The present disclosure is generally directed to a distribution and mixing grid, and in particular to an oxygen distribution and mixing grid for use in an oxy-combustion system for providing a uniform mixing of oxygen in a flue gas duct.
Steam generators, particularly those of the coal fired type, can generate harmful emissions. Recent efforts have focused on oxygen firing (e.g., oxy-combustion) which injects oxygen into a duct that transports flue gas into a fuel supply system (e.g., coal pulverizer system) and/or the steam generator. The oxygen can be supplied from an air separation unit. Due to the elimination of the inherent nitrogen that occurs with air firing, oxygen firing results in an essentially pure carbon dioxide product gas which can be more efficiently sequestered. Most oxygen fired steam generators utilize significant flue gas recirculation in order to maintain the required mass flow through the steam generator to support the heat transfer processes. Gas recirculation at high rates adds considerable cost, complexity, and increases the need for auxiliary power.
Typically oxygen from the air separation unit is mixed with the recycled flue gas streams forming an oxidant stream before entering the steam generator. There may be some limits placed on the concentration of oxygen in the oxidant stream. For example, the primary oxidant stream which transports pulverized fuel to the steam generator may be limited to about the 21% oxygen content of air to avoid problems with premature combustion of the fuel. Also oxygen contents much above 21% may require that ducts and other components be made of more expensive, higher grade materials suitable for the higher oxygen content. The duct and component limit is 23.5% for temperatures of 200-900° F., which the oxidant typically is subject to. Therefore, very good mixing of oxygen in the recycled flue gas stream is important.
According to aspects illustrated herein there is provided a distribution and mixing grid for mixing fluids, for example, mixing oxygen in a stream of flue gas, in a duct includes a plurality of lances arranged in a first plane and configured to be positioned transverse (e.g., perpendicular) to a flow direction of a first fluid, for example, flue gas, outside of the lances and within a predetermined flow area. Each of the plurality of lances has at least one inlet and a plurality of outlet nozzles. One or more of the outlet nozzles is directed generally in the flow direction of the first fluid outside of the lances, and is configured to discharge a second fluid (e.g., oxygen) therefrom.
According to further aspects illustrated herein, there is disclosed an oxy-combustion system including a furnace defining an interior combustion area, an oxygen supply system and a fuel supply system. The fuel supply system includes a primary flue gas inlet and a fuel outlet. The oxy-combustion system includes one or more flue gas processing systems (e.g., an air preheater, a particulate removal system, a sulfur removal system, a flue gas cooler and or a carbon dioxide removal system) positioned downstream of and in communication with the furnace. The oxy-combustion system includes a primary gas system defining a primary flue gas outlet. The primary gas system is in communication with one or more of the flue gas processing systems and/or the primary flue gas outlet is in fluid communication with the fuel inlet. The oxy-combustion system includes a secondary gas system in communication with one or more of the flue gas processing systems and the furnace. One or more of the oxygen discharge lines are in communication with the primary gas system and/or the secondary gas system. The oxy-combustion system includes a grid positioned in a duct of the primary gas system and/or the secondary gas system. The grid includes a plurality of lances arranged in a first plane and positioned transverse (e.g., perpendicular) to a flow direction of a flue gas outside of the lances and within a predetermined flow area. Each of the plurality of lances has at least one oxygen inlet and a plurality of outlet nozzles. The oxygen inlet is in communication with the oxygen supply system. One or more of the outlet nozzles is directed generally in the direction of the flue gas flowing outside of the lances, and are configured to discharge oxygen therefrom.
The above described and other features are exemplified by the following figures and in the detailed description
Referring now to the figures, which are exemplary embodiments, and wherein the like elements are numbered alike:
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The primary gas system 200 is configured to selectively receive flue gas from the oxy-combustion system 100 via a plurality of points, for example, 1) from a first point 201 located in the outlet duct 118 between the oxy-combustion furnace 110 and the air pre-heater 120, to the primary transport duct 222, via a tie line 210, the secondary transport duct 333 and another tie line 299; 2) from a second point 202 located in the gas duct 128 between the air pre-heater 120 and the particulate removal system 130 to the primary transport duct 222, via a tie line 220, the secondary transport duct 333 and the tie line 299; 3) a third point 203 located in the gas duct 138 between the particulate removal system 130 and the sulfur removal system 140 to the primary transport duct 222, via a tie line 230, the secondary transport duct 333 and the tie line 299; 4) a fourth point 204 located in the gas duct 148 between the sulfur removal system 140 and the flue gas cooler 150 to the primary transport duct 222, via a tie line 240, the secondary transport duct 333 and the tie line 299; and/or 5) a fifth point 205 located in the gas duct 158 between the flue gas cooler 150 and the gas processing system 160 to the primary transport duct 222, via a tie line 150.
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The secondary gas system 300 is configured to selectively receive flue gas from the oxy-combustion system 100 via a plurality of points, for example, 1) from a first point 201 located in the outlet duct 118 between the oxy-combustion furnace 110 and the air pre-heater 120 to the secondary transport duct 333, via the tie line 210; 2) from a second point 202 located in the gas duct 128 between the air pre-heater 120 and the particulate removal system 130 to the secondary transport duct 333, via the tie line 220; 3) a third point 203 located in the gas duct 138 between the particulate removal system 130 and the sulfur removal system 140 to the secondary transport duct 333, via the tie line 230; 4) a fourth point 204 located in the gas duct 148 between the sulfur removal system 140 and the flue gas cooler 150 to the secondary transport duct 333, via the tie line 240; and/or 5) a fifth point 205 located in the gas duct 158 between the flue gas cooler 150 and the gas processing system 160 via tie line 250.
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Each of the upper lances 510A and the bottom lances 510B have a plurality of nozzles formed therein for distribution of a gas, such as, oxygen therefrom, as described below. As shown best in
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As shown in FIGS. 2 and 4-6, each of the upper lances 510A and the bottom lances 510B includes a plurality of nozzles 555 formed therein. In one embodiment, the nozzles 555 are holes drilled through a surface of the upper lance 510A and the bottom lances 510B. As best shown in
The inventors used computational fluid dynamic (CFD) modeling and analysis to determine the quality of the mixing of oxygen and flue gas in ducts using many configurations of one or more static mixing grids modeled in one or more locations (e.g., multiple rows) in various flue duct configurations. While the CFD modeling was performed to quantify the mixing of oxygen in flue gas, the CFD modeling results are also applicable to the mixing of other fluids, gases, liquids, particulate solids and combinations thereof, such as but not limited to SO2, SO3 and mercury.
After modeling and analyzing CFD results for a significant number of configurations, the inventors surprisingly determined that the grid 500 demonstrated superior mixing compared to other configurations. For example, the CFD results for the grid 500 were unexpected because one skilled in the relevant art would have be discouraged from positioning a plurality of the lances 510A and 510B in a single plane, for example transverse to (e.g., perpendicular) to the flue gas flowing there around, because of the increase in pressure drop of the flue gas in the duct caused by the obstruction of the grid 500.
Mixing results for the grid 500 are presented as a coefficient of variation (CoV), which is a measure of the mixed gas homogeneity and equal to the standard deviation divided by the normalized average oxygen concentration at a particular location in the duct. CoV was determined for various lengths downstream of the grid 500. Length was normalized and presented in terms of diameters of duct, for example the duct equivalent diameters (L/D). A CoV of 0.05 is considered good mixing and 0.02 is considered excellent mixing. The results of the CFD modeling are shown in
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While the present invention has been described with reference to various exemplary embodiments, it will be understood by those skilled in the art that various changes may be made and equivalents may be substituted for elements thereof without departing from the scope of the invention. In addition, many modifications may be made to adapt a particular situation or material to the teachings of the invention without departing from the essential scope thereof. Therefore, it is intended that the invention not be limited to the particular embodiment disclosed as the best mode contemplated for carrying out this invention, but that the invention will include all embodiments falling within the scope of the appended claims.
This invention was made with government support under U.S. Contract No. DE-NT0005290. The U.S. government holds certain rights in this invention.