The present invention relates to a technique for improving gas flow distribution characteristics of a fuel cell.
In general, a fuel cell has a stack of a plurality of unit fuel cells. Fuel cells with a reaction gas channels formed inside the separators have been proposed to facilitate alignment of each member constituting the unit fuel cell while stacking these unit fuel cells, and to facilitate assemble of the fuel cell. For example, JP2002-15110A discloses a fuel cell having gas through holes provided on the electrode side of the reaction gas channel, for supplying reaction gas to the electrodes and for exhausting the reaction gas from the electrodes.
However, when reaction gas is supplied to the electrode via such a gas through hole, the flow rate of the reaction gas may be different at the downstream side of an electrode part that is close to the gas through hole and at the downstream side of another electrode part that is not close to the gas through hole, resulting in uneven reaction gas flow rate within the electrode.
The present invention is created considering the prior art problem described above, and its object is to uniformize the reaction gas flow rate in the electrode.
To achieve at least part of the above mentioned object, a fuel cell of the present invention is provided. The fuel cell has a plurality of unit fuel cells each having an electrode and a separator; and a gas manifold configured to pass through the plurality of the unit fuel cells, wherein the separator includes a plurality of gas channels configured to communicate the gas manifold and a gas passage existing on a surface of the electrode, the plurality of gas channels being located internally in the separator, each of the plurality of gas channels includes at least one gas through hole configured to open on a surface of the separator facing the electrode, and the gas through holes of the plurality of gas channels include a first through hole group provided at a first distance from the gas manifold, and a second through hole group provided at a second distance greater than the first distance from the gas manifold.
With this arrangement, since the flow of the reaction gas is disturbed by the collision of the reaction gas at the surface of the electrode, it is possible to increase the uniformity of the reaction gas flow rate in the electrode.
Note that the present invention can be realized with various aspects, for example, it is possible to realize it with an aspect of a fuel cell and a fuel cell system using that fuel cell, or a power generating device using that fuel cell system and an electric powered car incorporating that fuel cell system.
FIGS. 1(a) and 1(b) are explanatory drawings showing the configuration of a fuel cell stack 100 constituting a fuel cell.
FIGS. 2(a) to 2(c) are schematic drawings that show the shape of three plates 300, 400 and 500 constituting a unit fuel cell 200.
FIGS. 3(a) and 3(b) are explanatory drawings showing the fuel gas flow in the first embodiment.
FIGS. 4(a) and 4(b) are explanatory drawings showing the oxidant gas flow in the first embodiment.
FIGS. 5(a) and 5(b) are explanatory drawings showing the oxidant gas flow in the second embodiment.
FIGS. 6(a) and 6(b) are explanatory drawings showing the oxidant gas flow in the third embodiment.
FIGS. 7(a) to 7(c) are explanatory drawings showing the oxidant gas flow in the fourth embodiment.
The best mode for carrying out the invention is described in the following order based on embodiments.
Each of the three plates 300, 400 and 500 are flat plates with various shaped holes formed by press forming. These plates 300, 400 and 500 are formed from a material having gas impermeability and electrical conductivity such as stainless steel. These three plates 300, 400 and 500 are stacked to from a separator which has separated channels for the fuel gas, the oxidant gas, and the cooling water.
The membrane electrode assembly 600 has an electrolytic membrane 620, an anode 640, and a cathode 660. The electrolytic membrane 620 is an ion exchange membrane, which has high conductivity in the wet state, formed by a fluorine type resin such as Nafion (trademark of Dupont). The anode 640 and the cathode 660 are formed by a porous material having gas diffusion properties and conductivity such as a carbon cloth. On this anode 640 and cathode 660, fuel cell reaction catalyst such as platinum or platinum alloy is supported. Note that hereinafter, the anode 640 and the cathode 660 are collectively referred as an “electrode.”
The seal member 210 is formed from a material having gas impermeability, elasticity, and heat resistance such as silicon rubber. The seal member includes a hole for placing the membrane electrode assembly 600 at the center part of the seal member 210, as shown by the dashed lines.
Each of the three plates 300, 400, and 500 and the seal member 210 include a plurality of through holes (not illustrated). These through holes form the manifolds 110 to 160 when the unit fuel cells 200 are stacked to assemble the fuel cell stack 100. Note that hereafter, these through holes are also called “manifold holes.”
The unspent oxidant gas is supplied to the unit fuel cells 200 via the oxidant gas supply manifold 110, and the spent oxidant gas exhausted from the unit fuel cells 200 (cathode off gas) is exhausted via the oxidant gas exhaust manifold 120. The unspent fuel gas is supplied to the unit fuel cells 200 via the fuel gas supply manifold 130, and the spent fuel gas exhausted from the unit fuel cells 200 (anode off gas) is exhausted via the fuel gas exhaust manifold 140. Note that, since the oxidant gas and fuel gas are gases used for the fuel cell reaction, these gases are collectively called as a “reaction gas” in general.
The cooling water of the fuel cell stack 100 is supplied to the unit fuel cells 200 via the cooling water supply manifold 150. Then, the cooling water that flows in the cooling water channels (not illustrated) in the separator are exhausted from the fuel cell stack 100 via the cooling water exhaust manifold 160.
Comb-tooth shaped oxidant gas supply channel holes 542 for communicating the oxidant gas supply holes 440 and 442 and the oxidant gas supply manifold 110 are formed on the manifold hole 522 corresponding to the oxidant gas supply manifold 110. As a result, in the stack of these three plates 300, 400 and 500, a plurality of oxidant gas supply channels are formed, and the oxidant gas supply manifold 110 and the oxidant gas supply holes 440 and 442 are communicated.
Comb-tooth shaped oxidant gas exhaust channel holes 544 for communicating the oxidant gas exhaust holes 444 and the oxidant gas exhaust manifold 120 are formed on the manifold hole 524 corresponding to the oxidant gas exhaust manifold 120. Similarly, comb-tooth shaped fuel gas supply channel holes 546 for communicating the fuel gas supply manifold 130 and the fuel gas supply holes 350 are formed on the manifold hole 526 corresponding to the fuel gas supply manifold 130. Also, comb tooth shaped fuel gas exhaust channel holes 548 for communicating the fuel gas exhaust holes 354 and the fuel gas exhaust manifold 140 are formed on the manifold hole 528 corresponding to the fuel gas exhaust manifold 140.
In addition to these manifold holes 522 to 528 and the gas channel holes 542, 544, 546 and 548, the intermediate plate 500 includes a plurality of cooling water channel holes 550 that extend from the position of the cooling water supply manifolds 150 (manifold holes 330 and 430) to the position of the cooling water exhaust manifolds 160 (manifold holes 332 and 432). In the stack of the three plates 300, 400 and 500, these cooling water channel holes 550 form the cooling water channels that communicate the cooling water supply manifold 150 and the cooling water exhaust manifold 160.
FIGS. 3(a) and 3(b) are explanatory drawings showing the fuel gas flow in the first embodiment.
As shown in
As shown by the arrow in
FIGS. 4(a) and 4(b) are explanatory drawings showing the flow of oxidant gas in the first embodiment.
As shown in
In the unit fuel cells 200 configured in this way, the oxidant gas is supplied from the oxidant gas supply manifold 110 via the oxidant gas supply channel 810 to the cathode 660 as shown by the arrow in
In this case, the oxidant gas supplied from the upstream side oxidant gas supply hole 440 near the oxidant gas supply manifold 110 to the cathode 660 has its main flow direction in a parallel direction to the line C-C of
As shown in
In this way, with the first embodiment, by providing two oxidant gas supply holes 440 and 442 on one oxidant gas supply channel 810, it is possible to collide different direction oxidant gas flows. Because of this, the flow of the oxidant gas is disturbed by the collision of the oxidant gas flow in the cathode 660, so the uniformity of the oxidant gas flow rate in the cathode 660 increases.
Note that with the first embodiment, a plurality of oxidant gas supply holes constitute the first and second two oxidant gas supply hole groups, but the number of oxidant gas supply hole groups may be any number of 2 or greater. Even in this case, the distances from the oxidant gas supply manifold 110 (manifold hole 422) of each oxidant gas supply hole group are set to be mutually different.
FIGS. 5(a) and 5(b) are explanatory drawings showing the flow of oxidant gas in the second embodiment. With the second embodiment, the point that differs from the first embodiment is that the cathode side plate 400a includes oblong oxidant gas supply holes 440a and 442a instead of the circular oxidant gas supply holes 440 and 442. The other points are the same as the first embodiment.
As shown in
Note that with the second embodiment, the plurality of oxidant gas supply holes 440a are formed by communicating two oxidant gas supply holes 440 belonging to the first oxidant gas supply hole group, and the plurality of oxidant gas supply holes 442a are formed by communicating two oxidant gas supply holes 442 belonging to the second oxidant gas supply hole group. Because of this, we may say that the two oxidant gas supply hole groups have expanded through holes 440a and 442a respectively.
With the second embodiment as well, as shown in
With the second embodiment as well, the oxidant gas flow from the upstream side oxidant gas supply hole 440a and the oxidant gas flow from the downstream side oxidant gas supply hole 442a collide at the position of the oxidant gas supply channel hole 542. Because of this, the flow of the oxidant gas is disturbed by the collision of the oxidant gas flows in the cathode 660, so it is possible to increase the uniformity of the oxidant gas flow rate in the cathode 660.
Also, the oxidant gas supplied to the cathode 660 flows toward downstream from the overall oblong oxidant gas supply holes 440a and 442a. The oxidant gas supply holes 440a and 442a are formed across the entire width of the cathode 660, so it is possible to further increase the uniformity of the oxidant gas flow rate within the cathode 660.
The adjacent oxidant gas supply channel holes 542 are communicated by the oblong oxidant gas supply holes 440a and 442a. The adjacent oxidant gas supply channel holes 542 are communicated, so even if either of the oxidant gas supply channel holes 542 is blocked by a foreign substance incorporated in the oxidant gas, the oxidant gas is supplied to the cathode 660 through the oxidant gas supply channel holes 542 that is not blocked. Because of this, with the second embodiment, it is possible to suppress decrease in uniformity of the oxidant gas flow rate in cathode 660 due to blockage of the oxidant gas supply channel hole 542.
In this way, with the second embodiment as well, the same as with the first embodiment, the oxidant gas flow is disturbed by the collision of the oxidant gas flows in the cathode 660, so it is possible to increase the uniformity of the oxidant gas flow rate in the cathode 660.
The second embodiment is preferable to the first embodiment in that it is possible to suppress decrease in uniformity of the oxidant gas flow rate in the cathode 660 due to blocking of the oxidant gas supply channel hole 542. On the other hand, the first embodiment is preferable to the second embodiment in that the opening area of the oxidant gas supply holes provided on the cathode side plate is small, and it is possible to suppress a decrease in rigidity of the cathode side plate.
Note that with the second embodiment, the expanded through holes are formed by communicating two oxidant gas supply holes that belong to the same oxidant gas supply hole group, but generally, it is acceptable as long as the expanded through hole communicates L (L is any integer of 2 or more) oxidant gas supply holes provided on adjacent oxidant gas supply channels. For example, it is also possible to communicate the oxidant gas supply hole 440 provided on a certain oxidant gas supply channel and the oxidant gas supply hole 442 provided on the oxidant gas supply channel adjacent to that channel. In this case, the arrangement of the expanded through holes is in straight line form rather than in zigzag form.
FIGS. 6(a) and 6(b) are explanatory drawings showing the oxidant gas flow in the third embodiment. The third embodiment differs from the first embodiment in that the cathode side plate 400b further includes the oxide gas exhaust hole 446, and in that the oxidant gas exhaust channel holes 544b is formed so as to communicate the oxidant gas exhaust manifold 120 and the oxidant gas exhaust holes 444 and 446. The other points are the same as the first embodiment.
As shown in
As shown in
Note that with the third embodiment as well, the same as with the first embodiment, two oxidant gas supply holes 440 and 442 are provided on one oxidant gas supply channel 810. Because of this, the oxidant gas flow collides in the cathode 660, and the uniformity of the oxidant gas flow rate in the cathode 660 increases. Also, because the oxidant gas supply channel 810 is branched, it is possible to suppress decrease in uniformity of the oxidant gas flow rate in the cathode 660 due to blocking of the oxidant gas supply hole.
The third embodiment is preferable to the first embodiment in terms of being able to suppress decrease in uniformity of the oxidant gas flow rate of the downstream part of the cathode 660 due to blocking of the oxidant gas exhaust hole. On the other hand, the first embodiment is preferable to the third embodiment in that it is able to suppress decrease in rigidity of the cathode side plate because the number of oxidant gas exhaust holes provided on the cathode side plate is small.
Note that with the third embodiment, the cathode side plate 400b has two oxidant gas supply hole groups and two oxidant gas exhaust hole groups, but it is also possible to have M (M is any integer of 1 or greater) oxidant gas supply hole groups and N (N is any integer of 2 or greater) oxidant gas exhaust hole groups. Even when number of the oxidant gas supply hole group is 1, it is possible to suppress decrease in uniformity of the oxidant gas flow rate of the downstream part of the cathode 660 due to blocking of the oxidant gas exhaust hole.
FIGS. 7(a) to 7(c) are explanatory drawings showing the oxidant gas flow in the fourth embodiment. The fourth embodiment differs from the first embodiment in that one oxidant gas supply channel hole 542c has one of oxidant gas supply holes 440c, 442c, and that the oxidant gas supply hole 442c is formed in a horizontally long ellipse shape. The other points are the same as with the first embodiment.
As shown in
With the fourth embodiment, as shown in
With the fourth embodiment as well, the oxidant gas flow from the upstream side oxidant gas supply holes 440c and the oxidant gas flow from the downstream side oxidant gas supply holes 442c are collided at the position of the oxidant gas supply hole 442c. Because of this, the flow of the oxidant gas is disturbed by the collision of the oxidant gas flow in the cathode 660, so it is possible to increase the uniformity of the oxidant gas flow rate in the cathode 660.
Also, the oxidant gas supplied to the cathode 660 flows toward downstream from the overall circular oxidant gas supply holes 440c and the ellipse shaped oxidant gas supply holes 442c. These oxidant gas supply holes 440c and 442c are formed extending across the entire width of the cathode 660, so it is possible to increase the uniformity of the oxidant gas flow rate in the cathode 660.
In this way, with the fourth embodiment as well, the same as with the first embodiment, the flow of the oxidant gas is disturbed by the collision of the oxidant gas flow in the cathode 660, so it is possible to increase the uniformity of the oxidant gas flow rate within the cathode 660.
Note that with the fourth embodiment, the downstream side oxidant gas supply holes 442c have a horizontally long elliptical shape, and the upstream side oxidant gas supply hole 440c is circular, but as long as the total opening area of the downstream side oxidant gas supply holes are the same or greater than the total opening area of the upstream side oxidant gas supply holes, it is also possible to form the upstream side oxidant gas supply holes and the downstream side oxidant gas supply holes in different shapes. By forming the upstream side and downstream side oxidant gas supply holes in this way, by the collision of the oxidant gas flow from the upstream side oxidant gas supply holes and the oxidant gas from the downstream side oxidant gas supply holes, it is possible to disturb this flow.
Also, with the fourth embodiment, the oxidant gas supply holes corresponding to the adjacent oxidant gas exhaust channel holes are arranged on two straight lines of different mutual distances from the oxidant gas supply manifold, but it is also possible to arrange the oxidant gas exhaust holes corresponding to the adjacent oxidant gas exhaust channel holes on straight lines of mutually different distances from the oxidant gas exhaust manifold. In this case, the distance of the oxidant gas exhaust hole is greater than providing the oxidant gas exhaust hole on a single straight line, so the possibility of adjacent oxidant gas exhaust holes being blocked simultaneously by generated water is decreased. Because of this, it is possible to suppress decrease in uniformity of the gas at the downstream part of the cathode due to blocking of the oxidant gas exhaust holes.
In this case, for the oxidant gas exhaust holes, the oxidant gas exhaust holes are formed extending across the entire width of the cathode 660, further increasing the uniformity of the oxidant gas flow rate, so it is preferable to make the total opening area larger for one of the upstream side oxidant gas exhaust hole or the downstream side oxidant gas exhaust hole. In this case, it is possible to suppress decrease in the rigidity of the cathode side plate, so it is preferable to make the total opening area of the oxidant gas exhaust hole distance from the oxidant gas exhaust manifold larger than the total opening area of the oxidant gas exhaust hole nearer to the oxidant gas exhaust manifold.
Note that the present invention is not limited to the aforementioned embodiments and aspects, but can be implemented with various aspects in a scope that does not stray from the key points, and for example, the following kinds of variations are also possible.
E1. Variation 1:
With each of the aforementioned embodiments, as shown in
E2. Variation 2:
With each of the aforementioned embodiments, a separator having gas channels (oxidant gas supply channels, oxidant gas exhaust channels, fuel gas supply channels, fuel gas exhaust channels) that communicate the manifolds and the electrodes is formed by three plates, but it is also possible to form the separator using another configuration. For example, it is also possible to form a separator by stacking a member provided with a channel groove and a gas through hole for forming the gas channels, and a plurality of members containing members for separating the channels of the fuel gas, the oxidant gas, and the cooling water.
E3. Variation 3:
With each of the aforementioned embodiments, by forming the electrode with a single porous material that is used as a gas passage for passing the reaction gas through the electrode, but it is also possible to form the gas passage using another method. For example, by providing a gas diffusion layer formed using a porous material with a higher porosity than the porosity of the porous material of the electrolytic side on the electrode, the high porosity gas diffusion layer becomes the gas passage that passes through reaction gas. It is also possible to form a channel groove on the surface in contact with the electrode of the separator, and to use the channel formed by that channel groove and the electrode as the gas passage.
E4. Variation 4:
With each of the aforementioned embodiments, improvement of the uniformity of oxide gas flow rate in the cathode by application of the present invention is described, but it is also possible to improve the uniformity of the fuel gas flow rate in the anode by applying the present invention to the fuel gas channel.
Number | Date | Country | Kind |
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2004-354856 | Dec 2004 | JP | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/JP05/22910 | 12/7/2005 | WO | 5/14/2007 |