The embodiments herein generally relate to fuel cells, and, more particularly, to a fuel cell having flow fields which provide substantially uniform flow distribution, efficient removal of liquids and gases, reduced contact resistance, and robust implementation for production assembly procedures.
A fuel cell provides direct current electricity from two electrochemical reactions. The electrochemical reactions occur at electrodes to which reactants are fed. For example, in a direct methanol fuel cell (DMFC), a negative electrode (i.e., anode) is maintained by supplying a fuel such as methanol, whereas a positive electrode (i.e., cathode) is maintained by supplying oxygen or air. When providing a current, methanol is electrochemically oxidized at an anode electro-catalyst to produce electrons, which travel through an external circuit to a cathode electro-catalyst where the electrons are consumed together with oxygen in a reduction reaction. A circuit is maintained within the DMFC by the conduction of protons in an electrolyte.
A fuel cell stack typically includes a series of fuel cells. Each cell includes a pair of anode and cathode. A voltage across each cell is determined by the type of electrochemical reaction occurring in the cell. For example, for a typical single DMFC, the voltage can vary from 0 V to 0.9 V, depending on a current being generated. The current being generated in the cell depends on the operating condition and design of the cell, such as electro-catalyst composition/distribution and active surface area of a membrane electrode assembly (MEA), characteristics of a gas diffusion layer (GDL), flow field design of anode and cathode bipolar plates, cell temperature, reactant concentration, reactant flow and pressure distribution, reaction by-product removal, and so forth. The reaction area of a cell, number of cells in series, and the type of electrochemical reaction in the fuel cell stack determine a current and hence a power supplied by the fuel cell stack. For example, typical power for a DMFC stack can range from a few watts to several kilowatts.
A fuel cell system typically integrates a fuel cell stack with different subsystems for the management of water, fuel, air, humidification, and thermal condition. These subsystems are sometimes collectively referred to as a balance of the plant (BOP). The interface between the fuel cell stack and the BOP is referred to as a stack manifold. The stack manifold serves as a conduit for bi-directional flow distribution between the BOP and the fuel cell stack. Conduits for bi-directional fluid flows between the stack manifold and individual cells are called headers and are part of anode and cathode plate design.
Further, it is desirable for a volumetric density (e.g., in terms of kilowatts/liter) of a fuel cell stack to be as high as practical, which typically involves a reduction in a stack volume for a particular power delivered by the fuel cell stack. High power (e.g., greater than about 0.5 kilowatts) DMFC stacks typically suffer from mass transport restrictions of anodes and cathodes when operated at higher volumetric densities. In addition, the DMFC stacks can sometimes suffer from irreversible cathode damage arising from gas diffusion layer over-compression and silicon oxide deposition on the gas diffusion layer and the flow field plate of cathode side causing mass transport restriction. The effectiveness of the mass transport is typically affected by the degree of compression of the gas diffusion layers, and other characteristics such as porosity and Teflon content. A certain degree of compression is desirable to reduce Ohmic resistances between the anode flow field plate and the cathode flow field plate, the gas diffusion layers, and the catalyst coated membrane. However, too high a compression can crush fibers forming the gas diffusion layers and close pores through which mass transport occurs which may result in damage of the electrodes.
Therefore, there is a need to develop fuel cells having flow fields which provide substantially uniform flow distribution, efficient removal of liquids and gases, reduced contact resistance, and robust implementation for production assembly procedures
In view of the foregoing, an embodiment herein provides a fuel cell having an anode flow field plate having a flow field including a plurality of first lands and a plurality of first channels. Further, the fuel cell includes a cathode flow field plate having a flow field including a plurality of second lands and a plurality of second channels. A membrane electrode assembly is provided between the anode flow field plate and the cathode flow field plate. A width of each of the first channels is greater than a width of each of the second channels.
These and other aspects of the embodiments herein will be better appreciated and understood when considered in conjunction with the following description and the accompanying drawings.
The embodiments herein will be better understood from the following detailed description with reference to the drawings, in which:
a-2e illustrate anode flow field plates according to embodiments as disclosed herein;
a-3c illustrate a cathode flow field plates according to embodiments as disclosed herein;
a-4b illustrates membrane electrode assembly (MEA) stacked up with according to an embodiment as disclosed herein; and
a and 5b illustrate aspects of inlet and outlet ports for flow fields, according to some embodiments of the invention.
The embodiments herein and the various features and advantageous details thereof are explained more fully with reference to the non-limiting embodiments that are illustrated in the accompanying drawings and detailed in the following description. Descriptions of well-known components and processing techniques are omitted so as to not unnecessarily obscure the embodiments herein. The examples used herein are intended merely to facilitate an understanding of ways in which the embodiments herein may be practiced and to further enable those of skill in the art to practice the embodiments herein. Accordingly, the examples should not be construed as limiting the scope of the embodiments herein.
The embodiments herein disclose a composite gasket. Referring now to the drawings, and more particularly to
The bipolar plates 111b are made of graphite. It is to be noted that the bipolar plate 111b can also be made of a metal or an alloy. The bipolar plate 111b has two planar surfaces each of which define flow fields. A flow field on one planar surface facilitates a flow of anode reactants and by-products, and a flow field on the other planar surface facilitates cathode reactants and by-products.
Further, the monopolar plates 110b and 112b are made of graphite. It is to be noted that the monopolar plates 110b and 112b can be made of a metal or an alloy. Each of the monopolar plates 110b and 112b has a planar surface which defines a flow field therein. Each of the monopolar plates 110b and 112b defining flow field is configured to facilitate flow of reactants and by-products at either anode or cathode. The flow of reactants to the flow fields from the end plates 108b and 109b and the flow of unused reactants and by-products from the flow fields to the end plates 108b and 109b occur through headers 116b defined in the monopolar plates 110b and 112b and the bipolar plates 111b. A pair of anode and cathode flow fields with a MEA sandwiched there between is called a cell. In the illustrated embodiment, the manifolds of the end plates 108b and 109b act as distribution conduits for fluids between the cells in the fuel cell stack 100 and a balance of plant (BOP).
a shows an anode flow field plate 200 having a flow field F1 according to an embodiment. The flow field F1 has a plurality of lands 204 and a plurality of channels 202. Each of the channels 202 is defined between two adjacent lands 204. Each of the channels 202 is configured to be in fluid communication with a first port A1 and a second port A2. Each of the first and second ports A1 and A2 allows a passage of the fuel to or from the channels 202. In one embodiment, the fuel enters from the second port A2 and an initial flow of the fuel is vertically upwards and subsequently side wards relative to the flow field F1 and the anode flow field plate 200 as shown by the arrows. In another embodiment, the fuel enters from the first port A1 and an initial flow of the fuel is vertically down wards and subsequently side wards relative to the flow field F1 and the anode flow field plate 200 as shown by the arrows. Further, it has to be noted that with respect to the flow field F1, a length of a portion of a channel 202 configured to provide a horizontal flow (or sideward flow) is greater than a length of the portion of the channel 202 configured to provide a vertical flow (upward or downward flow).
F1G. 2b shows an anode flow field plate 200 having a flow field F2 according to another embodiment. The flow field F2 has a plurality of lands 204 and a plurality of channels 202. Each of the channels 202 is defined between two adjacent lands 204. Each of the channels 202 is configured to be in fluid communication with a first port A3 and a second port A4. Each of the first and second ports A3 and A4 allows a passage of the fuel to or from the channels 202. In one embodiment, the fuel enters from the first port A3 and an initial flow of the fuel is side wards and subsequently upwards relative to the flow field F2 and the anode flow field plate 200 as shown by the arrows. In another embodiment, the fuel enters from the second port A4 and an initial flow of the fuel is side wards and vertically down wards, subsequent to side ward flow, relative to the flow field F2 and the anode flow field plate 200 as shown by the arrows. Further, it has to be noted that with respect to the flow field F2, a length of a portion of a channel 202 configured to provide a vertical flow (upward or downward flow) is greater than a length of the portion of the channel 202 configured to provide a horizontal flow (sideward flow).
c shows an anode flow field plate 200 having a flow field F3 according to another embodiment. The flow field F3 has a plurality of lands 204 and a plurality of channels 202. Each of the channels 202 is defined between two adjacent lands 204. Each of the channels 202 is configured to be in fluid communication with a first port A5 and a second port A6. Each of the first and second ports A5 and A6 allows a passage of the fuel to or from the channels 202. In one embodiment, the fuel enters from the second port A6 and an initial flow of the fuel is side wards and subsequently upwards relative to the flow field F3 and the anode flow field plate 200 as shown by the arrows. In another embodiment, the fuel enters from the first port A5 and an initial flow of the fuel is side wards and vertically down wards, subsequent to side ward flow, relative to the flow field F3 and the anode flow field plate 200 as shown by the arrows. Further, it has to be noted that with respect to the flow field F3, a length of a portion of a channel 202 configured to provide a horizontal flow (sideward flow) is greater than a length of the portion of the channel 202 configured to provide a vertical flow (upward flow).
d shows an anode flow field plate 200 having a flow field F4 according to another embodiment. The flow field F4 has a plurality of lands 204 and a plurality of channels 202. Each of the channels 202 is defined between two adjacent lands 204. Each of the channels 202 is configured to be in fluid communication with a first port A7 and a second port A8. Each of the first and second ports A7 and A8 allows a passage of the fuel to or from the channels 202. In one embodiment, the fuel enters from the second port A8 and an initial flow of the fuel is vertically upward and subsequently sideward relative to the flow field F4 and the anode flow field plate 200 as shown by the arrows. In another embodiment, the fuel enters from the first port A7 and an initial flow of the fuel is vertically downwards and subsequently sideward relative to the flow field F4 and the anode flow field plate 200 as shown by the arrows. Further, it has to be noted that with respect to the flow field F4, a length of a portion of a channel 202 configured to provide a vertical flow (upward or downward flow) is greater than a length of the portion of the channel 202 configured to provide a horizontal flow (sideward flow).
e shows an anode flow field plate 200 having a flow field F with header ports 116a. The embodiment of
Now with respect to
a shows a cathode flow field plate 300 having a flow field F5 according to an embodiment. The flow field F5 has a plurality of lands 304 and a plurality of channels 302. Each of the channels 302 is defined between two adjacent lands 304. Each of the channels 302 is configured to be in fluid communication with a first port C1 and a second port C2. Each of the first and second ports C1 and C2 allows a passage of air to or from the channels 302. In one embodiment, the air enters from the first port C1 and an initial flow of the fuel is vertically upwards and subsequently sidewards relative to the flow field F5 and the cathode flow field plate 300 as shown by the arrows. In another embodiment, the air enters from the second port C2 and an initial flow of the fuel is vertically downwards and subsequently side wards, relative to the flow field F5 and the anode flow field plate 300 as shown by the arrows.
b shows a cathode flow field plate 300 having a flow field F6 according to another embodiment. The flow field F5 has a plurality of lands 304 and a plurality of channels 302. Each of the channels 302 is defined between two adjacent lands 304. Each of the channels 302 is configured to be in fluid communication with a first port C3 and a second port C4. Each of the first and second ports C1 and C2 allows a passage of air to or from the channels 302. In one embodiment, the air enters from the first port C3 and an initial flow of the fuel is side wards upwards and subsequently upwards relative to the flow field F6 and the cathode flow field plate 300 as shown by the arrows. In another embodiment, the air enters from the second port C4 and an initial flow of the fuel is side wards and subsequently down wards, relative to the flow field F6 and the anode flow field plate 300 as shown by the arrows.
c shows a cathode flow field plate 300 having a flow field F with header port 116b.
Now with respect to
a illustrates membrane electrode assembly MEA stack up according to an embodiment of the invention. An anode flow field plate 400a includes a plurality of lands 404a defining a plurality of channels 402a. The anode flow field plate 400a is configured to be in contact with a first gas diffusion layer (GDL) 405a provided near the anode. The first gas diffusion layer 403a is in contact with a first catalyst layer 405a. The first catalyst layer 405a for the anode is interfaced with the proton conductive polymer membrane 401. The proton conductive polymer membrane 401 is a Perfluro sulfonic acid (PFSA) membrane. Similarly, a cathode flow filed plate 400b, includes a plurality of lands 404b defining a plurality of channels 402b. The cathode flow field plate 400b is configured to be in contact with a second gas diffusion layer 403b provided near the cathode. The gas diffusion layer 403b is in contact with a second catalyst layer 405b. The second catalyst layer 405b is interfaced with the proton conductive polymer membrane 401.
In general, the assembly of gas diffusion layers (GDLs) 403a and 403b, the catalyst layers 405a and 405b, and the membrane 401 is referred to as membrane electrode assembly (MEA). The assembly of catalyst layers 405a and 405b and the membrane 401 is referred to as catalyst coated membrane (CCM).
It may be noted from the embodiment of
In a fuel cell stack, the entire setup is compressed to a set a compressed height for gas diffusion layers 403a and 403b (GDL). Under compression, each of the gas diffusion layers (GDLs) 403a and 403b are forced towards the CCM and the flow fields plates 400a and 400b. Enhancing the anode-to-cathode land contact ensures lower contact resistance. However, increasing the contact beyond a certain optimum level can sometimes result in higher mass transport losses and higher pressure drops in the channels 402a and 402b.
b illustrates lands 404a and 404b and channels 402a and 402b of the flow field plates 400a and 400b with respect to each other when arranged in a fuel cell stack. When viewed in conjunction with the flow patterns in
a and 5b illustrate aspects of inlet and outlet ports for anode flow fields, according to some embodiments of the invention.
Further,
In some embodiments, an anode flow field for high current DMFC operations can include one or more of the following features:
(1) Channel numbers ranging from 3 to 8, depending on current density, active area, and operating methanol concentration, wherein channels are substantially continuous with little or no splitting, branching or joining.
(2) Channel length ranging from about 1,000 mm to about 2,000 mm, depending on active area and operating methanol concentration.
(3) Channel depth and width are in the range of about 0.7 mm to about 1 mm and about 1 mm to about 2 mm, respectively.
(4) Channel geometry is varied based on operating current density.
(5) Channel-to-land width ratio varies from about 0.5 to about 3.
(6) Channels for one embodiment have reactants flowing in a generally horizontal direction and a generally upward direction.
(7) Channels for another embodiment have reactants flowing in alternating upward and downward directions.
(8) Plates are designed for current density operations from about 150 mA/cm2 to about 500 mA/cm2.
(9) Locations of a header port and slits at an inlet facilitate entry of anode fuel into channels.
(10) Anode entry slit area of about 0.1 cm2 to about 1 cm2 facilitates substantially uniform flow distribution.
(11) Area of slits or area under bridges is about 3 percent to about 8 percent of area of a header in a plate.
(12) Area of exit slits or area under bridges is oversized up to about 2 times relative to an entry slit to facilitate carbon dioxide removal.
(13) Exit header is oversized up to about 2 times to facilitate carbon dioxide removal.
(14) Exit header is positioned such that it acts as a primary carbon dioxide-liquid separation chamber.
In some embodiments, a cathode flow field for high current DMFC operations can include one or more of the following features:
(1) Plates are designed for current density operations from about 150 mA/cm2 to about 500 mA/cm2.
(2) Channel numbers ranging from 20 to 35, wherein channels are substantially continuous with little or no splitting, branching or joining.
(3) Channel length ranging from about 200 mm to about 1,000 mm, depending on active area, wherein channels are substantially continuous with little or no splitting, branching or joining.
(4) Channel width varies from about 0.8 mm to about 1.5 mm.
(5) Channel-to-land width ratio varies from about 0.5 to about 3.
(6) Channels for one embodiment have reactants flowing in a generally horizontal direction and a generally upward direction.
(7) Channels for another embodiment have reactants flowing in alternating upward and downward directions.
(8) High pressure drop from a header feeding channels facilitates substantially uniform reactant distribution between channels.
(9) Area of slits or area under bridges is about 20 percent to about 30 percent of area of a header in a plate.
(10) Exit header is positioned such that it acts as a primary water-vapor phase separation chamber.
In some embodiments, a DMFC stack can include one or more of the following features:
(1) A DMFC stack operating at low pressure drops of about 0.5 psi to about 2 psi on the cathode side for high current density operation.
(2) A width of graphite ribs bordering gaskets is sized appropriately to reduce or minimize breakage from gasket creep or swell due to contact with a methanol solution.
(3) Optimization of anode and cathode parallel overlap in the range of about 30 percent to about 40 percent of a total flow field area.
(4) An anode pitch in the range of about 0.4 cm to about 0.6 cm, and a cathode pitch in the range of about 0.2 cm to about 0.4 cm.
(5) Ramps at entries of flow fields to reduce turbulence in flows.
The foregoing description of the specific embodiments will so fully reveal the general nature of the embodiments herein that others can, by applying current knowledge, readily modify and/or adapt for various applications such specific embodiments without departing from the generic concept, and, therefore, such adaptations and modifications should and are intended to be comprehended within the meaning and range of equivalents of the disclosed embodiments. It is to be understood that the phraseology or terminology employed herein is for the purpose of description and not of limitation. Therefore, while the embodiments herein have been described in terms of preferred embodiments, those skilled in the art will recognize that the embodiments herein can be practiced with modification within the spirit and scope of the claims as described herein.
This application claims priority from U.S. Provisional Application No. 61/364,691 filed on Jul. 15, 2010, the complete disclosure of which is incorporated fully herein by reference.
Number | Date | Country | |
---|---|---|---|
61364691 | Jul 2010 | US |