The present technology relates to a fluid control apparatus and an electronic apparatus for transporting fluid by driving a diaphragm.
As a small and thin pump, a diaphragm type pump using a diaphragm is practically used. The diaphragm type pump is equipped with a pump chamber in which a volume is varied by bending deformation of the diaphragm, and can suck fluid into the pump chamber by increasing the volume and discharge the fluid from the pump chamber by decreasing the volume.
Generally, a suction port and a discharge port connected to the pump chamber are provided in a direction perpendicular to the diaphragm. For example, Patent Literature 1 discloses a piezoelectric pump in which a fluid suction port and a fluid discharge port are provided in a direction perpendicular to a vibrator.
However, in a case where the suction port and the discharge port are provided in the direction perpendicular to the diaphragm as described in Patent Literature 1, there is a problem that a cross-sectional shape of a flow path changes greatly among the pump chamber and the suction port and the discharge port, and flow path resistance increases.
In view of the above circumstances, an object of the present technology is to provide a fluid control apparatus having a diaphragm structure and small flow path resistance.
In order to achieve the above object, a fluid control apparatus according to the present technology includes a first space, two flat plate members, a drive mechanism, a second space, a first check valve, and a second check valve.
The first space has an inlet and an outlet.
The two flat plate members face each other via the first space, and at least one of the flat plate members is an elastic body having flexibility.
The drive mechanism bends the elastic body.
The second space adjoins the first space, communicates with the first space via the inlet, and has a suction port.
The first check valve allows fluid to flow from the suction port to the first space via the inlet.
The third space adjoins the first space, communicates with the first space via the outlet, and has a discharge port.
The second check valve allows the fluid to flow from the first space to the discharge port via the outlet.
At least one of the suction port and the discharge port is positioned on an extension surface of at least one of the two flat plate members.
To achieve the above object, an electronic apparatus according to the present technology includes a fluid control apparatus including a first space, two flat plate members, a drive mechanism, a second space, a first check valve, and a second check valve.
The first space has an inlet and an outlet.
The two flat plate members face each other via the first space, and at least one of the flat plate members is an elastic body having flexibility.
The drive mechanism bends the elastic body.
The second space adjoins the first space, communicates with the first space via the inlet, and has a suction port.
The first check valve allows fluid to flow from the suction port to the first space via the inlet.
The third space adjoins the first space, communicates with the first space via the outlet, and has a discharge port.
The second check valve allows the fluid to flow from the first space to the discharge port via the outlet.
At least one of the suction port and the discharge port is positioned on an extension surface of at least one of the two flat plate members.
A fluid control apparatus according to an embodiment of the present technology will be described.
[Schematic Configuration of Fluid Control Apparatus]
As shown in
The first housing member 101, the second housing member 102, and the third housing member 103 are bonded and form the first space 111, the second space 112, and the third space 113. The first housing member 101 is a plate-shaped member in which opening is formed to be the first space 111, the second space 112, and the third space 113. One surface of the first housing member 101 is defined as a first surface 101a, and a surface opposite to the first surface 101a is defined as a second surface 101b.
The second housing member 102 is a plate-shaped member that is bonded to the first surface 101a of the first housing member 101. The second housing member 102 includes a movable portion 102a and a fixed portion 102b. The movable portion 102a is positioned at a central portion of the second housing member 102, and is made of an elastic body. The shape of the movable portion 102a is not particularly limited, but can be a circular shape viewed from a direction (Z direction) perpendicular to the second housing member 102 and the third housing member 103. The fixed portion 102b is arranged around the movable portion 102a and is made of an inelastic body. The movable portion 102a is a diaphragm, is supported by the fixed portion 102b, and is configured to be bent by the drive mechanism 104.
The third housing member 103 is a plate-shaped member which is bonded to the second surface 101b of the first housing member 101. The third housing member 103 may be a plate-shaped member made of an inelastic body. A portion of the third housing member 103 facing the movable portion 102a is defined as a facing portion 103a. Note that the first housing member 101, the second housing member 102, and the third housing member 103 are together defined as a “housing” of the fluid control apparatus 100 in the following description.
As shown in
The second space 112 is a space adjoined to the first space 111, and communicates with the first space 111 via the inlet 111a. In addition, the second space 112 is provided with a suction port 112a. The suction port 112a is an opening provided in the second housing member 102, and the second space 112 communicates with an external space of the fluid control apparatus 100 via the suction port 112a. Incidentally, the suction port 112a may be connected with a pipe or the like for supplying the fluid to the suction port 112a.
The third space 113 is a space adjoined to the first space 111, and communicates with the first space 111 via the outlet 111b. In addition, the third space 113 has a discharge port 113a. The discharge port 113a is an opening provided in the second housing member 102, and the third space 113 communicates with the external space of the fluid control apparatus 100 via the discharge port 113a. The discharge port 113a may be connected to a pipe or the like into which the fluid discharged from the discharge port 113a flows.
The drive mechanism 104 bends the movable portion 102a. The drive mechanism 104 may be a piezoelectric element laminated on the movable portion 102a as shown in
The first check valve 105 allows the fluid to flow into the first space 111 from the suction port 112a via the inlet 111a. As shown in
In addition, the first check valve 105 may be provided in the inlet 111a to allow the fluid flowing from the second space 112 to the first space 111 to pass therethrough and prevent the fluid flowing from the first space 111 to the second space 112 from passing therethrough. The first check valve 105 may be, for example, a swing type check valve.
The second check valve 106 allows the fluid to flow from the first space 111 to the discharge port 113a via the outlet 111b. As shown in
In addition, the second check valve 106 may be provided at the outlet 111b to allow the fluid flowing from the first space 111 to the third space 113 to pass therethrough and prevent the fluid flowing from the third space 113 to the first space 111 from passing therethrough. The second check valve 106 may be, for example, a swing type check valve.
The fluid control apparatus 100 has the schematic configuration described above. Since the fluid control apparatus 100 has a configuration that the plate-shaped members (first housing member 101, second housing member 102, and third housing member 103) are laminated, thinning of the fluid control apparatus 100 is realized. The first housing member 101, the second housing member 102, and the third housing member 103 may be bonded by adhering, fastening, or other bonding methods. Although the third housing member 103 is the inelastic body in the above description, the third housing member 103 may also include the movable portion made of the elastic body similar to the second housing member 102, and the movable portion may be bent by the drive mechanism.
The shape of the housing (first housing member 101, second housing member 102, and third housing member 103) of the fluid control apparatus 100 is not particularly limited, but may be a quadrangular shape viewed from the direction (Z direction) perpendicular to the second housing member 102 and the third housing member 103 as shown in
[Operation of Fluid Control Apparatus]
An operation of the fluid control apparatus 100 will be described.
As shown in
As shown in
By repeating the bending of the movable portion 102a in this manner, the fluid is continuously sucked from the suction port 112a and discharged from the discharge port 113a. Thus, in the fluid control apparatus 100, a flow path is formed to be connected from the second space 112 to the first space 111 via the inlet 111a and from the first space 111 to the third space 113 via the outlet 111b, and the fluid is transported through the flow path.
[Position of Inlet and Outlet]
The suction port 112a and the discharge port 113a are positioned on an extension surface of the second housing member 102. As shown in
The suction port 112a and the discharge port 113a are provided on the surface 102c. As a result, flow path resistance of the fluid transported by the fluid control apparatus 100 can be reduced.
A first space 511 having a variable volume is provided between the first flat plate member 501 and the second flat plate member 502, and a second space 512 and a third space 513 are provided adjoined to the first space 511. An suction port 512a in which a first check valve 505 is arranged is provided in the second space 512, and a discharge port 513a in which a second check valve 506 is arranged is provided in the third space 513.
In the fluid control apparatus 500, the suction port 512a and the discharge port 513a are not arranged on extension surfaces of the first flat plate member 501 and the second flat plate member 502. In this case, as shown by arrows in
In contrast, in the fluid control apparatus 100 as shown in
[Flow Path Shape]
As described above, in the fluid control apparatus 100, the flow path is formed to be connected from the second space 112 to the first space 111 via the inlet 111a and from the first space 111 to the third space 113 via the outlet 111b. The flow path suitably has a shape in which cross-sectional areas of the flow path continuously change from the suction port 112a to the discharge port 113a.
The shape in which the cross-sectional areas of the flow path continuously change is, for example, is such that, when a cross-sectional area of a pipeline changes from Sa to Sb, a distance from a position on the pipeline having the cross-sectional area Sa to a position on the pipeline having the cross-sectional area Sb is 0 or more, and the pipelines connecting form Sa to Sb are connected by a smooth line, but it is not limited thereto. Furthermore, the cross-sectional area of the flow path is a cross-sectional area having a shortest flow line at a normal connecting from the inlet to the outlet of flow lines in the pipeline.
The second space 112 has a shape in which the cross-sectional area of the flow path gradually widens from the suction port 112a, and is connected to a side surface of the first space 111 via the inlet 111a. The third space 113 is connected to the side surface of the first space 111 via the outlet 111b, and has a shape in which the cross-sectional area of the flow path gradually decreases toward the discharge port 113a.
As shown by arrows in
As shown in (Equation 1), when a cross-sectional area ratio (S1/S2) of the piston 801 and the outlet 805 is large, large inertial resistance proportional to v2 is generated. Therefore, since the cross-sectional area of the flow path in the fluid control apparatus 600 and the fluid control apparatus 700 changes rapidly, the flow path resistance is increased.
In contrast, since the cross-sectional areas of the flow path continuously change in the fluid control apparatus 100 according to the present embodiment, it is possible to reduce the flow path resistance.
[Arrangement of Suction Port and Discharge Port]
An arrangement of the suction port 112a and the discharge port 113a will be described. Each of
As shown in
Note that, as shown in
Furthermore, as shown in
Although the positions of the suction port(s) 112a and the discharge port(s) 113a are not particularly limited, as shown in
By arranging the suction port(s) 112a and the discharge port(s) 113a at the corners of the housing, a space inside the housing can be used without waste. In addition, efficiency is possible even if the fluid control apparatuses 100 are tiled.
As shown in
In the fluid control apparatus 100, as shown in
Incidentally, in a case not only of each housing of each fluid control apparatus 100 in the quadrangular shape, but also of each housing in the hexagonal shape or the octagonal shape by arranging the suction ports 112a and the discharge ports 113a at the corners of the housings, the spaces among the first spaces 111 can be effectively utilized.
[Shapes of Second and Third Spaces]
As described above, the second space 112 is a space connecting the inlet port 112a and the inlet 111a, and forms the fluid flow path. The third space 113 is a space connecting the outlet 111b and the discharge port 113a, and forms the fluid flow path. Here, each of the second space 112 and the third space 113 may be a space in which the flow path using a curved surface is formed.
Such shapes of the second space 112 and the third space 113 enable a smooth connection between the suction port 112a and the first space 111, and between the first space 111 and the discharge port 113a, thereby reducing the flow path resistance.
[First Check Valve and Second Check Valve]
The first check valve 105 and the second check valve 106 are preferably swing type check valves.
Here, as shown in
[Areas of Inlet and Outlet]
The areas of the inlet 111a and the outlet 111b may be the same, but may be different as described below.
As shown in
The flow path resistance of the fluid is caused by a change of the cross-sectional area perpendicular to a direction of a flow velocity (cross-sectional area of flow path). Due to a difference between the cross-sectional area of the flow path on an upstream side and the cross-sectional area of the flow path on a downstream side with respect to the flow velocity, the general flow path resistance is as follows: In the following description, the fluid flowing through the fluid control apparatus 100 is assumed as air.
ξ is a coefficient that changes depending on an area ratio A1/A2, and is approximately 1.
CC and ξC are as shown in [Table 1] below, depending on A2/A1.
Therefore, in the flow path from the inlet 111a to the outlet 111b, a resistance coefficient of the outlet 111b becomes smaller than that of the inlet 111a when the area SB is made larger than the area SA, that is, SA<SB. Accordingly, the flow path resistance is reduced, and it is possible to create a smooth flow of fluid.
For example, the resistance coefficient ζd of the inlet 111a and the resistance coefficient ζc of the outlet 111b are calculated. When the area SA is 0.1 mm2, the representative cross-sectional area Sr is 0.9 mm2, and the area SB is 0.3 mm2, the resistance coefficient is 0.889, and the resistance coefficient ζc is 0.34. In the case of SA<SB, the resistance coefficient of the outlet 111b becomes smaller than the resistance coefficient ζd of the inlet 111a.
From the above, it is preferable that the inlet 111a and the outlet 111b have the relationship SA<SB and SA/SB<0.3. In the above description, the case where the fluid flowing through the fluid control apparatus 100 is air has been described, but even when the fluid is other than air, the inlet 111a and the outlet 111b become SA<SB, whereby the resistance coefficient of the outlet 111b can be made smaller than that of the inlet 111a, that is, the flow path resistance can be made smaller.
The sizes of the first space 111, the second space 112, and the third space 113 are not particularly limited, but, for example, the diameter DA may be 1 mm, the diameter DB may be 2 mm, and the diameter Dr may be 9 mm.
[Other Configurations of Second Space and Third Space]
The second space 112 and the third space 113 may have the cross-sectional areas of the flow path that continuously change.
As shown in
Furthermore, as shown in
As shown in
The fluid control apparatus 100 having a total area (2SA) of the inlet 111a smaller than a total area (3SB) of the outlet 111b is preferable because the flow path resistance is small. The number of the second spaces 112 and the number of the third spaces 113 are not limited to those described above, and may be one or more. Each of the second space 112 and the third space 113 may have the cross-sectional areas of the flow path that continuously change as shown in
Furthermore, as shown in
The number of the second spaces 112 and the third spaces 113 is not limited, and may be one or more. The second space 112 and the third space 113 may have the cross-sectional areas of the flow path that continuously change as shown in
[Other Configuration of First Space]
The first space 111 may have the following configuration.
As shown in
From the state equation of the gas (PV=nRT), when the volume of the first space 111 is V and a volume change amount when the movable portion 102a bends is ΔV, the pressure P′ is expressed by the following (Equation 4).
Therefore, when ΔV is constant and the volume V is reduced, it is possible to increase the degree of influence of ΔV, and to increase the delivery pressure of the fluid control apparatus 100. In the space between the movable portion 102a and the facing portion 103a, the space outside the wall 111c, that is, the space other than the first space 111, is not used for transporting the fluid, and therefore, a filler or the like may be filled and sealed.
By forming the first space 111 in this shape, it is possible to reduce the flow path resistance of the fluid flowing in the first space 111. The shape of the first space 111 is not limited to the trapezoidal shape, and it is also possible to adopt another shape in which the cross-sectional areas of the flow path continuously increase from the inlet 111a to the outlet 111b.
[Configuration of second housing member] The second housing member 102 may have the following configuration.
As shown in
The spring portion 102d is formed so as to have lower rigidity than the fixed portion 102b, and promotes bending of the movable portion 102a by causing elastic deformation. The rigidity of the spring portion 102d is different from the rigidity of the movable portion 102a, and may be larger or smaller than the rigidity of the movable portion 102a. The spring portion 102d may be made of the same material as the movable portion 102a and the fixed portion 102b, or may be made of different materials. The spring portion 102d is formed in the entire region between the movable portion 102a and the fixed portion 102b, and there is no gap between the movable portion 102a and the fixed portion 102b, or the gap may be minimal.
As shown in
Especially considering the operation above an audible range, it is structurally necessary to use a secondary resonance mode where the end of the movable portion 701 is forced oppositely, the region G2 which does not contribute to extrusion of the fluid is formed. In addition, a resonant mode of a lower order mode may occur simultaneously.
In contrast, the second housing member 102 included in the fluid control apparatus 100 operates as follows.
In the second housing member 102, a gap is not provided between the fixed portion 102b and the movable portion 102a, or the gap is minimized such that passing the fluid through the gap is restricted and a loss is prevented. In addition, since no gap is provided or the gap is minimum, the rigidity of the spring portion 102d can be made larger than the rigidity of the spring portion 707, and a primary resonance mode can be shifted beyond the audible range. In addition, since the movable portion 102a is in a resonance mode in which an opposite force does not occur, efficient driving becomes possible.
[Other Configuration of Second Housing Member]
The second housing member 102 may further have the following configuration.
The spring portion 102d may have a concavo-convex structure. As shown in
Furthermore, as shown in
Here, a total area of the gaps 102f is formed to be equal to or less than a total area of the springs 102g viewed from the direction perpendicular to the second housing member 102 (Z direction). By making the total area of the gaps 102f equal to or less than the total area of the springs 102g, it is possible to reduce the amount of fluid passing through the gaps 102f. Note that the number of the spring portions 102d and the number of the gaps 102f are not limited to those shown in
The fluid control apparatus 100 including the second housing member 102 having each configuration was measured for a displacement amount. The measurement results are shown in the following Table 2.
In Table 2, “Comparative Example” has the diaphragm structure provided in the fluid control apparatus 700 (see
“Structure 2” has a structure of the second housing member 102 including the spring portion 102d (see
“Maximum displacement” is the displacement amount of the movable portion from the fixed portion (
As shown in [Table 2], the opposite force displacement occurs in “Comparative Example”, whereas the occurrence of the opposite force displacement is prevented in “Structure 1”, “Structure 2”, and “Structure 3”.
[Other Configuration of Third Housing Member]
The third housing member 103 may have the movable portion similar to the second housing member 102.
The movable portion 103c is positioned at the central portion of the third housing member 103 and is made of the elastic body. The fixed portion 103d is arranged around the movable portion 103c and is made of the inelastic body. The spring portion 103e is provided between the movable portion 103c and the fixed portion 103d. The spring portion 103e is different in rigidity from the movable portion 103c, and the end surface T positioned on the outer periphery of the spring portion 103e is fixed to the fixed portion 103d. The movable portion 103c and the spring portion 103e constitute the elastic body.
A drive mechanism 107, which is a piezoelectric element or the like, is provided on the movable portion 103c, and the movable portion 103c is configured to be bent by the drive mechanism 107 and functions as the diaphragm. The spring portion 103e may have various configurations as described above, similar to the spring portion 102d.
[Other Configuration of Drive Mechanism]
The drive mechanism 104 may have the following configuration.
As shown in
Furthermore, as shown in
[Vibration Support Member]
The fluid control apparatus 100 may include a vibration support member.
[Modification]
The housing of the fluid control apparatus 100 in the above embodiments is constituted by laminating the first housing member 101, the second housing member 102, and the third housing member 103, but may be constituted of a single housing member.
The movable portion 110 is bent by the drive mechanism 104 such as the piezoelectric element. The first space 111 is provided between an opposing portion 109a, which is a portion of the housing member 109 facing the movable portion 110, and the movable portion 110, and the second space 112 and the third space 113 are provided adjoined to the first space 111. Also in this configuration, the flow path resistance can be reduced by providing the suction port 112a and the discharge port 113a on the extension surface of the opposing portion 109a which is a flat plate member. Furthermore, between the movable portion 110 and the housing member 109, a spring portion having rigidity different from the movable portion 110 may be provided.
[Electronic Apparatus]
Applications of the fluid control apparatus 100 are not particularly limited, and can be mounted on the electronic apparatus, for example. The fluid control apparatus 100 can discharge air in the electronic apparatus to the outside or suck air from the outside of the electronic apparatus. Furthermore, the fluid control apparatus 100 can be utilized as a cooling device for suppressing heat generation by blowing the fluid to the heating element in the electronic apparatus. Since the fluid control apparatus 100 can be small-sized, it can be easily built into the electronic apparatus.
The present technology may also have the following structures.
(1)
A fluid control apparatus, including:
a first space having an inlet and an outlet;
two flat plate members facing each other via the first space, at least one of the flat plate members being an elastic body having flexibility;
a drive mechanism that bends the elastic body;
a second space that adjoins the first space, communicates with the first space via the inlet, and has a suction port;
a first check valve that allows fluid to flow from the suction port to the first space via the inlet;
a third space that adjoins the first space, communicates with the first space via the outlet, and has a discharge port; and
a second check valve that allows the fluid to flow from the first space to the discharge port via the outlet, in which
at least one of the suction port and the discharge port is positioned on an extension surface of at least one of the two flat plate members.
(2)
The fluid control apparatus according to (1), in which
a volume of the first area is varied by bending the elastic body.
(3)
The fluid control apparatus according to (1) or (2), in which
a flow path connected from the second space to the first space via the inlet and from the first space to the third space via the outlet has cross-sectional areas that continuously change in the first space, the second space, and the third space.
(4)
The fluid control apparatus according to any one of (1) to (3), in which
the drive mechanism is a piezoelectric element, and the piezoelectric element is laminated on the elastic body.
(5)
The fluid control apparatus according to any one of (1) to (4), having a laminated structure in which a plurality of plate-shaped members are bonded.
(6)
The fluid control apparatus according to any one of (1) to (5), in which
a housing of the fluid control apparatus has a polygon shape viewed from a direction perpendicular to the two flat plate members,
the first space has a circular shape viewed from the direction perpendicular to the two flat plate members, and
at least one of the suction port and the discharge port is arranged at a corner of the housing.
(7)
The fluid control apparatus according to (6), in which
the second space forms a flow path using a curved surface extending from the suction port to the inlet from in a direction perpendicular to the extension surface of the two flat plate members to in a direction parallel to the extension surface, and
the third space forms a flow path using a curved surface extending from the outlet to the discharge port from in the direction parallel to the extension surface to in the direction perpendicular to the extension surface.
(8)
The fluid control apparatus according to (7), in which
the second check valve has a swing type structure and is in close contact to the curved surface of the third space when the valve is opened.
(9)
The fluid control apparatus according to any one of (1) to (8), in which
when an area of the inlet is denoted as SA and an area of the outlet is denoted as SB, SA<SB.
(10)
The fluid control apparatus according to (9), in which
the fluid is air, and SA/SB<0.3.
(11)
The fluid control apparatus according to any one of (1) to (10), in which
a part of the second space and a part of the third space are provided between the two flat plate members.
(12)
The fluid control apparatus according to any one of (1) to (11), in which
the second space has cross-sectional areas of the flow path continuously changing from the suction port to the inlet, and
the third space has cross-sectional areas of the flow path continuously changing from the outlet to the discharge port.
(13)
The fluid control apparatus according to any one of (1) to (12), including a plurality of the second spaces, a plurality of the third spaces, a plurality of the inlets, and a plurality of the outlets, in which
a total area of the plurality of the inlets is smaller than a total area of the plurality of the outlets.
(14)
The fluid control apparatus according to (13), in which
the largest area of the inlet among the plurality of the inlets is smaller than the smallest area of the outlet among the plurality of the outlets.
(15)
The fluid control apparatus according to any one of (9) to (14), in which
the first space is formed such that the cross-sectional areas of the flow path continuously increase from the inlet to the outlet.
(16)
The fluid control apparatus according to any one of (1) to (15), in which
the elastic body has a movable portion and a spring portion that has rigidity different from the movable portion and connects the movable portion to an outer periphery.
(17)
The fluid control apparatus according to (16), in which
the movable portion and the spring portion are made of materials being different each other in rigidity.
(18)
The fluid control apparatus according to (16), in which
the spring portion has a concavo-convex structure.
(19)
The fluid control apparatus according to any one of (16) to (18), in which
the movable portion is formed integrally with the drive mechanism.
(20)
The fluid control apparatus according to any one of (16) to (18), in which
the movable portion is bent by the drive mechanism connected to the movable portion.
(21)
The fluid control apparatus according to any one of (16) to (20), in which
the spring portion has at least one gap and at least one spring, and a total area of the gap is equal to or less than a total area of the spring viewed from the direction perpendicular to the two flat plate members.
(22)
An electronic apparatus, including:
a fluid control apparatus, including
at least one of the suction port and the discharge port is positioned on an extension surface of at least one of the two flat plate members.
Number | Date | Country | Kind |
---|---|---|---|
2019-103467 | Jun 2019 | JP | national |
Filing Document | Filing Date | Country | Kind |
---|---|---|---|
PCT/JP2020/019821 | 5/19/2020 | WO |
Publishing Document | Publishing Date | Country | Kind |
---|---|---|---|
WO2020/246232 | 12/10/2020 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
5718567 | Rapp | Feb 1998 | A |
6629820 | Kornelsen | Oct 2003 | B2 |
8066494 | Kamitani | Nov 2011 | B2 |
9157428 | Kim | Oct 2015 | B2 |
20020197167 | Kornelsen | Dec 2002 | A1 |
20050074340 | Xu | Apr 2005 | A1 |
20090214362 | Kanai | Aug 2009 | A1 |
20090232684 | Hirata | Sep 2009 | A1 |
20130058818 | Hirata | Mar 2013 | A1 |
20140178223 | Kim | Jun 2014 | A1 |
20140294629 | Kim | Oct 2014 | A1 |
20220372965 | Kawaguchi | Nov 2022 | A1 |
Number | Date | Country |
---|---|---|
105822527 | Aug 2016 | CN |
2248891 | Apr 1992 | GB |
S59221485 | Dec 1984 | JP |
S62-070677 | Apr 1987 | JP |
H051669 | Jan 1993 | JP |
10502861 | Mar 1998 | JP |
H10-184549 | Jul 1998 | JP |
H11-311184 | Nov 1999 | JP |
2000265963 | Sep 2000 | JP |
2002227770 | Aug 2002 | JP |
2006295147 | Oct 2006 | JP |
2007507663 | Mar 2007 | JP |
2007162525 | Jun 2007 | JP |
2008163902 | Jul 2008 | JP |
2009293626 | Dec 2009 | JP |
2012528980 | Nov 2012 | JP |
2019065708 | Apr 2019 | JP |
WO-2005012729 | Feb 2005 | WO |
WO-2018033347 | Feb 2018 | WO |
Number | Date | Country | |
---|---|---|---|
20220260067 A1 | Aug 2022 | US |