The present invention relates to a method of measuring the flow rate of a gas-liquid fluid mixture.
The determination of gas and liquid flow rates in gas-liquid fluid mixtures is important in the oil and gas industry.
An example of an apparatus for measuring such flow rates is Schlumberger's Vx™ system (see e.g. I. Atkinson, M. Berard, B.-V. Hanssen, G. Ségéral, 17th International North Sea Flow Measurement Workshop, Oslo, Norway 25-28 Oct. 1999 “New Generation Multiphase Flowmeters from Schlumberger and Framo Engineering AS”) which comprises a vertically mounted Venturi flow meter, a dual energy gamma-ray hold up measuring device and associated processors. This system allows the simultaneous calculation of gas, water and oil volumetric flow rates in multi phase flows.
Although providing proven performance, the Vx™ system and other conventional multiphase flow meters are relatively expensive, which tends to preclude their application in “brown” field sites (i.e. oil and gas wells where capacity has fallen below about 1000 barrels/day (0.0018 m3/sec)) and other low hydrocarbon producers. However, such sites probably account for around 2-3 million oil and gas wells worldwide.
Thus there is a need for a relatively inexpensive flow meter that nonetheless has sufficient linearity and repeatability over a range of gas volume fractions (GVFs). For example, the GVF in flow from “brown” field sites can vary from about 15 to about 95%.
In general terms, the present invention provides a method and a corresponding apparatus for determining a flow rate of a fluid, such as a gas-liquid fluid mixture
In a first aspect, the present invention provides a method for determining a flow rate of a gas-liquid fluid mixture including the steps of:
providing a conduit through which the gas-liquid fluid mixture flows;
conditioning the fluid mixture in the conduit to separate the liquid in the mixture from the gas;
measuring the hold up of the separated liquid;
measuring the velocity of the separated liquid;
measuring the velocity of the separated gas; and
determining the flow rate of the gas-liquid fluid mixture from the hold up and the velocities.
Typically, and conveniently, the measurements can be made on the same conduit transverse cross-section. However, if the conditioned flow is sufficiently stable, the measurements can be spaced along the conduit
Unlike the Vx™ system, which requires gamma-ray-determined hold ups to calculate flow rates, the method for measuring a flow rate can use relatively inexpensive technology, such as ultrasound, to measure the hold up and the liquid velocity. A further advantage relative to the Vx™ system is that health and safety issues pertaining to the use of gamma-ray sources can be avoided.
Advantageously, the conduit does not need to be horizontal. Indeed, the approach is independent of conduit orientation. Further, the approach is highly scalable, and can be applied to flow through conduits of widely varying diameter.
Preferably, the liquid is separated from the gas by swirling the flow in the conduit to form a liquid annulus around a gas core. For example, the conduit may have a swirl element, such as a helical insert or vane assembly, for inducing the mixture to exhibit swirling flow. The swirl element may include one or more spiral-shaped members extending along the conduit in the direction of fluid flow. Preferably, the spiral shaped members are positioned at the wall of the conduit and, when viewed along the axis the conduit, leave a central core of the conduit unimpeded (i.e. they do not extend radially inwards as far as the central axis of the conduit). Alternatively, the swirl element may be formed by a tangential flow inlet to the conduit.
An advantage of swirling flow is that it is relatively easy to induce and sustain, and is symmetrical about the flow axis. However, alternatively, the flow can be conditioned to exhibit stratified flow to separate the liquid from the gas.
When swirling flow is adopted, preferably the hold up is measured by determining the thickness of the liquid annulus.
Preferably the position of an interface between the separated liquid and the separated gas is determined to measure the hold up. For example, as indicated above, the position of the interface can be determined ultrasonically. Additionally (or indeed alternatively), the velocity of the separated liquid can be measured ultrasonically.
Preferably, the dynamic pressure of the separated gas is determined to measure the velocity of the separated gas. For example, the dynamic pressure can be determined using a Pitot tube. This can be a low cost and robust approach that may be applied to a large operating range of flow velocities. However, alternatively, the velocity of the separated gas can be measured using e.g. a vortex shedder or an insertion turbine meter.
Preferably, the static pressure of the separated gas and/or the temperature of the separated gas are also measured. These measurements allow the flow rate to be converted to standard conditions. Advantageously, a Pitot tube device can measure the static pressure at the same time as dynamic pressure. Further, such a device can easily incorporate a thermometer.
To compensate for irregularities in the flow and to reduce the effect of noise in the measurements, the hold up and velocity measurements may be time-averaged.
The liquid of the mixture may comprise oil and/or water. The gas may comprise natural gas. Thus the gas-liquid fluid mixture may be a mixture of natural gas, condensate and optionally water.
A second aspect of the present invention provides an apparatus for providing measurements useable in determining a flow rate of a gas-liquid fluid mixture, the apparatus including:
a conduit through which the gas-liquid fluid mixture can flow, in use the fluid mixture in the conduit being conditioned to separate the liquid in the mixture from the gas;
a device for measuring the hold up of the separated liquid;
a device for measuring the velocity of the separated liquid; and
a device for measuring the velocity of the separated gas;
wherein the hold up and the velocities are usable to determine a flow rate of the gas-liquid fluid mixture.
The apparatus can be used in the performance of the method of the first aspect. Optional features of the first aspect may therefore be applied, singly or in combination, to the second aspect.
Thus the apparatus may further include a swirl element for conditioning the fluid by swirling the flow in the conduit to form a liquid annulus around a gas core. The hold up measuring device can then determine the thickness of the liquid annulus to measure the hold up. However, more generally, the hold up measuring device may determine the position of an interface between the separated liquid and the separated gas to measure the hold up.
The hold up measuring device may determine the position of the interface ultrasonically. Additionally (or alternatively) the liquid velocity measuring device may measure the velocity of the separated liquid ultrasonically. Preferably, the hold up measuring device and the liquid velocity measuring device are combined in one ultrasonic measuring device.
Preferably, the gas velocity measuring device determines the dynamic pressure of the separated gas to measure the velocity of the separated gas. For example, the gas velocity measuring device can include a Pitot tube device to determine the dynamic pressure. Preferably, the static pressure of the separated gas and/or the temperature of the separated gas are also measured by suitable devices. For example, the static pressure can be measured by the Pitot tube device, and the temperature by a thermometer provided alongside the Pitot tube device.
Advantageously, the apparatus can have no moving parts.
The devices may measure a time-averaged hold up and time-averaged velocities.
A third aspect of the present invention provides a flow meter for determining a flow rate of a gas-liquid fluid mixture, the flow meter including:
the apparatus of the second aspect; and
a processor arranged to determine the flow rate of the gas-liquid fluid mixture using the hold up and the velocities measured by the apparatus.
The processor may calculate a time-averaged hold up and time-averaged velocities from sequences of respective measurements.
A further aspect of the present invention provides an oil well pipeline or a gas well pipeline including an apparatus according to the second aspect or a meter according to the third aspect.
A further aspect of the present invention provides an apparatus according to the second aspect when conveying a gas-liquid fluid mixture, or a meter according to the third aspect when conveying a gas-liquid fluid mixture.
Embodiments of the invention will now be described by way of example with reference to the accompanying drawings, in which:
The apparatus comprises a conduit 11 of circular cross-section and diameter D. A gas-liquid fluid mixture flows through the conduit in the direction indicated by arrow 12. A swirl element (not shown), such as a helical insert in the conduit or a tangential flow inlet to the conduit, induces the mixture to exhibit swirling flow as indicated by arrow 13. An effect of this swirling flow is that liquid from the mixture is displaced to the wall of the conduit to form a liquid annulus around a gas core of radius a, as shown schematically in
Returning to
Opposite the Pitot tube device 14, a clamp-on ultrasonic measuring device 15 measures the position of the interface between the liquid annulus and the gas core. The device 15 also measures the velocity profile of the liquid across the thickness of the annulus. Possible configurations for device 15 are described in the Appendix. Although the ultrasonic measuring device 15 is shown in
The ultrasonic measuring device 15 provides the liquid velocity, v(t), as a function of liquid depth, t, and the liquid holdup by measuring the liquid layer thickness, h. The total liquid volumetric flow rate, qL, in the conduit is thus given by:
It remains then to determine the gas volumetric flow rate, qG.
Assuming a flat gas velocity profile, qG is given by:
where vG is the gas velocity.
vG is related the Pitot tube dynamic pressure measurement, ΔP, by the relation:
ΔP=kρGvG2 Eq.III
where ρG is the gas density, and k is a calibration factor which varies as a function of the Reynolds number, Re (=ρGvGa/μG, μG being the gas viscosity), of the gas in the core.
The relation between k and Re can be shown experimentally to take the form shown schematically with a solid line in
Then, using the value for k, vG determined from Eq.III provides qG from Eq.II, and the total flow rate qL+qG from Eq.I and Eq.II. The temperature and static pressure measurements by device 14 allow these flow rates to be converted to standard conditions, if needed.
Thus, by connecting the outputs of the Pitot tube device 14 and the ultrasonic measuring device 15 to a processor (not shown) which is suitably configured for performing the above analysis, flow meter readings for the liquid, gas and/or the total flow rate can be obtained.
Although the analysis uses the axial gas velocity, rather than the tangential gas velocity or a combination of the axial and tangential velocities, in Re, the analysis is still valid. This is because the ratio of the axial to the tangential gas velocity is fixed and determined by a constant ratio between cross-sectional areas of the swirl element (e.g. the ratio between the cross-sectional area of a tangential flow inlet and the cross-sectional area of the conduit, or the ratio between the proportion of the conduit cross-section affected by a helical insert and the proportion of the conduit cross-section which is unaffected).
Also the effect of the swirl on the dynamic pressure measurement does not significantly alter the analysis. In particular, the difference, due to swirl, between the gas pressure, P0, at a point on the centre line of the conduit and the gas pressure, Pa, at a point on the gas-liquid interface is:
Pa−P0=kρG(aΩG) Eq.IV
where ΩG is the angular velocity of the gas. For typical line pressures and dimensions, it can be shown that the value of kρG(aΩG)2 is not a significant factor.
The conduit does not need to be horizontal, and the approach is highly scalable, allowing it to be applied to flow through conduits of different diameter. In particular, the approach should be applicable to fluid mixtures flowing through standard full bore (i.e. 2 inch/5.1 cm internal diameter) piping.
The measurements can be averaged over time to account for irregularities in the flow, and to reduce the effect of noise on individual measurements.
Other techniques could be used to obtain the liquid annulus thickness, and the liquid and gas velocities, but most of these have drawbacks relative to the ultrasound-Pitot tube approach. For example, γ-rays could be used to determine the liquid annulus thickness, but γ-ray equipment is expensive and has health and safety implications. A vortex shedder or an insertion turbine meter could be used instead of a Pitot tube to measure the gas velocity, but such devices tend to be more intrusive than Pitot tubes. Also, if conversion to standard conditions is needed, it would still be necessary to incorporate temperature and static pressure measurements.
The above embodiment has been described in relation to a fluid mixture conditioned to exhibit swirling flow. Other conditioned flows can be envisaged, however. For example, the liquid and the gas could be conditioned to exhibit stratified flow. Ultrasound could again be used to determine the liquid holdup and liquid velocity, and a Pitot tube device could be used to determine the gas velocity. A possible difficulty, however, would be correctly positioning the Pitot tube in the gas portion of the flow. For example, if the GVF is very low, it may be difficult to position the Pitot tube in the gas. Conversely, if the GVF is very high, it may necessary to take pressure readings measurements across the thickness of the gas layer in order to properly characterise the gas velocity in that layer.
When the fluid mixture is conditioned to exhibit swirling flow, an option is to include a constriction region, such as a Venturi, in the conduit, and to take the measurements at this region. At the constriction region, conservation of angular momentum can increase the swirl velocity and lead to a better separation of liquid and gas. However, as the thickness of the liquid layer would be reduced in the constriction region, care may have to be taken that the resolution of the device or devices for measuring the hold up of the separated liquid and the velocity of the separated liquid is sufficient.
While the invention has been described in conjunction with the exemplary embodiments described above, many equivalent modifications and variations will be apparent to those skilled in the art when given this disclosure. Accordingly, the exemplary embodiments of the invention set forth above are considered to be illustrative and not limiting. Various changes to the described embodiments may be made without departing from the spirit and scope of the invention.
An example of clamp-on ultrasonic measuring device 5 is shown in
Preferably the aforementioned transducers are mounted on the exterior of the flow-carrying pipe, performing non-invasive measurements, although they may also be used in direct contact with the liquid phase in an invasive manner. The transducers work in a pulse-echo mode, in which an ultrasonic pulse with an appropriate frequency spectrum, is emitted into the flow and echoes from various interfaces, such as the liquid/pipe-wall interface and the gas/liquid interface, are recorded for further signal processing. The centre frequency of the pulse spectrum can typically range from 100 kHz to 100 MHz, but preferably from 500 kHz to 10 MHz. An appropriate signal processor records the signals from TR1 and TR2, and calculates the flow related parameters−speed of sound, interface position (and hence holdup), flow velocity, flow rate, acoustic impedance and component mixing ratio (such as WLR).
Assuming a typical pulse-echo measurement process for both TR1 and TR2, the principle for measuring the gas/liquid interface position and the speed of sound can be explained with the help of
Tα=T0α+T1+T2 Eq.1
where
is the round trip travel time of the pulse in the pipe wall plus that inside the transducer,
is the out-going pulse travel time from the pipe wall to the gas/liquid interface, and
is the return echo travel time from the interface to the pipe wall. Note that, in
In equation 1, T0α is a constant that can be determined by a calibration measurement. Note that, because of the round trip nature, the effects of V on T1 and T2 tend to compensate each other. The round trip travel time in liquid is:
Now, for typical oilfield liquid, the value of c2 is typically in the region of 1000 to 1500 m/s, β2, as a design parameter, is normally less than 30° and V normally should be less than 20 m/s. Therefore we have
(V·sin β2)2<<c2. Eq.6
Using V=20 m/s, c2=1000 m/s, and β2=30′, we have (V·sin β2)2/c22=˜0.01%. The square operation helps to make this ratio very small. It is therefore very reasonable to omit the term related to flow velocity V in equation 5, and equation 1 becomes
According to Snell's law of refraction:
one can rewrite equation 7 into
where γ=sin β1/c1 is a constant because the speed of sound and the refraction angle in the pipe wall material are known.
Since there are two unknown variables, h2 and c2, in equation 9, one needs another independent measurement and this is provided by transducer TR2.
TR2 performs a pulse-echo measurement similar to that of TR1. However its pulse incidence angle, β1, and hence the refraction angle, β2, have very different values to those of TR1. To simplify the analysis, one chooses β1=0° i.e. normal incidence. Thus the measured round trip pulse-echo travel time is
where
is the round trip travel time in the pipe wall, which is a known constant. Note that in equation 10, the flow velocity effect is absent. This is due to the fact that the pulse travel direction is perpendicular to that of the average flow velocity.
Dividing equation 10 by equation 9 yields
Therefore one can derive the average speed of sound in the liquid layer as
where (Tp−T0p)<(Tα−T0α).
With the knowledge of c2, one can use either equation 10 or equation 9 to obtain the liquid layer thickness h2. The knowledge of h2 will then allow the liquid holdup to be derived.
Obviously the speed of sound measurement is essential for deriving the liquid layer thickness from the transit time based measurements. The knowledge of c2 will also be required for correcting flow velocity measurement made with either the time-of-flight or the Doppler method, which is sensitive to the speed of sound. In addition to these primary applications, one may be able to use the value of c2 to derive other useful parameters under some circumstances. For instance, for a liquid phase consisting of a homogeneous mixture of two components, the speed of sound c2 can be correlated to the mixing ratio, α. The method for deriving α from c2 has been described e.g. in Gudmundsson J. S. and Celius H. K, “Gas-Liquid Metering Using Pressure Pulse Technology”, paper SPE56584, presented at the 1999 SPE Annual Technical Conference and Exhibition, Houston, 3-6 October. A useful application of this is the water-in-liquid ratio (WLR) measurement, provided that the liquid phase is gas-free and consists only of two components, i.e. oil and water. Note that the gas-free condition is important because the c2 contrast between oil and water is small (1300 m/s versus 1500 m/s) and the presence of a small percentage of un-separated gas bubbles will have an overwhelming effect on c2, making WLR determination difficult.
Since c2 is sensitive to the content of gas in liquid, it may be used to monitor the quality of the liquid/gas separation process.
The setup shown in
ZL=ρmx·c2x Eq.14
where ρmx and c2x are the density and the speed of the sound in the near wall region of the liquid phase. If the liquid mixture is homogeneous everywhere, then ρmx=ρm and c2x=c2. With c2 determined from equation 13, the mixture density ρm can be derived from the measured acoustic impedance ZL. The mixture density offers an additional way of deriving the component mixing ratio, such as water liquid ratio, αwlR, through equation 15, if the densities of the individual components, such as ρw and ρo, are known.
ρm=αwlR·w+(1−αwlR)·ρo Eq.15
The liquid holdup, derived via the measured thickness of the liquid layer, h2, can be combined with a velocity measurement to produce the flow rate of the liquid phase. The velocity measurement methods will be described in conjunction with some example embodiments.
In one embodiment, the first angled-incidence ultrasonic transceiver, TR1, is a narrow-band transducer that facilitates a pulsed, also known as range-gated, Doppler measurement. The second transducer, TR2, which preferably has a normal-incidence angle to the pipe-wall, can also be a narrow-band one that facilitates a range-gated Doppler measurement. The details of the narrow-band transducer design and the principle of such a Doppler system for flow velocity measurement have been described in GB patent application no. 2363455. Here it is sufficient to say that such a system produces two profiles as its output—a flow velocity versus echo-delay-time profile and a Doppler signal-energy versus echo-delay-time profile. An example sketch of these is shown in
The left side of
Similarly for the Doppler energy profile, the zero-valued section corresponds to the regions inside the transducer and inside the pipe wall. In the liquid layer, the flowing reflectors generate certain level of Doppler signal energy. The energy level of each range-gate depends on factors such as the impedance mismatch between the reflectors and the continuous liquid phase, the concentration and size distribution of the reflectors in the corresponding sample volume in the liquid, which determine the scattering cross-section. At the interface, this energy level increases dramatically because of very large reflective surface.
The length of the zero section on the velocity or the energy profile can be measured to identify the liquid/pipe-wall interface and to obtain the constant time T0a in equation 13. The position of the gas/liquid interface is identified from the maxima on the Doppler energy profile or that on the velocity profile. The travel time of the angled incidence pulse in liquid, Tα−T0α, is measured by the time difference between this maxima and the wall position on the profile.
To derive the flow rate, each value on the measured velocity profile is multiplied with its representative cross-sectional area to generate a local flow rate value. For a stratified flow, the liquid cross-section is divided into sub-areas by parallel horizontal lines (see FIG. 6, as described in GB patent application number 2363455). For an annular flow, the liquid cross-section is divided into as many concentric annular-shaped regions as the number of non-zero velocity points on the velocity profile, which are within Tα−T0α (see
where n is the number of non-zero velocity points within Tα−T0α on the Doppler profile, Ai and Vi are the area and the velocity of the ith region.
Similar to the operation of TR1, TR2 can also be a narrow band transducer and operated to perform range-gated Doppler measurement. The difference is that the incidence angle of TR2 is perpendicular to the pipe-wall. TR2 can use the same emitting frequency as that of TR1, or a different one to that of TR1. The Doppler velocity profile produced by TR2 may not be of much use because the average velocity along the radial direction of the pipe is zero. The Doppler energy profile, on the other hand, should still show non-zero values in the flow region because the reflectors tend to move instantaneously in all the directions. Although the average velocity in the pulse direction is zero, the instantaneous energy value is absolute and will not cancel out. At least, at the fluctuating gas/liquid interface, there will be significant Doppler signal energies generated. Therefore the method of identifying the interface through the energy maxima still applies to the normal incidence measurement. This allows the travel time Tp in equation 13 to be determined. The constant travel time in pipe-wall, T0p, can be determined in several ways. For example, as a preferred method, the echoes at the original emission frequency (non-Doppler echoes) can be examined and the echo time corresponding to the pipe-wall/liquid interface can be measured. In this way, TR2 performs a simple time-domain pulse-echo measurement in addition to range-gated Doppler measurement at the same time. This gives T0p directly (c1 is known). As another example, if the energy profile is non-zero across the entire liquid layer, then the pipe wall can be identified from the zero value section of the Doppler energy profile.
The basic measurement process can be summarized with the flow chart shown in
As a variation to the previously described embodiment, a wide band (high time-resolution pulse) transceiver TR3 may be used to perform a time-domain pulse-echo measurement with a normal incidence angle. TR3 can be used either as a replacement for the narrow band Doppler transceiver, TR2, or as an additional transducer alongside the Doppler transceiver TR2 to provide redundancy of measurements.
The basic principle of the pulse-echo based measurement can be explained with the help of
where ZL is the acoustic impedance of the liquid in contact with the inner pipe wall and Zp that of the pipe. In equation 17, Zp is known. If the reflection coefficient, r2, can be measured, then the impedance, ZL, can be determined, i.e.
The amplitude reflection coefficient, r2, can be determined by measuring the decay rate of the echo series produced by interface 2. For instance, it can be shown that [10] a simplified expression for r2 is given by:
where r1 is the amplitude reflection coefficient at interface 1, A and B are the echo amplitudes as shown in
ZL=ρm·cL′ Eq.20
where ρm is given by equation 15 and
is referred to as the Wood equation in Gudmundsson J. S. and Celius H. K, ibid. If one knows the density, ρw, speed of sound, cw, (and hence the impedance, Zw) for water and those for oil, then with the measured impedance, ZL, one can derive αwlR from a combination of equations 20, 15 and 21.
In addition to the impedance measurement, the pulse-echo method also measures the thickness of the liquid layer. This is done through the echoes produced from interface 3 (shown in red color in
As another variation, additional narrow-band transducers, e.g. TR4, TR5 etc. may be added to the basic embodiment to perform additional pulsed Doppler measurements. These transducers have different values for the incidence angle, β1, and for the emission frequency, fe, compared to those of TR1. The main idea is to make a robust velocity profile measurement. If the liquid layer is thin and the liquid phase contains only small sized reflectors, then a high frequency (short wave length) transducer, say at 10 MHz, will provide higher measurement resolution and sensitivity than can be provided by a low frequency one, say, at 1 MHz. However, the high frequency transducer needs to have a smaller incidence angle, β1, than that used by a low frequency transducer. This is because the flow velocity measurement limit is given by:
where fprf is the pulse repeat frequency of the Doppler measurement, which typically ranges from 100 HZ to 100 kHz.
An example variation of a basic embodiment including additional transducers is illustrated in
The transducers used in the embodiment can be based on conventional piezoelectric crystals, PVDF films, composite arrays, phase-delayed arrays and devices with beam focusing functionalities.
The system disclosed here can be combined with a time-of-flight measurement system based on pitch-catch (system with separate transmitters and receivers) technique to form a more robust integrated system that is applicable to a wider range of flow conditions. For instance, the pitch-catch system works when there are no moving reflectors in the liquid phase to produce detectable Doppler signal.
Number | Name | Date | Kind |
---|---|---|---|
3938738 | Nagel et al. | Feb 1976 | A |
4044943 | Brown et al. | Aug 1977 | A |
4232549 | Migrin et al. | Nov 1980 | A |
4282751 | Brown et al. | Aug 1981 | A |
4312234 | Rhodes et al. | Jan 1982 | A |
4467659 | Baumoel | Aug 1984 | A |
5007293 | Jung | Apr 1991 | A |
5203211 | Jung | Apr 1993 | A |
5251490 | Kronberg | Oct 1993 | A |
5287752 | Den Boer | Feb 1994 | A |
5396807 | Dowty et al. | Mar 1995 | A |
5400657 | Kolpak et al. | Mar 1995 | A |
5463906 | Spani et al. | Nov 1995 | A |
5501099 | Whorff | Mar 1996 | A |
5591922 | Segeral et al. | Jan 1997 | A |
5654502 | Dutton | Aug 1997 | A |
5693891 | Brown et al. | Dec 1997 | A |
5719329 | Jepson et al. | Feb 1998 | A |
5793216 | Constant | Aug 1998 | A |
5905208 | Ortiz et al. | May 1999 | A |
6058787 | Hughes | May 2000 | A |
6284023 | Torkildsen et al. | Sep 2001 | B1 |
6575043 | Huang et al. | Jun 2003 | B1 |
6622574 | Fincke | Sep 2003 | B2 |
6719048 | Ramos et al. | Apr 2004 | B1 |
6758100 | Huang | Jul 2004 | B2 |
6831470 | Xie et al. | Dec 2004 | B2 |
7327146 | Simon | Feb 2008 | B2 |
7454981 | Gysling | Nov 2008 | B2 |
20070157737 | Gysling et al. | Jul 2007 | A1 |
20080163700 | Huang | Jul 2008 | A1 |
20080223146 | Atkinson et al. | Sep 2008 | A1 |
20080319685 | Xie et al. | Dec 2008 | A1 |
20090114038 | Atkinson et al. | May 2009 | A1 |
Number | Date | Country |
---|---|---|
0076882 | Apr 1983 | EP |
2152213 | Jul 1985 | GB |
2177803 | Jan 1987 | GB |
2238615 | Jun 1991 | GB |
2279146 | Dec 1994 | GB |
2300265 | Oct 1996 | GB |
2343249 | May 2000 | GB |
2343249 | Jan 2001 | GB |
2363455 | Dec 2001 | GB |
2359435 | May 2002 | GB |
2363455 | Oct 2002 | GB |
2376074 | Dec 2002 | GB |
2406386 | Mar 2005 | GB |
2420299 | May 2006 | GB |
2447490 | Sep 2008 | GB |
2454256 | May 2009 | GB |
8902066 | Mar 1989 | WO |
9108444 | Jun 1991 | WO |
9533980 | Dec 1995 | WO |
9724585 | Jul 1997 | WO |
0003207 | Jan 2000 | WO |
0123845 | Apr 2001 | WO |
2004106861 | Dec 2004 | WO |
2005031311 | Apr 2005 | WO |
2005040732 | May 2005 | WO |
2007105961 | Sep 2007 | WO |
2007129897 | Nov 2007 | WO |
2008029025 | Mar 2008 | WO |
2008084182 | Jul 2008 | WO |
2008110805 | Sep 2008 | WO |
2009037434 | Mar 2009 | WO |
2009037435 | Mar 2009 | WO |
2009056841 | May 2009 | WO |
Number | Date | Country | |
---|---|---|---|
20090229375 A1 | Sep 2009 | US |