Claims
- 1. Cosmetic or dermatological emulsion of the water-in-oil type, comprising an aqueous phase emulsified by means of a silicone surfactant in a continuous fatty phase containing at least one fluorohydrocarbon, wherein said fluorohydrocarbon is liquid, solid or pasty, has a substitution ratio of between 0.5 and 95%, has at least one hydrocarbon group and has the formula (I):
- (R.sub.F).sub.x --(A).sub.y --(R.sub.H).sub.2 (I)
- in which:
- x represents 1, 2 or 3,
- y represents 0 or 1,
- z represents 0, 1, 2 or 3,
- on the condition that y and z are not simultaneously 0, and that when z is 0, x is 2 or 3,
- R.sub.F represents a fluorinated radical selected from the group consisting of saturated and unsaturated, linear, branched and cyclic, aliphatic and aromatic fluorinated radicals which may be functionalized by insertion, terminal or pendant substitution of the backbone by at least one organic functional group selected from the group consisting of an alcohol, thiol, acid, carbonyl, sulfoxide, ester, amide, amine, phosphate, ethylene, acetylene, enamide and sulfonamide, interrupted by one or more oxygen or sulfur atoms or carrying hydrogen substituents or halogen substituents other than fluorine, provided that for any two carbon atoms of the skeleton, no more than one of said substituents other than fluorine is present on said two carbon atoms,
- R.sub.H is an aliphatic hydrocarbon radical selected from the group consisting of saturated and unsaturated, linear and branched radicals, which may be functionalized by insertion, terminal or pendant substitution of the backbone by at least one organic functional group selected from the group consisting of an alcohol, thiol, acid, carbonyl, sulfoxide, ester, amide, amine, phosphate, ethylene, acetylene, enamide and sulfonamide, or interrupted by one or more oxygen or sulfur atoms,
- A represents a di-, tri- or quadrivalent radical of the formula: ##STR20## or cyclic, aliphatic or aromatic structures or ethylenic unsaturations; the aqueous phase representing 10 to 90% by weight of the emulsion and said emulsion being in the form of a milk, a cream for skin or hair care, anti-sun cream, coloured cream, foundation, lipstick, mascara or blusher.
- 2. Emulsion according to one of claim 1, wherein the formula for the fluorohydrocarbon is the following formula (III):
- R.sub.1 --(CH.sub.2).sub.n --X--(C.sub.3 H.sub.5 (OH))--(Y).sub.x --R.sub.2(III)
- where C.sub.3 H.sub.5 (OH) represents: ##STR21## R.sub.1 represents a linear or branched perfluorinated C.sub.4 -C.sub.20 alkyl radical or a mixture of linear or branched perfluorinated C.sub.4 -C.sub.20 radicals,
- R.sub.2 represents a linear or branched C.sub.1 -C.sub.22 alkyl radical or a mixture of linear or branched C.sub.1 -C.sub.22 alkyl radicals or a C.sub.6 -C.sub.10 aryl or C.sub.7 -C.sub.15 aralkyl radical,
- X and Y, which are identical or different, represent: ##STR22## provided that X and Y do not simultaneously represent ##STR23## n is between 0 and 4, and x represents 0 or 1
- or the formula (IV):
- R.sub.F --(CH.sub.2).sub.n --X--(C.sub.3 H.sub.5 (OH))--Y--(CH.sub.2).sub.m --R'.sub.F (IV)
- in which C.sub.3 H.sub.5 (OH) represents the structures: ##STR24## R.sub.F and R'.sub.F, which are identical or different, represent a linear or branched perfluorinated C.sub.4 -C.sub.20 alkyl radical or a mixture of linear or branched perfluorinated C.sub.4 -C.sub.20 alkyl radicals;
- m and n, which are identical or different, represent 0, 1, 2, 3 or 4;
- X and Y, which are identical, are --O-- or --S--;
- or the formula (I')
- R.sub.F --(CH.sub.2).sub.n --X--(C.sub.3 H.sub.5 (OH))--Y--(CH.sub.2).sub.m --R'.sub.F (I')
- in which C.sub.3 H.sub.5 (OH) represents the structures: ##STR25## R.sub.F and R'.sub.F, which are identical or different, represent a linear or branched perfluorinated C.sub.4 -C.sub.20 alkyl radical or a mixture of linear or branched perfluorinated C.sub.4 -C.sub.20 alkyl radicals;
- m and n, which are identical or different, represent 0, 1, 2, 3 or 4 and X is O and Y is S or X is S and Y is O;
- or the formula (V): ##STR26## where Y is OH, and Z is ##STR27## or alternatively Y is --CH.sub.2 OH and Z is --O--OCH.sub.3 X represents ##STR28## and R.sub.F represents a linear or branched perfluorinated C.sub.4 -C.sub.20 alkyl radical, or a mixture of linear or branched perfluorinated C.sub.4 -C.sub.20 alkyl radicals;
- or the formula (VI):
- R.sub.F --CH.dbd.CH--CH.sub.2 --O--CH.sub.2 --(C.sub.2 H.sub.4 --OW)(VI)
- where
- C.sub.2 H.sub.4 OW designates: ##STR29## W designating: ##STR30## R designates a linear or branched C.sub.1 -C.sub.18 alkyl radical, R' designates --CH.sub.3 or --OH, in the ortho or para position, and
- R.sub.F represents a linear or branched perfluorinated C.sub.4 -C.sub.20 alkyl radical, or a mixture of linear or branched perfluorinated C.sub.4 -C.sub.20 alkyl radicals;
- or the formula (VII): ##STR31## in which n is an integer equal to 6 or 8 and p is 1 or 2.
- 3. Emulsion according to claim 1, wherein the continuous phase contains at least 50% by weight of fluorohydrocarbon.
- 4. Emulsion according to claim 1, wherein the silicone surfactant is of the following formula (II): ##STR32## in which X represents CH.sub.3, (CH.sub.2).sub.p --(C.sub.2 H.sub.4 O).sub.m --(C.sub.3 H.sub.6 O).sub.n --R.sub.2
- Y represents (CH.sub.2).sub.p --O--(C.sub.2 H.sub.4 O).sub.m --(C.sub.3 H.sub.6 O).sub.n --R.sub.2
- R.sub.1 represents a C.sub.2 -C.sub.18 alkyl radical
- R.sub.2 represents H, a C.sub.1 -C.sub.5 alkyl radical, an aryl radical or an acetyl radical,
- p=1 to 5
- m=0 to 50
- n=0 to 30, m and n not simultaneously being 0
- a=0 to 100
- b=1 to 50
- c=0 to 300,
- or the following formula: ##STR33## in which R and R.sub.1 are C.sub.1 to C.sub.8 alkyl groups, a and b have a value between 0 and 200 and x has a value between 1 and 100, a and b not simultaneously being zero.
- 5. Emulsion according to claim 4, wherein it comprises a silicone surfactant of formula (II) where a is zero in combination with at least one hydrocarbon surfactant with an HLB less than 7.
- 6. Emulsion according to claim 1, wherein the silicone surfactants are used in proportions of between 0.5 and 40% by weight relative to the weight of the emulsion.
- 7. Emulsion according to claim 6, wherein the silicone surfactants are used in proportions of between 2 and 10% by weight relative to the weight of the emulsion.
- 8. Emulsion according to claim 1, wherein it comprises, in addition, at least one pulverulent product of natural or synthetic origin.
- 9. Emulsion according to claim 1, which further comprises, in the fatty phase, an excipient selected from the group consisting of oils, waxes, oily gelling agents, screening agents, vitamins, hormones, antioxidants, preservatives, colorants and perfumes and, in the aqueous phase, an excipient selected from the group consisting of polyols, gelling agents, swelling agents, amino acids, colorants and active agents.
- 10. Emulsion according to claim 1, wherein the fluorohydrocarbons have a substitution ratio of between 10 and 80%.
- 11. A water-in-oil type cosmetic or dermatological emulsion comprising an aqueous phase emulsified by a silicone surfactant, in a continuous fatty phase containing at least one fluorohydrocarbon, wherein said fluorohydrocarbon has at least one hydrocarbon group, a substitution ratio of between 0.5 and 95% and is liquid, solid or pasty, and said silicone surfactant has the formula (II): ##STR34## in which: X represents CH.sub.3, (CH.sub.2).sub.p --(C.sub.2 H.sub.4 O).sub.m --(C.sub.3 H.sub.6 O).sub.n --R.sub.2,
- Y represents (CH.sub.2).sub.p --O--(C.sub.2 H.sub.4 O).sub.m --(C.sub.3 H.sub.6 O).sub.n --R.sub.2,
- R.sub.1 represents a C.sub.2 -C.sub.18 alkyl radical,
- R.sub.2 represents H, a C.sub.1 -C.sub.5 alkyl radical, an aryl radical or an acetyl radical,
- p=1 to 5,
- m=0 to 50,
- n=0 to 30, m and n not simultaneously being 0,
- a=0 to 100,
- b=1 to 50, and
- c=0 to 300
- or the formula (VIII): ##STR35## wherein R and R.sub.1 are C.sub.1 to C.sub.8 alkyl groups, a and b have a value between 0 and 200, a and b not simultaneously being zero, and x has a value between 1 and 100;
- the aqueous phase representing 10 to 90% by weight of the emulsion, said emulsion being in the form of a milk, a cream for skin or hair care, anti-sun cream, coloured cream, foundation, lipstick, mascara or blusher.
Priority Claims (1)
Number |
Date |
Country |
Kind |
92 12608 |
Oct 1992 |
FRX |
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Parent Case Info
This application is a continuation of application Ser. No. 08/139,163, filed Oct. 21, 1993, now abandoned.
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Continuations (1)
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Number |
Date |
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Parent |
139163 |
Oct 1993 |
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