Patent Application
20140183087
None.
1. Field of the Disclosure
The present disclosure relates to micro-fluid ejection devices. More particularly, it relates to fluid level sensing tank used for inkjet printers.
2. Description of the Related Art
Emerging inkjet printer technologies separate the printheads from the ink supply to help reduce the cost for the consumer. With this separation, the ink supply item has to be smart or needs to have some form of identification to report to the printer and user, such as the information of what and how much ink it contains. This information is critical to the life and reliability of the printhead. For example, accurate ink level detection prevents “dry firing” of the printhead and also prevents air ingestion into the fluidic system. A typical ink level detection method consists of a dot/fire counting algorithm in firmware with an out of ink sensor to inform the system and user the status of ink supply. This firmware dot/fire counting method is an estimation based on the number of printhead fires and a fluid evaporation constant. This estimation is not as accurate as desired for permanent printheads, primarily due to drop size variation which may exceed by 20%.
Still other detection methods sense ink level by means of capacitors, optics, weight, ultrasound, magnets, floats, torque sensors, electrical probes, or the like. All these methods require either some form of external stimulus and/or a sensing mechanism. U.S. patent application Ser. No. 13/149,154 to Nicholson et al. discloses a closed system or a smart ink tank with the driving, sensing and capacitance measuring all contained on the supply item. There are challenges with this electrical and mechanical approach, such as requiring materials and chemical specifications to be well designed so that fluid level sensing method functions properly.
The chemical components of ink typically have properties that are best for print quality but not good for a quickly responsive fluid level measurement system. One component in particular is the level of surfactant found in inks. Surfactants lower the surface tension of liquids and act as a wetting agent. This component allows the ink to properly cling or stick to surfaces of printing medium (e.g. paper). However, this component is not good for any ink level detection method that requires fluid to roll off from surfaces quickly. If inks tend to cling or stick to tank material of ink supply item, the accuracy of the ink level measurement system will be affected.
The wettability of a solid surface by a liquid may be quantified by a contact angle. The higher the contact angle the less spreading/wetting of the liquid is on the surface. Generally, if the water contact angle is larger than 90°, the solid surface is considered hydrophobic. Highly hydrophobic surfaces made of low surface energy materials have water contact angles as high as about 120°. Super hydrophobic surfaces are highly rough surfaces having a water contact angle of greater than about 150°.
There is a need to achieve a balance between the tank material surface energy and ink chemistry to eliminate the problem with ink clinging to the tank material. Ink wetting characteristics may be modified by altering the type and concentration of surfactant in the ink composition. However, modification of the ink chemistry may lead to changes in print quality. The surface of the tank material may be made more hydrophobic to lower the surface energy, thus preventing the ink from clinging. A tank container with surface energy that balances with the ink chemistry is desired for an accurate ink level measurement system without compromising ink print quality.
The present disclosure provides a fluid tank for micro-fluid ejection devices. The fluid tank includes housing with an interior surface coating. The interior surface coating has a highly hydrophobic to super hydrophobic surface with water contact angle of greater than about 120° and surface energy of less than about 20 mJ/m2. The interior surface coating includes nanoparticles and hydrophobic materials. In one example embodiment, the interior surface coating is formed by depositing a slurry of nanoparticles and hydrophobic solution on interior surface of housing. In another example embodiment, the interior surface coating is formed by depositing nanoparticles, being formed from gas phase reaction, on interior surface of housing, and encapsulating deposited nanoparticles with hydrophobic materials through chemical vapor deposition.
The interior surface coating of the fluid tank prevents fluid such as ink to stick or cling to the tank surface. The fluid tank is suitable as ink container having ink level measurement system. The fluid tank allows an accurate and quickly responsive ink level measurement system without compromising ink print quality.
The accompanying drawings incorporated in and forming a part of the specification, illustrate several aspects of the present disclosure, and together with the description serve to explain the principles of the present disclosure.
It is to be understood that the disclosure is not limited in its application to the details of construction and the arrangement of components set forth in the following description or illustrated in the drawings. The disclosure is capable of other embodiments and of being practiced or of being carried out in various ways. Also, it is to be understood that the phraseology and terminology used herein is for the purpose of description and should not be regarded as limiting. The use of “including,” “comprising,” or “having” and variations thereof herein is meant to encompass the items listed thereafter and equivalents thereof as well as additional items. Further, the terms “a” and “an” herein do not denote a limitation of quantity, but rather denote the presence of at least one of the referenced item.
With reference to
In one example embodiment, the fluid tank 10 includes at least one pair of opposed sensing elements 50 disposed in the housing 12 to detect a fluid level. The pair of opposed sensing elements 50 may include, but are not limited to, conductive plates whose capacitance varies upon the application of electrical energy according to an amount of liquid that exists between the plates. With greater amounts of fluid, the plates have a greater amount of capacitance. With lesser amount of fluid, the plates have a lesser amount of capacitance.
The housing 12 is made of plastic. Techniques for producing the housing 12 envision blow molding, injection molding, etc. as well as heat-staking, gluing, etc. Selecting the materials and designing the production, in addition to ascertaining conditions for shipping, storing, use, etc., includes further focusing on criteria, such as costs, ease of implementation, durability, leakage, and the like. In one example embodiment, the housing 12 comprises polypropylene. Polypropylene materials have a water contact angle of about 85° to about 92°. Water easily rolls off from polypropylene materials. However, ink tends to cling or adhere on polypropylene materials having a lower contact angle, which may be about 30° to about 60°. In another example embodiment, the housing 12 comprises polytetrafluoroethylene or derivatives containing fluorine groups. Polytetrafluoroethylene provides a more hydrophobic surface yielding a higher water or ink contact angle compared to polypropylene. However, polytetrafluoroethylene is relatively costly and has complex molding or processing related issues. In some other example embodiment, the housing 12 comprises a blend of polypropylene and polytetrafluoroethylene particles.
The interior surface coating 15 provide the housing 12 with a highly hydrophobic to super hydrophobic interior surface having a water contact angle of greater than about 120° and a surface energy of less than about 20 mJ/m2. The interior surface coating 15 is constructed to have good adherence with the housing material while having a surface with high contact angle for the ink to repel. The interior surface coating 15 includes a single or multiple layers.
The interior surface coating 15 includes nanoparticles and hydrophobic material. The nanoparticles provide the interior surface of the housing 12 with texture and roughness, thus providing highly hydrophobic to super hydrophobic surfaces when combined with hydrophobic materials. Nanoparticles include, but are not limited to, metal oxides such as silica, alumina, titanium dioxide and tin oxide. Nanoparticles have particle sizes ranging from about 5 to about 100 nanometers (nm).
Hydrophobic materials include, but are not limited to, organic silanes. Examples of organic silanes are listed in Table 1 with their corresponding water contact angle when formed into film.
In one example embodiment, the interior surface coating 15 is formed through a surface coating method illustrated in
In another example embodiment, the interior surface coating 15 is formed through a surface coating method illustrated in
In particular, aluminum oxide nanoparticles formed through gas phase reaction of trimethyl aluminum and water vapor in deposition chamber are deposited on interior surface of the housing 12. The deposited aluminum oxide particles are then encapsulated with pentafluorodecyltrichlorosilane through chemical vapor deposition, still on the same deposition chamber. The formed interior surface coating 15 has a surface with water contact angle of about 150°. Pentafluorodecyltrichlorosilane is a hydrophobic material forming a plain film having a surface with water contact angle of about 114°. Providing the pentafluorodecyltrichlorosilane on a roughened surface or surface deposited with nanoparticles, obtains a coating with super hydrophobic surface having water contact angle of about 150°.
Fluid tanks each having two parallel conductive plates are prepared. Fluid tank A includes a polypropylene housing without an interior surface coating and is filled with water to represent as control for evaluation. Fluid tank B is similar with fluid tank A but being filled with ink to represent as comparative example for evaluation. Fluid tank C includes a polypropylene housing, and an interior surface coating comprising aluminum oxide nanoparticles and perfluorodecyltrichlorosilane oligomer formed according to the surface coating method illustrated in
In the evaluation, the conductive plates of the fluid tanks filled with fluids are attached to a volt meter. The voltage readings before and after agitating the fluid tanks are then recorded as a function of time to track the fluid settling response time for each fluid tanks.
The foregoing description illustrates various aspects of the present disclosure. It is not intended to be exhaustive. Rather, it is chosen to illustrate the principles of the present disclosure and its practical application to enable one of ordinary skill in the art to utilize the present disclosure, including its various modifications that naturally follow. All modifications and variations are contemplated within the scope of the present disclosure as determined by the appended claims. Relatively apparent modifications include combining one or more features of various embodiments with features of other embodiments.
