Fluid purification methods, devices, and systems

Information

  • Patent Grant
  • 10189728
  • Patent Number
    10,189,728
  • Date Filed
    Tuesday, July 19, 2016
    8 years ago
  • Date Issued
    Tuesday, January 29, 2019
    5 years ago
Abstract
A fluid purification system has cells whose purifying capability can be regenerated. Some of the cells are arranged in series to reach a high level of purification. An automatic valve network is controlled to cycle the cells in a way that levels the loads on each, thereby maximizing the service interval for replacing expired cells, enabling all of the cells to be replaced at the same time after having each contributing approximately equally to the purification load, and operated such that at any one time, at least one cell is regenerated so as to enable continuous up-time.
Description
BACKGROUND

Electronic deionization (EDI) is an established method for purification of water by removing ionic solutes. EDI uses filter units, hereafter referred to as cells, which have a membrane. EDI uses electricity in addition to a membrane to filter material including solutes. The membranes of cells can be regenerated electrically and by reverse flushing and are therefore regarded as re-usable. The number of regeneration cycles of cell may be limited because of gradual permanent degradation of the membrane of the cell.


Ionic solutes may be expressed as total dissolved solids (TDS) in parts per million (PPM). As indicated above, an EDI cell may be capable of 85% to 95% TDS reduction. Higher levels of purification can be achieved with three or more EDI cells connected in series to achieve a ratio of TDS in the input water to that in the output water as shown in the table below. For example, water containing 1000 ppm TDS may have the TDS reduced at each stage of a series-connected cells as follows.


1000 TDS×90% Stage 1=900 TDS Reduction | out=100 ppm


100 TDS×90% Stage 2=90 TDS Reduction | out=10 ppm


10 TDS×90% Stage 3=9 TDS Reduction | out=1 ppm


1.0 ppm remaining from 1000 TDS starting concentration


When an EDI cell is actively removing ions, membranes of the cell are charged with electricity creating anionic and cationic bonding sites. EDI cells require regeneration after a period of time. During regeneration, the polarity on the membranes is reversed and water forced in a reverse direction to push the ions out of the bonding sites and flush the captured ions out of the cell.


In EDI technology, a membrane, such as a re-usable membrane, has a finite service life. In general, the service life is a function of the number of regeneration cycles. During regeneration, the membrane is exposed to concentrated solutes. Progressive scaling of calcium carbonate and other solutes can occur during the regeneration cycle. As scale forms, the membrane becomes permanently degraded, ultimately requiring replacement.


SUMMARY

Embodiments of the disclosed subject matter relate to fluid purification methods, devices, and systems. In particular, embodiments of the disclosed subject matter involve multi-cell and multi-stage batch electronic deionization systems, methods, and devices.


Embodiments include multiple cell, multi-stage purification systems, for example a four-cell, three-stage EDI system is described. In the disclosed embodiments, a predetermined purity is achieved while also optimizing a service interval between the replacements of one or more permanently degraded cells resulting from the system use, including multiple regeneration cycles of the cells in each stage. The disclosed subject matter may be adapted to achieve, for example, 99.9% total dissolved solids (TDS) reduction versus only 85% to 95% TDS reduction in a single stage system in which fluid flows through a single stage. FIG. 1 shows an example of a two-cell system according to the prior art in which valves 26 are operated to produce a reverse flow in cell 114 to regenerate it while cell 216 receives a forward flow to purify the flowing water. Flushed reversed flow is drained through a drain. The flow restrictors 24 and check valves 26 cooperate with the valves to divert some of the purified water to the cell undergoing regeneration by reverse flow. A flow sensor and pressure switch 28 are provided. In addition to higher purity, a four-cell, three-stage, system or device can provide a much higher service life than a conventional two-cell single stage system.


Embodiments include a three-stage system or device comprised or consisting of three paired cells in fixed position. Such a system or device can also achieve about 99.9% TDS reduction.


Objects and advantages of embodiments of the disclosed subject matter will become apparent from the following description when considered in conjunction with the accompanying drawings.





BRIEF DESCRIPTION OF THE DRAWINGS

Embodiments will hereinafter be described in detail below with reference to the accompanying drawings, wherein like reference numerals represent like elements. The accompanying drawings have not necessarily been drawn to scale. Where applicable, some features may not be illustrated to assist in the description of underlying features.



FIG. 1 is a block diagram of a two-cell electronic deionization system according to the prior art.



FIG. 2 is a block diagram of a fluid purification system according to embodiments of the disclosed subject matter.



FIGS. 3A-3D shows regeneration cycles of respective stages of a four-cell, three-stage electronic deionization system or device according to embodiments of the disclosed subject matter.



FIG. 4 shows another embodiment in which a cell to be regenerated in a cell of a multi-stage purifier is regenerated while a parallel multi-stage purifier purifies fluid and then the multi-stage purifiers switch for regeneration of the next cell to be regenerated.





DESCRIPTION OF EMBODIMENTS

As used in the description, the term cell may refer to any kind of fluid purification element. Although specific examples are described which employ EDI cells in the context of water purification, it should be understood that the term cell may refer to one or more units that produce a reduction in filterable content of a fluid stream. In the case of EDI embodiments, the cells reduce ionic species as well particulates. Preferably, particulates are substantially removed from the fluid stream prior to passing through an EDI purification system.


Embodiments described hereinbelow include multi-stage, multi-cell systems. In this case, each stage of an N-stage system may include one or more cells and the one or more cells will be arranged so that a first stage purifies fluid and outputs purified fluid to a second stage attached to it in a series relationship so that it can further purify the fluid. The series continues until the fluid is purified by an Nth stage. Fluid may also flow through cell modules that are arranged within a cell in a parallel relationship in each stage. To simplify discussion, such a stage, having multiple cell modules or filter units in which a flow is divided to flow through separate units, will still be called a “cell” herein.


In a multi-stage system, the first cell in a series (that is, the first stage, which is receiving fluid from the source to be treated and not from an upstream cell stage) has the greatest filtering load. In embodiments, the first cell in the series is always the next cell to be regenerated. In further embodiments, multiple cells awaiting regeneration may stand by and be regenerated in parallel. The second cell in the series has a lighter load because the fluid it receives has a lower amount of material to remove. The third cell will have even less filtering load and so on for as many cells as are in the series.



FIG. 2 is a block diagram of a fluid purification system 101 according to embodiments of the disclosed subject matter. The system 101 may be, for example, a water purification plant that generates pure water used for medical treatment, for example, dialysate used in renal replacement therapy. The downstream consuming process 116, in such a case, may represent a process that stores pure water to be used later in the preparation of treatment fluids or a proportioning system that adds specific materials such as solutes for preparing treatment fluids such as dialysate. Water from a source may be filtered initially by a sediment filter 100 and then pass through a backflow preventer 102. A pump 104 may be included but the system may also operate on source water line pressure, if sufficient. The fluid (advantageously, water) from the pump or backflow preventer 104, 102 may be applied to an EDI purification system 108, in the present case identified as a 3-stage, 4 cell EDI system powered and controlled by a controller 109. The fluid treated by the EDI system 108 may be further treated by a UV treatment cell 106 which may provide degradation of some chemicals or bio-contaminants. A chemical deionization stage including a dual bed 110 and mixed bed 112 stage may further deionize the fluid (again, the system in the principal embodiment is directed to water, so the deionization would be used to deionize water). An ultrafiltration stage 114 may be provided for, as in a principal environment, to capture pyrogens and/or infectious particles. The latter is particularly useful for medical applications where the product fluid is used for medical purposes and thereby may come in contact with a patient's body. As indicated above, the consuming process 116 may be any of a variety of consuming processes. A drain may receive fluid from a valve 120 that diverts product fluid from the upstream stages to the drain during transient cycles or for testing during startup before a steady state product fluid production cycle begins. As will be explained further on, the EDI system 108 also produces waste water during regeneration of the cells. Note that the EDI system 108 may be replaced with any type of multi-stage multiple element filtration or purification system, where cells other than EDI type cells, whose purification capability can be regenerated, may be used.



FIGS. 3A-3D shows stages of a four-cell, three-stage EDI system or device according to embodiments of the disclosed subject matter. The system shown in FIG. 2 can include the four-cell, three-stage electronic deionization system, for example at 108 as indicated. The EDI system of FIGS. 3A-3D may be used in other systems as well or as a stand-alone deionization system. The system of FIGS. 3A-3D may also be used with non-EDI purification cells that are regenerated using reverse flow or by other means.


Embodiments of the disclosed subject matter can include a three-stage electronic deionization system. Optionally, the system or device can include four cells. Other embodiments based on a different number of cells are also possible, for example, a two stage system or four or more stages in a system. In addition, as mentioned, a single cell may include more than one purification unit connected in parallel or series.


Each of the cells 340, 342, 344, and 346 can be connected and controlled to operate for fluid purification or regeneration. For fluid purification, fluid flows in a forward direction to produce product fluid; in an embodiment, water flows to produce product water. In the case of an EDI cell, a forward voltage is applied. To operate for regeneration, the fluid flows in a reverse direction through the cell and, in the case of an EDI cell, a reverse voltage is applied to the cell undergoing regeneration. A controller may apply the voltage and control valves to subject a selected cell to the regeneration and purification modes automatically and for predefined volumes of fluid or time intervals. In addition, the regeneration modes may be triggered my measured levels of contamination in the product fluid. For example, the ion concentration of product, in water purification embodiments, may be measured using a resistivity sensor and the signal used by the controller to control valves and voltages for the mode establishment as discussed. In the following discussion, it is assumed the fluid is water, but other fluids may be used and the cells configured for the purification of other types of fluids, correspondingly.


The four cells can be inter-connected by tubing and valves, for example, as shown in FIGS. 3A-3D. Each cell is shown at 340, 342, 344, and 346. The number of cells may vary in alternative embodiments. At any given time, three of the cells 340, 342, 344, and 346 are connected in series for continuous production of product water. For example, in FIG. 3A, the cell 346 is undergoing regeneration and cells 340, 342, and 344 are connected in series to produce product water. Part of the product water output from the final cell in the series, cell 340, is diverted to reverse flush cell 346 and the resulting waste stream flowed to a drain. To accomplish the simultaneous production and regeneration, control valves are set such that valves 302, 320, 316, 314, 304, 308, 312, 324, 328, and 326 are closed while valves 330, 332, 310, 322, 306, and 318 are open. In FIG. 3A, the dotted lines indicate lines where no flow occurs and the solid lines and arrows indicate that flow is occurring and the direction of the flow in the indicated lines. It can be seen by the arrangement of the flow paths that the identified regenerating and product water flows result as indicated by the solid and dotted lines.


In FIG. 3B, the cell 340 is undergoing regeneration and cells 340, 342, and 346 are connected in series to produce product water. Part of the product water output from the final cell in the series, cell 346, is diverted to reverse flush cell 344 and the resulting waste stream flowed to a drain. To accomplish the simultaneous production and regeneration, control valves are set such that valves 304, 314, 306, 308, 312, 322, 330, 320, 328, and 318 are closed while valves 302, 310, 332, 324, 326, and 316 are open. In FIG. 3B, the dotted lines indicate lines where no flow occurs and the solid lines and arrows indicate that flow is occurring and the direction of the flow in the indicated lines. It can be seen by the arrangement of the flow paths that the identified regenerating and product water flows result as indicated by the solid and dotted lines.


In FIG. 3C, the cell 342 is undergoing regeneration and cells 340, 344, and 346 are connected in series to produce product water. Part of the product water output from the final cell in the series, cell 344, is diverted to reverse flush cell 342 and the resulting waste stream flowed to a drain. To accomplish the simultaneous production and regeneration, control valves are set such that valves 304, 306, 310, 316, 322, 324, 318, 330, 320, and 332 are closed while valves 314, 302, 308, 312, 326, and 328 are open. In FIG. 3C, the dotted lines indicate lines where no flow occurs and the solid lines and arrows indicate that flow is occurring and the direction of the flow in the indicated lines. It can be seen by the arrangement of the flow paths that the identified regenerating and product water flows result as indicated by the solid and dotted lines.


In FIG. 3D, the cell 340 is undergoing regeneration and cells 342, 344, and 346 are connected in series to produce product water. Part of the product water output from the final cell in the series, cell 342, is diverted to reverse flush cell 340 and the resulting waste stream flowed to a drain. To accomplish the simultaneous production and regeneration, control valves are set such that valves 302, 310, 314, 318, 316, 308, 326, 324, 330, and 332 are closed while valves 304, 306, 312, 320, 322, and 328 are open. In FIG. 3D, the dotted lines indicate lines where no flow occurs and the solid lines and arrows indicate that flow is occurring and the direction of the flow in the indicated lines. It can be seen by the arrangement of the flow paths that the identified regenerating and product water flows result as indicated by the solid and dotted lines.


To illustrate that a variety of arrangements of a fluid management system (the valve network embodiments being a fluid management systems), an alternative arrangement regenerates one member of a series while the other members of the series wait. To allow continuous purification, a second series operates while the one is regenerated. By providing a suitable fluid management system (or valve network) all of the cells in each series can be suitably arranged in the series so that the most recently regenerated cell is last in the series (so product water comes out of it) and the cell that has been used for the longest time or volume of fluid since regeneration is first in the series. FIG. 4 shows such a system where two multi-stage purifiers 218 and 220 each has a 4-stage 4-cell series. In FIG. 4 a cell to be regenerated (for example one in side 218) is regenerated while a parallel multi-stage purifier (for the example 220) purifies fluid and then the two multi-stage purifiers switch for regeneration of the next cell in the parallel multi-stage purifier is regenerated. The cells may be shifted in order so that the most recently regenerated cell is always last in the series by controlling the valves 271 by the controller 210. The valves 259 through 261 may be operated by controller 210 so that a forward flow goes only to one side at a time while a reverse flow through a respective flow restrictor 24 returns through one of the valves 260 or 262 to the drain 20 with the check valves blocking flow so as to ensure the correct open flow path. Although not labeled individually, each series has valves that may be operated by the controller 210 to provide the aforementioned serial arrangement of cells. It may be confirmed that the arrangement of FIG. 4 produces the desirable features of the other embodiments in which the purification load is distributed uniformly among the cells 275 of each multi-stage purifier 218 and 220. As a result, the cells may be replaced at less frequent intervals, after permanent exhaustion, and may be regenerated automatically. The foregoing embodiment of FIG. 4 may have sensors for detecting TDS reduction from source to product as in the foregoing embodiments. As in prior systems, flow sensors and pressure switch 28, backflow preventers, etc. may be provided.


Variations of the FIG. 4 embodiment are possible. For example each multi-stage purifier may have N cells and but N-M stages such that M stages are regenerated at a time and the cells ready for regeneration are switched out. For example, in a 4 cells system, three stages may be used in series and one stage left on standby to be switched into the circuit, and the first one to be regenerated switched out to await the next regeneration cycle which occurs when the second cell requiring regeneration is ready for regeneration. The valves 271 would be operated to regenerate both cells requiring regeneration in parallel (parallel flow).


The interconnection of cells, tubing, and valves can be controlled such that product water flows through any three cells in series at all times. A fourth cell can be controlled such that it is in a regeneration state or in an idle state. In embodiments, each cell may progress through the following sequence: regeneration->stage three->stage two->stage 1. Optionally, each cell may progress through the aforementioned sequence such that no two cells are at the same stage at the same time. Thus, embodiments can include four cells that are controllable so as to operate in a rotating series to support three states of deionization plus a regeneration state.


One advantage embodiments of the disclosed subject matter provide is increased membrane life. This can be achieved by embodiments of the disclosed subject matter by spreading out usage of the four membranes based on the aforementioned cell operational sequence. That is to say, relative to service life of the membrane, life optimization can be achieved by spreading the service life over four membranes instead of two in a two-cell system. Note that a single cell must have an adjacent cell to supply purified water during regeneration. Assume that a pair of cells can have a service life of 1.0 units of volume, for instance, for a two membrane system. This can limit the interval between membrane exchange to 1.0 units of volume. The combination of four cells has a total service life of approximately 1.95 units of volume, for instance, for a four membrane system. As an example, systems, devices and methods according to embodiments of the disclosed subject matter, for instance four membrane systems, can have a service interval between membrane exchange of 1.95 units of volume, or a 95% increase over two-cell systems.


The increased combined service life of the four membranes is possible because during stage two operation a membrane can be exhausted at 1/10th the rate of a single-stage system, and a membrane during stage three operation can be exhausted at 1/100th the rate of a single stage system.


In any of the embodiments, water may be received at the source at pressure such that the water is conveyed through the valve system using the pressure from the source. Alternatively any of the embodiments may be provided with a pump to convey water. Note that any of the above systems may be modified by the inclusion of an arbitrary number of cells. Each or any cell in the embodiments may be replaced by one or more separate cells arranged in series or parallel. The cells may include any type of filtration or purification device that is capable of being regenerated. The cells may include a purification element such as one or more filter membranes, plates such as in an electrostatic precipitator, depth loading medium, inertial separator elements, or any other type of purification element(s). The cells are also permanently exhausted after being subjected to multiple regeneration cycles. In any of the embodiments, instead of purifying water, other fluids may be purified and used for processing including non-aqueous solvents, fuels, food products, cleaning fluids, etc.


In any of the embodiments disclosed, the regeneration cycle may be triggered by a measured reduction in TDS or a threshold level of purity in the product stream which may be measured by a suitable sensor, for example, turbidity, conductivity or resistivity, pH, particle counting, optical diffusion, density, thermal conductivity temperature, or other property. The regeneration cycle may also be triggered by a predictive algorithm such as a measured volume of purified fluid having passed through since the last cycle or a predetermined time. A controller may be suitably configured to implement any of these criteria according to known techniques.


In any of the disclosed embodiments, the valves and flow channels may take a variety of different forms depending on the capacity and type of fluid. Examples of configurations are shown, but a variety of different configurations are possible.


According to embodiments, the disclosed subject matter includes a water purification system in which multiple cells are interconnected by a valving network, wherein each of the cells includes at least one purification element, for example, a membrane or other type of contaminant separator. A controller is configured to control the valves of the valving network and a source of water is connected to the valving network to provide water to be purified. The water may also be used for regenerating cells so the valving network includes a drain. A product water outlet is also provided. The controller is configured to, at a first time, generate a reverse flow of water through a first subset of the cells while simultaneously flowing water in a forward direction through two or more cells in a second subset, while connecting the two or more cells in the second in series. Thus the two or more cells of the series define a multiple stage purification component that provide purified water using a part of the valving network to conduct the water between the source and the product water outlet. The controller is further configured to direct a flow of water from the first subset of the cells to the drain while directing a flow from a last one of the two or more cells connected in series to a product water outlet. The cells in the first subset and the cells in the second subset are mutually exclusive, that is, the cell or cells being regenerated are not used, at the same time, for water purification, so the subsets are disjoint.


In variations of the previous embodiment, the controller may be further configured to, at a second time, generate a reverse flow of water through a third subset of the cells while simultaneously flowing water in a forward direction through two or more cells in a fourth subset, while connecting the two or more cells in the fourth subset in series. In this variation,


The cells in the third subset and the cells in the fourth subset may be mutually exclusive and wherein the cells in the first set and the third set may be mutually exclusive.


In the variations of the previous embodiments, the reverse flow of water may be effective to regenerate the cells. The cells may be electronic deionization cells. In further variations, the controller may be configured to apply a reverse voltage to the cells in the first and third subsets at said first and second times, respectively. At the first time, the reverse flow of water may be water from last cell of the second subset in the series of cells which may be thereby purified water. At the second time, the reverse flow of water may be water from last cell of the fourth subset in the series of cells which may be thereby purified water. The second and fourth subsets may be interconnected in series such as to produce a 99.9% reduction in total dissolved solids in the water received from the source by the valve network.


According to embodiments, the disclosed subject matter includes a water purification system with multiple cells interconnected by a valving network, wherein each of the cells has a membrane. For example, the cells may be EDI cells. The controller of the present embodiment is configured to, at regeneration times that can be selected by the controller, select each of the cells in turn to be a currently selected cell to be regenerated and to regenerate it by causing a reverse flow of water therethrough while simultaneously controlling the valves of the valve network to flow water from the source in series through the cells other than the currently selected cell to form a series of cells, the series of cells having a first cell which receives the water from the source and a final cell which provides purified water to the product water outlet. The water that reverse flows through the cell being regenerated can come from the cells being used for purification. The controller is configured such that, at each of said regeneration times, said each cell may be selected after it has been the first cell in the series of cells at a prior respective time.


The valve network in this and all the embodiments can have connectors by which the cells can be removed and replaced with new ones as they expire after multiple purification and regeneration cycles. The above operations may be repeated may times until the cells expire. This may be done under control of the controller automatically. The regeneration cycles may be triggered by time, or an event, for example, the cells may rotated and regenerated as described above whenever the reduction in TDS, for the full series of cells, (i.e., the reduction in TDS from the source water to the product water) falls below a predetermined level. The controller may also monitor how much purified water is produced and generate a display to replace the cells manually when, between points where the product water quality falls below the predetermined level, the amount of produced water falls below a predetermined volume.


The controller may be configured such that the final cell in the series, at a given regeneration time, may be the cell selected to be regenerated at the most recent previous regeneration time. Each of the cells in the series may be arranged in order of time since its last turn as the selected cell to be regenerated such that the most recently regenerated cell may be said final cell. The product water may be used in the reverse flow of water in any of the embodiments including the present one and the variations of it.


The series of cells may be selected and arranged in number and/or capacity, so that they are, collectively—in the series—effective to achieve a 99.9% reduction total dissolved solids. As mentioned, the cells can be, or include, electronic deionization (EDI) cells. The number of cells may be at least three in advantageous embodiments. The regeneration times may be selected by the controller responsively to a measurement of water quality at a point in said series. Each of the cells in the series may be arranged in order of time (or cumulative treated fluid volume) since its last turn as the selected cell to be regenerated such that the most recently regenerated cell may be said final cell.


To measure total fluid volume, for those embodiments in which the total cumulative volume is used for control, a flow meter may be used, for example, a rate meter or a displaced volume meter.


According to embodiments, the disclosed subject matter includes a fluid purification system with multiple cells interconnected by a valving network, wherein each of the cells has a purification element such as a filter membrane, an EDI membrane, a depth loading filter, an inertial separation filter, an electrostatic precipitator or some other kind of separation element (or a plurality thereof) that removes contaminants or other materials from a fluid stream. The controller is configured to, at regeneration times, select each of the cells in turn to be a currently selected cell to be regenerated and to regenerate it by causing a reverse flow of fluid therethrough while simultaneously controlling the valves of the valve network to flow fluid from the source in series through the cells other than the currently selected cell to form a series of cells, the series of cells having a first cell which receives the fluid from the source and a final cell which provides purified fluid to the product fluid outlet. The controller is configured such that, at each of said regeneration times, said each cell may be selected after it has been the first cell in the series of cells at a prior respective time.


In the embodiment of the last paragraph, the controller may be configured such that the final cell in the series, at a given regeneration time, may be the cell selected to be regenerated at the most recent previous regeneration time. Each of the cells in the series may be arranged in order of time since its last turn as the selected cell to be regenerated such that the most recently regenerated cell may be said final cell. Product fluid may be used in the reverse flow of fluid. The series of cells may be effective to achieve a 99.9% reduction total dissolved solids.


According to embodiments, the disclosed subject matter includes an installation for a fluid purification system that may be operable after the attachment of cells adapted for purifying fluid. This embodiment includes only the fluid handling circuit without the purification elements or cells. A fluid transport network has fluid channels, a controller, and valves are operable by the controller. The fluid transport network includes cell connectors adapted to receive cells adapted for purifying fluid and to direct forward and reverse flows through connected cells. The fluid transport network has connections for source fluid, purified product fluid, and waste fluid. The fluid transport network and controller are configured such that the controller operates the valves so that, at a first time, fluid may be directed from the source through connected first cells in a forward direction, in series, such that multiple purifications stages may be defined, the first cells forming a series with a first series cell being in a first position of the series and receiving the source fluid, a last series cell being in a last position of the series outputting product fluid, and intermediate series cells. The fluid transport network and controller are configured such that the controller operates the valves so that at said first time, fluid may be directed in a reverse direction through a connected second cell whereby simultaneous multi-stage purification and cell regeneration may be achieved The fluid transport network and controller are configured to operate the valves to rearrange the connected first cells and the second cell by replacing the last series cell with the second cell and replacing the second cell with the first series cell. The fluid transport network and controller are configured such that the controller operates the valves so that at said second time, fluid may be directed in a reverse direction through second cell, which was the first series cell at the first time. The rearrangement of cells in the series may be accomplished without disconnecting any of the cells from any of the respective cell connectors.


In the embodiment of the last paragraph, the controller may be configured to apply a reverse a voltage of the second cell and apply a forward voltage to the first cells. The fluid may be water. The fluid transport network may have water channels and the network is configured to connect to water and water purification cells. The connectors may be adapted for receiving electronic deionization cells. In a variation, the first cells, at the first time, may be at least three in number having the first series cell, the last series cell and intermediate cells ordered by rank in the series; and the intermediate cells, at the second time, may be moved forward in rank so that the first series cell may be replaced by the intermediate cell of a lowest rank. Cells may be connected to said cell connectors to form an embodiment in which the cells are part of the embodiment rather than a system adapted to receive the cells. In the embodiments with cells and without, the controller may be adapted to operate the valves such that each of the cells may be repositioned successively through the series, taking a turn at each rank at respective times and taking a turn as the second cell to be regenerated.


According to embodiments, the disclosed subject matter includes a method of purifying water, which includes flowing water from a source, serially, through a series of electronic deionization (EDI) cells in a forward direction through each cell of the series so that a first cell of the series if of a lowest rank of the series and the last cell of the series may be of a highest rank of the series. The flowing is performed by a controller by controlling automatic valves controlled by the controller. The method includes using the controller and the automatic valves, positioning a freshly-regenerated cell in place of a last cell of said series while repositioning the other cells in the series by moving each cell to a lower rank so that the second rank may be repositioned as the first cell of the series. The method further includes using the controller and the automatic valves, regenerating the last cell by flowing water therethrough in a reverse direction.


In variations of the method of the foregoing embodiment of the last paragraph, the method may include repeating the flowing using the cell regenerated in said regenerated in said regenerating. The method may also include repeating the positioning and the regenerating multiple times so that each cell takes more than one turn at each rank and may be regenerated substantially an equal number of times. each cell may contain more than one water purification module arranged in series or in parallel.


According to embodiments, the disclosed subject matter includes a method of purifying fluid that includes flowing fluid from a source, serially, through a series of cells in a forward direction through each cell of the series so that a first cell of the series if of a lowest rank of the series and the last cell of the series may be of a highest rank of the series. The cells are each adapted to purify fluid flowing therethrough. The flowing is performed by a controller by controlling automatic valves controlled by the controller. The method includes using the controller and the automatic valves, positioning a freshly-regenerated cell in place of a last cell of said series while repositioning the other cells in the series by moving each cell to a lower rank so that the second rank may be repositioned as the first cell of the series. The method includes using the controller and the automatic valves, regenerating the last cell by flowing fluid therethrough in a reverse direction.


The method of the last paragraph may include repeating the flowing using the cell regenerated in said regenerated in said regenerating. The method may include positioning and the regenerating multiple times so that each cell takes more than one turn at each rank and may be regenerated substantially an equal number of times. Each cell may contain more than one fluid purification module arranged in series or in parallel.


According to embodiments, the disclosed subject matter includes a method of purifying fluid including using a controller and a fluid management system, directing fluid through a series of cells to purify the fluid in multiple stages while regenerating at least another cell such that fluid can be purified continuously without interruption for the regenerating. The method includes using the controller and fluid management system, changing the flow paths of the fluid management system so that the directing and regenerating may be effective to subject each cell to an equal load so that each cell may be exhausted at the same time, after being subjected to multiple instances of said regenerating.


The changing the flow path may include flowing fluid in a reverse direction through a respective cell during said regenerating and flowing fluid in a forward direction through respective cells during said directing. The fluid may be water and the cells may be electronic deionization cells.


It will be appreciated that the modules, processes, systems, and sections described above can be implemented in hardware, hardware programmed by software, software instruction stored on a non-transitory computer readable medium or a combination of the above. For example, a method for purifying water or other fluids and form maintaining a purification system can be implemented, for example, using a processor configured to execute a sequence of programmed instructions stored on a non-transitory computer readable medium. For example, the processor can include, but not be limited to, a personal computer or workstation or other such computing system that includes a processor, microprocessor, microcontroller device, or is comprised of control logic including integrated circuits such as, for example, an Application Specific Integrated Circuit (ASIC). The instructions can be compiled from source code instructions provided in accordance with a programming language such as Java, C++, C#.net or the like. The instructions can also comprise code and data objects provided in accordance with, for example, the Visual Basic™ language, LabVIEW, or another structured or object-oriented programming language. The sequence of programmed instructions and data associated therewith can be stored in a non-transitory computer-readable medium such as a computer memory or storage device which may be any suitable memory apparatus, such as, but not limited to read-only memory (ROM), programmable read-only memory (PROM), electrically erasable programmable read-only memory (EEPROM), random-access memory (RAM), flash memory, disk drive and the like.


Furthermore, the modules, processes, systems, and sections can be implemented as a single processor or as a distributed processor. Further, it should be appreciated that the steps mentioned above may be performed on a single or distributed processor (single and/or multi-core). Also, the processes, modules, and sub-modules described in the various figures of and for embodiments above may be distributed across multiple computers or systems or may be co-located in a single processor or system. Exemplary structural embodiment alternatives suitable for implementing the modules, sections, systems, means, or processes described herein are provided below.


The modules, processors or systems described above can be implemented as a programmed general purpose computer, an electronic device programmed with microcode, a hard-wired analog logic circuit, software stored on a computer-readable medium or signal, an optical computing device, a networked system of electronic and/or optical devices, a special purpose computing device, an integrated circuit device, a semiconductor chip, and a software module or object stored on a computer-readable medium or signal, for example.


Embodiments of the method and system (or their sub-components or modules), may be implemented on a general-purpose computer, a special-purpose computer, a programmed microprocessor or microcontroller and peripheral integrated circuit element, an ASIC or other integrated circuit, a digital signal processor, a hardwired electronic or logic circuit such as a discrete element circuit, a programmed logic circuit such as a programmable logic device (PLD), programmable logic array (PLA), field-programmable gate array (FPGA), programmable array logic (PAL) device, or the like. In general, any process capable of implementing the functions or steps described herein can be used to implement embodiments of the method, system, or a computer program product (software program stored on a non-transitory computer readable medium).


Furthermore, embodiments of the disclosed method, system, and computer program product may be readily implemented, fully or partially, in software using, for example, object or object-oriented software development environments that provide portable source code that can be used on a variety of computer platforms. Alternatively, embodiments of the disclosed method, system, and computer program product can be implemented partially or fully in hardware using, for example, standard logic circuits or a very-large-scale integration (VLSI) design. Other hardware or software can be used to implement embodiments depending on the speed and/or efficiency requirements of the systems, the particular function, and/or particular software or hardware system, microprocessor, or microcomputer being utilized. Embodiments of the method, system, and computer program product can be implemented in hardware and/or software using any known or later developed systems or structures, devices and/or software by those of ordinary skill in the applicable art from the function description provided herein and with a general basic knowledge of control systems and/or computer programming arts.


Moreover, embodiments of the disclosed method, system, and computer program product can be implemented in software executed on a programmed general purpose computer, a special purpose computer, a microprocessor, or the like.


It is, thus, apparent that there is provided, in accordance with the present disclosure, systems, methods, and devices for purifying fluids. Many alternatives, modifications, and variations are enabled by the present disclosure. Features of the disclosed embodiments can be combined, rearranged, omitted, etc., within the scope of the invention to produce additional embodiments. Furthermore, certain features may sometimes be used to advantage without a corresponding use of other features. Accordingly, Applicants intend to embrace all such alternatives, modifications, equivalents, and variations that are within the spirit and scope of the present invention.

Claims
  • 1. A method of purifying water, comprising: flowing water from a source along a flow path defined by automatic valves through a plurality of electronic deionization cells in a series, each of the cells having an inlet that receives input water and an outlet that outputs filtered water when flow through the cell is in a forward direction, a first cell encountered by the water in the series having a lowest rank in the series, the rank increasing along the series, and a last cell encountered by the water in the series having a highest rank in the series; andperiodically changing a configuration of the flow path by controlling the automatic valves by a controller, whereina first portion of the water that has passed through all cells except the cell having the highest rank is collected as purified water,a second portion of said water that has passed through all cells except the cell having the highest rank flows through the cell having the highest rank in a reverse direction, opposite of the forward direction, to regenerate said cell having the highest rank, andsaid periodically changing the configuration of the flow path includes switching the automatic valves such that in a changed flow path configuration the cell having the lowest rank becomes the cell having the highest rank that receives water in the reverse direction and a rank of each other cell decrements to a next lower rank, respectively.
  • 2. The method of claim 1, further comprising: repeating the periodically changing the configuration.
  • 3. The method of claim 1, further comprising: repeating the flowing the water from the source and the periodically changing the configuration of the flow path multiple times so that each cell takes more than one turn at each rank and is regenerated substantially an equal number of times.
  • 4. The method of claim 3, wherein each cell contains more than one water purification module arranged in series or in parallel.
  • 5. A method of purifying fluid, comprising: using a controller and a fluid management system, directing the fluid serially through a plurality of cells, each cell of the plurality of cells having a single flow path through which said fluid flows and trapping impurities present in the fluid flowing along said single flow path to purify the fluid in multiple stages while regenerating at least one cell of the plurality of cells such that fluid is purified continuously by cells other than said one cell of the plurality of cells without interruption for the regenerating; andusing the controller and fluid management system, changing flow paths of the fluid management system so that the directing and regenerating are effective to subject each cell of the plurality of cells to an equal filtering load so that each cell is exhausted at the same time, after being subjected to multiple instances of said regenerating, wherein the fluid is water and the cells are electronic deionization cells.
  • 6. The method of claim 5, wherein the changing of the flow paths includes flowing fluid in a reverse direction through a respective cell during said regenerating and flowing fluid in a forward direction through respective cells during said directing.
CROSS REFERENCE TO RELATED APPLICATIONS

This application is a continuation of U.S. patent application No. 15/187,689 filed Jun. 20, 2016, which is a continuation application of U.S. patent application No. 13/713,767 filed Dec. 13, 2012, which claims the benefit of U.S. Provisional Application No. 61/570,108 filed Dec. 13, 2011, all of which are hereby incorporated by reference in their entirety herein.

US Referenced Citations (209)
Number Name Date Kind
2788319 Pearson Apr 1957 A
2860095 Katz et al. Nov 1958 A
2995334 Henderson et al. Aug 1961 A
3034085 Pauler et al. May 1962 A
3100486 Nehring Aug 1963 A
3103335 Martinez Sep 1963 A
3252124 Hansen May 1966 A
3579441 Brown May 1971 A
3709365 Czaplinski et al. Jan 1973 A
3786810 Pannier et al. Jan 1974 A
3926797 Gigou et al. Dec 1975 A
4059512 Harris Nov 1977 A
4144884 Tersteegen et al. Mar 1979 A
4202332 Tersteegen et al. May 1980 A
4246101 Selby, III Jan 1981 A
4370983 Lichtenstein Feb 1983 A
4432765 Oscarsson Feb 1984 A
4495067 Klein et al. Jan 1985 A
4564132 Lloyd-Davies Jan 1986 A
4596550 Troutner Jun 1986 A
4623450 Vantard et al. Nov 1986 A
4626240 Edelman et al. Dec 1986 A
4643389 Elson et al. Feb 1987 A
4661246 Ash Apr 1987 A
4698153 Matsuzaki et al. Oct 1987 A
4711715 Polaschegg Dec 1987 A
4753371 Michielin et al. Jun 1988 A
4784495 Jonsson et al. Nov 1988 A
4804474 Blum Feb 1989 A
4810388 Trasen Mar 1989 A
5032265 Jha et al. Jul 1991 A
5079236 Drizen et al. Jan 1992 A
5102399 Chu Apr 1992 A
5139483 Ryan Aug 1992 A
5141493 Jacobsen et al. Aug 1992 A
5194157 Ghezzi et al. Mar 1993 A
5221483 Glenn et al. Jun 1993 A
5259954 Taylor Nov 1993 A
5308333 Skakoon May 1994 A
5352364 Kruger et al. Oct 1994 A
5368555 Sussman et al. Nov 1994 A
5423768 Folden et al. Jun 1995 A
5484397 Twardowski Jan 1996 A
5484431 Scharf et al. Jan 1996 A
5498338 Kruger et al. Mar 1996 A
5536412 Ash Jul 1996 A
5578181 Hirose et al. Nov 1996 A
5591344 Kenley et al. Jan 1997 A
5622626 Matkovich et al. Apr 1997 A
5645734 Kenley et al. Jul 1997 A
5662642 Isono et al. Sep 1997 A
5690831 Kenley et al. Nov 1997 A
5702597 Chevallet et al. Dec 1997 A
5707038 Cocatre-Zilgien Jan 1998 A
5725776 Kenley et al. Mar 1998 A
5779905 Morandi et al. Jul 1998 A
5782762 Vining Jul 1998 A
5783072 Kenley et al. Jul 1998 A
5910252 Truitt et al. Jun 1999 A
5919357 Wilkins et al. Jul 1999 A
5951859 Miura et al. Sep 1999 A
5951863 Kruger et al. Sep 1999 A
5972225 Karras et al. Oct 1999 A
6017433 Mani Jan 2000 A
6039877 Chevallet et al. Mar 2000 A
6044691 Kenley et al. Apr 2000 A
6083670 Sugawara et al. Jul 2000 A
6106723 Grandics et al. Aug 2000 A
6132616 Twardowski et al. Oct 2000 A
6136201 Shah et al. Oct 2000 A
6146536 Twardowski Nov 2000 A
6187207 Brauer Feb 2001 B1
6200466 Bender Mar 2001 B1
6254567 Treu et al. Jul 2001 B1
6284142 Muller Sep 2001 B1
6287516 Matson et al. Sep 2001 B1
6331252 El Sayyid et al. Dec 2001 B1
6428518 Brengle et al. Aug 2002 B1
6475385 Boyce et al. Nov 2002 B1
6485649 Terava et al. Nov 2002 B1
6492320 Guo et al. Dec 2002 B2
6561997 Weitzel et al. May 2003 B1
6572576 Brugger et al. Jun 2003 B2
6579253 Burbank et al. Jun 2003 B1
6582385 Burbank et al. Jun 2003 B2
6589482 Burbank et al. Jul 2003 B1
6595943 Burbank Jul 2003 B1
6607697 Muller Aug 2003 B1
6626857 Ohta et al. Sep 2003 B1
6638477 Treu et al. Oct 2003 B1
6638478 Treu et al. Oct 2003 B1
6649063 Brugger et al. Nov 2003 B2
6656423 Joslyn Dec 2003 B1
6679988 Gsell Jan 2004 B2
6691058 Blakley Feb 2004 B2
6726914 Aoki Apr 2004 B2
6730266 Matson et al. May 2004 B2
6743193 Brugger et al. Jun 2004 B2
6745903 Grandics Jun 2004 B2
6814724 Taylor Nov 2004 B2
6818133 Wolter et al. Nov 2004 B1
6830553 Burbank et al. Dec 2004 B1
6852090 Burbank et al. Feb 2005 B2
6855122 Ohta et al. Feb 2005 B1
6908546 Smith Jun 2005 B2
6942634 Odland Sep 2005 B2
6955655 Burbank et al. Oct 2005 B2
6962575 Tal Nov 2005 B2
6982038 Dolecek et al. Jan 2006 B2
7059206 Kingston et al. Jun 2006 B1
7108790 Collins et al. Sep 2006 B2
7214312 Brugger et al. May 2007 B2
7226538 Brugger et al. Jun 2007 B2
7314569 C et al. Jan 2008 B2
7322969 Hattori et al. Jan 2008 B2
7353634 Grott Apr 2008 B2
7410473 Levin et al. Aug 2008 B2
7419597 Brugger et al. Sep 2008 B2
7473238 Brugger et al. Jan 2009 B2
7544300 Brugger et al. Jun 2009 B2
7622044 Grott Nov 2009 B2
7718065 Jordan May 2010 B2
7842002 Mantle Nov 2010 B2
7875183 Bradwell et al. Jan 2011 B2
7967984 Midorikawa et al. Jun 2011 B2
8070707 Gelfand et al. Dec 2011 B2
8092684 Leonard et al. Jan 2012 B2
8142633 Batchelder et al. Mar 2012 B2
8147696 Pandya Apr 2012 B1
8281937 Collins et al. Oct 2012 B2
8366883 Bednarek et al. Feb 2013 B2
8501009 Peterson et al. Aug 2013 B2
8524086 Peterson et al. Sep 2013 B2
8535525 Heyes et al. Sep 2013 B2
8603021 Levin et al. Dec 2013 B2
8685251 Smejtek et al. Apr 2014 B2
20010016699 Burbank et al. Aug 2001 A1
20010021817 Brugger et al. Sep 2001 A1
20010037079 Burbank et al. Nov 2001 A1
20010039441 Ash Nov 2001 A1
20010048909 Taylor Dec 2001 A1
20020084188 Tran et al. Jul 2002 A1
20020085952 Ellingboe et al. Jul 2002 A1
20020104800 Collins et al. Aug 2002 A1
20020120227 Childers et al. Aug 2002 A1
20020121471 Pedrazzi Sep 2002 A1
20020167322 He et al. Nov 2002 A1
20020190000 Baurmeister Dec 2002 A1
20030010701 Collins et al. Jan 2003 A1
20030010717 Brugger et al. Jan 2003 A1
20030010719 Brugger et al. Jan 2003 A1
20030042201 Sizelove et al. Mar 2003 A1
20030051767 Coccaro et al. Mar 2003 A1
20030080140 Neas et al. May 2003 A1
20030105435 Taylor Jun 2003 A1
20030130606 Tuck Jul 2003 A1
20030148017 Tuominen et al. Aug 2003 A1
20030168389 Astle et al. Sep 2003 A1
20030173297 Grandics Sep 2003 A1
20030236481 Burbank Dec 2003 A1
20040045881 Collins et al. Mar 2004 A1
20040060866 Radunsky et al. Apr 2004 A1
20040068219 Summerton et al. Apr 2004 A1
20040069709 Brugger et al. Apr 2004 A1
20040089594 Collins et al. May 2004 A1
20040186415 Burbank et al. Sep 2004 A1
20040217057 Rovatti Nov 2004 A1
20040221643 Ehwald et al. Nov 2004 A1
20040222139 Brugger et al. Nov 2004 A1
20040232079 Taylor et al. Nov 2004 A1
20050029192 Arnold Feb 2005 A1
20050045548 Brugger et al. Mar 2005 A1
20050061743 Buttner Mar 2005 A1
20050067341 Green Mar 2005 A1
20050103622 Jha May 2005 A1
20050103717 Jha May 2005 A1
20050171501 Kelly Aug 2005 A1
20050209547 Burbank et al. Sep 2005 A1
20050215975 Mathias et al. Sep 2005 A1
20050242032 Sugito et al. Nov 2005 A1
20060021944 Carson et al. Feb 2006 A1
20060231495 Freydina et al. Oct 2006 A1
20070007208 Brugger et al. Jan 2007 A1
20070038191 Burbank et al. Feb 2007 A1
20070158267 Micheli Jul 2007 A1
20070179422 Schnell et al. Aug 2007 A1
20070215474 Batchelder et al. Sep 2007 A1
20070248489 Taylor et al. Oct 2007 A1
20070260168 Brugger et al. Nov 2007 A1
20080053905 Brugger et al. Mar 2008 A9
20080173574 Silveri Jul 2008 A1
20080185294 Cai et al. Aug 2008 A1
20080203023 Burbank et al. Aug 2008 A1
20080210606 Burbank Sep 2008 A1
20080221218 Nelissen et al. Sep 2008 A1
20080223795 Bakajin et al. Sep 2008 A1
20080230450 Burbank et al. Sep 2008 A1
20090127194 Joo May 2009 A1
20100004590 Hedmann et al. Jan 2010 A1
20100051544 Berg Mar 2010 A1
20100051546 Vuong et al. Mar 2010 A1
20100191377 Smith et al. Jul 2010 A1
20100204765 Hall et al. Aug 2010 A1
20110186521 Burbank et al. Aug 2011 A1
20110315632 Freije, III Dec 2011 A1
20120006670 Kamen et al. Jan 2012 A1
20120261315 Collins et al. Oct 2012 A1
20130126430 Kenley et al. May 2013 A1
20130206574 Kamen et al. Aug 2013 A1
Foreign Referenced Citations (27)
Number Date Country
8305713 Dec 1985 DE
19704564 Aug 1998 DE
1891999 Feb 2008 EP
2221102 Aug 2010 EP
2505559 Oct 2012 EP
2514723 Oct 2012 EP
2135598 Sep 1984 GB
2003175101 Jun 2003 JP
2004000583 Jan 2004 JP
1996036370 Nov 1996 WO
1996037440 Nov 1996 WO
1999056696 Nov 1999 WO
2002032476 Apr 2002 WO
2003006100 Jan 2003 WO
2003006139 Jan 2003 WO
2003103533 Dec 2003 WO
2002095675 Feb 2004 WO
2004062710 Jul 2004 WO
2004080282 Sep 2004 WO
2004084972 Oct 2004 WO
2004066121 Mar 2005 WO
2005068043 Jul 2005 WO
2005092397 Oct 2005 WO
2006074429 Jul 2006 WO
2007118235 Oct 2007 WO
2008156795 Dec 2008 WO
2009112816 Sep 2009 WO
Related Publications (1)
Number Date Country
20160340214 A1 Nov 2016 US
Provisional Applications (1)
Number Date Country
61570108 Dec 2011 US
Continuations (2)
Number Date Country
Parent 15187689 Jun 2016 US
Child 15214438 US
Parent 13713767 Dec 2012 US
Child 15187689 US