The present invention generally relates to a fluid distributor for distributing a fluid within a mass transfer column or reactor and to an up-flow reactor that employs the fluid distributor.
Mass transfer columns are configured to contact at least two fluid streams in order to provide product streams of specific composition and/or temperature. The term “mass transfer column” as used herein is intended to encompass cross flow liquid-vapor contactors, absorbers, separators, distillation columns, divided wall columns, liquid-liquid extractors, scrubbers, and evaporators, which facilitate heat and/or mass transfer between two or more fluid phases. Some mass transfer columns, such as those used in multicomponent absorption and distillation, are configured to contact gas and liquid phases, while other mass transfer columns, like extractors, are configured to contact two liquid phases of differing density.
In some types of mass transfer columns known as reactors, chemical reactions between two or more fluid streams, sometimes facilitated by catalyst, are designed to occur. In one type of reactor, two or more fluid phases are introduced into a lower region of the reactor and flow co-currently upwardly to an upper region of the reactor where they are removed. A fixed bed of catalyst particles may be provided in the co-current flow path of the fluid streams to cause the intended catalytic reaction between the fluid streams before they are removed from the reactor.
In order to ensure good performance of the reactor, it is important to have an even distribution of both fluid streams across the cross-sectional area of the reactor as they co-currently ascend through the reactor and the catalyst bed. The heavier fluid stream, such as a liquid stream, typically enters through a nozzle at the center of the bottom head of the reactor and the lighter fluid stream, such as a gas or vapor stream, enters through a feed pipe that penetrates the wall of the reactor and connects to a distributor that is placed underneath the catalyst bed. If either of these fluid streams is not spread out over the cross-section of the reactor before they enter the catalyst bed, the desired contact of the two fluid streams within the catalyst bed is not achieved, resulting in a reduction in the performance of the reactor.
At the top of the catalyst bed the two fluid streams have to be separated to minimize the carry-over of one fluid stream into the other that may adversely affect the performance of the reactor. This carry-over is particularly problematic when the fluid streams are a liquid stream and a gas or vapor stream because the presence of carry-over gas in the liquid stream may cause cavitation that degrades the impeller of the pump that is used to withdraw the liquid phase from the reactor.
In one conventional approach to separation of the fluid streams in these types of two-phase, co-current, up-flow reactors, an impermeable disk is placed on top of chordal beams that hold a catalyst hold-down grid or baffle in place. The impermeable disk has a smaller diameter than a shell of the reactor to form an annular space for the flow of fluid between the impermeable disk and the shell. The mixed phase from the top of the catalyst bed flows around the impermeable disk, ascends through this annular space, and enters a calming zone above the impermeable disk where separation of the fluid streams is designed to occur. An intake pipe with a surrounding permeable shroud is positioned a preselected distance above the center of the impermeable disk for removal of the heavier phase from the reactor.
In order to improve the performance of these types of reactors, a need exists for improvements in the distribution of the fluid streams in the lower region of the reactor, such as before they enter the catalyst bed, and for the separation of the fluid streams in the upper region of the reactor, such as after they have ascended through the catalyst bed and prior to removal from the reactor.
In one aspect, the present invention is directed to a fluid distributor for distributing a fluid in an up-flow reactor. The fluid distributor comprises: a supply pipe and a plurality of fluid distribution arms that extend from the supply pipe, each of the fluid distribution arms having a plurality of holes for discharging the fluid when the fluid is within the fluid distribution arms and is under pressure; an elongated hood overlaying and spaced from and at least partially surrounding each of the fluid distribution arms and constructed to redirect the fluid when discharged from the plurality of holes in the fluid distribution arms, each hood having a plurality of holes for allowing the passage of the fluid through the hood, each of the hoods comprising a plurality of hood segments positioned end to end along a length of the fluid distribution arm and having deflectors to impede the fluid from flowing between adjacent ones of the hood segments.
In another aspect, the present invention is directed to a two-phase, co-current, up-flow reactor comprising: a shell defining an open internal region; a first fluid inlet and a second fluid inlet positioned in a lower region of the shell for introducing a first fluid and a second fluid, respectively, within the shell; a first fluid outlet and a second fluid outlet positioned in an upper region of the shell for removing the first fluid and the second fluid, respectively, from within the shell; a fluid distributor as described above positioned in the open internal region with the supply pipe of the fluid distributor in fluid flow communication with the first fluid inlet; a fluid distributor plate positioned above the second fluid inlet in a flow path of the second fluid when introduced within the shell through the second fluid inlet, said fluid distributor plate having a plurality of openings arranged to redistribute the second fluid across a cross section of the open internal region.
In a further aspect, the present invention is directed to a two-phase, co-current, up-flow reactor comprising: a shell defining an open internal region; a first fluid inlet and a second fluid inlet positioned in a lower region of the shell for introducing a first fluid and a second fluid, respectively, within the shell; a first fluid outlet and a second fluid outlet positioned in an upper region of the shell for removing the first fluid and the second fluid, respectively, from within the shell; spaced-apart coplanar lower support beams connected to the shell and extending chordally across the open internal region; a catalyst support grid positioned above and supported by the coplanar lower support beams; a catalyst hold-down baffle spaced above the support grid and having a central impermeable area that defines an annular flow path for the first and second fluids through the catalyst hold-down baffle in a region between the central impermeable area and an inner surface of the shell; spaced-apart coplanar upper support beams connected to the shell and extending chordally across the open internal region and supporting the catalyst hold-down baffle; an annular trough supported above the coplanar upper support beams and spaced inwardly from the inner surface of the shell for receiving the second fluid and ascending through the annular flow path; a central open region defined by the annular trough and into which the second fluid enters after overflowing the annular trough; and an intake pipe for the second fluid and having an inlet end spaced above the central impermeable area and extending upwardly to the second fluid outlet for removing the second fluid from the central open region.
In the accompanying drawings that form part of the specification and in which like reference numerals are used to indicated like components in the various views:
Turning now to the drawings in greater detail and initially to
The reactor 10 comprises an upright external shell 12 that defines a vertically extending open internal region 14 in which a catalytic or other reaction between two or more fluid streams is intended to occur. The shell 12 may have the illustrated cylindrical cross-sectional shape, or other cross-sectional shapes, such as polygonal, may be used. The shell 12 may be of any suitable diameter, thickness, and height, and is constructed of rigid materials that are inert to, or compatible with, the fluids and conditions that are present during the operation of the reactor 10.
One or more fluid streams may be introduced into the reactor 10 by way of one or more inlets, such as a first fluid inlet 16 that enters the reactor 10 through a side wall of the shell 12 and a second fluid inlet 18 that is centrally positioned in a bottom head of the shell 12. The fluid streams may both be liquid phases of different densities or, more typically, one phase is a liquid phase and the other is a gaseous or vapor phase. In one application, a gas or vapor stream enters the reactor 10 as a first fluid through the first fluid inlet 16 in the side wall of the shell 12 and a liquid stream enters the reactor 10 as a second fluid through the second fluid inlet 18 in the bottom head of the shell 12.
After ascending from a lower region to an upper region of the reactor 10, the fluid streams are removed from the reactor 10 by one or more overhead outlets, such as a first fluid outlet 20 an upper head of the shell 12 that is offset from a center axis of the shell 12 and a second fluid outlet 22 that is centrally positioned in the upper head of the shell 12. The denser fluid stream may typically be removed through the centrally positioned second fluid outlet 22 and the less dense fluid stream may be removed through the offset first fluid outlet 20.
Turning additionally to
The first fluid is distributed across the cross section of the open internal region 14 of the shell 12 by a fluid distributor 28 that is spaced a preselected distance above the fluid distributor plate 24 in the lower region of the reactor 10. The structure of the fluid distributor 12 can best be seen in
Each of the fluid distribution arms 32 is provided with a plurality of holes 40 for discharging the first fluid when it is within the fluid distribution arms 32 and is under pressure. The holes 40 are spaced apart along a longitudinal length of each fluid distribution arm 32. The number, size and location of the holes 40 in each fluid distribution arm 32 are selected in combination with the orifice plates 38 or other flow regulators so that the first fluid is discharged with the desired volumetric flow and placement across the cross section of the open internal region 14. Similarly, the number and orientation of the normally coplanar fluid distribution arms 32 may be selected to facilitate a more uniform distribution of the first fluid.
To counteract the tendency of the first fluid to jet out of the holes 40 in the fluid distribution arms 32, elongated hoods 42 are provided to redirect the first fluid when it is discharged from the plurality of holes 40 in the fluid distribution arms 32. The elongated hoods 40 overlay and are spaced from and at least partially surround each of the fluid distribution arms 32. Each of the elongated hoods 42 has a plurality of holes 44 that allow the passage of the first fluid through the elongated hood 42. In one embodiment, the holes 44 in the hoods 42 are not aligned with the holes 40 in the fluid distribution arms 32 so that the momentum of the first fluid is disrupted by impacting against an undersurface of the elongated hoods 42. Each of the elongated hoods 42 may be formed by multiple walls that intersect at preselected angles so that the holes 44 provided in these walls discharge the first fluid in different directions to provide a more uniform distribution of the first fluid across the cross section of the open internal region 14. In one embodiment, opposite ones of the walls that form the sides of the elongated hoods 42 have a saw-tooth lower edge (not shown) to accommodate irregularities in the interface of the first and second fluids in relation to the lower edge such as might result from misalignment of the fluid distribution arms 32.
Each of the elongated hoods 42 may comprise a plurality of individual hood segments 42a that are positioned end to end along a longitudinal length of each of the fluid distribution arms 32. Deflectors 46 are provided within each hood segment 42a to impede the first fluid from flowing between adjacent ones of the hood segments 42a, which might otherwise lead to deviation from the desired distribution of the first fluid.
Spaced-apart and coplanar lower support beams 48 are connected to the shell 12, such as be using beam seats 49, and extend in a chordal fashion across the open internal region 14 of the shell 12. A support grid 50 is positioned above and supported by the lower support beams 48. The support grid 50 may be formed from multiple, individual support grid panels 50a (e.g.,
The lower support beams 48 and the fluid distribution arms 32 may be constructed and arranged so that the fluid distribution arms 32 extend between and extend parallel with the lower support beams 48 below the support grid 50. In one embodiment, one of the lower support beams 48 is positioned between each adjacent pair of the fluid distribution arms 32. The fluid distribution arms 32 and other parts of the fluid distributor 28 for the second fluid may be attached to the shell 12 by bolting bars or other means. The support grid 50 may be attached to the shell 12 by a support ring 57 or other means.
After the first fluid and the second fluid ascend as a mixture through the catalyst bed 52, they are separated in the upper portion of the open internal region 14 of the shell 12 before being removed from the reactor 10 through the first fluid outlet 20 and second fluid outlet 22, respectively. This separation is provided in part by the structures described below with reference to
A catalyst hold-down baffle 58 is spaced above the support grid 50 and above the catalyst bed 52 (
The central impermeable area 60 may be formed by an imperforate disk 66 (
An annular trough 68 is supported above the upper support beams 64, such as by resting on an upper surface of the upper support beams 64. The annular trough 68 is spaced inwardly from the inner surface of the shell 12 a preselected distance. In one embodiment, the annular trough 68 is spaced inwardly from the inner surface of the shell 12 a sufficient distance so that it is generally in vertical alignment with an outer edge of the imperforate disk 66. The annular trough 68 comprises spaced-apart outer and inner side walls 70 and 72, respectively, and a connecting floor 74. In one embodiment, the outer side wall 70 is angled outwardly and includes a further outwardly angled lip 76 that constricts an area above the annular region 62. The inner side wall 72 may extend vertically and include a similar outwardly angled lip 78 that impedes fluid from sloshing over the inner side wall 72.
A splash baffle 80 may be positioned above the annular trough 68 for restricting the second fluid and any intermixed first fluid from jumping over the annular trough 68 and for directing it into the annular trough 80. A lower portion of the splash baffle 80 may be positioned within the annular trough 80 and an upper portion of the splash baffle 80 may extend upwardly a preselected distance above the annular trough 80. The splash baffle 80 may be annular in construction so that it is coextensive and concentric with the annular trough 80. Both the splash baffle 80 and the annular trough 68 may be formed from linear segments that are joined together to form a polygonal shape as illustrated in the drawings or they may be of a circular shape.
A central open region 82 (
The central open region 82 may be formed as a sump, such as by using upright plates 92 (
Studies using computational fluid dynamics have shown that the features of the present invention provide improvements in the distribution of the first and second fluids across the open internal region 14 of the reactor 10 and subsequent separation of the first and second fluids, which should lead to improvements in reactor performance and a reduction in degradation of downstream pumps or other processing equipment.
From the foregoing, it will be seen that this invention is one well adapted to attain all the ends and objectives hereinabove set forth, together with other advantages that are inherent to the invention.
It will be understood that certain features and subcombinations are of utility and may be employed without reference to other features and subcombinations. This is contemplated by and is within the scope of the claims.
Since many possible embodiments may be made of the invention without departing from the scope thereof, it is to be understood that all matter herein set forth or shown in the accompanying drawings is to be interpreted as illustrative and not in a limiting sense.
This application claims priority to U.S. Provisional Patent Application No. 63/228,616 filed Aug. 3, 2021, with the above-identified application being incorporated by reference herein in its entirety.
Filing Document | Filing Date | Country | Kind |
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PCT/IB2022/057213 | 8/3/2022 | WO |
Number | Date | Country | |
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63228616 | Aug 2021 | US |