Patent Grant
8177905
This invention relates to the spraying of cementitious compositions and to admixtures for use in such spraying.
The spraying of cementitious compositions such as concrete is regularly used in a number of applications, most notably in tunnelling. It is a requirement that such compositions be able to be easily conveyed (usually by pumping) to a spray nozzle. This can be achieved by the addition to the cementitious composition that is to be pumped and sprayed, at the mix stage, of an admixture which confers improved fluidity of the mix. There is a considerable variety of such admixtures known to and used by the art.
It has now been found that an especially effective admixture may be prepared by the combination of particular selected components. The invention therefore provides a fluidising admixture for use with sprayable cementitious compostions, the admixture consisting of
In a preferred embodiment of the invention, the polymer is characterised as follows—any moiety or group present in the polymer description hereinabove and not specifically mentioned in the following embodiment is absent from the embodiment, and any numerical value not specifically mentioned remains unaltered from that of the polymer description hereinabove;
In a further preferred embodiment, the polymer is characterised as follows—any moiety or group present in the description of the preferred embodiment hereinabove and not specifically mentioned in the following further preferred embodiment is absent from the further preferred embodiment, and any numerical value not specifically mentioned remains unaltered from that of the preferred embodiment description hereinabove;
a) the moiety is according to formula Ia;
The polymers for use in this invention preferably have a weight-average molecular weight of from 5000-50000, preferably from 10000-40000.
Typical examples of preferred polymers may be prepared by the reaction of methoxypolyethyleneglycol-monovinyl ether, maleic anhydride, amine-terminated ethylene oxide-propylene oxide block copolymer and acrylic acid. Examples of these materials and their preparation may be found in International Application WO 00/77058 the contents of which are incorporated herein by reference.
The invention also provides a method of imparting flow to a cementitious composition, comprising the addition thereto of an admixture as hereinabove described.
The invention also provides a method of spraying a cementitious composition by preparing a cementitious mix and conveying the mix to a spray nozzle, there being added to the mix at preparation an admixture as hereinabove described.
The proportions of the solids of the three components in the admixture are as follows:
The admixture will always contain a proportion of water, and the admixture will never be 100% solids, as the “limits” and “more preferred” columns would seem to suggest is possible. However, the skilled person will be able to determine appropriate compositions in each case, by simple experimentation.
The admixture is added to a cementitious mixture at a rate of from 0.2-2.0%, preferably from 0.5-0.8% by weight solids on cement.
The admixture according to this invention may be used in conjunction with all the conventional admixtures used in the spraying of cementitious compositions, for example, the various accelerators commonly added at the spray nozzle. The admixture according to the invention works well with both the classic alkali types (such as aluminates, caustic alkalis and “water glass”) and the newer alkali-free, generally aluminium compound-based types.
The admixture according to the invention performs at least as well as known fluidity-improving admixtures. It has the additional major practical advantage of having a very long shelf life. This means that it can be prepared well in advance of use and stored for several months without any segregation of ingredients. Moreover, it maintains this stability in the adverse conditions often found in tunnels, such as high temperatures, on exposure to which many conventional admixtures are no longer stable.
The invention is further described with reference to the following examples.
An admixture is prepared by mixing the following components
1The material used is “MVA 2453 L/44%” ex Degussa.
As a comparison, there is added to samples of the same concrete mix the same proportion of a high performance, commercially-available fluidising agent GLENIUM® T 803 ex MBT (Schweiz) AG. These mixes are tested by means of (a) a flow table, and (b) spraying.
The flow table tests are as follows:
For the spray testing, there is added at the nozzle in both cases 7% by weight on cement of a commercially-available shotcrete accelerator, MEYCO® SA160 (ex MBT (Schweiz) AG. The compressive strength is measured in a variety of ways and over different times and the results are shown in the following table:
2A method for testing compressive strength, in which a metal needle is pushed into concrete and the resistance to its entry is measured. Suitable for relatively soft materials.
3A method for testing compressive strength, in which a metal nail is fired into a concrete and its penetration measured. Suitable for concretes at a later stage after setting.
4A method for testing compressive strength, in which a cylindrical core is drilled from a hardened concrete and tested on a testing apparatus.
The admixture according to the invention has performance characteristics comparable with those of the high performance commercial material.
Samples of the admixture are tested in a mortar by flow table and for setting time. The mortar is a 1:3 blend of CEM I 42.5 Portland cement and CEM standard sand (according to DIN EN 196-1), and the admixture samples are added at a rate of 1% solids by weight on cement. Samples are also stored at 20° C., 30° C. and 40° C. for six months. At the end of the six months, the admixtures remained visually unaffected. The actual test results are shown in the following table:
It can be seen that the properties are only slightly changed.
This application is a continuation of U.S. Ser. No. 12/040,475, filed on Feb. 29, 2008 which is a continuation of U.S. Ser. No. 10/524,466, filed on Nov. 14, 2005, now abandoned, which is a national stage application under 35 U.S.C. §371 of International Application No. PCT/EP2002/010045, filed Sep. 9, 2002, from which application priority is claimed.
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|---|---|---|---|
| 3964921 | Persinski et al. | Jun 1976 | A |
| 4040854 | Persinski et al. | Aug 1977 | A |
| 4222784 | Caspar et al. | Sep 1980 | A |
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| 6767164 | Shimizu et al. | Jul 2004 | B2 |
| Number | Date | Country |
|---|---|---|
| 678526 | Sep 1991 | CH |
| 0 508 158 | Oct 1992 | EP |
| 0 508 158 | Apr 1996 | EP |
| 2 347 415 | Sep 2000 | GB |
| WO 0077058 | Dec 2000 | WO |
| Number | Date | Country | |
|---|---|---|---|
| 20100130647 A1 | May 2010 | US |
| Number | Date | Country | |
|---|---|---|---|
| Parent | 12040475 | Feb 2008 | US |
| Child | 12694796 | US | |
| Parent | 10524466 | US | |
| Child | 12040475 | US |
