Claims
- 1. A fluorescent pigment comprising:
- from 0.10 to 15.0 weight percent, based on total weight of pigment, of a fluorescent dye; and
- from 85-99.9 weight percent, based on total weight of pigment, of a thermoplastic condensation polymer, said thermoplastic condensation polymer assembled from monomers comprising:
- a) from about 55.0 to about 75.0 weight percent, based on the thermoplastic condensation polymer weight of an aromatic dicarboxylic acid;
- b) from about 5.0 to about 25.0 weight percent, based on the thermoplastic condensation polymer weight of a diamine selected from the group consisting of: an aliphatic diamine having from 2-6 carbon atoms; cycloaliphatic diamines having from 4-8 carbon atoms; or mixtures thereof; and
- c) from 0.0 to about 30.0 weight percent, based on the thermoplastic condensation polymer weight of at least one monomer selected from the group consisting of: an aliphatic alkanolamine having from 2-5 carbon atoms; an aliphatic diol having from 2-5 carbon atoms; and a cycloaliphatic diol having not more than 8 carbon atoms; and mixtures thereof.
- wherein said pigment is insoluble in acetone and said pigment further characterized by having an average particle size from about 0.1-200 microns.
- 2. The pigment of claim 1 further including up to ten (10) weight percent cross-linker based on the weight of polymer matrix.
- 3. The pigment of claim 2 wherein the cross-linker is from three (3) to six (6) weight percent.
- 4. A fluorescent pigment of claim 2;
- wherein the aromatic dicarboxylic acid is selected from the group consisting of isophthalic acid, terephthalic acid and 2,6-naphthalene dicarboxylic acid;
- wherein the diamine is selected from the group consisting of ethylene diamine, propylene diamine and trans-1,4-diaminocyclohexane;
- wherein the aliphatic alkanol amine is selected from the group consisting of ethanolamine, propanolamine; wherein the aliphatic diol is selected from the group consisting of ethylene glycol, propylene glycol;
- wherein in the cycloaliphatic diol is cyclohexane dinethanol;
- further comprising a modifier selected from the group consisting of p-aminobenzoic acid, p-hydroxybenzoic, benzoic acid, cyclohexane carboxylic acid, cyclohexylamine, benzylamine, benzyl alcohol, cyclohexanol, zinc oxide, zinc carbonate, antimony triacetate, antimony pentoxide, antimony trioxide, calcium oxide, calcium carbonate, calcium hydroxide, magnesium hydroxide, magnesium oxide and magnesium carbonate;
- wherein in the cross-linker is selected from the group consisting of glycerine, pentaerythritol, dipentaerythritol, and trimethylol propane;
- and the dye is selected from the group consisting of a xanthene, a denzothioxanthene, a coumarin, a naphthalimide, a benzoxanthene and an acridine.
- 5. A fluorescent pigment comprising:
- 1) from 0.10 to 15.0 weight percent fluorescent dye, weight percent based on the total pigment weight;
- 2) from 85.0 to 99.9 weight percent, based on the total pigment weight, of a thermoplastic condensation polymer, said polymer assembled from monomers comprising:
- a) from about 58.0 to 65.0 weight percent, based on said thermoplastic condensation polymer, weight of an aromatic dicarboxylic acid;
- b) from about 5.0 to 15.0 weight percent, based on said thermoplastic condensation polymer weight, of a diamine selected from the group consisting of aliphatic diamines having from 2-6 carbon atoms and cycloaliphatic diamines having from 4-8 carbon atoms;
- c) from about 10.0 to 20.0 weight percent, based on said thermoplastic condensation polymer weight, of a monomer selected from the group consisting of: an aliphatic alkanolamine having from 2-5 atoms; an aliphatic diol having from 2-5 carbon atoms; and a cycloaliphatic diol having from 6-8 carbon atoms; and
- said pigment is insoluble in acetone and said pigment is further characterized by having an average particle size from about 0.1-200 microns.
- 6. The pigment of claim 5 further including up to ten (10) weight percent cross-linker based on the weight of polymer matrix.
- 7. The pigment of claim 6 wherein the cross-linker is from three (3) to six (6) weight percent.
- 8. A fluorescent pigment of claim 7;
- wherein the aromatic dicarboxylic acid is selected from the group consisting of isophthalic acid, terephthalic acid and 2,6-naphthalene dicarboxylic acid;
- wherein the diamine is selected from the group consisting of ethylene diamine, propylene diamine and trans-1,4-diaminocyclohexane;
- wherein the aliphatic alkanol amine is selected from the group consisting of ethanolamine, propanolamine; wherein the aliphatic diol is selected from the group consisting of ethylene glycol, propylene glycol; wherein in the cycloaliphatic diol is cyclohexane dinethanol;
- further comprising a modifier selected from the group consisting of p-aminobenzoic acid, p-hydroxybenzoic, benzoic acid, cylcohexane carboxylic acid, cyclohexylamine, benzylamine, benzyl alcohol, cyclohexanol, zinc oxide, zinc carbonate, antimony triacetate, antimony pentoxide, antimony trioxide, calcium oxide, calcium carbonate, calcium hydroxide, magnesium hydroxide, magnesium oxide and magnesium carbonate;
- wherein in the cross-linker is selected from the group consisting of glycerine, pentaerythritol, dipentaerythritol, and trimethylol propane;
- and the dye is selected from the group consisting of a xanthene, a denzothioxanthene, a coumarin, a naphthalimide, a benzoxanthene and an acridine.
CROSS REFERENCE TO RELATED APPLICATIONS
This is a continuation of copending application Ser. No. 07/542,497 filed on Jun. 25, 1990 (now abandoned), which is a continuation in part of copending application Ser. No. 07/409,099 filed Sept. 19, 1989 (now abandoned).
US Referenced Citations (9)
Continuations (2)
|
Number |
Date |
Country |
Parent |
542497 |
Jun 1990 |
|
Parent |
409099 |
Sep 1989 |
|