This invention relates generally to an apparatus for fluid treatment, and more particularly relates to an apparatus for injecting a treating agent into a fluid stream while generating enhanced fluid phase turbulence to better distribute and mix the injected treating agent into the fluid.
During the course of treating a fluid, for instance to control the atmospheric emission of polluting contaminants, it is common to disperse a treating agent into the fluid in order to combine with a catalyst to treat the undesired component of the fluid. In general, a mixing apparatus is used to disperse the treating agent into the fluid. Holes, which include hardened holes, holes, nozzles, injection nozzles, and the like, can be used for this purpose. Since simple ejection of the agent from such holes is not very effective in thoroughly mixing the agent with the fluid, it is also known to use baffles (sometimes also referred to as “deflectors” and “flow mixers”), usually positioned directly downstream of the injection point to encourage turbulence, thereby enhancing the mixing of the agent with the fluid.
One of the applications of the mixing apparatus is the treatment of flue gas containing nitric oxide and nitric dioxide (collectively, “NOx”) and other hazardous chemicals produced during the combustion of fossil fuels. NOx emissions may be minimized by catalytically reducing flue gas NOx to nitrogen and water using ammonia (NH3) in a chemical reaction before releasing the gas into the atmosphere.
Flue gas may be treated by passing the gas through treatment systems, which attempt to provide maximum exposure of the catalyst to the flue gas in order to ensure that all the flue gas comes sufficiently into contact with the catalyst for treatment.
In the treatment systems, a treating agent, such as ammonia, is typically introduced into the flue gas stream by the mixing apparatus comprised of pipes having a plurality of holes. The mixing apparatus is designed to provide an even distribution of ammonia throughout the flue gas. The holes on the mixing apparatus are usually arranged such that the ammonia is injected into the flue gas towards a catalyst bed located downstream in the treatment system.
Ammonia is commonly injected through the mixing apparatus into the flow of flue gas by utilizing an external ammonia vaporization system wherein liquid ammonia, either in an anhydrous or aqueous state, is vaporized in a heater or vaporizer, mixed with dilution air, and then routed to the mixing apparatus for injection into the flow of flue gas at a location upstream of the mixing apparatus. Typically, the ammonia is diluted with water prior to being injected through the mixing apparatus into the flow of flue gas.
To increase the mixing efficiency, some mixing apparatus include baffles disposed adjacent to the holes of the pipes or baffles installed between the pipes. Known mixing apparatus commonly utilize horizontal baffles for creating a turbulent mixing effect. Other mixing apparatus utilize square pipes rather than conventional circular pipes. Other known apparatus utilize baffles located in an upstream position from the pipes to create a wake downstream to increase the ammonia flue gas mixing efficiency.
It is therefore desirable to provide a mixing apparatus that evenly distributes the ammonia into the flue gas before reaching downstream catalyst for heat recovery, steam generation systems, packaged boilers, simple or combined cycle catalyst systems, and fired heaters.
In accordance with a broad aspect of the present invention, there is provided a flow mixer comprising a middle section having a first side and a second side, one or both of the first side and the second side having an edge furcated along its length.
In accordance with another broad aspect of the invention, the furcated edge of the flow mixer comprises a first branch and a second branch.
In accordance with another broad aspect of the invention, there is provided a fluid mixing apparatus for mixing a first fluid with a second fluid having a flow direction comprising: at least one pipe having a plurality of holes; and at least one flow mixer, each of which is associated with one of the at least one pipe, the at least one flow mixer each having a middle section, one or both sides of which having a furcated lengthwise edge.
In accordance with another broad aspect of the invention, there is provided a method of mixing a first fluid with a second fluid stream having a flow direction comprising: providing at least one flow mixer in the second fluid stream, the at least one flow mixer comprising a middle section, one or both lengthwise sides of which having a furcated edge; and injecting the first fluid into the second fluid stream near the at least one flow mixer.
Drawings are included for the purpose of illustrating certain aspects of the invention. Such drawings and the description thereof are intended to facilitate understanding and should not be considered limiting of the invention. Drawings are included, in which:
The detailed description set forth below in connection with the appended drawings is intended as a description of various embodiments of the present invention and is not intended to represent the only embodiments contemplated by the inventor. The detailed description includes specific details for the purpose of providing a comprehensive understanding of the present invention. However, it will be apparent to those skilled in the art that the present invention may be practiced without these specific details.
Each pipe 14 has a central lengthwise axis and pipes 14 may have their central axes substantially vertical and in substantially parallel alignment with each other in apparatus 10. However, those skilled in the art will appreciate that other axial alignments and arrangements may be used with apparatus 10, such as horizontal or diagonal. As shown, pipes 14 are aligned along the same plane, but pipes 14 may also be in a staggered arrangement.
The holes 16 direct a treating agent into the flow of the flue gas. Holes 16 may be staggered on either side along the length of the pipe 14. The distance between adjacent holes on one side of the pipe 14 is designated h. Holes 16 may be angled upstream or downstream relative to the flow of flue gas.
Flow mixers 20 include any object designed to disrupt and/or redirect fluid flow. Flow mixers 20 are disposed near pipes 14 or supported on pipes 14. In one embodiment, flow mixers 20 are disposed along the length of pipes 14. Each of flow mixers 20 may be a single piece of material that spans substantially the entire length of pipes 14. Alternatively, each of flow mixers 20 may comprise of a plurality of sections, wherein adjacent sections are separated by a gap 21, which provides space to allow for any thermal expansion of the flow mixer 20. Flow mixer 20 may be secured to existing mixing systems on the upstream side or downstream side of pipes 14.
Referring to both
Arrows A illustrate the general flow path of the treating agent as it exits pipes 14 and encounters the surface of flow mixer 20. Referring to
The flue gas and injected treating agent mixture flow around branches 22 and 24 in order to continue travelling downstream. A second mixing zone G and a third mixing zone K are provided in the turbulent vortices created as the mixture flows around branches 22 and 24, respectively, in between adjacent flow mixers. In each mixing zone, more exchange of energy between the flue gas and the treating agent takes place, resulting in an increased mixing efficiency between the two fluids.
As shown in
The data shown in Table 1 below is collected from the testing of a model of the prior art injection apparatus shown in
The testing on the model is done with a tracer gas flow rate of 19 actual cubic feet per minute (ACFM) and a flue gas flow rate of 7013 ACFM. The concentration of the tracer gas is measured at various locations downstream from the pipes using a probe attached to a gas analyzer.
The numbers in Table 1 are normalized concentration values of the tracer gas viewed in the direction of flow. The values in table 1 are generated from measuring the concentration of the tracer gas at 60 locations on a plane substantially perpendicular to the direction of flow F at about 8′ downstream from the pipes. More specifically, measurements were taken in a grid-like pattern having six columns across the width of the flue conduit and ten rows along the height of the flue conduit, which provides 60 measurement locations on that plane. Normalized concentration is calculated using the following formula:
Based on the data in Table 1, the root mean square (RMS) deviation is 12.3%. RMS deviation is the standard deviation of the population divided by the mean. Since RMS is a statistical measure of variation, a high RMS deviation percentage indicates poor mixing of tracer gas as some areas have higher concentrations of tracer gas than others. The lower the RMS deviation percentage, the more evenly distributed the tracer gas since a low RMS deviation percentage indicates that the concentrations of tracer gas at various data points are roughly the same.
Referring to
Based on the data in Table 2, the RMS deviation in the normalized tracer gas concentration is 4.7%. This is better than the results from the set up of
Referring to
Based on the data in Table 3, the RMS deviation in the normalized tracer gas concentration is 3.9%. Therefore, flow mixer 20 is shown to be useful in enhancing the distribution and mixing of injected treating agent in flue gas flow.
The previous description of the disclosed embodiments is provided to enable any person skilled in the art to make or use the present invention. Various modifications to those embodiments will be readily apparent to those skilled in the art, and the generic principles defined herein may be applied to other embodiments without departing from the spirit or scope of the invention. Thus, the present invention is not intended to be limited to the embodiments shown herein, but is to be accorded the full scope consistent with the claims, wherein reference to an element in the singular, such as by use of the article “a” or “an” is not intended to mean “one and only one” unless specifically so stated, but rather “one or more”. All structural and functional equivalents to the elements of the various embodiments described throughout the disclosure that are know or later come to be known to those of ordinary skill in the art are intended to be encompassed by the elements of the claims. Moreover, nothing disclosed herein is intended to be dedicated to the public regardless of whether such disclosure is explicitly recited in the claims. For US patent properties, it is noted that no claim element is to be construed under the provisions of 35 USC 112, sixth paragraph, unless the element is expressly recited using the phrase “means for” or “step for”.