Flow Shifting Coolant During Freeze Start-Up To Promote Stack Durability And Fast Start-Up

Information

  • Patent Application
  • 20080026274
  • Publication Number
    20080026274
  • Date Filed
    July 27, 2006
    18 years ago
  • Date Published
    January 31, 2008
    16 years ago
Abstract
An auxiliary coolant system, for a fuel cell stack system, includes a reversible coolant pump, a control valve, and plumbing lines. The pump enables the reversal of the coolant flow direction in the fuel cell stack system. The auxiliary coolant system is in parallel with the primary coolant system, and communicates with the primary coolant system via valves. During start-up, when coolant flow is from right-to-left through the fuel cell stack system, one valve of the primary coolant system will be partly open and control the amount of cold coolant make-up from the primary coolant system to the fuel cell stack while the valve of the auxiliary coolant system will be controlling the temperature differential between the inlet and outlet of the stack.
Description

BRIEF DESCRIPTION OF THE DRAWINGS

The present invention will become more fully understood from the detailed description and the accompanying drawings, wherein:



FIG. 1 is a graphical view of stack temperature as a function of time for a fuel cell stack system with a conventional coolant system, in accordance with the prior art;



FIG. 2 is a schematic view of an auxiliary coolant system for a fuel cell stack system, in accordance with the general teachings of the present invention; and



FIG. 3 is a graphical view of stack temperature as a function of time for a fuel cell stack system with an auxiliary coolant system, in accordance with the general teachings of the present invention.





DETAILED DESCRIPTION OF THE INVENTION

The following description of the preferred embodiment(s) is merely exemplary in nature and is in no way intended to limit the invention, its application, or uses.


In order to avoid the large temperature distribution within a cell during freeze start-up and enable fast start-up of fuel cell system, a coolant flow shifting operation system and methodology is proposed in accordance with the general teachings of the present invention.


Referring to FIG. 2, there is shown a schematic view of an auxiliary coolant system 10 for a fuel cell stack system 12, in accordance with the general teachings of the present invention. A primary coolant system 14 is shown in fluid communication with both the auxiliary coolant system 10 and the fuel cell stack system 12. Various conduits, pipes and/or the like can be employed to provide fluid communication among the three systems, as is known in the art.


In this operating methodology, during start-up, subzero coolant is introduced to the fuel cell stack via a coolant outlet 16 and a coolant inlet 18 intermittently through an arrangement of a series of valves 20, 22, respectively, which can function as control valves.


In accordance with one aspect of the present invention, the auxiliary coolant system 10 is employed to provide, among other things, a coolant flow shifting capability during start-up. The auxiliary coolant system 10 primarily includes a reversible coolant pump 24, valve 20, and plumbing line 26 (e.g., by-pass line), respectively, for coolant flow shifting. A radiator 28 is shown as being in fluid communication with both the primary coolant system 14 and the auxiliary coolant system 10.


More specifically, the reversible coolant pump enables the flow direction of the coolant in the fuel cell stack system 12 to be reversed. It should be appreciated that the auxiliary coolant system 10 communicates with the primary coolant system 14 via valve 22.


By way of a non-limiting example, during start-up, when coolant flow is from right-to-left through the fuel cell stack system 12, i.e., in the direction of arrow F1, valve 20 will be used to control the temperature differential between the inlet and outlet of the stack and valve 22 will be partly open. The cold-coolant make-up from the primary coolant system 14 will be controlled by the relative opening of valve 20 and valve 22. Similarly, when flow is from left-to-right through the fuel cell stack system 12, i.e., in the direction of arrow F2, valve 20 will be used to control the temperature differential between the inlet and outlet of the stack and valve 22 will be closed. The coolant shifting cycle time should be determined by the heat-up requirement and the coolant volume of a stack plus the coolant volume of an auxiliary coolant loop at a given fuel cell system.


The shorter the coolant shifting cycle is, the faster the stack heats up and the less temperature distribution across the stack. To enable a faster coolant shifting cycle, it is preferable to minimize the coolant volume in the auxiliary coolant loop and the coolant volume in the stack headers and active area. The coolant volume in the auxiliary coolant loop can be minimized by closely coupling the auxiliary coolant loop with the stack. The stack header coolant volume can be reduced by filling the header area with low pressure drop and low thermal mass porous media, such as solid hollow spheres. It has been reported that coolant volume reduction in the stack active area can be achieved through stamped metal plate design.


Referring to FIG. 3, there is shown a graphical view of stack temperature as a function of time for a fuel cell stack system with an auxiliary coolant system, in accordance with the general teachings of the present invention.


In this view, the simulation results are shown for temperature profiles in a fuel cell stack system during start-up with coolant flow shifting, as previously described. As with the system shown in FIG. 1, the fuel cell stack system is represented by ten elements. As shown, the coolant flow shifting methodology of the present invention, e.g., with a six second cycle time, reduces the predicted cell maximum temperature difference from 50° C. (see FIG. 1) to 35° C., as shown in FIG. 3.


In the simulation, the coolant inlet temperature profile, as a function of time, was the same for both cases. As shown in FIG. 3, by introducing a 6 second coolant flow shift cycle, the maximum temperature spread within a cell is reduced from 50° C. (similar to levels seen in experiments) down to 35° C., assuming even current distribution. It should be noted that the temperature spread can further reduced by using an even shorter coolant flow shift cycle (e.g., less than 6 seconds). Modeling studies have been performed to demonstrate that a more even temperature distribution can be achieved within a fuel cell stack system through a coolant flow shifting methodology as described herein.


The present invention will provide numerous benefits for controlling temperature distribution through a fuel cell stack system, including but not limited to: (1) a reduction of the down-the-channel temperature distribution within a cell during freeze start-up, thus reducing the RH variation within the cell, prolonging MEA durability, and/or allowing for faster start-up; (2) a reduction of the temperature distribution within a cell during freeze start-up, thus reducing the impact of the temperature variation on the mechanical stress of the bipolar plate, DM and/or MEA; and (3) fast start-up of the entire fuel cell system.


The description of the invention is merely exemplary in nature and, thus, variations that do not depart from the gist of the invention are intended to be within the scope of the invention. Such variations are not to be regarded as a departure from the spirit and scope of the invention.

Claims
  • 1. A fuel cell system, comprising: a fuel cell stack system;a primary coolant system in fluid communication with the fuel cell stack system, wherein the primary coolant system is operable to introduce a cold coolant into the fuel cell stack system in a first direction during start-up; andan auxiliary coolant system in fluid communication with the primary coolant system, wherein the auxiliary coolant system is selectively operable to reverse the flow of coolant into the fuel cell stack system in a second direction during start-up.
  • 2. The invention according to claim 1, wherein the primary coolant system includes a valve member selectively operable to control the amount of cold coolant flow into the fuel cell stack system in a first direction during start-up.
  • 3. The invention according to claim 1, wherein the auxiliary coolant system includes a reversible coolant pump member.
  • 4. The invention according to claim 3, wherein the reversible coolant pump is operable to allow the flow of the coolant into the fuel cell stack system to be reversed in a second direction during start-up.
  • 5. The invention of claim 4 wherein the reversible coolant pump has variable speed and the reversible coolant pump can control the temperature differential between the inlet and the outlet of the stack.
  • 6. The invention according to claim 4, wherein a flow shifting cycle time of the fuel cell stack system is determined by the heat-up requirement and coolant volume of the fuel cell stack system plus the coolant volume in the auxiliary coolant loop.
  • 7. The invention according to claim 6, wherein a short flow shifting cycle is operable to allow the fuel cell stack system to warm up such that the temperature across the stack is substantially evenly distributed.
  • 8. The invention according to claim 7, wherein the short flow shifting cycle can be achieved through coolant volume reduction in an auxiliary coolant loop, coolant volume reduction in a fuel cell stack system header area, or coolant volume reduction in a fuel cell stack system active area.
  • 9. The invention according to claim 3, wherein the auxiliary coolant system includes a valve member selectively operable to control the temperature differential between an inlet and an outlet of the fuel cell stack system.
  • 10. The invention according to claim 9, the valve member is a control valve, whose valve position is feedback controlled by the temperature difference between the fuel cell stack system's inlet and outlet temperatures.
  • 11. The invention according to claim 3, further comprising a by-pass conduit selectively operable to permit coolant to bypass a radiator during start-up.
  • 12. A fuel cell system, comprising: a fuel cell stack system;a primary coolant system in fluid communication with the fuel cell stack system, wherein the primary coolant system is operable to introduce a cold coolant into the fuel cell stack system in a first direction during start-up, wherein the primary coolant system includes a valve member selectively operable to control the amount of cold coolant flow into the fuel cell stack system in a first direction during start-up; andan auxiliary coolant system in fluid communication with the primary coolant system, wherein the auxiliary coolant system is selectively operable to reverse the flow of coolant into the fuel cell stack system in a second direction during start-up.
  • 13. The invention according to claim 12, wherein the auxiliary coolant system includes a reversible coolant pump member.
  • 14. The invention according to claim 13, wherein the reversible coolant pump is operable to allow the flow of the coolant into the fuel cell stack system to be reversed in a second direction during start-up.
  • 15. The invention of claim 14 wherein the reversible coolant pump has variable speed and the reversible coolant pump can control the temperature differential between the inlet and the outlet of the stack.
  • 16. The invention according to claim 14, wherein a flow shifting cycle time of the fuel cell stack system is determined by the heat-up requirement and coolant volume of the fuel cell stack system plus the coolant volume in the auxiliary coolant loop.
  • 17. The invention according to claim 16, wherein a short flow shifting cycle is operable to allow the fuel cell stack system to warm up such that the temperature across the stack is substantially evenly distributed.
  • 18. The invention according to claim 17, wherein the short flow shifting cycle can be achieved through coolant volume reduction in an auxiliary coolant loop, coolant volume reduction in a fuel cell stack system header area, or coolant volume reduction in a fuel cell stack system active area.
  • 19. The invention according to claim 13, wherein the auxiliary coolant system includes a valve member selectively operable to control the temperature differential between an inlet and an outlet of the fuel cell stack system
  • 20. The invention according to claim 19, the valve member is a control valve, whose valve position is feedback controlled by the temperature difference between the fuel cell stack system's inlet and outlet temperatures.
  • 21. The invention according to claim 13, further comprising a by-pass conduit selectively operable to permit coolant to bypass a radiator during start-up.
  • 22. A fuel cell system, comprising: a fuel cell stack system;a primary coolant system in fluid communication with the fuel cell stack system, wherein the primary coolant system is operable to introduce a cold coolant into the fuel cell stack system in a first direction during start-up, wherein the primary coolant system includes a valve member selectively operable to control the amount of cold coolant flow into the fuel cell stack system in a first direction during start-up; andan auxiliary coolant system in fluid communication with the primary coolant system, wherein the auxiliary coolant system is selectively operable to reverse the flow of coolant into the fuel cell stack system in a second direction during start-up;wherein the auxiliary coolant system includes a reversible coolant pump member.
  • 23. The invention according to claim 20, wherein the reversible coolant pump is operable to allow the flow of the coolant into the fuel cell stack system to be reversed in a second direction during start-up. In the case that the reversible coolant pump is variable-speed, the speed of the reversible pump can also be used to control the temperature differential between the inlet and outlet of the stack
  • 24. The invention of claim 23 wherein the reversible coolant pump has variable speed and the reversible coolant pump can control the temperature differential between the inlet and the outlet of the stack.
  • 25. The invention according to claim 23, wherein a flow shifting cycle time of the fuel cell stack system is determined by the heat-up requirement and coolant volume of the fuel cell stack system plus the coolant volume in the auxiliary coolant loop.
  • 26. The invention according to claim 25, wherein a short flow shifting cycle is operable to allow the fuel cell stack system to warm up such that the temperature across the stack is substantially evenly distributed.
  • 27. The invention according to claim 26, wherein the short flow shifting cycle can be achieved through coolant volume reduction in an auxiliary coolant loop, coolant volume reduction in a fuel cell stack system header area, or coolant volume reduction in a fuel cell stack system active area.
  • 28. The invention according to claim 22, wherein the auxiliary coolant system includes a valve member selectively operable to control the temperature differential between an inlet and an outlet of the fuel cell stack system
  • 29. The invention according to claim 28, the valve member is a control valve, whose valve position is feedback controlled by the temperature difference between the fuel cell stack system's inlet and outlet temperatures.
  • 30. The invention according to claim 22, further comprising a by-pass conduit selectively operable to permit coolant to bypass a radiator during start-up.