The present application claims the benefit of British Patent Application No. GB 0721107.1 filed Oct. 27, 2007, and the benefit of PCT International Application No. PCT/GB2008/051003 filed Oct. 27, 2008, both of which are incorporated herein by reference for all purposes.
The present invention relates to a device for use in the treatment of fluid, and relates particularly but not exclusively, to a device used in the treatment of compressed air.
The adsorbent beads become saturated with impurity molecules after a certain amount of air has passed over them in that they are no longer able to adsorb impurity molecules. In order to continue to effectively treat air, the adsorbent properties of the beads need to be regenerated by removing previously adsorbed impurity molecules. This is achieved by pumping treated air at near atmospheric pressure back through a column containing beads to be regenerated. The treated air removes impurity molecules from the surfaces of such beads.
The apparatus illustrated in
The apparatus illustrated in
A problem with the apparatus illustrated in
Furthermore, existing ‘packed bed’ desiccant devices also suffer from settlement of the beads and attrition which includes the blocking of downstream valves due to dust being produced by breakdown of the beads as they rub against each other. Channelling where gaps open up in the bed and by-pass where settling of the beads means that they must be operated vertically which limits their flexibility in use. Hot spots and deterioration of adsorption performance due to poor heat loss from the bed lead to poor drying performance and higher than necessary energy consumption.
Preferred embodiments of the present invention seek to overcome the above disadvantages of the prior art.
According to the present invention there is provided, a fluid treatment device comprising:—
a vessel having access means for allowing a fluid to enter and leave the vessel; and
at least one element having at least one aperture extending at least partially into the element wherein the element is formed from at least one porous material adapted to adsorb at least one impurity from said fluid.
By providing an element having at least one aperture extending at least partially into the element allows an increased surface area of adsorbent material to contact fluid as it flows through the device providing the advantage of treating air faster and more effectively than when simply pumping air through a column containing a plurality of desiccant adsorbent beads. This also decreases the drop in compressed air pressure across the vessel. Furthermore, the use of hollow fibres decreases problems such as settling of beads that leads to the rubbing of beads against each other causing them to break down. Thus problems of damage to downstream apparatus such as valves are reduced. This also allows the device to be used in any orientation and not just vertically as seen in bead columns of the prior art.
In a preferred embodiment the fluid treatment device further comprises sealing means wherein the sealing means and the or each element define a plurality of volumes within the vessel.
By providing more than one volume inside the vessel provides that advantage of allowing air to be forced from one volume into another through the pores of the porous material forming the element (typically a hollow fibre) when there is a pressure differential between any two volumes. This allows purging of the device without the need to pump in treated air from an external source in that air which has passed through the hollow fibres may be used to purge the porous material comprising that same element if it is made to pass back through it when the pressure in one of the volumes is reduced. As a result the volume of purge air used is significantly reduced and can in some circumstances be completely eliminated.
In another preferred embodiment the sealing means and the or each element define at least one volume which is only in communication with the access means through pores in the porous material.
By having one volume that is not in communication with the access means, the advantage is provided that where a hollow fibre is used all of the air that is being treated can be directed up the centre of the column. This has the advantage that it is generally the case that the pores at the centre of the fibre are larger making it easier for the impurities to be adsorbed. This also has the advantage that the vast majority of the adsorption of impurities takes place towards the inner surface of the fibre. Therefore when purge air passes through the fibre (from the second volume that is not in communication with the access means, that is from the outer surface of the hollow fibre to the inner surface) the process of desorption only needs to take place over a short distance adjacent the inner surface.
In a further preferred embodiment the aperture in the element extends through the element.
In a preferred embodiment the aperture in the element does not extend through the element.
By providing an element comprising an aperture that does not extent through its entire length, all air must pass through the pores of the porous material comprising that element which can be made to act as a filter in addition to a drying means. This provides the advantage that air which passes through the porous material of such an element is both free from particulate and molecular impurities.
In another preferred embodiment the fluid treatment device further comprises at least one heating element engaged with at least one element.
By providing a heating element in engagement with an element this provides the advantage that air is heated as it passes through the porous material of that element increasing the ability of such air to carry the water and provides rapid evaporation of water making it easier for water molecules to be removed from the porous material during the purging step. As a result the porous material is more effectively regenerated.
In a further preferred embodiment the device further comprises at least one filter placed within the vessel.
By providing at least one filter in the vessel of the air treatment device, this provides the advantage that the air which passes through the filter is both free from particulate and molecular impurities.
In a preferred embodiment the treatment device comprises at least one fluid input portion and at least one fluid output portion.
In another preferred embodiment the porous material is a nano porous material.
According to another aspect of the present invention there is provided a method of removing impurities from a fluid comprising the steps of:
pumping at least one fluid into an inlet of a vessel and out of at least one outlet of said vessel, the vessel having at least one first and at least one second volume separated by at least one element formed of porous material adapted to adsorb at least one impurity from said fluid, wherein pumping fluid through said vessel increases the pressure of the fluid in the or each first and second volume;
closing a valve adjacent said outlet thereby preventing said fluid flowing out of said outlet; and
exposing said inlet to lower pressure thereby allowing fluid in said first and second volumes to pass through said inlet.
In a preferred method said fluid in said vessel is only able to transfer between said first and second volumes by flowing through the pores in said element.
In another preferred method said fluid is pumped into at least one aperture extending at least partially into said element.
In a further preferred method said element is heated.
In a preferred method said fluid is pumped through at least one filter placed within said vessel.
In another preferred method said porous material is a nano-porous material.
Preferred embodiments of the invention will now be described, by way of example only and not in any (imitative sense, with reference to the accompanying drawings in which:—
With reference to
Potting resin provides seals 214 and 216 which are adapted to engage the inner wall of the vessel and heating element or the outer wall of the hollow column of porous material so as to define two volumes. A first defined volume 218 is only in communication with the apertures 202 and 204 of the vessel through the pores in porous material 206. In contrast a second defined volume 220 is freely in communication with the aperture 202 and 204 since it constitutes the space within the aperture of the hollow column of porous material which communicates with both apertures of the vessel. Air is able to pass through the porous material forming the hollow column and may thus transfer between the two volumes.
The operation of the air treatment device shown in
When wet air comes into contact with the nano porous material on the internal surface of the hollow column, water molecules in the air become adsorbed by the porous material and are removed from the flow of air. The further that air propagates through aperture 208 along axis 210 the more time wet air has to contact the surface of nano porous material. This ensures that the further that air travels along the aperture the smaller the number of water molecules there is in such air. Air is pumped through the aperture in the hollow column of porous material and out of the second aperture 204 in the vessel. Air pumped out of the vessel into the auxiliary component contains significantly less water molecules than air initially pumped in.
It is to be noted that, before air is pumped into the vessel, both the first volume 218 and second volume 220 are at the same pressure. However, as air is pumped into the vessel, the pressure of air in the second volume initially increases at a higher rate than the pressure of air in the first volume, thus creating a pressure differential between the two volumes. In order to equalise the pressure between the two volumes air is made to pass through the porous material of the hollow column from the second defined volume to the first. As air passes through the porous material a significant fraction of the water molecules in such air are adsorbed such that the air passing into the first volume effectively constitutes a reservoir of dry air.
At a point in time before the porous material becomes saturated with water molecules and is unable to remove a desired amount of water molecules from wet air pumped into the vessel, the porous material needs to be regenerated by purging as illustrated in
When both apertures of the vessel remain sealed the pressure is equal in both of the defined volumes within the vessel. If the first aperture is then opened, air exits out of the second volume through the first aperture and into a region of lower air pressure thus reducing the air pressure in the second volume. This again produces a pressure differential between the first and second volumes. To equalise the air pressure between the two volumes, dry air is forced from within the first volume through the porous material of the hollow column into the second volume. As dry air passes through the porous material, water molecules that had previously been adsorbed by the porous material are removed from the porous material so as to once again constitute an impurity fraction in the air flow. This water molecule containing air is further forced from the vessel and into the region of lower air pressure. A small volume of dry air, from another source, may be blown down the aperture 208 to assist this purging process. Heating element 212 may be used to heat the porous material constituting the hollow fibre. This heats the air as it passes through the porous material increasing its ability to carry the water and provides rapid evaporation of water making it easier for water molecules to be removed from the porous material during the purging step. As a result the porous material is more effectively regenerated.
The vessel may once again be connected to a source of wet air to be dried and is re-pressurised before the above process repeated in that the adsorbent properties of the porous material are regenerated by the self purging step.
A second embodiment of the invention is illustrated in
The operation of the air treatment device illustrated in
Wet air is pumped into the first aperture of the vessel and is directed by the seal into aperture 308 of the hollow column of porous material 306. As air is pumped into the vessel the air pressure in the first volume 324 initially becomes greater than the air pressure in the second volume 326 such that there exists a pressure differential between the two defined volumes on either side of the porous material constituting the hollow column. In order to equalise the pressure between the two defined volumes air passes through the porous material from the first volume and into the second. As wet air comes into contact with the porous material water molecules become adsorbed by the porous material and are thus removed from the air flow such that the air transferred to the second volume contains a significantly reduced number of water molecules. Such dry air is then pumped out of the vessel through the second aperture 304 to an auxiliary component.
Once the porous material becomes nearly saturated with impurity molecules and is unable to sufficiently dry wet air pumped into the vessel, the porous material needs to be regenerated by a purging step as illustrated in
The dry air residing in the second volume within the sealed vessel constitutes a dry air reservoir which is used to purge the porous material. With both apertures of the vessel sealed the air pressure in both defined volumes within the vessel on either side of the porous material is equal. However when the first aperture of the vessel is opened, the air in the first volume is forced through the first aperture and out of the vessel into a region of lower pressure. This once again produces a pressure differential between the two defined volumes within the vessel wherein the dry air in the second volume is now at a higher pressure than air in the first. This ensures that air in the second volume passes back through the porous material constituting the hollow column wherein doing so water molecules that had previously been adsorbed by the porous material are removed from such porous material so as to once again constitute an impurity fraction in the air flow. The water molecule containing air is further forced from the vessel and into the region of lower pressure. Heating element 312 heats the air as it passes through the porous material increasing its ability to carry water and provides rapid evaporation of water making it easier for water molecules to be removed from the porous material during the purging step. As a result the porous material is more effectively regenerated.
The vessel may once again be connected to a source of wet air to be dried and is re-pressurised before the above process repeated in that the adsorbent properties of the porous material are regenerated by the self purging step.
A third embodiment of the invention is illustrated in
The operation of the air treatment device illustrated in
Wet air is pumped into the first aperture of the vessel and due to the presence of seal 414 the air pressure in the first volume 424 initially becomes greater than the air pressure in the second volume 426 such that there exists a pressure differential between the two defined volumes on either side of the porous material forming the hollow column. In order to equalise the pressure between the two defined volumes air passes through the porous material from the first volume and into the second. As wet air comes into contact with the porous material water molecules become adsorbed by the porous material and are thus removed from the air flow such that the air transferred to the second volume contains a significantly reduced number of water molecules. Such dry air is then pumped out of the vessel through the second aperture 404 to an auxiliary component.
Once the porous material becomes nearly saturated with impurity molecules and is unable to sufficiently dry wet air pumped into the vessel, the porous material needs to be regenerated by a purging step as illustrated in
The dry air residing in the second volume within the sealed vessel constitutes a dry air reservoir which is used to purge the porous material. With both apertures of the vessel sealed the air pressure in both defined volumes within the vessel on either side of the porous material is equal. However when the first aperture of the vessel is opened, the air in the first volume is forced through the first aperture and out of the vessel into a region of lower pressure. This once again produces a pressure differential between the two defined volumes within the vessel wherein the dry air in the second volume is now at a higher pressure than air in the first. This ensures that air in the second volume passes back through the porous material forming the hollow column wherein doing so water molecules that had previously been adsorbed by the porous material are removed from such porous material so as to once again constitute an impurity fraction in the air flow. Such water molecule containing air is further forced from the vessel and into the region of lower pressure. Heating element 412 may be used to heat the porous material forming the hollow fibre. This heats the air as it passes through the porous material increasing its ability to carry water and provides rapid evaporation of water making it easier for water molecules to be removed from the porous material during the purging step. As a result the porous material is more effectively regenerated.
The vessel may once again be connected to a source of wet air to be dried and is re-pressurised and the above process repeated in that the adsorbent properties of the porous material are regenerated by the self purging step.
The embodiments of the invention discussed above have been described through the use of a single hollow fibre. It must be noted that when any of the embodiments of the invention are used in practice, more than one hollow fibre may be utilised as illustrated in
Other impurities in air may consist of oils or particulate solids. A further aspect of the present invention is a regenerative filter to remove such impurities from air.
Air treatment device 500 in
The vessel may then once again be connected to a source of air to be treated and the above process repeated in that the adsorbent properties of porous material constituting the hollow fibre bundles are regenerated by the self purging step.
A second device incorporating a regenerative filter is illustrated in
An illustration of an air treatment device according to any of the embodiments previously discussed is illustrated in
Air treatment devices according to any of the embodiments discussed may be used in any combination with one another wherein an example of such a combination is illustrated in
Column 702 initially operates in a drying stage in that air is pumped into column 702 from a source of air requiring treatment wherein treated air is then pumped out column 702. Column 704 is initially depressurised wherein such a depressurisation step involves self purging as air is forced out of the column. After depressurisation, column 704 is re-pressurised before the cycle repeats itself but for the opposite column in that column 704 operates in a drying stage and column 702 is depressurised resulting in self purging of column 702.
In comparison to the prior art apparatus illustrated in
It will be appreciated by persons skilled in the art that the above embodiments have been described by way of example only and not in any limitative sense, and that various alterations and modifications are possible without departure from the scope of the invention as defined by the appended claims. For example, all of the embodiments of the air treatment device disclosed in this application can be adapted and used to remove impurities from other fluids. Furthermore, the heating element could be located on the inside of the aperture 408. This would be of particular use in the embodiment shown in
Number | Date | Country | Kind |
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0721107.1 | Oct 2007 | GB | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/GB2008/051003 | 10/27/2008 | WO | 00 | 4/26/2010 |
Publishing Document | Publishing Date | Country | Kind |
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WO2009/053760 | 4/30/2009 | WO | A |
Number | Name | Date | Kind |
---|---|---|---|
2379321 | Sutcliffe et al. | Jun 1945 | A |
4919695 | Trepaud | Apr 1990 | A |
5108464 | Friesen et al. | Apr 1992 | A |
6126724 | Martin et al. | Oct 2000 | A |
20030205130 | Neu et al. | Nov 2003 | A1 |
Number | Date | Country |
---|---|---|
397 128 | Aug 1933 | GB |
08 084907 | Apr 1996 | JP |
Entry |
---|
The International Search Report and Written Opinion as mailed on Jan. 27, 2009 for International Application No. PCT/GB2008/051003. |
Number | Date | Country | |
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20100251891 A1 | Oct 2010 | US |