Flocked transfer and article of manufacturing including the flocked transfer

Information

  • Patent Grant
  • 7390552
  • Patent Number
    7,390,552
  • Date Filed
    Tuesday, September 23, 2003
    20 years ago
  • Date Issued
    Tuesday, June 24, 2008
    16 years ago
Abstract
A flocked transfer is produced by applying a release agent to a release sheet and then applying the flocking to the release agent. Unlike the traditional method, a binder and hot melt film is not applied to the back of the flock. The transfer (which is essentially a flocked release sheet) is then applied to a substrate (i.e., an item of clothing, a rubber pad, etc.) by positioning a sheet of thermosetting hot melt film on the substrate; placing the transfer on the hot melt film with the flock in contact with the hot melt film; and applying heat and pressure. The heat melts the thermosetting hot melt film to bind the flock to the substrate and binds the flocking together. This method reduces the costs involved in producing flocked articles, especially for articles produced on a continuous basis.
Description
BACKGROUND OF THE INVENTION

This invention relates to flocked transfers, and, in particular, to an improved method of making flocked transfers which can reduce the cost and time required of producing transfers by a significant amount.


Heretofore, flocked transfers have generally been produced by applying a release agent to a release sheet. The flocking is applied to the release sheet in the desired pattern. A binder and a permanent hot melt adhesive are applied to the back of the flocking, and the transfer is allowed to dry. The binder is required hold the flocking in the desired pattern. The hot melt adhesive, which is applied to the transfer as a powder, is used to adhere the transfer to a substrate, such as an article of clothing, a neoprene pad, etc. The transfer is applied to the substrate by placing the transfer on the substrate with the dried hot melt adhesive in contact with the substrate. Heat, such as from an iron, is then applied to the release sheet. The heat melts the hot melt adhesive to cause hot melt adhesive to flow into intimate contact with the substrate, forming a mechanical and molecular bond with the substrate. The release agent then allows for the release sheet to be removed from the transfer, leaving the flocking exposed on the substrate.


This traditional method has worked well for years. However, the method can be improved upon to reduce the cost of producing the transfer, and hence, the cost of the item containing the transfer.


BRIEF SUMMARY OF THE INVENTION

In accordance with the invention, generally stated, a flocked transfer of the present invention is produced by applying a release agent to a release sheet and then applying the flocking to the release agent. Unlike the traditional method, a binder and adhesive are not applied to the ends of the flock.


To form an article of manufacture with the flocked transfer, a thermosetting adhesive film (in the form of a sheet or cut to shape) is positioned on the substrate to which the transfer is to be applied. The thermosetting film is preferably a polyester or polyurethane film, but can be any thermosetting film. The flock with the release adhesive and release sheet (i.e., the transfer) is then placed on the sheet of permanent adhesive film with the release sheet up, so that the flocking is in contact with the permanent adhesive film. Heat is then applied to the transfer. The heat melts the permanent adhesive film, and secures the flock to the substrate. Because the permanent adhesive film is thermosetting, even if it is subsequently subjected to heat, it will not remelt, nor become tacky, and hence, there is no risk of fibers becoming matted down in any of this type of adhesive, which could otherwise ruin the plush pile effect. In addition, it is likely that the use of a thermoset powder could be added to a bond print latex flock adhesive binder, to serve as a method for increasing the adhesion and again reducing the risk of any remelting, or becoming tacky, when the flock transfer is subsequently exposed to heat. It is known that there is a much stronger adhesion with thermosetting materials, because thermoset materials will cross-link with a chemical reaction and thereby adhere the flock fibers to it, which become chemically attached thereto. Through the usage of this invention, the finished flock surface is more plush, soft, because more of the fiber is exposed and extends upwardly out of the adhesive, than with the screen-printed latex, as currently used. Also, this affords better soil release during washing or cleaning because of less fiber/adhesive entanglement occurs with the flock, during application.





BRIEF DESCRIPTION OF THE SEVERAL VIEWS OF THE DRAWINGS


FIG. 1 is a cross-sectional view of a prior art flock transfer;



FIG. 2 is a cross-sectional view of a flock transfer of the present invention;



FIG. 3 is an exploded view of the transfer, a permanent adhesive sheet, and a substrate used to make an article of manufacture;



FIG. 4 is a cross-sectional view of an article of manufacture using the transfer of the present invention, showing a part of the transfer applied to part of the substrate and a part of the transfer and permanent adhesive film spaced from the substrate; and



FIG. 5 is a schematic drawing of a process for continuously producing articles of manufacture, such as mouse pads, coasters, etc.





Corresponding reference numerals will be used throughout the several figures of the drawings.


DETAILED DESCRIPTION OF THE INVENTION

The following detailed description illustrates the invention by way of example and not by way of limitation. This description will clearly enable one skilled in the art to make and use the invention, including what I presently believe is the best mode of carrying out the invention.


A prior art flocked transfer 101 is shown in FIG. 1. As is known, such transfers include a dimensionally stable release sheet 103 to which a conventional flock transfer release adhesive 105 is applied in a pattern which corresponds to the overall image to be flocked. The flock 107 is then electrostatically coated into the release adhesive 105. A binder adhesive 109 is applied to the exposed ends of the flock to bind the flock together as a unit. Lastly, a hot melt adhesive film 111 is applied. The transfer is then allowed to dry. The transfer is applied to a substrate, as is known, by positioning the transfer on a substrate, such as a shirt or other item of clothing, with the hot melt adhesive in contact with the substrate, and applying heat to the transfer. The heat activates the hot melt adhesive to adhere the transfer to the substrate.


This process is described in my prior patent, U.S. Pat. No. 4,810,549, as well as in my co-pending application, Ser. No. 09/548,839 filed Apr. 13, 2000, both of which are incorporated herein by reference. In U.S. Pat. No. 4,810,549, a plush textured multicolored flock is disclosed in which differing colors of flock having a length greater than 0.3 mm are applied sequentially to a release adhesive coated base sheet through predetermined areas of masked screens. The applied flock is thereafler coated with a binder adhesive, such as a liquid water-based acrylic (40-60% water), which binds the flock into a unit. In one configuration, the binder adhesive contains an additional adhesive, such as a hot melt, for binding the transfer to a substrate. In an alternative configuration, the hot melt adhesive (which is usually a granular polyester or nylon) is formed as a separate layer. U.S. application Ser. No. 09/548,839, filed Apr. 13, 2000, discloses a mouse pad produced by applying differently colored flock (having a length of 1 mm and 3.3 Dtex) electrostatically through a screen to a release adhesive-coated paper sheet. A binder adhesive, such as a water-based acrylic, is screen printed to the flock afler contacting the release adhesive. The binder adhesive may contain a hot melt or the hot melt may be applied to the free surface of the binder adhesive. The hot melt adhesive is bonded to a surface, such as a rubber pad, using heat and pressure. The release adhesive and paper sheet are then removed. In one process configuration, a flock-coated adhesive carrier sheet, a solid pre-formed binder adhesive film or heat seal film, and the rubber base material are thermally fused together in a drying oven.


A flocked transfer 1 of the present invention is shown in FIG. 2. The transfer 1 of the present invention includes a release sheet 3 to which a conventional release agent, such as wax, has been applied. The release agent is applied to the sheet in the shape of the pattern of the flocking. Flocking 7 is then applied to the release agent, and hence to the release sheet, to form the transfer. The flocking 7 is applied, for example, in the manner as described in my prior patent, U.S. Pat. No. 4,810,549, which is incorporated herein by reference. Unlike the prior art processes, the transfer 1 of this embodiment is made without the use of a binder adhesive or a hot melt adhesive. As is discussed below, a thermosetting film is used to adhere the transfer to a substrate.


With reference to FIG. 3, an article of manufacture, such as an item of clothing having a transfer 1 applied thereto, a mouse pad, coaster, or other item having a flocked surface is easily produced using the transfer 1. The article of manufacture 11 is produced by positioning a hot melt or thermosetting permanent adhesive sheet 13 between a substrate 15 and the flocked release sheet. The sheet is, for example, a sheet of thermosetting polyester, available from Bostik, Inc. The sheet can also be made from a thermosetting polyurethane. Any other thermosetting film should also work well. The substrate can be an item of clothing, a rubber pad (for producing a mouse pad or coaster), etc. The sheet can be precut to correspond to the shape of the transfer 1. The transfer 1 is then positioned on the sheet with the flock 7 against the sheet 13. Heat is applied to the transfer through the release sheet to activate the permanent adhesive sheet. The sheet then acts to both bind the flock 7 together and to adhere the flock 7 to the substrate 15. Preferably, to assemble the article, the flocked release sheet, the permanent adhesive sheet (which is preferably the thermosetting film), and the substrate are brought together and passed through a heat-laminating press where the three parts are subject to temperature of about 300° F. (about 150° C.) and pressure (about 40-50 psi) for about 30 seconds. It has been found that a medium-to-firm pressure has been most advantageous in providing for assembly of this type of plush flocked transfer. The pressure and heat will cause the permanent adhesive sheet to adhere to the flock and the substrate. Additionally, the thermosetting film will cross-link or cure, to give a strong attachment of the flock to the substrate.


Articles, such as mouse pads or coaster, in which the entire top surface of the article is covered with the flocking can be produced on a continuous basis, as shown in FIG. 5. Rolls 21, 23, and 25 of a flocked release sheet 1, the permanent adhesive sheet 13, and the substrate 15 are provided. The three parts are brought together at a laminating station 33. Rollers can be provided in front of the station 33 so that the three elements are adjacent each other as they enter the laminating station. In the laminating station, heat and pressure are applied to the three sheets (the flocked release sheet, the permanent adhesive sheet, and the substrate) to melt the permanent adhesive sheet. The melted permanent adhesive sheet will then cure or cross-link, as noted above, to adhere the flock to the substrate. A web 35 exits the laminating station. The web 35 is then allowed to cool. The web 35 is ultimately directed to a cutting station where it is cut into individual articles. Once the web 35 is cooled, it can be directed immediately to a cutting station (after the sheet 35 cools), or can it can be wound up on an uptake roller to be cut into individual articles at a later time, or at a different location. At the cutting station, the release sheet is removed from the flock and gathered on an uptake roll or is otherwise disposed of. After the release sheet has been removed from the flock, the substrate with the flock adhered thereto is cut to form the articles 11. It is also likely that one could remove the release liner either before or after the die cutting procedure.


Preferably, the release sheet is flocked and supplied in roll form as shown in FIG. 5. However, the flocking of the release sheet could be made part of the process.


To produce flocked articles, such as shirts, jackets, etc., which cannot be easily flocked on a continuous basis, the permanent adhesive sheet can be applied to the transfer 1 prior to applying the transfer to the substrate. To do this, the thermosetting film is placed in contact with the flock of the transfer, and the transfer and release sheet are heated to a temperature at which the thermosetting film become tacky, but below the temperature at which the thermosetting film begins to cure and cross-link. This will adhere the thermosetting film to the transfer 1 to form a transfer which can later be applied to an article by positioned the transfer with the thermosetting film in position on the article (i.e., piece of clothing) and applying heat and pressure to the transfer, for example, with an iron, sufficient to melt the thermosetting film, to cause the film to cure and cross-link.


The method eliminates two steps from the prior art method: (1) application of the binder adhesive and (2) application, cleaning, sintering, and drying of the hot melt adhesive. In a continuous process, the present method also eliminates a station for applying the binder and hot melt adhesives as well as a station for drying the completed transfer. Because a station is not needed to apply (i.e., print) the binder and hot melt adhesives to the flocking as part of the transfer, the machinery required to produce the article 11 is much less expensive (both in actual costs and in maintenance costs). Additionally, because the binder adhesive and hot melt adhesive is not used, the cost of the article of manufacture is significantly reduced.


As various changes could be made in the above constructions without departing from the scope of the invention, it is intended that all matter contained in the above description or shown in the accompanying drawings shall be interpreted as illustrative and not in a limiting sense.

Claims
  • 1. A flocked assembly, comprising: flock, said flock comprised of first ends and opposing second ends;a pre-formed, solid, and self-supporting thermosetting film, wherein substantially all opposing second ends are in contact with and adhered to the thermosetting film; andwherein the thermosetting film is: free of a binder adhesive positioned between the thermosetting film and flock;of substantially uniform thickness;substantially flat upper and lower surfaces; andis not adhered to a substrate.
  • 2. A transfer comprising the flocked assembly of claim 1.
  • 3. The flocked assembly of claim 2, wherein said first ends of said flock are adhered to a release sheet by a release agent and wherein the thermosetting film contacts said opposing second ends of the flock.
  • 4. The transfer of claim 3, wherein the transfer is free of an acrylic adhesive.
  • 5. The transfer of claim 4, wherein said second ends of the flock are embedded in the thermosetting film and wherein the thermosetting film comprises a thermosetting polyester.
  • 6. The flocked assembly of claim 1, wherein the thermosetting film is a thermosetting polyurethane film or a thermosetting polyester film.
  • 7. The flocked assembly of claim 1, wherein the thermosetting film is precut to correspond to a shape of the transfer and wherein the thermosetting film is a thermosetting polyurethane.
  • 8. The flocked assembly of claim 3, wherein the release agent and release sheet are located on a first surface of the flock and the thermosetting film is positioned on a second surface of the flock and the first and second surfaces are in an opposing relationship.
  • 9. The flocked assembly of claim 1, wherein there is no hot melt thermoplastic adhesive located between the thermosetting film and the flock.
  • 10. The flocked assembly of claim 1, wherein the thermosetting film is not fully crosslinked.
  • 11. The flocked assembly of claim 1, wherein the flock is in direct physical contact with the thermosetting film.
  • 12. The flocked assembly of claim 1, wherein the thermosetting film is not fully activated.
  • 13. The flocked assembly of claim 1, wherein the thermosetting film is continuous.
  • 14. A flocked assembly, comprising: flock; anda solid, self-supporting thermosetting film, wherein the flock is in contact with and adhered to the thermosetting film, wherein there is no intermediate adhesive positioned between the thermosetting film and flock and wherein the thermosetting film is not adhered to a substrate.
  • 15. The flocked assembly of claim 14, wherein said flock comprised of first ends and opposing second ends, wherein the thermosetting film is pre-formed and self-supporting, wherein substantially all second ends of the flock physically contact the thermosetting film, and wherein the thermosetting film has a substantially uniform thickness and substantially flat upper and lower surfaces.
  • 16. The flocked assembly of claim 14, further comprising: a release sheet; anda release agent in contact with the release sheet, wherein first ends of said flock are adhered to the release sheet by the release agent and wherein the thermosetting film contacts opposing second ends of the flock.
  • 17. The flocked assembly of claim 16, wherein said second ends of flock are not in contact with a hot melt binder adhesive.
  • 18. The flocked assembly of claim 17, wherein the thermosetting film comprises a thermosetting polyester and wherein the thermosetting film is not in contact with an acrylic or a hot melt thermoplastic adhesive.
  • 19. The flocked assembly of claim 18, wherein the thermosetting film is a thermosetting polyurethane film or a thermosetting polyester film.
  • 20. The flocked assembly of claim 14, wherein the flocked assembly is a transfer, wherein the thermosetting film is precut to correspond to a shape of the transfer, and wherein the thermosetting film is a thermosetting polyurethane.
  • 21. The flocked assembly of claim 14, wherein the thermosetting film is not fully crosslinked.
  • 22. The flocked assembly of claim 14, wherein there is no acrylic or hot melt thermoplastic binder adhesive located between the thermosetting film and the flock.
  • 23. The flocked assembly of claim 14, wherein the flock is in direct physical contact with the thermosetting film.
  • 24. The flocked assembly of claim 14, wherein the thermosetting film is not fully activated.
  • 25. The flocked assembly of claim 14, wherein the flock is embedded in the thermosetting film.
  • 26. A flocked assembly, having: flock; anda self-supporting thermosetting film that is not adhered to a substrate and acts as the adhesive for the flock, wherein there is no binder adhesive located intermediate to said thermosetting film and said flock.
  • 27. The flocked assembly of claim 26, wherein said flock is comprised of first ends and opposing second ends, wherein the thermosetting film is a pre-formed solid, wherein substantially all second ends of the flock contact the thermosetting film, and wherein the thermosetting film has a substantially uniform thickness and substantially flat upper and lower surfaces.
  • 28. The flocked assembly of claim 26, further having: a release sheet;a release agent in contact with the release sheet, wherein first ends of said flock are adhered to the release sheet by the release agent; andwherein the thermosetting film: contacts opposing second ends of the flock,comprises a thermosetting polyester, andis not in contact with an acrylic or a hot melt thermoplastic adhesive.
  • 29. The flocked assembly of claim 26, wherein the thermosetting film is a thermosetting polyurethane film or a thermosetting polyester film.
  • 30. The flocked assembly of claim 26, wherein the flocked assembly is a transfer, wherein the thermosetting film is precut to a shape of the transfer, and wherein the thermosetting film is a thermosetting polyurethane.
  • 31. The flocked assembly of claim 26, wherein the thermosetting film is not fully crosslinked.
  • 32. The flocked assembly of claim 26, wherein there is no acrylic or hot melt thermoplastic binder adhesive located between the thermosetting film and the flock.
  • 33. The flocked assembly of claim 26, wherein the flock is in direct physical contact with and embedded in the thermosetting film.
  • 34. The locked assembly of claim 26, wherein the thermosetting film is not fully activated.
CROSS-REFERENCE TO RELATED APPLICATIONS

The present application is a continuation of U.S. patent application Ser. No. 09/621,830 filed Jul. 24, 2000. The entire disclosure of the prior application is considered to be part of the disclosure of the present application and is hereby incorporated by reference.

US Referenced Citations (195)
Number Name Date Kind
D66035 McIntosh Nov 1924 S
1905989 Safir et al. Apr 1933 A
D108581 Robinson Feb 1938 S
D114814 Hoos May 1939 S
D122192 De Moreau Aug 1940 S
D125860 Haas Mar 1941 S
D162533 Goldfarb Mar 1951 S
2592602 Saks Apr 1952 A
2636837 Summers Apr 1953 A
2916403 Calderwood Dec 1959 A
2999763 Sommer Sep 1961 A
D195245 Edesess May 1963 S
3215584 McConnell et al. Nov 1965 A
3314845 Perri Apr 1967 A
3377232 Mencock et al. Apr 1968 A
3459579 Newman Aug 1969 A
3496054 Baigas Feb 1970 A
3529986 Kappas et al. Sep 1970 A
3565742 Stephens et al. Feb 1971 A
3622434 Newman Nov 1971 A
3639149 Spalding Feb 1972 A
3644267 Jackson, Jr. et al. Feb 1972 A
3657060 Haigh Apr 1972 A
3660200 Anderson et al. May 1972 A
3674611 Petry et al. Jul 1972 A
3772132 Dulin, Jr. Nov 1973 A
3775205 Hermann et al. Nov 1973 A
3793050 Mumpower, Jr. Feb 1974 A
3803453 Hull Apr 1974 A
3816060 Koskolos Jun 1974 A
3816211 Haigh Jun 1974 A
3837946 Gribbin Sep 1974 A
3887737 Baxter et al. Jun 1975 A
3900676 Alderson Aug 1975 A
3903331 Klein Sep 1975 A
3917883 Jepson Nov 1975 A
3936554 Squier Feb 1976 A
3956552 Geary May 1976 A
3961116 Klein Jun 1976 A
3969559 Boe Jul 1976 A
3979538 Gilman et al. Sep 1976 A
3989869 Neumaier et al. Nov 1976 A
4018956 Casey Apr 1977 A
4025678 Frank May 1977 A
4031281 Keeling Jun 1977 A
4034134 Gregorian et al. Jul 1977 A
4035532 Gregorian et al. Jul 1977 A
4062992 Power et al. Dec 1977 A
4088708 Riew May 1978 A
4102562 Harper et al. Jul 1978 A
4120713 Jensen et al. Oct 1978 A
4142929 Otomine et al. Mar 1979 A
4160851 Lienert et al. Jul 1979 A
4201810 Higashiguchi May 1980 A
4218501 Kameya et al. Aug 1980 A
4269885 Mahn May 1981 A
4273817 Matsuo et al. Jun 1981 A
4282278 Higashiguchi Aug 1981 A
4292100 Higashiguchi Sep 1981 A
4294641 Reed et al. Oct 1981 A
4308296 Chitouras Dec 1981 A
4314813 Masaki Feb 1982 A
4314955 Boden et al. Feb 1982 A
4340623 Justus Jul 1982 A
4340632 Wells et al. Jul 1982 A
4352924 Wooten et al. Oct 1982 A
4362773 Shikinami Dec 1982 A
4369157 Conner Jan 1983 A
4370374 Raabe et al. Jan 1983 A
4385588 Bennetot May 1983 A
4387214 Passmore et al. Jun 1983 A
4388134 Long et al. Jun 1983 A
4390387 Mahn Jun 1983 A
4396662 Higashiguchi Aug 1983 A
4405401 Stahl Sep 1983 A
4418106 Landler et al. Nov 1983 A
4423106 Mahn Dec 1983 A
4430372 Knoke et al. Feb 1984 A
4438533 Hefele Mar 1984 A
4446274 Okazaki et al. May 1984 A
4465723 Knoke et al. Aug 1984 A
4510274 Okazaki et al. Apr 1985 A
4539166 Richartz et al. Sep 1985 A
4574018 Masuda et al. Mar 1986 A
4582658 Reichmann et al. Apr 1986 A
4588629 Taylor May 1986 A
4610904 Mahn et al. Sep 1986 A
4650533 Parker et al. Mar 1987 A
4652478 Maii Mar 1987 A
4668323 Lenards et al. May 1987 A
4670089 Hanson Jun 1987 A
4681791 Shibahashi et al. Jul 1987 A
4687527 Higashiguchi Aug 1987 A
4741791 Howard et al. May 1988 A
4790306 Braun et al. Dec 1988 A
4793884 Horikiri Dec 1988 A
4797320 Kopp et al. Jan 1989 A
4810321 Wank et al. Mar 1989 A
4810549 Abrams et al. Mar 1989 A
4812247 Fahner et al. Mar 1989 A
4834502 Bristol et al. May 1989 A
4895748 Squires Jan 1990 A
4931125 Volkmann et al. Jun 1990 A
4980216 Rompp Dec 1990 A
5008130 Lenards Apr 1991 A
5009950 Wagner et al. Apr 1991 A
5026591 Henn et al. Jun 1991 A
5041104 Seal Aug 1991 A
5043375 Henning et al. Aug 1991 A
5047103 Abrams et al. Sep 1991 A
5053179 Masui et al. Oct 1991 A
5059452 Squires Oct 1991 A
5077116 Lefkowitz Dec 1991 A
5108530 Niebling, Jr. et al. Apr 1992 A
5112423 Liebe, Jr. May 1992 A
5115104 Bunyan May 1992 A
5154871 Wagner et al. Oct 1992 A
5198277 Hamilton et al. Mar 1993 A
5207851 Abrams May 1993 A
5217563 Niebling et al. Jun 1993 A
5217781 Kuipers Jun 1993 A
5248536 Du Katz Sep 1993 A
5274039 Sirinyan et al. Dec 1993 A
5306567 Kuo et al. Apr 1994 A
5338603 Mahn et al. Aug 1994 A
5346746 Abrams Sep 1994 A
5350474 Yamane Sep 1994 A
5350830 Kuo et al. Sep 1994 A
5358789 Kuo et al. Oct 1994 A
5383996 Dressler Jan 1995 A
D365342 Evenson et al. Dec 1995 S
D366654 Lovegrove et al. Jan 1996 S
5489359 Yamane Feb 1996 A
5529650 Bowers et al. Jun 1996 A
5534099 Yamamoto Jul 1996 A
5564249 Borys et al. Oct 1996 A
5597637 Abrams et al. Jan 1997 A
5622587 Barthelman Apr 1997 A
5693400 Hamilton et al. Dec 1997 A
D391572 Lee Mar 1998 S
5762379 Salmon et al. Jun 1998 A
5766397 Jones Jun 1998 A
5771796 Morrison et al. Jun 1998 A
5804007 Asano Sep 1998 A
5858156 Abrams et al. Jan 1999 A
5900096 Zemel May 1999 A
5912065 Kukoff Jun 1999 A
5922436 Banfield et al. Jul 1999 A
5981009 Iacono et al. Nov 1999 A
6010764 Abrams Jan 2000 A
6083332 Abrams Jul 2000 A
6102686 Eschenfelder Aug 2000 A
6110560 Abrams Aug 2000 A
6113149 Dukatz Sep 2000 A
6146485 Iacono et al. Nov 2000 A
6170881 Salmon et al. Jan 2001 B1
6171678 Holeschovsky et al. Jan 2001 B1
6202549 Mitsam et al. Mar 2001 B1
6224707 Lion May 2001 B1
6247215 Van Alboom et al. Jun 2001 B1
6249297 Lion Jun 2001 B1
6257866 Fritz et al. Jul 2001 B1
6264775 Holeschovsky et al. Jul 2001 B1
6277312 Hansen et al. Aug 2001 B1
6296908 Reihs et al. Oct 2001 B1
6299715 Langsdorf et al. Oct 2001 B1
6350504 Alboom et al. Feb 2002 B1
6376041 Morrison et al. Apr 2002 B1
6387472 Reck et al. May 2002 B1
6428877 Suss et al. Aug 2002 B1
6436506 Pinter et al. Aug 2002 B1
6451148 Jenner Sep 2002 B1
6569538 Kaschel May 2003 B1
6660352 Hsu et al. Dec 2003 B2
6676796 Pinter et al. Jan 2004 B2
7229680 Crompton Jun 2007 B1
20010008039 Alboom et al. Jul 2001 A1
20010008672 Norvell et al. Jul 2001 A1
20020098329 Abrams Jul 2002 A1
20030129353 Abrams Jul 2003 A1
20040058120 Abrams Mar 2004 A1
20040170799 Carr et al. Sep 2004 A1
20050081985 Abrams Apr 2005 A1
20050158508 Abrams Jul 2005 A1
20050266204 Abrams Dec 2005 A1
20050268407 Abrams Dec 2005 A1
20060026778 Lion Feb 2006 A1
20060029767 Lion Feb 2006 A1
20060251852 Abrams Nov 2006 A1
20070003761 Miyazono et al. Jan 2007 A1
20070022548 Abrams Feb 2007 A1
20070026189 Abrams Feb 2007 A1
20070102093 Abrams May 2007 A1
20070110949 Abrams May 2007 A1
20070148397 Abrams Jun 2007 A1
Foreign Referenced Citations (86)
Number Date Country
E 93 557 Aug 1988 AT
E 135 427 Aug 1996 AT
606651 Feb 1991 AU
653994 Oct 1994 AU
0506601 Mar 1996 BE
757 595 Apr 1967 CA
2010076 Aug 1990 CA
1306411 Aug 1992 CA
2064300 Sep 1992 CA
757595 Apr 1997 CA
3883517 May 1994 DE
69208910 Aug 1996 DE
197 34 316 Feb 1999 DE
0122656 Oct 1984 EP
0 210 304 Feb 1987 EP
0 280 296 Aug 1988 EP
0 351 079 Jan 1990 EP
0506601 Sep 1992 EP
0506601 May 1996 EP
0 685 014 Jun 1997 EP
0913271 Oct 1998 EP
0 989 227 Mar 2000 EP
1.480.860 May 1967 FR
2.210.149 Jul 1974 FR
2543984 Oct 1984 FR
2 659 094 Mar 1990 FR
2 784 619 Oct 1998 FR
2 784 619 Apr 2000 FR
2846202 Apr 2004 FR
1171296 Nov 1969 GB
1 447 049 Aug 1976 GB
1 466 271 Mar 1977 GB
2 065 031 Jun 1981 GB
2 126 951 Apr 1984 GB
2214869 Sep 1989 GB
0506601 Sep 1992 GB
55104 Apr 1984 IE
55104 May 1990 IE
0329767 Aug 1993 IT
24637BE96 Jun 1996 IT
52-155270 Dec 1977 JP
54-163934 Dec 1979 JP
55079143 Jun 1980 JP
55-147171 Nov 1980 JP
356058824 May 1981 JP
56 108565 Aug 1981 JP
56107080 Aug 1981 JP
56 141877 Nov 1981 JP
58 62027 Apr 1983 JP
358062027 Apr 1983 JP
59 115885 Jul 1984 JP
60-171138 Sep 1985 JP
60-236738 Nov 1985 JP
S61-146368 Jul 1986 JP
63118544 May 1988 JP
64-61299 Mar 1989 JP
2-25667 Jun 1990 JP
5-201196 Aug 1993 JP
05255021 Oct 1993 JP
08-267625 Oct 1996 JP
10059790 Mar 1998 JP
11277662 Oct 1999 JP
11348159 Dec 1999 JP
02000084977 Mar 2000 JP
2000-094563 Apr 2000 JP
2000-208564 Jul 2000 JP
2001270019 Oct 2001 JP
220373 Sep 1999 KR
2003063833 Jul 2003 KR
306099 Jun 1989 NO
62640 Jul 1993 TW
WO 7901146 Dec 1979 WO
WO 8901829 Mar 1989 WO
WO 9009289 Aug 1990 WO
WO 9419530 Sep 1994 WO
WO 0207959 Jan 2002 WO
WO 0209925 Feb 2002 WO
WO 02058854 Aug 2002 WO
WO 03031083 Apr 2003 WO
WO 2004005023 Jan 2004 WO
WO 2004005413 Jan 2004 WO
WO 2004005600 Jan 2004 WO
WO 2005035235 Apr 2005 WO
WO 2005118948 Dec 2005 WO
886259 Apr 1990 ZA
922154 Feb 1993 ZA
Related Publications (1)
Number Date Country
20040058120 A1 Mar 2004 US
Continuations (1)
Number Date Country
Parent 09621830 Jul 2000 US
Child 10670091 US