Patent Application
20100297394
The present invention relates to a floor covering with improved slip resistance and appearance and to a method of manufacturing such a floor covering.
There is a demand from consumers of non-slip floor coverings for such floor coverings with an improved appearance.
A way of ameliorating this problem has been sought.
According to the present invention there is provided a slip-resistant plastics floor covering having a first layer of plastics material which first layer of plastics material has on its upper surface a particulate layer of one or more transparent coated inorganic particles which particles impart slip-resistance to the floor covering.
The advantages of the present invention include that the transparency of the inorganic particles improves the appearance of the floor covering, particularly where the floor covering has a design layer. This is because the inorganic particles are not usually visible to the user of the floor covering. This allows the particle to blend in when used on a patterned floor covering. In comparison, conventional non-slip particles are generally opaque and thus affect the appearance of the floor covering.
A further advantage of the particles used in the invention is that as the coating on the particles wears off in use, the particles do not become more visible because they are transparent. This had been a problem in the past when coloured opaque particles had been used, for example coloured silicon carbide particles.
In some aspects, the one or more particles are exposed at the upper surface of the first layer.
The one or more transparent coated inorganic particles used in the invention may be transparent or semi-transparent. The one or more particles may be coated with an adhesion coating and/or a tinted coating. An adhesion coating is a coating which enhances the adhesion between the one or more particles and the first layer of plastics material. An example of an adhesion coating is a silane, for example a silane coupling agent. A suitable silane is an optionally substituted straight or branched chain C1-8-alkyl silane wherein a suitable substituent is preferably a halogen (e.g. fluorine or chlorine), hydroxyl or amino group. The silane coating may be applied in association with an alcohol e.g. a straight or branched chain C1-8-alkyl alcohol.
A tinted coating may be a transparent or semi-transparent coloured coating. Such a coating can further reduce the visibility of the one or more particles whilst allowing any colouring of the floor covering to show through. A tinted coating may be an inorganic or a polymeric coating. A polymeric tinted coating may be a thermoset polymeric coating, for example an epoxy or polyurethane coating.
To coat the transparent inorganic particles with a transparent or semi-transparent organic coating, the following procedure is employed. The particles are mixed under low shear with the liquid coating. The particles are optionally pre-coated with a coupling agent to improve adhesion of the final coating. The organic coating can be a two component epoxy or alternatively it could be a water based or solvent based epoxy or a two part solvent based polyurethane or waterborne polyurethane or acrylic.
The application of frictional heat and/or externally applied heat reduces the viscosity of the coating system, allowing good coverage before the onset of curing which is accompanied by a rise in the viscosity. With a water based system, the water may first be removed at 100° C.
Full curing is achieved after the coating has fully hardened onto the inorganic particles and there is no evidence of residual coating liquid. The resulting product is then sieved to give correct particle size distribution. Particle agglomeration is avoided by optimising the ratio of coating material to inorganic particles and agitation by tumbling or stirring in a rotary action mixer.
To coat the transparent inorganic particles with a transparent or semi-transparent inorganic coating, the following procedure is employed. An inorganic pigmented coating such as vitreous enamel is fused onto the inorganic particle at a high temperature.
The transparent coated inorganic particle may be a transparent coated quartz, glass or aluminium oxide particle. In some aspects, it may be a transparent coated aluminium oxide particle.
The transparent coated inorganic particle may have a particle size of from 0.1 mm, particularly from 0.2 mm, especially from 0.4 mm to 1.5 mm, particularly to 1.2 mm, especially to 0.6 mm. In some aspects, the transparent coated inorganic particle may have a size determined by F36 grade (FEPA Standard 42-GB-1984 measurement) of 0.4 to 0.6 mm.
The flooring material according to the invention has an upper surface which is formed by the first layer of plastics material. The particulate layer is arranged such that substantially all (in some aspects all) of the particles are exposed at the upper surface of the floor covering. The particulate layer may be arranged such that the one or more particles penetrate the first layer of plastics material. This is in order that the one or more particles is embedded in the first layer such that they are hard to dislodge.
The plastics material used to form the first layer of plastics material may be substantially free from the particles which provide a slip-resistant effect. This is in order to reduce costs and to ensure that the upper surface of the first layer is uniform. A further advantage of having the first layer substantially free from the particles is that it improves the appearance of the first layer. This is particularly the case where the first layer is substantially transparent or clear. The first layer of plastics material may be free from a plasticizer.
The first layer of plastics material is optionally either a layer of substantially clear plastics material such that the layer is substantially translucent or substantially transparent or a layer of coloured plastics material.
The coating of the particles may be matched to the colour and/or appearance of the plastics material of the first layer. Where the first layer is a layer of substantially clear plastics material, the particles may be substantially clear and/or substantially translucent; where the first layer is a layer of coloured plastics material, the particles may be tinted to match the colour of the plastics material.
Substantially transparent particles used in the invention may have a refractive index within ±0.2 of the clear coat layer.
Optionally the floor covering further includes an additive commonly used in the art such as a UV stabiliser, a biocide, and/or a flow aid such as fumed silica.
The first layer of plastics material is optionally either a coating layer or a base layer. Where the first layer is a coating layer, the floor covering additionally comprises at least one base layer; the particles may penetrate through the first layer to the base layer.
Where the first layer of plastics, material is a coating layer, it may include a thermoplastic or a cross-linkable polymer or copolymer. For the cross-linkable polymer or copolymer, cross-linking may be effected by condensation or by a free radical route such as using UV radiation. It will be understood that a cross-linkable polymer used in the invention is generally a thermoset polymer. Examples of suitable polymers or copolymers include PvdF, a polyester, polyurethane, or acrylic polymer or copolymer, an epoxy resin, and/or an olefin/modified olefin copolymer. The coating layer may include an acrylic polymer. In some aspects, the coating layer may include a mixture of an acrylic polymer with PvdF. In some aspects, the coating layer is substantially free from a thermosetting polymer or co-polymer. This is because thermosetting polymers or copolymers may not be generally sufficiently fast curing or flexible enough to be useful in the coating layer of the floor covering.
A first layer or a base layer for use in the floor covering according to the invention may comprise a plastics material such as a thermoplastic polymer (for example a PVC, a polyurethane, and/or a plasticised acrylic polymer) or a thermoset polymer (for example a polyester, an acrylic, a polyurethane and/or an epoxypolymer). In some aspects, the plastics material is a PVC plastisol or a plasticised acrylic material.
The floor covering may include a reinforcing support; in some aspects, the support is a glass fibre reinforced non-woven support.
The floor covering may optionally comprise one or more additional base layers; in some aspects, up to three layers are envisaged.
The floor covering optionally includes a design layer. A design layer comprises a layer of ink or a printed film layer (the film is preferably formed from a plastics material such as PVC) which gives the floor covering an attractive appearance. In order that the design layer is visible, the first layer is substantially transparent when the floor covering includes a design layer. In some aspects, one or more substantially transparent base layers are optionally provided between the first layer and the design layer.
The floor covering may optionally further contain a decorative additive such as a quartz chip, a pigment, a stone chip (e.g. limestone, marble or granite) and/or a pigmented PVC chip. In some aspects, the floor covering is embossed. Where the plastics material is a thermoset polymer, the floor covering optionally includes an aggregate such as crushed glass, granite, flint, calcined flint, marble, quartz or another decorative stone and/or a further grit to provide slip resistance such as calcined flint, calcined bauxite, silicon carbide, aluminium oxide, transparent aluminium oxide and/or brown aluminium oxide. The particle size of the grit is from 0.05 mm to 1.5 mm, especially to 1.0 mm. In some aspects, the grit may have a range of particle sizes.
Where the plastics material is a thermoplastic polymer, the floor covering according to the invention optionally further comprises one or more additional particulate materials such as a glass bead or flake, crushed glass, white aluminium oxide, clear quartz, an alumina silicate, micaceous material (such as Mica), nylon powder, a nylon bead, a rubber particle, rubber powder, a polymeric powder, a polymeric bead, a ceramic material, a synthetic crystal, a fibre (such as a fibre of Nylon), titanium dioxide, wax and/or liquid rubber. In some aspects, the first layer and/or the floor covering according to the invention is substantially free from opaque particulate material.
A suitable plastisol paste for use as a plastics material in the present invention comprises about 100 parts of plastics material (e.g. PVC powder), from 30 to 70 parts of a plasticiser, from 0 to 100 parts of mineral filler, from 1 to 3 parts of a thermal stabiliser and from 0 to 6 parts of a pigment (where the parts are parts per hundred of resin).
According to the invention there is also provided a method of manufacturing a slip resistant floor covering which method comprises the steps of:
applying a first layer of plastics material;
applying a particulate layer of transparent coated inorganic particles to an upper surface of the first layer; and
curing the plastics material such that it forms a continuous film; wherein the particles provide a slip-resistant effect.
The method of the invention may comprise a step of applying at least one base layer. In such a method, the first layer is a coating layer which is applied to an upper surface of the base layer. In some aspects, the steps of the method of the invention may be carried out sequentially. The step of applying the particulate layer may be carried out such that the particles are exposed on the upper surface of the layer.
The method of the invention may comprise a step of applying a design layer wherein the first layer of plastics material is substantially clear and is applied to an upper surface of the design layer. In some aspects, the method of the invention comprises steps of:
applying a base layer;
applying a design layer on an upper surface of the base layer; and
applying a first layer on an upper surface of the design layer. This method may comprise a step of applying one or more substantially transparent base layers on the upper surface of the design layer.
The invention will now be described with reference to the following Figures of the accompanying drawings which are not intended to limit the scope of the invention in which:
The first embodiment of a floor covering 1 illustrated in
As an alternative to the embodiment depicted in
The second embodiment of a floor covering 101 illustrated in
As an alternative to the embodiment depicted in
The third embodiment of a floor covering 201 illustrated in
As an alternative to the embodiment depicted in
The fourth embodiment of a floor covering 301 illustrated in
As an alternative to the embodiment depicted in
The invention is further illustrated with reference to the following examples which are not intended to limit the scope of the invention claimed.
In this Example, the method of preparing silane coated aluminium oxide particles is described.
Transparent aluminium oxide particles graded F36 (FEPA Standard 42-GB-1984 measurement) may be supplied by Bond Minerals and Polymers. Particles coated with a silane coupling agent improve adhesion of the particles to the first layer. The coupling agent solution can be added to the inorganic particles at 0.3 parts per hundred of inorganic particles and blended in a low shear rotary action mixer before force drying if necessary.
In this Example, the method of preparing tinted aluminium oxide particles is described.
Silane coated aluminium oxide particles prepared as described in Preparative Example 1 or uncoated aluminium oxide particles may be used. A resin system may be added to dry particles to coat them whilst mixing. Mixing is continued until the coating is cured. The product is forced dry and post cured if necessary.
The resin is added at a rate of 120 g per m2 of inorganic particles surface area.
The following resin system formulations may be used:
In each two part resin system the whole of part A is mixed with the whole of part B before application to the inorganic particles. Typically the particles are mixed with the two part resin system in a ribbon or other rotary low shear mixer for about 60 minutes after which time the coating on the inorganic particles should be hard enough to handle.
Plastisols having the formulations given in Table 1 were produced as described below.
In each case, the ingredients were weighed in to a 50 litre steel vessel and mixed by a trifoil shaft mixer at 100 rpm for 4 minutes and a dissolver shaft at 1800 rpm for 2 minutes. Aluminium oxide particles (from Washington Mills) size F40 (FEPA Standard 42-GB-1984 measurement) were weighed into plastisol B (10% w/w) and mixed.
A thermoplastic powder coating C having the formulation shown in Table 2 was produced as described below.
The ingredients were weighed and blended by being tumbled together. The blend was extruded in an extruder with the screw rotation set at 313 rpm, the barrel set at 200° C. and the feed zone set at 30° C. The extrudate was collected in large containers (of dimensions: 380 mm×305 mm×75 mm) and allowed to cool slowly at ambient temperature for 8 hours. The resulting blocks were broken, into smaller pieces by mechanical attrition. The material was then ground in an disc mill, using a single pass and no intermediate sieving screen. The temperature of the material prior to its introduction into the mill was -100° C.; the mill was maintained at −35° C. during grinding. 99% of the resulting powder was of a size of below 90 microns and the average powder size was 37 μm.
In this Example, the preparation of a floor covering as depicted in
Plastisol B was spread coated onto a substrate to a thickness of 1 mm by knife over roller. The substrate was a 2 m width cellulose/polyester support reinforced with a glass crennette moving at a rate of 7 metres/minute. The system was then passed into a convection oven where it was exposed to 160° C. for 2 minutes. The system was then passed through a series of cooling rollers before it was over coated with plastisol A to a total thickness of 2 mm by knife over bed.
Tinted transparent coated aluminium oxide particles having a first layer of polyurethane and a second layer of epoxy, prepared as described in Preparative Example 2 were then scattered onto the surface of the plastisol at a rate of 75 g/m2. The system was then passed in to a convection oven where it was exposed to 190° C. for 3 minutes before being embossed, cooled and wound up for subsequent trimming to size.
Comparative visual tests showed that the appearance of the floor covering prepared was not impaired by the addition of the anti-slip material. Indeed, when viewed at a distance of greater than about 1 m, the aluminium oxide particles were not visible on the surface of the floor covering. The slip resistance of the floor covering was measured and was found to have a value recommended by the UK Slip Resistance Group guidelines as giving low potential to slip.
In this Example, the preparation of a floor covering as depicted in
Plastisol A was spread coated on a substrate to a thickness of 2 mm by knife over roller. The substrate was a 2 m width cellulose/polyester support reinforced with a glass crennette moving at a rate of 3 metre/minute. Particles of coloured quartz of a size of 1.2-1.8 mm were then scattered on to the surface of the plastisol at a rate of 500 g/m2. The coated web was then passed under a 50 kW medium wave infra red heater (width 2.5 m; length 1 m). The heater was positioned at a height of 10 cm above the web. The power output of the heater was adjusted so that the surface of the plastisol as it exited the infra red zone was fully solidified (‘gelled’) to the touch.
An acrylic based clear coating powder C, was then applied to the surface at a rate of 80±30 g/m2 using a scatter powder coating application system. Tinted transparent coated aluminium oxide particles having a first layer of polyurethane and a second layer of epoxy, prepared as described in Preparative Example 2 were then scattered on to the surface at the rate of 75 g/m2. The system was then passed in to a convection oven where it was exposed to 190° C. for 2 minutes before being embossed, cooled and wound up for subsequent trimming to size.
In this Example, the preparation of a floor covering as depicted in
Plastisol B was spread coated onto a substrate to a thickness of 1 mm by knife over roller. The substrate was a 2 m width cellulose/polyester support reinforced with a glass crennette moving at a rate of 7 metres/minute. The system was then passed over a gel drum to partially cure and flatten the layer of plastisol.
A wood print PVC film having a thickness of 0.1 mm was then laminated onto the system by the application of pressure to the hot surface of the gelled PVC.
Plastisol A was spread coated on the system to a thickness of 2 mm by knife over roller. The coated web was then passed under a 50 kW medium wave infra red heater (width 2.5 m; length 1 m). The heater was positioned at a height of 10 cm above the web. The power output of the heater was adjusted so that the surface of the plastisol as it exited the infra red zone was fully solidified (‘gelled’) to the touch.
An acrylic based clear coating powder C, was then applied to the surface at a rate of 80±30 g/m2 using a scatter powder coating application system. Tinted transparent coated aluminium oxide particles having a first layer of polyurethane and a second layer of epoxy, prepared as described in Preparative Example 2 were then scattered on to the surface at the rate of 75 g/m2. The system was then passed in to a convection oven where it was exposed to 190° C. for 2 minutes before being embossed, cooled and wound up for subsequent trimming to size.
An epoxy resin having the components set out in Table 3 was prepared by mixing and then was cast into a tile-shaped mould.
The resulting cast tile was ground to expose the aggregate particles and to provide a flat profile. It was found that such tiles, despite exhibiting good slip resistance, can, when cleaned aggressively in service, become polished, thus reducing slip resistance. The inclusion of tinted transparent coated aluminium oxide particles having a high polished stone value within the epoxy matrix provides harder particles in the surface which do not become polished during cleaning and thus maintain slip resistance.
| Number | Date | Country | Kind |
|---|---|---|---|
| 0617389.2 | Sep 2006 | GB | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/GB2007/003315 | 9/4/2007 | WO | 00 | 6/9/2010 |
