Patent Application
20220235491
The present invention relates to a nozzle for use in an electrospinning spinneret. In a further aspect the present invention relates to an electrospinning spinneret comprising one or more nozzles.
International patent publication WO 2016/126201 A1 discloses a spinneret for use in electrospinning production of a filament. An inside surface of a chamber of the spinneret is provided with an electrode baffle structure to provide an electrical charge to the fluid in the chamber.
The present invention seeks to provide an improved nozzle for use in an electrospinning spinneret, wherein the nozzle provides improved high voltage efficiency, reduced corona formation and arcing as well as reduced ozone production. The nozzle further increases safety for operators.
According to the present invention, a nozzle of the type mentioned in the preamble is provided, wherein the nozzle comprises a material transporting channel having a wall, wherein the wall has a droplet forming end surface, and wherein the nozzle further comprises an electrode that extends through the material transporting channel at least up to the end surface of the wall. The end surface of the material transporting channel is a surface perpendicular to a longitudinal direction of (the material transporting channel of) the nozzle, and is arranged for electrospinning, i.e. forming and/or supporting a droplet of liquefied material (dissolved or molten), from which a fiber is electrospun during operation. It is noted that the present invention embodiments can also be advantageously used in electrospraying, forming particles instead of fibers.
The nozzle of the present invention, in particular the electrode thereof, provides a highly efficient transportation of the charge to the formed droplet, and at the same time allows to keep the charging of the nozzle, more specific in the material transporting channel, to a minimum. Focussing the charge towards the end of the nozzle/droplet results in a high charge density inside the droplet. This in turn significantly improves high voltage efficiency of the nozzle and reduces power consumption. When applied in an electrospinning spinneret comprising one or more of the present invention nozzles, a highly efficient and reliable and more reproducible electrospinning process can be obtained.
The present invention will be discussed in more detail below, with reference to the attached drawings, in which
Electrospinning is a method to produce continuous fibres with a diameter ranging from a few tens of nanometres to a few tens of micrometres. To produce such fibres, a suitable liquefied material may be fed through a channel of a small nozzle as part of an electrospinning “spinneret” arrangement. The liquefied material may be electrically charged by applying a high voltage (HV) between an electrode arranged on the nozzle and an opposing collector electrode spaced remote therefrom (e.g. on a target surface). The electric field being generated causes a cone-shape deformation of a droplet of the liquefied material being formed at a tip portion of the nozzle (also named Taylor cone). When surface tension of the droplet is overcome by electrical force, a jet of liquefied material moves out of the droplet producing a fiber that moves towards the opposing electrode. During flight towards the opposing electrode, the fiber is continuously stretched and elongated by different forces acting on it, thereby reducing its diameter and allowing it to solidify. The solidification may be induced by e.g. evaporation of a solvent or cooling of the material, such that a solid fiber is deposited on a target collector. This target collector may be placed just in front of the opposing electrode or the opposing electrode itself may be used as the target collector.
The material transporting channel 2 comprises an end surface 4 for forming and/or supporting a droplet “D” of liquefied material. This end surface 4 is located at an outlet end 1b of the nozzle 1. The end surface 4 of the material transporting channel 2 is a surface perpendicular to a longitudinal direction of the nozzle 1, more particular of a longitudinal direction of the material transporting channel 2, and is arranged for electrospinning, i.e. forming and/or supporting a droplet of liquid material, from which a fiber is electrospun during operation,
The nozzle 1 further comprises an electrode 5 that extends through the material transporting channel 2, i.e. through the passageway 2a, at least up to the end surface 4 of the wall 3.
Note that when the nozzle 1 is used in an electrospinning spinneret in operation, the electrode 5 may be connected to a high voltage (HV) power supply 6 and, as part of the electrospinning spinneret, a collector 7 may be arranged opposite to the electrode 5 and spaced apart therefrom. When the nozzle 1 is in use, there is a voltage difference between the electrode 5 and collector 7.
According to the invention, by allowing the electrode 5 to extend all the way to at least the end surface 4 of the wall 3, a sharply focused charge can be created in the droplet D whilst not needing to further increase the high voltage applied to the electrode 5. The focussed charge in the droplet is achieved as electric charge tends to concentrate at a sharp edge surface such as the end of the electrode 5. As per the present invention, since a tip of the electrode 5 at or extending from the end surface 4 is considered closest to such an opposing collector 7 when the nozzle is used in an electrospinning spinneret, electric charge sharply focusses on the tip of the electrode 5 during an electrospinning process.
As depicted in
The end surface 4 provides a basis at which a droplet of liquid material can be formed into a Taylor cone when the nozzle 1 is in use. Furthermore, the outermost nozzle point must be understood as being a point of the nozzle 1 opposing collector 7 when the nozzle 1 is used in an electrospinning spinneret.
To further focus electric charge density in the droplet D, in an advantageous embodiment the electrode 5, e.g. the electrode tip 5a, extends beyond the end surface 4 of the wall 3. So in these embodiments, the electrode 5, in particular the electrode tip 5a, extends over a non-zero extension length L beyond the end surface 4.
In an exemplary embodiment, the electrode 5 extends from the end surface 4 of the wall 3 over a distance of at least half of a diameter of the material transporting channel 2. In this embodiment the extension length L is at least half of the diameter of the material transporting channel 2 near to the end surface 4 to allow the electrode 5, e.g. the electrode tip 5a, to sufficiently extend into the droplet D when the nozzle 1 is in use and sharply focus the charge density in the droplet D. In an exemplary embodiment, the extension length L is between 0 and 5 mm, thereby allowing for a wide range of size of droplets D. In a specific embodiment, the extension length L may be about 1 micron, which may already provide a well-focused charge density in the droplet D.
As further depicted in
In a further embodiment the electrode 5 extends circumferentially along the wall 3 toward the end surface 4 (or the wall termination point 8 or outermost nozzle point 10). In this way a tubular electrode 5 may be obtained to allow for a circumferential or ring-like focused electric charge on the end surface 4.
In an advantageous embodiment, the electrode 5 is an electrically conductive deposited layer, e.g. deposited on the wall 3, for reduced design complexity of the nozzle 1 and facilitate manufacturing thereof through, e.g., using electroplating, PVD, chemical coating etc. In an advantageous embodiment the electrically conductive deposited layer comprises gold (Au), silver (Ag), and/or copper (Cu) to provide excellent electrical conductivity for creating a strongly focussed electric field at the end surface 4. In
In an embodiment, the material transporting channel 2 may comprise a non-conductive material, so that only the electrode 5 and in particular the electrode tip 5a contributes to the electrical field in the droplet D. In an embodiment, the non-conductive material may be a polymer or synthetic material. In an alternative embodiment the non-conductive material may be a ceramic material, which provides for a mechanically durable material transporting channel 2. In an even further embodiment, the non-conductive material may be a glass material.
In an alternative embodiment the material transporting channel 2 may (partially) comprise or be made of an electrically conductive material. Although this possibly provides for a secondary region of (weaker) focussed electric charge at the end surface 4, a much stronger primary focused electric charge is provided by the electrode 5.
As mentioned above, according to the invention the electrode 5 extends through the material transporting channel 2 at least up to the end surface 4 of the wall 3 which will be located closest to an opposing collector 7 when the nozzle 1 is used in an electrospinning spinneret. The electrode 5 allows for strongly focussed electric charge in the droplet D for improving stable fibre formation and also to reduce the voltage applied to the electrode 5 as much as possible, thereby improving high voltage efficiency.
Prior art electrospinning spinneret designs often use all metal parts in nozzles in order to provide a high voltage from the nozzle toward a droplet. However, the amount of (exposed) metal of nozzles increases when the number of nozzles in an electrospinning spinneret increases, yielding a lower charge density at each nozzle of the electrospinning spinneret, and possibly resulting in mutual influencing of the electric field in the different nozzles. To compensate for such lower charge density, the electrode voltage must be increased in such prior art designs.
Other prior art electrospinning spinneret designs use conductivity of a liquid solution in order to transfer electric energy. However, (variable) conductivity of such a liquefied material solution has a direct effect on performance and power requirements of the electrospinning process.
Another problem seen with prior art multi-nozzle electrospinning spinnerets is that increasing the electrode voltage often yields an unstable electrospinning process due to higher repulsion forces of charged fibres
The nozzle 1 of the present invention reduces the above mentioned interaction if multiple nozzles 1 are used in a spinneret as there is a sharply focused electric charge density at the electrode 5 rather than the nozzle 1 itself, i.e. the material transporting channel 2. This in turn reduces loss of electric charge density at the droplet D and improves high voltage efficiency and lowers power consumption.
As shown, each of the electrodes 5, 5′ extends at least up to their respective end surfaces 4, 4′ of the walls 3, 3′. This allows for sharply focused electric charge densities at the droplets D, D′ and as such each individual nozzle 1, 1′ exhibits improved high voltage efficiency and lower power consumption.
According to the present invention, an electrospinning spinneret is thus provided comprising one or more nozzles 1, 1′ as described above, thereby reducing the power to operate the electrospinning spinneret as well as reducing interaction/interference between the one or more nozzles 1, 1′, thereby simplifying control of the electrospinning process.
In an embodiment, an electrode distance X between two or more electrodes 5, 5′ may be chosen so as to further control the influence/interaction between the electric charge of each nozzle 1, 1′
In an embodiment, the electrospinning spinneret may further comprise a fluid supply (not shown) for each of the one or more nozzles 1, 1′ as well as a control unit (not shown) for individually controlling a flow rate of each fluid supply to achieve optimal fibre formation at each nozzle 1, 1′. In an embodiment, the fluid supply may provide to each of the one or more nozzles 1, 1′ a liquefied material M, M′, e.g. a polymeric material M, M′.
In a further embodiment, the electrospinning spinneret further comprises a high voltage power supply 6, 6′ for each of the one or more nozzles 1, 1′, and a control unit for individually controlling the output of each high voltage power supply 6, 6′, see e.g. the embodiment shown in
Utilizing a particular arrangement of a plurality of nozzles 1, 1′ allows for electrospinning spinnerets that exhibit high voltage efficiency, provide reduced nozzle interference, and consume less power. For example, in an embodiment the electrospinning spinneret, the one or more nozzles 1, 1′ are arranged in a circular arrangement. Such a circular arrangement can be miniaturized (i.e. made smaller) as the plurality of nozzles 1, 1′ exhibit less mutual interference because of the increased focussed electric charge density at each of the electrodes 5, 5′. In a specific group of embodiments, the electrospinning spinneret may comprise a circular arrangement of five nozzle at an angular separation of 72° degrees, or e.g. six nozzles at angular separation of 60° degrees.
The electrospinning spinneret of the present invention may also comprise a plurality of nozzles 1, 1′ that are arranged in alternative fashion. For example, in an embodiment the plurality of nozzles 1, 1′ may be arranged in an m x n array, m and n being integers. As with circular arrangements, the nozzle 1 of the present invention allows for an array of m x n nozzles 1,1′ that can be arranged more densely (e.g. at an equidistant spacing) without introducing unwanted interference between the plurality of nozzles 1, 1′.
In the above, exemplary embodiments of the present invention have been described with reference to the drawings, which may also be described by the following numbered and interrelated embodiments.
Embodiment 1. A nozzle (1) for an electrospinning spinneret, wherein the nozzle (1) comprises a material transporting channel (2) having a wall (3), wherein the wall (3) has an end surface (4) for forming a droplet, wherein the nozzle (1) further comprises an electrode (5) extending through the material transporting channel (2) at least up to the end surface (4) of the wall (3).
Embodiment 2. The nozzle according to embodiment 1, wherein the electrode (5) extends beyond the end surface (4) of the wall (3).
Embodiment 3. The nozzle according to embodiment 1, wherein the electrode (5) extends from the end surface (4) of the wall over a distance (L) of at least half of a diameter of the channel (2).
Embodiment 4. The nozzle according to any one of embodiments 1-3, wherein the electrode (5) is positioned on an inner surface of the wall (3).
Embodiment 5. The nozzle according to embodiment 4, wherein the electrode (5) is an electrically conductive deposited layer.
Embodiment 6. The nozzle according to embodiment 4, wherein the electrode (5) is arranged centrally within the material transporting channel (2).
Embodiment 7. The nozzle according to embodiment 6, wherein the electrode (5) is a wire.
Embodiment 8. The nozzle according to any one of embodiments 1-7, wherein the material transporting channel (2) is of an electrically non-conductive material.
Embodiment 9. The nozzle according to embodiment 8, wherein the electrically non-conductive material is a polymer or synthetic material.
Embodiment 10. The nozzle according to embodiment 8, wherein the electrically non-conductive material is a ceramic material.
Embodiment 11. The nozzle according to any one of embodiments 1-7, wherein the material transporting channel (2) comprises electrically conductive material.
Embodiment 12. An electrospinning spinneret comprising one or more nozzles (1, 1′) according to any one of embodiments 1-11.
Embodiment 13. The electrospinning spinneret according to embodiment 12, further comprising a fluid supply for each of the one or more nozzles (1, 1′), and a control unit for individually controlling the flow rate of each fluid supply.
Embodiment 14. The electrospinning spinneret according to embodiment 12 or 13, further comprising a high voltage power supply (6, 6′) for each of the one or more nozzles (1, 1′), and a control unit for individually controlling the output of each high voltage power supply (6. 6).
Embodiment 15. The electrospinning spinneret according to embodiment 12, 13 or 14, wherein the one or more nozzles (1, 1′) are arranged in a circular arrangement.
Embodiment 16. The electrospinning spinneret according to embodiment 12, 13 or 14, wherein the one or more nozzles (1, 1′) are arranged in an m x n array, m and n being integers.
The present invention has been described above with reference to a number of exemplary embodiments as shown in the drawings. Modifications and alternative implementations of some parts or elements are possible, and are included in the scope of protection as defined in the appended claims.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2023086 | May 2019 | NL | national |
| Filing Document | Filing Date | Country | Kind |
|---|---|---|---|
| PCT/NL2020/050273 | 4/30/2020 | WO | 00 |
