Alboom et al. Jul 2001 A1
20010008672 Norvell et al. Jul 2001 A1
20020009571 Abrams Jan 2002 A1
20020098329 Abrams Jul 2002 A1
20030129353 Abrams Jul 2003 A1
20030186019 Abrams Oct 2003 A1
20030207072 Abrams Nov 2003 A1
20030211279 Abrams Nov 2003 A1
20040050482 Abrams Mar 2004 A1
20040053001 Abrams Mar 2004 A1
20040055692 Abrams Mar 2004 A1
20040058120 Abrams Mar 2004 A1
20040081791 Abrams Apr 2004 A1
20040170799 Carr et al. Sep 2004 A1
20050081985 Abrams Apr 2005 A1
20050158508 Abrams Jul 2005 A1
20050266204 Abrams Dec 2005 A1
20050268407 Abrams Dec 2005 A1
20060026778 Lion Feb 2006 A1
20060029767 Lion Feb 2006 A1
20060251852 Abrams Nov 2006 A1
20070003761 Miyazono et al. Jan 2007 A1
20070022548 Abrams Feb 2007 A1
20070026189 Abrams Feb 2007 A1
Foreign Referenced Citations (81)
Number Date Country
E 93 557 Aug 1988 AT
E 135 427 Aug 1996 AT
606651 Feb 1991 AU
653994 Oct 1994 AU
0506601 Mar 1996 BE
757595 Apr 1967 CA
2010076 Aug 1990 CA
1306411 Aug 1992 CA
2064300 Sep 1992 CA
3883517 May 1994 DE
69208910 Aug 1996 DE
019734316A 1 Feb 1999 DE
0122656 Oct 1984 EP
351079 Jun 1986 EP
0 210304 Feb 1987 EP
0 280 296 Feb 1988 EP
0506601 Sep 1992 EP
0685014 Dec 1995 EP
0506601 May 1996 EP
0913271 Oct 1998 EP
0 989 227 Mar 2000 EP
1 480 860 May 1967 FR
2210149 Jul 1974 FR
2543984 Oct 1984 FR
2 659 094 Mar 1990 FR
9002623 Mar 1990 FR
2784619 Oct 1998 FR
2846202 Apr 2004 FR
1171296 Nov 1969 GB
1466271 Dec 1973 GB
1 447 049 Aug 1976 GB
2065031 Dec 1979 GB
2126951 Sep 1983 GB
2214869 Sep 1989 GB
0506601 Sep 1992 GB
55104 Apr 1984 IE
0329767 Aug 1993 IT
24637BE96 Jun 1996 IT
52-155270 Dec 1977 JP
54-163934 Dec 1979 JP
55079143 Jun 1980 JP
55-147171 Nov 1980 JP
356058824 May 1981 JP
56107080 Aug 1981 JP
56108565 Aug 1981 JP
56141877 Nov 1981 JP
58062027 Apr 1983 JP
359115885 Jul 1984 JP
60-171138 Sep 1985 JP
60-236738 Nov 1985 JP
63118544 May 1988 JP
64-61299 Mar 1989 JP
2-25667 Jun 1990 JP
5-201196 Aug 1993 JP
05255021 Oct 1993 JP
08-267625 Oct 1996 JP
10059790 Mar 1998 JP
11277662 Oct 1999 JP
11348159 Dec 1999 JP
020000084977 Mar 2000 JP
2001270019 Oct 2001 JP
220373 Sep 1999 KR
2003063833 Jul 2003 KR
306099 Jun 1989 NO
62640 Jul 1993 TW
WO 7901146 Dec 1979 WO
WO 8901829 Mar 1989 WO
WO 9009289 Aug 1990 WO
WO 9419530 Sep 1994 WO
PCTUS0123195 Jan 2002 WO
WO 02107959 Jan 2002 WO
WO 0209925 Feb 2002 WO
WO 02058854 Aug 2002 WO
WO 03031083 Apr 2003 WO
WO 2004005023 Jan 2004 WO
WO 2004005413 Jan 2004 WO
WO 2004005600 Jan 2004 WO
WO 2005035235 Apr 2005 WO
WO 2005118948 Dec 2005 WO
886259 Apr 1990 ZA
922154 Feb 1993 ZA
Related Publications (1)
Number Date Country
20030186019 A1 Oct 2003 US
Divisions (1)
Number Date Country
Parent 09735721 Dec 2000 US
Child 10455575 US
Continuation in Parts (1)
Number Date Country
Parent 09621830 Jul 2000 US
Child 09735721 US