The present disclosure relates to aerosol delivery devices such as smoking articles, and more particularly to aerosol delivery devices that may utilize electrically generated heat for the production of aerosol (e.g., smoking articles commonly referred to as electronic cigarettes). The smoking articles may be configured to heat an aerosol precursor, which may incorporate materials that may be made or derived from, or otherwise incorporate tobacco, the precursor being capable of forming an inhalable substance for human consumption.
Many smoking devices have been proposed through the years as improvements upon, or alternatives to, smoking products that require combusting tobacco for use. Many of those devices purportedly have been designed to provide the sensations associated with cigarette, cigar or pipe smoking, but without delivering considerable quantities of incomplete combustion and pyrolysis products that result from the burning of tobacco. To this end, there have been proposed numerous smoking products, flavor generators and medicinal inhalers that utilize electrical energy to vaporize or heat a volatile material, or attempt to provide the sensations of cigarette, cigar or pipe smoking without burning tobacco to a significant degree. See, for example, the various alternative smoking articles, aerosol delivery devices and heat generating sources set forth in the background art described in U.S. Pat. Nos. 7,726,320 to Robinson et al. and 8,881,737 to Collett et al., which are incorporated herein by reference. See also, for example, the various types of smoking articles, aerosol delivery devices and electrically-powered heat generating sources referenced by brand name and commercial source in U.S. Pat. Pub. No. 2015/0212232 to Bless et al., which is incorporated herein by reference. Additionally, various types of electrically powered aerosol and vapor delivery devices also have been proposed in U.S. Pat. Pub. Nos. 2014/0096781 to Sears et al. and 2014/0283859 to Minskoff et al., as well as U.S. patent application Ser. Nos. 14/282,768 to Sears et al., filed May 20, 2014; 14/286,552 to Brinkley et al., filed May 23, 2014; 14/327,776 to Ampolini et al., filed Jul. 10, 2014; and 14/465,167 to Worm et al., filed Aug. 21, 2014; all of which are incorporated herein by reference.
It would be desirable to provide functionality for control of a microfluidic system of an aerosol delivery device.
The present disclosure relates to aerosol delivery devices, methods of forming such devices, and elements of such devices. The present disclosure includes, without limitation, the following example implementations. In some example implementations, an aerosol delivery device is provided and comprises a housing defining a reservoir configured to retain aerosol precursor composition. Contained within the housing is a heating element controllable to activate and vaporize components of the aerosol precursor composition, a valve configured to control a flow of aerosol precursor composition from the reservoir to the heating element, a sensor configured to measure a reflectance or temperature of the heating element and generate a corresponding signal, and a control component. The control component is configured to receive the corresponding signal and determine a volume of aerosol precursor composition at the heating element based on the reflectance or temperature so measured. The control component is also configured to control the valve to decrease or increase a rate of the flow of aerosol precursor composition in response to the volume being respectively above or below a predetermined threshold volume.
In some example implementations of the aerosol delivery device of the preceding or any subsequent example implementation, or any combination thereof, the sensor is or includes an optical liquid-level sensor configured to measure the reflectance of light at the heating element, and the control component is configured to determine the volume of aerosol precursor composition based on the reflectance of light so measured.
In some example implementations of the aerosol delivery device of any preceding or any subsequent example implementation, or any combination thereof, the sensor is or includes a temperature sensor configured to measure the temperature of the heating element, and the control component is configured to determine the volume of aerosol precursor composition based on the temperature so measured.
In some example implementations of the aerosol delivery device of any preceding or any subsequent example implementation, or any combination thereof, the valve is or includes a single-phase induction motor having a motor speed that is variable and proportional to the rate of the flow of aerosol precursor composition, and the control component being configured to control the valve includes being configured to control the valve to respectively decrease or increase the motor speed and thereby the rate.
In some example implementations of the aerosol delivery device of any preceding or any subsequent example implementation, or any combination thereof, the predetermined threshold volume includes first and second threshold volumes, and the control component being configured to control the valve includes being configured to control the valve to decrease or increase the rate of the flow of aerosol precursor composition in response to the volume being respectively above the first threshold volume or below the second threshold volume.
In some example implementations of the aerosol delivery device of any preceding or any subsequent example implementation, or any combination thereof, the first and second threshold volumes are respectively 100 milliliters (mL) and 10 mL, and the control component being configured to control the valve to decrease or increase the rate includes being configured to control the valve to incrementally decrease or increase the rate until respectively the flow of aerosol precursor composition stops or the volume is greater than 100 mL.
In some example implementations of the aerosol delivery device of any preceding or any subsequent example implementation, or any combination thereof, the control component being configured to control the valve includes being configured to control the valve only in instances in which a flow of liquid through at least a portion of the housing is detected, and the aerosol delivery device further comprises a pressure sensor configured to measure a pressure of the flow of liquid and generate a second corresponding signal, and the control component is configured to receive the second corresponding signal and control the valve to further decrease or increase the rate of the flow of aerosol precursor composition in proportion to the pressure so measured.
In some example implementations of the aerosol delivery device of any preceding or any subsequent example implementation, or any combination thereof, the control component being configured to control the valve includes being configured to control the valve only in instances in which a flow of liquid through at least a portion of the housing is detected, and the aerosol delivery device further comprises pressure and humidity sensors configured to measure a pressure of the flow of liquid, a volumetric pressure, and a humidity of an environment of the aerosol delivery device, and generate second corresponding signals. The control component being configured to receive the corresponding signal further includes being configured to receive the second corresponding signals. The control component being configured to determine the volume of the aerosol precursor composition further includes being configured to determine an optimal rate of the flow of aerosol precursor composition based on the volume of the aerosol precursor composition so determined, and the pressure of the flow of liquid, the volumetric pressure and the humidity so measured. The control component being configured to control the valve to includes being configured to control the valve to decrease or increase the rate to match the optimal rate so determined.
In some example implementations of the aerosol delivery device of any preceding or any subsequent example implementation, or any combination thereof, the aerosol delivery device further comprises a liquid-flow sensor configured to measure the rate of the flow of aerosol precursor composition to the heating element, and a display controllable to present the rate so measured.
In some example implementations of the aerosol delivery device of any preceding or any subsequent example implementation, or any combination thereof, the reservoir is a refillable reservoir, and the aerosol delivery device further comprises a liquid-level sensor configured to measure a volume of the aerosol precursor composition within the refillable reservoir and generate a second corresponding signal, and a communication interface configured to enable wireless communication of the second corresponding signal or another signal that conveys the volume of the aerosol precursor composition within the refillable reservoir so measured to a remote ordering system configured to automatically order a container for refilling the reservoir in response to the volume being below a second predetermined threshold.
In some example implementations, a control body coupled or coupleable with a cartridge to form an aerosol delivery device is provided. The cartridge defines a reservoir configured to retain aerosol precursor composition, and is equipped with a heating element controllable to activate and vaporize components of the aerosol precursor composition and a valve configured to control a flow of aerosol precursor composition from the reservoir to the heating element. The control body comprises a housing and, within the housing, a sensor configured to measure a reflectance or temperature of the heating element and generate a corresponding signal, and a control component. The control component is configured to receive the corresponding signal and determine a volume of aerosol precursor composition at the heating element based on the reflectance or temperature so measured. The control component being configured to control the valve to decrease or increase a rate of the flow of aerosol precursor composition in response to the volume being respectively above or below a predetermined threshold volume.
In some example implementations of the control body of the preceding or any subsequent example implementation, or any combination thereof, the sensor is or includes an optical liquid-level sensor configured to measure the reflectance of light at the heating element, and the control component is configured to determine the volume of aerosol precursor composition based on the reflectance of light so measured.
In some example implementations of the control body of any preceding or any subsequent example implementation, or any combination thereof, the sensor is or includes a temperature sensor configured to measure the temperature of the heating element, and the control component is configured to determine the volume of aerosol precursor composition based on the temperature so measured.
In some example implementations of the control body of any preceding or any subsequent example implementation, or any combination thereof, the valve is or includes a single-phase induction motor having a motor speed that is variable and proportional to the rate of the flow of aerosol precursor composition, and the control component being configured to control the valve includes being configured to control the valve to respectively decrease or increase the motor speed and thereby the rate.
In some example implementations of the control body of any preceding or any subsequent example implementation, or any combination thereof, the predetermined threshold volume includes first and second threshold volumes, and the control component being configured to control the valve includes being configured to control the valve to decrease or increase the rate of the flow of aerosol precursor composition in response to the volume being respectively above the first threshold volume or below the second threshold volume.
In some example implementations of the control body of any preceding or any subsequent example implementation, or any combination thereof, the first and second threshold volumes are respectively 100 milliliters (mL) and 10 mL, and the control component being configured to control the valve to decrease or increase the rate includes being configured to control the valve to incrementally decrease or increase the rate until respectively the flow of aerosol precursor composition stops or the volume is greater than 100 mL.
In some example implementations of the control body of any preceding or any subsequent example implementation, or any combination thereof, the control component being configured to control the valve includes being configured to control the valve only in instances in which a flow of liquid through at least a portion of the housing is detected, the aerosol delivery device further comprises a pressure sensor configured to measure a pressure of the flow of liquid and generate a second corresponding signal, and the control component is configured to receive the second corresponding signal and control the valve to further decrease or increase the rate of the flow of aerosol precursor composition in proportion to the pressure so measured.
In some example implementations of the control body of any preceding or any subsequent example implementation, or any combination thereof, the control component being configured to control the valve includes being configured to control the valve only in instances in which a flow of liquid through at least a portion of the housing is detected, and the control body further comprises pressure and humidity sensors configured to measure a pressure of the flow of liquid, a volumetric pressure, and a humidity of an environment of the aerosol delivery device, and generate second corresponding signals. The control component being configured to receive the corresponding signal further includes being configured to receive the second corresponding signals, and the control component being configured to determine the volume of the aerosol precursor composition further includes being configured to determine an optimal rate of the flow of aerosol precursor composition based on the volume of the aerosol precursor composition so determined, and the pressure of the flow of liquid, the volumetric pressure and the humidity so measured. The control component being configured to control the valve to includes being configured to control the valve to decrease or increase the rate to match the optimal rate so determined.
In some example implementations of the control body of any preceding or any subsequent example implementation, or any combination thereof, the aerosol delivery device further comprises a liquid-flow sensor configured to measure the rate of the flow of aerosol precursor composition to the heating element, and a display controllable to present the rate so measured.
In some example implementations of the control body of any preceding or any subsequent example implementation, or any combination thereof, the reservoir is a refillable reservoir, and the aerosol delivery device further comprises a liquid-level sensor configured to measure a volume of the aerosol precursor composition within the refillable reservoir and generate a second corresponding signal, and a communication interface configured to enable wireless communication of the second corresponding signal or another signal that conveys the volume of the aerosol precursor composition within the refillable reservoir so measured to a remote ordering system configured to automatically order a container for refilling the reservoir in response to the volume being below a second predetermined threshold.
These and other features, aspects, and advantages of the present disclosure will be apparent from a reading of the following detailed description together with the accompanying drawings, which are briefly described below. The present disclosure includes any combination of two, three, four or more features or elements set forth in this disclosure, regardless of whether such features or elements are expressly combined or otherwise recited in a specific example implementation described herein. This disclosure is intended to be read holistically such that any separable features or elements of the disclosure, in any of its aspects and example implementations, should be viewed as intended, namely to be combinable, unless the context of the disclosure clearly dictates otherwise.
It will therefore be appreciated that this Brief Summary is provided merely for purposes of summarizing some example implementations so as to provide a basic understanding of some aspects of the disclosure. Accordingly, it will be appreciated that the above described example implementations are merely examples and should not be construed to narrow the scope or spirit of the disclosure in any way. Other example implementations, aspects and advantages will become apparent from the following detailed description taken in conjunction with the accompanying drawings which illustrate, by way of example, the principles of some described example implementations.
Having thus described the disclosure in the foregoing general terms, reference will now be made to the accompanying drawings, which are not necessarily drawn to scale, and wherein:
The present disclosure will now be described more fully hereinafter with reference to example implementations thereof. These example implementations are described so that this disclosure will be thorough and complete, and will fully convey the scope of the disclosure to those skilled in the art. Indeed, the disclosure may be embodied in many different forms and should not be construed as limited to the implementations set forth herein; rather, these implementations are provided so that this disclosure will satisfy applicable legal requirements. As used in the specification and the appended claims, the singular forms “a,” “an,” “the” and the like include plural referents unless the context clearly dictates otherwise.
As described hereinafter, example implementations of the present disclosure relate to aerosol delivery systems. Aerosol delivery systems according to the present disclosure use electrical energy to heat a material (preferably without combusting the material to any significant degree) to form an inhalable substance; and components of such systems have the form of articles most preferably are sufficiently compact to be considered hand-held devices. That is, use of components of preferred aerosol delivery systems does not result in the production of smoke in the sense that aerosol results principally from by-products of combustion or pyrolysis of tobacco, but rather, use of those preferred systems results in the production of vapors resulting from volatilization or vaporization of certain components incorporated therein. In some example implementations, components of aerosol delivery systems may be characterized as electronic cigarettes, and those electronic cigarettes most preferably incorporate tobacco and/or components derived from tobacco, and hence deliver tobacco derived components in aerosol form.
Aerosol generating pieces of certain preferred aerosol delivery systems may provide many of the sensations (e.g., inhalation and exhalation rituals, types of tastes or flavors, organoleptic effects, physical feel, use rituals, visual cues such as those provided by visible aerosol, and the like) of smoking a cigarette, cigar or pipe that is employed by lighting and burning tobacco (and hence inhaling tobacco smoke), without any substantial degree of combustion of any component thereof. For example, the user of an aerosol generating piece of the present disclosure can hold and use that piece much like a smoker employs a traditional type of smoking article, draw on one end of that piece for inhalation of aerosol produced by that piece, take or draw puffs at selected intervals of time, and the like.
Aerosol delivery systems of the present disclosure also can be characterized as being vapor-producing articles or medicament delivery articles. Thus, such articles or devices can be adapted so as to provide one or more substances (e.g., flavors and/or pharmaceutical active ingredients) in an inhalable form or state. For example, inhalable substances can be substantially in the form of a vapor (i.e., a substance that is in the gas phase at a temperature lower than its critical point). Alternatively, inhalable substances can be in the form of an aerosol (i.e., a suspension of fine solid particles or liquid droplets in a gas). For purposes of simplicity, the term “aerosol” as used herein is meant to include vapors, gases and aerosols of a form or type suitable for human inhalation, whether or not visible, and whether or not of a form that might be considered to be smoke-like.
Aerosol delivery systems of the present disclosure generally include a number of components provided within an outer body or shell, which may be referred to as a housing. The overall design of the outer body or shell can vary, and the format or configuration of the outer body that can define the overall size and shape of the aerosol delivery device can vary. Typically, an elongated body resembling the shape of a cigarette or cigar can be a formed from a single, unitary housing or the elongated housing can be formed of two or more separable bodies. For example, an aerosol delivery device can comprise an elongated shell or body that can be substantially tubular in shape and, as such, resemble the shape of a conventional cigarette or cigar. In one example, all of the components of the aerosol delivery device are contained within one housing. Alternatively, an aerosol delivery device can comprise two or more housings that are joined and are separable. For example, an aerosol delivery device can possess at one end a control body comprising a housing containing one or more reusable components (e.g., an accumulator such as a rechargeable battery and/or supercapacitor, and various electronics for controlling the operation of that article), and at the other end and removably coupleable thereto, an outer body or shell containing a disposable portion (e.g., a disposable flavor-containing cartridge).
Aerosol delivery systems of the present disclosure most preferably comprise some combination of a power source (i.e., an electrical power source), at least one control component (e.g., means for actuating, controlling, regulating and ceasing power for heat generation, such as by controlling electrical current flow the power source to other components of the article—e.g., a microprocessor, individually or as part of a microcontroller), a heater or heat generation member (e.g., an electrical resistance heating element or other component, which alone or in combination with one or more further elements may be commonly referred to as an “atomizer”), an aerosol precursor composition (e.g., commonly a liquid capable of yielding an aerosol upon application of sufficient heat, such as ingredients commonly referred to as “smoke juice,” “e-liquid” and “e-juice”), and a mouthend region or tip for allowing draw upon the aerosol delivery device for aerosol inhalation (e.g., a defined airflow path through the article such that aerosol generated can be withdrawn therefrom upon draw).
More specific formats, configurations and arrangements of components within the aerosol delivery systems of the present disclosure will be evident in light of the further disclosure provided hereinafter. Additionally, the selection and arrangement of various aerosol delivery system components can be appreciated upon consideration of the commercially available electronic aerosol delivery devices, such as those representative products referenced in background art section of the present disclosure.
In various examples, an aerosol delivery device can comprise a reservoir configured to retain the aerosol precursor composition. The reservoir particularly can be formed of a porous material (e.g., a fibrous material) and thus may be referred to as a porous substrate (e.g., a fibrous substrate).
A fibrous substrate useful as a reservoir in an aerosol delivery device can be a woven or nonwoven material formed of a plurality of fibers or filaments and can be formed of one or both of natural fibers and synthetic fibers. For example, a fibrous substrate may comprise a fiberglass material a cellulose acetate material, a carbon material, a polyethylene terephthalate (PET) material, a rayon material, or an organic cotton material can be used. A reservoir may be substantially in the form of a container and may include a fibrous material included therein.
In some example implementations, one or both of the control body 102 or the cartridge 104 of the aerosol delivery device 100 may be referred to as being disposable or as being reusable. For example, the control body may have a replaceable battery, rechargeable battery (e.g., rechargeable thin-film solid state battery) or rechargeable supercapacitor, and thus may be combined with any type of recharging technology, including connection to a typical wall outlet, connection to a car charger (i.e., a cigarette lighter receptacle), connection to a computer, such as through a universal serial bus (USB) cable or connector, connection to a photovoltaic cell (sometimes referred to as a solar cell) or solar panel of solar cells, wireless connection to a Radio Frequency (RF), wireless connection to induction-based charging pads, or connection to a RF-to-DC converter. Further, in some example implementations, the cartridge may comprise a single-use cartridge, as disclosed in U.S. Pat. No. 8,910,639 to Chang et al., which is incorporated herein by reference.
The cartridge 104 can be formed of a cartridge shell 212 enclosing a reservoir 214 configured to retain the aerosol precursor composition, and including a heater 216 (sometimes referred to as a heating element). In various configurations, this structure may be referred to as a tank; and accordingly, the terms “cartridge,” “tank” and the like may be used interchangeably to refer to a shell or other housing enclosing a reservoir for aerosol precursor composition, and including a heater.
As shown, in some examples, the reservoir 214 may be in fluid communication with a liquid transport element 218 adapted to wick or otherwise transport an aerosol precursor composition stored in the reservoir housing to the heater 216. In some examples, a valve 220 may be positioned between the reservoir and heater, and configured to control a flow of aerosol precursor composition from the reservoir to the heater.
Various examples of materials configured to produce heat when electrical current is applied therethrough may be employed to form the heater 216. The heater in some of these examples may be a resistive heating element such as a wire coil. Example materials from which the wire coil may be formed include titanium (Ti), platinum (Pt), nichrome (NiCrFe) Kanthal (FeCrAl), Nichrome, Molybdenum disilicide (MoSi2), molybdenum silicide (MoSi), Molybdenum disilicide doped with Aluminum (Mo(Si,Al)2), graphite and graphite-based materials (e.g., carbon-based foams and yarns), silver palladium (AgPd) conductive inks, boron doped silica, and ceramics (e.g., positive or negative temperature coefficient ceramics). Example implementations of heaters or heating members useful in aerosol delivery devices according to the present disclosure are further described below, and can be incorporated into devices such as illustrated in
For example, in some implementations, the heater 216 includes an electrically-conductive carbon element disposed adjacent to a heat-conductive substrate, such as that disclosed in U.S. patent application Ser. No. 15/133,916 to Sur et al., filed Apr. 20, 2016, which is incorporated herein by reference. In such an arrangement, the heater may be configured to receive the aerosol precursor from the reservoir 214 onto the heat-conductive substrate. In this manner, the aerosol precursor may be delivered into engagement with or onto the heat-conductive substrate to form the aerosol in response to heat from the electrically-conductive carbon element conducted through the heat-conductive substrate. In some aspects, the liquid-transport element 218 may be operably engaged between the reservoir and the heat-conductive substrate, and configured to deliver the aerosol precursor from the reservoir and onto the heat-conductive substrate. In these implementations, the liquid-transport element may comprise, for example, a pump apparatus or a wick arrangement.
In one particular aspect, the reservoir 214 is configured to dispense the aerosol precursor on a surface of the heat-conductive substrate of the heater 216. Accordingly, in such instances, the heat-conductive substrate may have the electrically-conductive carbon element mounted on, applied to, or otherwise engaged with a surface of the heat conductive substrate, and the aerosol precursor may be dispensed by the liquid-transport element 218 onto an opposing surface of the heat-conductive substrate. The heat from the electrically-conductive carbon element is conducted through the heat-conductive substrate, wherein contact or other engagement between the aerosol precursor and the heated surface causes the aerosol precursor to form an aerosol in response to the heat. In some embodiments, the electrically-conductive carbon element may comprise an electrically-conductive graphene element, more particularly, an electrically conductive square graphene sheet or graphene foil, or a plurality of electrically conductive square graphene sheets or graphene foils stacked together.
An opening 224 may be present in the cartridge shell 212 (e.g., at the mouthend) to allow for egress of formed aerosol from the cartridge 104.
The cartridge 104 also may include one or more electronic components 226, which may include an integrated circuit, a memory component, a sensor, or the like. The electronic components may be adapted to communicate with the control component 204 and/or with an external device by wired or wireless means. The electronic components may be positioned anywhere within the cartridge or a base 228 thereof.
Although the control component 204 and the flow sensor 206 are illustrated separately, it is understood that the control component and the flow sensor may be combined as an electronic circuit board with the air flow sensor attached directly thereto. Further, the electronic circuit board may be positioned horizontally relative the illustration of
The control body 102 and the cartridge 104 may include components adapted to facilitate a fluid engagement therebetween. As illustrated in
A coupler and a base useful according to the present disclosure are described in
U.S. Pat. App. Pub. No. 2014/0261495 to Novak et al., which is incorporated herein by reference. For example, the coupler 230 as seen in
The aerosol delivery device 100 may be substantially rod-like or substantially tubular shaped or substantially cylindrically shaped in some examples. In other examples, further shapes and dimensions are encompassed—e.g., a rectangular or triangular cross-section, multifaceted shapes, or the like.
The reservoir 214 illustrated in
In use, when a user draws on the aerosol delivery device 100, airflow is detected by the flow sensor 206, and the heater 216 is activated to vaporize components of the aerosol precursor composition. Drawing upon the mouthend of the aerosol delivery device causes ambient air to enter the air intake 236 and pass through the cavity 232 in the coupler 230 and the central opening in the projection 234 of the base 228. In the cartridge 104, the drawn air combines with the formed vapor to form an aerosol. The aerosol is whisked, aspirated or otherwise drawn away from the heater and out the opening 224 in the mouthend of the aerosol delivery device.
In some examples, the aerosol delivery device 100 may include a number of additional software-controlled functions. For example, the aerosol delivery device may include a power-source protection circuit configured to detect power-source input, loads on the power-source terminals, and charging input. The power-source protection circuit may include short-circuit protection, under-voltage lock out and/or over-voltage charge protection. The aerosol delivery device may also include components for ambient temperature measurement, and its control component 204 may be configured to control at least one functional element to inhibit power-source charging—particularly of any battery—if the ambient temperature is below a certain temperature (e.g., 0° C.) or above a certain temperature (e.g., 45° C.) prior to start of charging or during charging.
Power delivery from the power source 208 may vary over the course of each puff on the device 100 according to a power control mechanism. The device may include a “long puff” safety timer such that in the event that a user or component failure (e.g., flow sensor 206) causes the device to attempt to puff continuously, the control component 204 may control at least one functional element to terminate the puff automatically after some period of time (e.g., four seconds). Further, the time between puffs on the device may be restricted to less than a period of time (e.g., 100 seconds). A watchdog safety timer may automatically reset the aerosol delivery device if its control component or software running on it becomes unstable and does not service the timer within an appropriate time interval (e.g., eight seconds). Further safety protection may be provided in the event of a defective or otherwise failed flow sensor 206, such as by permanently disabling the aerosol delivery device in order to prevent inadvertent heating. A puffing limit switch may deactivate the device in the event of a pressure sensor fail causing the device to continuously activate without stopping after the four second maximum puff time.
The aerosol delivery device 100 may include a puff tracking algorithm configured for heater lockout once a defined number of puffs has been achieved for an attached cartridge (based on the number of available puffs calculated in light of the e-liquid charge in the cartridge). The aerosol delivery device may also contain a sensor chip that measures, in real-time, the amount of aerosol precursor in the reservoir. If the aerosol precursor composition level is substantially low, or the reservoir is empty, the aerosol delivery device may prevent current from being delivered and thereby prevent overheating the heating element. The aerosol delivery device may include a sleep, standby or low-power mode function whereby power delivery may be automatically cut off after a defined period of non-use. Further safety protection may be provided in that all charge/discharge cycles of the power source 208 may be monitored by the control component 204 over its lifetime. After the power source has attained the equivalent of a predetermined number (e.g., 200) of full discharge and full recharge cycles, it may be declared depleted, and the control component may control at least one functional element to prevent further charging of the power source. The aerosol device may also have a mechanical switch or a proximity based sensor switch to activate the heater 216 in lieu of a flow sensor configured to detect the flow of air through the aerosol delivery device and thereby effect activation of the heater.
The various components of an aerosol delivery device according to the present disclosure can be chosen from components described in the art and commercially available. Examples of batteries that can be used according to the disclosure are described in U.S. Pat. App. Pub. No. 2010/0028766 to Peckerar et al., which is incorporated herein by reference.
The aerosol delivery device 100 can incorporate the sensor 206 or another sensor or detector for control of supply of electric power to the heater 216 when aerosol generation is desired (e.g., upon draw during use). As such, for example, there is provided a manner or method of turning off power to the heater when the aerosol delivery device is not be drawn upon during use, and for turning on power to actuate or trigger the generation of heat by the heater during draw. Additional representative types of sensing or detection mechanisms, structure and configuration thereof, components thereof, and general methods of operation thereof, are described in U.S. Pat. No. 5,261,424 to Sprinkel, Jr., U.S. Pat. No. 5,372,148 to McCafferty et al., and PCT Pat. App. Pub. No. WO 2010/003480 to Flick, all of which are incorporated herein by reference.
The aerosol delivery device 100 most preferably incorporates the control component 204 or another control mechanism for controlling the amount of electric power to the heater 216 during draw. Representative types of electronic components, structure and configuration thereof, features thereof, and general methods of operation thereof, are described in U.S. Pat. No. 4,735,217 to Gerth et al., U.S. Pat. No. 4,947,874 to Brooks et al., U.S. Pat. No. 5,372,148 to McCafferty et al., U.S. Pat. No. 6,040,560 to Fleischhauer et al., U.S. Pat. No. 7,040,314 to Nguyen et al., U.S. Pat. No. 8,205,622 to Pan, U.S. Pat. App. Pub. No. 2009/0230117 to Fernando et al., U.S. Pat. App. Pub. No. 2014/0060554 to Collet et al., U.S. Pat. App. Pub. No. 2014/0270727 to Ampolini et al., and U.S. patent application Ser. No. 14/209,191 to Henry et al., filed Mar. 13, 2014, all of which are incorporated herein by reference.
Representative types of substrates, reservoirs or other components for supporting the aerosol precursor are described in U.S. Pat. No. 8,528,569 to Newton, U.S. Pat. App. Pub. No. 2014/0261487 to Chapman et al., U.S. patent application Ser. No. 14/011,992 to Davis et al., filed Aug. 28, 2013, and U.S. patent application Ser. No. 14/170,838 to Bless et al., filed Feb. 3, 2014, all of which are incorporated herein by reference. Additionally, various wicking materials, and the configuration and operation of those wicking materials within certain types of electronic cigarettes, are set forth in U.S. Pat. App. Pub. No. 2014/0209105 to Sears et al., which is incorporated herein by reference.
The aerosol precursor composition, also referred to as a vapor precursor composition, may comprise a variety of components including, by way of example, a polyhydric alcohol (e.g., glycerin, propylene glycol or a mixture thereof), nicotine, tobacco, tobacco extract and/or flavorants. Representative types of aerosol precursor components and formulations also are set forth and characterized in U.S. Pat. No. 7,217,320 to Robinson et al. and U.S. Pat. Pub. Nos. 2013/0008457 to Zheng et al.; 2013/0213417 to Chong et al.; 2014/0060554 to Collett et al.; 2015/0020423 to Lipowicz et al.; and 2015/0020430 to Koller, as well as WO 2014/182736 to Bowen et al, the disclosures of which are incorporated herein by reference. Other aerosol precursors that may be employed include the aerosol precursors that have been incorporated in the VUSE® product by R. J. Reynolds Vapor Company, the BLU™ product by Imperial Tobacco Group PLC, the MISTIC MENTHOL product by Mistic Ecigs, and the VYPE product by CN Creative Ltd. Also desirable are the so-called “smoke juices” for electronic cigarettes that have been available from Johnson Creek Enterprises LLC.
Additional representative types of components that yield visual cues or indicators may be employed in the aerosol delivery device 100, such as visual indicators and related components, audio indicators, haptic indicators and the like. Examples of suitable LED components, and the configurations and uses thereof, are described in U.S. Pat. No. 5,154,192 to Sprinkel et al., U.S. Pat. No. 8,499,766 to Newton, U.S. Pat. No. 8,539,959 to Scatterday, and U.S. patent application Ser. No. 14/173,266 to Sears et al., filed Feb. 5, 2014, all of which are incorporated herein by reference.
Yet other features, controls or components that can be incorporated into aerosol delivery devices of the present disclosure are described in U.S. Pat. No. 5,967,148 to Harris et al., U.S. Pat. No. 5,934,289 to Watkins et al., U.S. Pat. No. 5,954,979 to Counts et al., U.S. Pat. No. 6,040,560 to Fleischhauer et al., U.S. Pat. No. 8,365,742 to Hon, U.S. Pat. No. 8,402,976 to Fernando et al., U.S. Pat. App. Pub. No. 2005/0016550 to Katase, U.S. Pat. App. Pub. No. 2010/0163063 to Fernando et al., U.S. Pat. App. Pub. No.
2013/0192623 to Tucker et al., U.S. Pat. App. Pub. No. 2013/0298905 to Leven et al., U.S. Pat. App. Pub. No. 2013/0180553 to Kim et al., U.S. Pat. App. Pub. No. 2014/0000638 to Sebastian et al., U.S. Pat. App. Pub. No. 2014/0261495 to Novak et al., and U.S. Pat. App. Pub. No. 2014/0261408 to DePiano et al., all of which are incorporated herein by reference.
The control component 204 includes a number of electronic components, and in some examples may be formed of a printed circuit board (PCB) that supports and electrically connects the electronic components. The electronic components may include a microprocessor or processor core, and a memory. In some examples, the control component may include a microcontroller with integrated processor core and memory, and may further include one or more integrated input/output peripherals. In some examples, the control component may be coupled to a communication interface 246 to enable wireless communication with one or more networks, computing devices or other appropriately-enabled devices. Examples of suitable communication interfaces are disclosed in U.S. patent application Ser. No. 14/638,562, filed Mar. 4, 2015, to Marion et al., which is incorporated herein by reference. And examples of suitable manners according to which the aerosol delivery device may be configured to wirelessly communicate are disclosed in U.S. patent application Ser. No. 14/327,776, filed Jul. 10, 2014, to Ampolini et al., and U.S. patent application Ser. No. 14/609,032, filed Jan. 29, 2015, to Henry, Jr. et al., all of which are incorporated herein by reference.
As previously indicated, in some examples, a valve 220 may be positioned between the reservoir 214 and heater 216, and configured to control a flow of aerosol precursor composition from the reservoir to the heater. In at least some of these examples, the control body 102 may include a sensor 248 configured to measure a reflectance (e.g., reflectance of light) at, or temperature of, the heater, from which the control component 204 may determine a volume of aerosol precursor composition at the heater and control the valve.
In some examples, the predetermined threshold volume includes first and second threshold volumes, and the control component 204 may control the valve 220 to decrease or increase the rate of the flow of aerosol precursor composition in response to the volume being respectively above the first threshold volume or below the second threshold volume. According to some examples, the first and second threshold volumes may respectively be 100 milliliters (mL) and 10 mL. Further, in some examples, and the control component may control the valve to incrementally decrease or increase the rate until respectively the flow of aerosol precursor composition stops or the volume is greater than the first threshold volume (e.g., 100 mL).
In some example implementations, the valve 220 is or includes a single-phase induction motor having a motor speed that is variable and proportional to the rate of the flow of aerosol precursor composition. In these examples, the control component 204 may control the valve to respectively decrease or increase the motor speed and thereby the rate of the flow of aerosol precursor composition.
As also shown in
In these examples, the control component 204 may be configured to determine the volume of aerosol precursor composition based on the reflectance so measured. Various methods may be utilized to determine the volume of aerosol precursor composition at the heater 216 from the measured reflectance. For example, in an instance in which the sensor 248 includes the optical liquid-level sensor 302, when the volume of aerosol precursor composition at the heater 216 is high, the lux value of luminescence is low because the aerosol precursor composition (liquid) absorbs the light at the heater. In an instance in which there is no aerosol precursor composition at the heater, the light shines through the sensor and the lux value of luminescence is high and thereby indicates that the volume of aerosol precursor composition at the heating element is low. In some implementations, at least a portion of the heater may be marked such that the marking may point to the volume being half-full, full or empty based on the reflectance of light at the heater. Accordingly, as used herein, determining the volume of aerosol precursor composition may refer to determining a relative volume of aerosol precursor composition at the heating element.
In some examples, the sensor 248 is or includes a temperature sensor 304 configured to measure the temperature of the heater 216. In these examples, the control component may be configured to determine the volume of aerosol precursor composition based on the temperature so measured. Various methods may be utilized to determine the volume of aerosol precursor composition at the heater 216 from the measured temperature. For example, if the volume of aerosol precursor composition at the heater is constant, then the measured temperature is also constant provided the current delivered thereto is constant throughout a given puff duration. If the temperature increases it indicates that the volume of aerosol precursor composition at the heater is low. If the temperature decreases it indicates more aerosol precursor composition may be available than required and thus the liquid-level at the heater should be decreased. Examples of suitable temperature sensors may include the Multi-Sensor High Accuracy Digital Temperature Measurement System (LTC2983) commercial product manufactured by Linear Technology. In some examples in which the temperature sensor is coupled with a resistance temperature detector (RTD) or thermocouple, the temperature sensor may measure temperature up to 800 degrees Celsius.
It should be noted that while the illustrated implementation of
As previously indicated, the control component 204 is configured to control the valve 220 based on the volume of aerosol precursor composition at the heater 216. In some example implementations, the control component may be configured to control the valve 220 only in instances in which a flow of liquid through at least a portion of the aerosol delivery device 100 is detected by the flow sensor 206. In these examples, the control body may include a number of sensors in addition to the sensor 248 for further control of the valve. As illustrated in
In another example, the pressure sensor 402 may be configured to measure a pressure of the flow of liquid through the aerosol delivery device and an atmospheric pressure and generate second signals corresponding to respectively the pressure of the flow of liquid and the volumetric pressure (e.g., volumetric liquid pressure). In these examples, the pressure is inversely proportional to the liquid flow rate such that a single sensor may be utilized to measure the pressure and liquid flow rate. The control body may also comprise a humidity sensor 404 configured to measure a humidity of the environment and generate a second signal corresponding to the humidity so measured.
In these implementations, the control component 204 may be configured to receive the second corresponding signals, and determine an optimal rate of the flow of aerosol precursor composition based on the volume of the aerosol precursor composition so determined, and the pressure of the flow of liquid, the volumetric pressure and the humidity so measured. In some examples, an optimal rate of the flow of aerosol precursor composition may include a constant rate of the flow of aerosol precursor composition. In these examples, various methods may be utilized to determine the optimal rate based on a number of parameters. For example, by providing a constant volume of aerosol precursor composition over a puff duration, the rate of flow may be constant (e.g., optimal rate=volume/puff duration). In some examples, the volume may be determined by a cross-sectional area, depth or thickness of the aerosol precursor composition such that by providing a constant cross-sectional area, depth or thickness, and puff duration, the rate of the flow of aerosol precursor composition may be constant. The control component may then control the valve 220 to decrease or increase the rate to match the optimal rate so determined. It should be noted that as discussed herein a “match” may be or include a substantial or approximate match of the optimal rate with respect to and within an acceptable error of the design specifications of the valve, engineering tolerances, and the like.
In addition to the valve 220, other functional element(s) of the aerosol delivery device 100 may be controlled in any of a number of different manners. As shown in
As another example, the reservoir 214 may be a refillable reservoir and the control body 102 may comprise a liquid-level sensor 506 configured to measure a volume of the aerosol precursor composition within the refillable reservoir and generate a second signal corresponding signal. In these examples, the communication interface 246 may be configured to enable wireless communication of the second corresponding signal or another signal that conveys the volume of the aerosol precursor composition within the refillable reservoir so measured to a remote ordering system 508. The remote ordering system may then be configured to automatically order a container for refilling the reservoir in response to the volume being below a second predetermined threshold. In some of these examples, the communication interface may further initiate payment of the order using near-field communication.
The foregoing description of use of the article(s) can be applied to the various example implementations described herein through minor modifications, which can be apparent to the person of skill in the art in light of the further disclosure provided herein. The above description of use, however, is not intended to limit the use of the article but is provided to comply with all necessary requirements of disclosure of the present disclosure. Any of the elements shown in the article(s) illustrated in
Many modifications and other implementations of the disclosure set forth herein will come to mind to one skilled in the art to which this disclosure pertains having the benefit of the teachings presented in the foregoing descriptions and the associated drawings. Therefore, it is to be understood that the disclosure is not to be limited to the specific implementations disclosed, and that modifications and other implementations are intended to be included within the scope of the appended claims. Moreover, although the foregoing descriptions and the associated drawings describe example implementations in the context of certain example combinations of elements and/or functions, it should be appreciated that different combinations of elements and/or functions may be provided by alternative implementations without departing from the scope of the appended claims. In this regard, for example, different combinations of elements and/or functions than those explicitly described above are also contemplated as may be set forth in some of the appended claims. Although specific terms are employed herein, they are used in a generic and descriptive sense only and not for purposes of limitation.
Number | Name | Date | Kind |
---|---|---|---|
1771366 | Wyss et al. | Jul 1930 | A |
2057353 | Whittemore, Jr. | Oct 1936 | A |
2104266 | McCormick | Jan 1938 | A |
3200819 | Gilbert | Aug 1965 | A |
4284089 | Ray | Aug 1981 | A |
4303083 | Burruss, Jr. | Dec 1981 | A |
4735217 | Gerth et al. | Apr 1988 | A |
4848374 | Chard et al. | Jul 1989 | A |
4907606 | Lilja et al. | Mar 1990 | A |
4922901 | Brooks et al. | May 1990 | A |
4945931 | Gori | Aug 1990 | A |
4947874 | Brooks et al. | Aug 1990 | A |
4947875 | Brooks et al. | Aug 1990 | A |
4986286 | Roberts et al. | Jan 1991 | A |
5019122 | Clearman et al. | May 1991 | A |
5042510 | Curtiss et al. | Aug 1991 | A |
5054319 | Fling | Oct 1991 | A |
5060671 | Counts et al. | Oct 1991 | A |
5093894 | Deevi et al. | Mar 1992 | A |
5144962 | Counts et al. | Sep 1992 | A |
5249586 | Morgan et al. | Oct 1993 | A |
5261424 | Sprinkel, Jr. | Nov 1993 | A |
5322075 | Deevi et al. | Jun 1994 | A |
5353813 | Deevi et al. | Oct 1994 | A |
5369723 | Counts et al. | Nov 1994 | A |
5372148 | McCafferty et al. | Dec 1994 | A |
5388574 | Ingebrethsen et al. | Feb 1995 | A |
5408574 | Deevi et al. | Apr 1995 | A |
5468936 | Deevi et al. | Nov 1995 | A |
5498850 | Das | Mar 1996 | A |
5515842 | Ramseyer et al. | May 1996 | A |
5530225 | Hajaligol | Jun 1996 | A |
5564442 | MacDonald et al. | Oct 1996 | A |
5649554 | Sprinkel et al. | Jul 1997 | A |
5666977 | Higgins et al. | Sep 1997 | A |
5687746 | Rose et al. | Nov 1997 | A |
5726421 | Fleischhauer et al. | Mar 1998 | A |
5727571 | Meiring et al. | Mar 1998 | A |
5743251 | Howell et al. | Apr 1998 | A |
5799663 | Gross et al. | Sep 1998 | A |
5819756 | Mielordt | Oct 1998 | A |
5865185 | Collins et al. | Feb 1999 | A |
5865186 | Volsey, II | Feb 1999 | A |
5878752 | Adams et al. | Mar 1999 | A |
5894841 | Voges | Apr 1999 | A |
5934289 | Watkins et al. | Aug 1999 | A |
5954979 | Counts et al. | Sep 1999 | A |
5967148 | Harris et al. | Oct 1999 | A |
6040560 | Fleischhauer et al. | Mar 2000 | A |
6053176 | Adams et al. | Apr 2000 | A |
6089857 | Matsuura et al. | Jul 2000 | A |
6095153 | Kessler et al. | Aug 2000 | A |
6125853 | Susa et al. | Oct 2000 | A |
6155268 | Takeuchi | Dec 2000 | A |
6164287 | White | Dec 2000 | A |
6196218 | Voges | Mar 2001 | B1 |
6196219 | Hess et al. | Mar 2001 | B1 |
6516796 | Cox | Feb 2003 | B1 |
6598607 | Adiga et al. | Jul 2003 | B2 |
6601776 | Oljaca et al. | Aug 2003 | B1 |
6615840 | Fournier et al. | Sep 2003 | B1 |
6688313 | Wrenn et al. | Feb 2004 | B2 |
6772756 | Shayan | Aug 2004 | B2 |
6803545 | Blake et al. | Oct 2004 | B2 |
6854461 | Nichols | Feb 2005 | B2 |
6854470 | Pu | Feb 2005 | B1 |
7117867 | Cox et al. | Oct 2006 | B2 |
7293565 | Griffin et al. | Nov 2007 | B2 |
7513253 | Kobayashi et al. | Apr 2009 | B2 |
7775459 | Martens, III et al. | Aug 2010 | B2 |
7832410 | Hon | Nov 2010 | B2 |
7845359 | Montaser | Dec 2010 | B2 |
7896006 | Hamano et al. | Mar 2011 | B2 |
8127772 | Montaser | Mar 2012 | B2 |
8314591 | Terry et al. | Nov 2012 | B2 |
8365742 | Hon | Feb 2013 | B2 |
8402976 | Fernando et al. | Mar 2013 | B2 |
8499766 | Newton | Aug 2013 | B1 |
8528569 | Newton | Sep 2013 | B1 |
8550069 | Alelov | Oct 2013 | B2 |
8851081 | Fernando et al. | Oct 2014 | B2 |
20020146242 | Vieira | Oct 2002 | A1 |
20030226837 | Blake et al. | Dec 2003 | A1 |
20040118401 | Smith et al. | Jun 2004 | A1 |
20040129280 | Woodson et al. | Jul 2004 | A1 |
20040200488 | Felter et al. | Oct 2004 | A1 |
20040226568 | Takeuchi et al. | Nov 2004 | A1 |
20050016550 | Katase | Jan 2005 | A1 |
20060016453 | Kim | Jan 2006 | A1 |
20060032501 | Hale | Feb 2006 | A1 |
20060047368 | Maharajh | Mar 2006 | A1 |
20060196518 | Hon | Sep 2006 | A1 |
20070074734 | Braunshteyn et al. | Apr 2007 | A1 |
20070102013 | Adams et al. | May 2007 | A1 |
20070215167 | Crooks et al. | Sep 2007 | A1 |
20080085103 | Beland et al. | Apr 2008 | A1 |
20080092912 | Robinson et al. | Apr 2008 | A1 |
20080216833 | Pujol | Sep 2008 | A1 |
20080257367 | Paterno et al. | Oct 2008 | A1 |
20080276947 | Martzel | Nov 2008 | A1 |
20080302374 | Wengert et al. | Dec 2008 | A1 |
20090095311 | Hon | Apr 2009 | A1 |
20090095312 | Herbrich et al. | Apr 2009 | A1 |
20090126745 | Hon | May 2009 | A1 |
20090188490 | Hon | Jul 2009 | A1 |
20090230117 | Fernando et al. | Sep 2009 | A1 |
20090272379 | Thorens et al. | Nov 2009 | A1 |
20090283103 | Nielsen et al. | Nov 2009 | A1 |
20090320863 | Fernando et al. | Dec 2009 | A1 |
20100043809 | Magnon | Feb 2010 | A1 |
20100083959 | Siller | Apr 2010 | A1 |
20100200006 | Robinson et al. | Aug 2010 | A1 |
20100229881 | Hearn | Sep 2010 | A1 |
20100242974 | Pan | Sep 2010 | A1 |
20100307518 | Wang | Dec 2010 | A1 |
20100313901 | Fernando et al. | Dec 2010 | A1 |
20110005535 | Xiu | Jan 2011 | A1 |
20110011396 | Fang | Jan 2011 | A1 |
20110036363 | Urtsev et al. | Feb 2011 | A1 |
20110036365 | Chong et al. | Feb 2011 | A1 |
20110094523 | Thorens et al. | Apr 2011 | A1 |
20110126848 | Zuber et al. | Jun 2011 | A1 |
20110155153 | Thorens et al. | Jun 2011 | A1 |
20110155718 | Greim et al. | Jun 2011 | A1 |
20110168194 | Hon | Jul 2011 | A1 |
20110265806 | Alarcon et al. | Nov 2011 | A1 |
20110309157 | Yang et al. | Dec 2011 | A1 |
20120042885 | Stone et al. | Feb 2012 | A1 |
20120048266 | Alelov | Mar 2012 | A1 |
20120060853 | Robinson et al. | Mar 2012 | A1 |
20120111347 | Hon | May 2012 | A1 |
20120132643 | Choi et al. | May 2012 | A1 |
20120227752 | Alelov | Sep 2012 | A1 |
20120231464 | Yu et al. | Sep 2012 | A1 |
20120260927 | Liu | Oct 2012 | A1 |
20120279512 | Hon | Nov 2012 | A1 |
20120318882 | Abehasera | Dec 2012 | A1 |
20130037041 | Worm et al. | Feb 2013 | A1 |
20130056013 | Terry et al. | Mar 2013 | A1 |
20130081625 | Rustad et al. | Apr 2013 | A1 |
20130081642 | Safari | Apr 2013 | A1 |
20130192619 | Tucker et al. | Aug 2013 | A1 |
20130255702 | Griffith, Jr. et al. | Oct 2013 | A1 |
20130306084 | Flick | Nov 2013 | A1 |
20130319439 | Gorelick et al. | Dec 2013 | A1 |
20130340750 | Thorens et al. | Dec 2013 | A1 |
20130340775 | Juster et al. | Dec 2013 | A1 |
20140000638 | Sebastian et al. | Jan 2014 | A1 |
20140020693 | Cochand | Jan 2014 | A1 |
20140060554 | Collett et al. | Mar 2014 | A1 |
20140060555 | Chang et al. | Mar 2014 | A1 |
20140096781 | Sears et al. | Apr 2014 | A1 |
20140096782 | Ampolini et al. | Apr 2014 | A1 |
20140109921 | Chen | Apr 2014 | A1 |
20140157583 | Ward et al. | Jun 2014 | A1 |
20140209105 | Sears et al. | Jul 2014 | A1 |
20140253144 | Novak et al. | Sep 2014 | A1 |
20140261408 | DePiano et al. | Sep 2014 | A1 |
20140261486 | Potter et al. | Sep 2014 | A1 |
20140261487 | Chapman et al. | Sep 2014 | A1 |
20140261495 | Novak et al. | Sep 2014 | A1 |
20140270727 | Ampolini et al. | Sep 2014 | A1 |
20140270729 | DePiano et al. | Sep 2014 | A1 |
20140270730 | DePiano et al. | Sep 2014 | A1 |
20140345631 | Bowen et al. | Nov 2014 | A1 |
20150007838 | Fernando et al. | Jan 2015 | A1 |
20150053217 | Steingraber et al. | Feb 2015 | A1 |
20150216237 | Wensley | Aug 2015 | A1 |
20160037826 | Hearn et al. | Feb 2016 | A1 |
20160106936 | Kimmel | Apr 2016 | A1 |
20160198767 | Verleur | Jul 2016 | A1 |
20160202108 | Kopansky et al. | Jul 2016 | A1 |
20170027229 | Cameron | Feb 2017 | A1 |
20170048930 | Marsh | Feb 2017 | A1 |
20170135401 | Dickens | May 2017 | A1 |
20170157341 | Pandya | Jun 2017 | A1 |
20180042308 | Takeuchi | Feb 2018 | A1 |
Number | Date | Country |
---|---|---|
276250 | Jul 1965 | AU |
2 641 869 | May 2010 | CA |
1541577 | Nov 2004 | CN |
2719043 | Aug 2005 | CN |
200997909 | Jan 2008 | CN |
101116542 | Feb 2008 | CN |
101176805 | May 2008 | CN |
201379072 | Jan 2010 | CN |
103826756 | May 2014 | CN |
104411875 | Mar 2015 | CN |
104768407 | Jul 2015 | CN |
10 2006 004 484 | Aug 2007 | DE |
102006041042 | Mar 2008 | DE |
20 2009 010 400 | Nov 2009 | DE |
0 295 122 | Dec 1988 | EP |
0 430 566 | Jun 1991 | EP |
0 845 220 | Jun 1998 | EP |
1 618 803 | Jan 2006 | EP |
2 316 286 | May 2011 | EP |
2469850 | Nov 2010 | GB |
2005-0037919 | Apr 2005 | KR |
2 536 115 | Dec 2014 | RU |
2 596 108 | Aug 2016 | RU |
WO 199748293 | Dec 1997 | WO |
WO 2003034847 | May 2003 | WO |
WO 2004043175 | May 2004 | WO |
WO 2004080216 | Sep 2004 | WO |
WO 2005099494 | Oct 2005 | WO |
WO 2007078273 | Jul 2007 | WO |
WO 2007131449 | Nov 2007 | WO |
WO 2009105919 | Sep 2009 | WO |
WO 2009155734 | Dec 2009 | WO |
WO 2010003480 | Jan 2010 | WO |
WO 2010045670 | Apr 2010 | WO |
WO 2010073122 | Jul 2010 | WO |
WO 2010118644 | Oct 2010 | WO |
WO 2010140937 | Dec 2010 | WO |
WO 2011010334 | Jan 2011 | WO |
2012085203 | Jun 2012 | WO |
WO 2012072762 | Jun 2012 | WO |
WO 2012100523 | Aug 2012 | WO |
2013042002 | Mar 2013 | WO |
2013083634 | Jun 2013 | WO |
WO 2013089551 | Jun 2013 | WO |
2014037794 | Mar 2014 | WO |
2015153443 | Oct 2015 | WO |
WO 2017153270 | Sep 2017 | WO |
Number | Date | Country | |
---|---|---|---|
20180070632 A1 | Mar 2018 | US |