Claims
- 1. A method of manufacturing a fluorocarbon-based polymer lamination coating film which comprises an inner layer comprising an adsorbed film, and an outer layer comprising a cross-linked fluorine-based polymer film wherein the inner layer is bonded onto a substrate surface with siloxane bonds, and said inner layer is bonded to said outer layer, comprising
- contacting a silane-based surface active material, capable of reaction with an active hydrogen, with the substrate surface to form the adsorbed film, and
- bonding the fluorine-based polymer by a cross-linking reaction process on the adsorbed film.
- 2. The method of manufacturing the fluorocarbon-based polymer lamination coating film according to claim 1, wherein the silane-based surface active material is selected from the group consisting of alkyl silane halide, alkenyl silane halide, alkynyl silane halide, alkoxyl-based silane, fluoroalkyl silane halide, fluoroalkenyl silane halide, fluoroalkynyl silane halide and fluoroalkoxyl-based silane.
- 3. The method of manufacturing the fluorocarbon-based polymer lamination coating film according to claim 1, wherein the adsorbed film is formed on the surface of the substrate by bringing the substrate in contact with a non-aqueous organic solvent containing the silane-based surface active material; and wherein the fluorine-based polymer film is then formed by coating fluorine-based polymer molecules onto the adsorbed film.
- 4. The method of manufacturing the fluorocarbon-based polymer lamination coating film according to claim 1, further comprising irradiating said fluorine-based polymer bonded by a cross-linking reaction process, after bonding the fluorine-based polymer on the adsorbed film.
- 5. The method of manufacturing the fluorocarbon-based polymer lamination coating film according to claim 1, wherein at least one of the silane-based surface active material and the fluorine-based polymer contains C.dbd.C and/or C.tbd.C bonds.
- 6. The method of manufacturing the fluorocarbon-based polymer lamination coating film according to claim 1, wherein said fluorine-based polymer is a solvent soluble polymer.
- 7. The method of manufacturing the fluorocarbon-based polymer lamination coating film according to claim 1, wherein said substrate is made of a member selected from the group consisting of metals, ceramics, glass and plastics.
- 8. The method of manufacturing the fluorocarbon-based polymer lamination coating film according to claim 1, wherein said substrate is made of a plastic material treated in a plasma or corona atmosphere containing oxygen.
Priority Claims (1)
Number |
Date |
Country |
Kind |
2-302021 |
Nov 1990 |
JPX |
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Parent Case Info
This application is a continuation of U.S. application Ser. No. 08/278,126, filed Jul. 21, 1994, now abandoned, which is a continuation of U.S. application Ser. No. 08/061,284, filed May 14, 1993, now abandoned, which is a divisional of U.S. application Ser. No. 07/786,824, filed Nov. 1, 1991, now U.S. Pat. No. 5,238,746.
US Referenced Citations (2)
Number |
Name |
Date |
Kind |
4761316 |
Ogawa |
Aug 1988 |
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4992300 |
Ogawa et al. |
Feb 1991 |
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Divisions (1)
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Number |
Date |
Country |
Parent |
786824 |
Nov 1991 |
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Continuations (2)
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Number |
Date |
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Parent |
278126 |
Jul 1994 |
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Parent |
61284 |
May 1993 |
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