Embodiments of the subject matter described herein relate generally to solar cells. More particularly, embodiments of the subject matter relate to solar cell fabrication processes and structures.
Solar cells are well known devices for converting solar radiation to electrical energy. A solar cell has a front side that faces the sun during normal operation to collect solar radiation and a backside opposite the front side. Solar radiation impinging on the solar cell creates electrical charges that may be harnessed to power an external electrical circuit, such as a load. The external electrical circuit may be electrically connected to diffusion regions of the solar cell by way of metal contacts.
In one embodiment, a metal contact of a solar cell is formed by electroplating copper using an electroplating seed that is formed on a dielectric layer. The electroplating seed includes an aluminum layer that connects to a diffusion region of the solar cell through a contact hole in the dielectric layer. A nickel layer is formed on the aluminum layer, with the nickel layer-aluminum layer stack forming the electroplating seed. The copper is electroplated in a copper plating bath that has methanesulfonic acid instead of sulfuric acid as the supporting electrolyte.
These and other features of the present disclosure will be readily apparent to persons of ordinary skill in the art upon reading the entirety of this disclosure, which includes the accompanying drawings and claims.
A more complete understanding of the subject matter may be derived by referring to the detailed description and claims when considered in conjunction with the following figures, wherein like reference numbers refer to similar elements throughout the figures.
In the present disclosure, numerous specific details are provided, such as examples of materials, process steps, and structures, to provide a thorough understanding of embodiments. Persons of ordinary skill in the art will recognize, however, that the disclosure can be practiced without one or more of the specific details. In other instances, well-known details are not shown or described to avoid obscuring aspects of the disclosure.
To be commercially viable against other sources of energy, solar cells need to be manufactured at relatively low cost and with high yield. One way of lowering the cost of manufacturing solar cells is to use printed aluminum as an electroplating seed for copper metal contacts. However, aluminum can have an adhesion problem when exposed to high acid copper plating baths typically employed in copper electroplating processes.
The adhesion problem is illustrated in
2Al(s)+3H2SO4(aq)→2Al3(aq)+3SO42−(aq)+3H2(g)
with a ΔG(r×n)=−971.0 kJ/mol
The aluminum in the electroplating seed has a thin, dense layer of aluminum oxide that may need to be penetrated before the above-noted chemical reaction can occur. The reaction of aluminum oxide with sulfuric acid is given by:
Al2O3+3H2SO4→Al2(SO4)3+3H2O
with a ΔG(r×n)=−100.5 kJ/mol.
The negative ΔG(r×n), i.e., negative Gibbs free energy, of the aluminum and aluminum oxide reactions indicates that corrosion will occur when aluminum and aluminum oxide are exposed to sulfuric acid.
Referring to
The solar cell 200 has a front side 121 that faces toward the sun during normal operation to collect solar radiation, and a backside 122 that is opposite the front side 121. In one embodiment, the solar cell 200 is an all back contact solar cell in that all of its diffusion regions and metal contacts connected to the diffusion regions are on the backside 122. Note, however, that the disclosed techniques may apply equally to other types of solar cells. For example, in other embodiments, the solar cell 200 has a diffusion region 202 of one polarity on the backside 122 and another diffusion region of another polarity on the front side 121.
Still referring to
In
In
In
2Al(s)+6CH3SO3H(aq)→2Al3+(aq)+6CH3SO3−(aq)+3H2(g)
with a ΔG(r×n)=−1039.4 kJ/mol
The reaction of methanesulfonic acid with aluminum oxide is given by:
Al2O3+3CH3SO4H→Al2(SO4)3+3CH4
with a ΔG(r×n)=459.3 kJ/mol
Although the reaction of methanesulfonic acid with aluminum still gives a negative ΔG(r×n), the reaction of methanesulfonic acid with aluminum oxide gives a positive ΔG(r×n). The positive ΔG(r×n) indicates that the methanesulfonic acid will not significantly corrode the aluminum oxide. Thus, the aluminum oxide layer 123 protects the aluminum layer 205 from being attacked by the methanesulfonic acid.
It is to be noted that although the nickel layer 206 is on the aluminum layer 205, the nickel layer 206 is porous and accordingly allows methanesulfonic acid (or sulfuric acid in other plating baths) to seep through and corrode the aluminum layer 205. The methanesulfonic copper plating bath may therefore be advantageous when the electroplating seed includes nickel as an adhesion layer.
In one embodiment, the methanesulfonic acid copper plating bath employed in the electroplating of the copper layer 207 comprises methanesulfonic acid (MSA), Cu-MSA, and, hydrochloric acid, as well as standard commercial plating organic additives, such as accelerators, suppressors, levelers, brighteners, and grain refiners. The pH of the methanesulfonic acid copper plating bath may be approximately −0.6, but generally may have a pH less than 1. Such a methanesulfonic acid copper plating bath may be commercially obtained from the OM Group, Inc., for example. Other suitable copper plating baths with methanesulfonic acid and with no sulfuric acid may also be employed without detracting from the merits of the present disclosure.
In one embodiment, the copper layer 207 is electroplated using the electroplating seed 124 to a thickness of 10-80 μm, such as about 35 μm. For example, the copper layer 207 may be formed by dipping the sample of
In one embodiment, the copper layer 207 electrically connects to the diffusion region 202, and serves as a metal contact of the solar cell 200. As can be appreciated, the copper layer 207 may be patterned or electroplated with an appropriate mask to have a variety of shapes depending on the particulars of the solar cell 200. For example, when the diffusion region 202 is a P-type diffusion region, the copper layer 207 may be configured as a positive metal contact finger that is interdigitated with another copper metal contact finger that electrically connects to an N-type diffusion region.
A nickel layer is thereafter formed on the aluminum layer (step 212). In one embodiment, the nickel layer and the aluminum layer form an electroplating seed for subsequent electroplating of a copper layer.
A metal contact of the solar cell is formed by electroplating copper in a copper plating bath that comprises methanesulfonic acid and has no sulfuric acid (step 213). As can be appreciated by one of ordinary skill in the art, “no sulfuric acid” or “without sulfuric acid” means that the copper plating bath either has zero amount of sulfuric acid or no appreciable amount of sulfuric acid to react with and corrode aluminum oxide. The copper is electroplated on the electroplating seed to electrically connect to the diffusion region of the solar cell.
The techniques described herein may facilitate improved adhesion of layers of a solar cell. Such improved adhesion can be shown by reduced corrosion of the electroplating seed, as shown in
Methods and structures for forming metal structures of solar cells have been disclosed. While specific embodiments of the disclosure have been provided, it is to be understood that these embodiments are for illustration purposes and not limiting. Many additional embodiments will be apparent to persons of ordinary skill in the art reading this disclosure.
Number | Name | Date | Kind |
---|---|---|---|
8241763 | Buesing et al. | Aug 2012 | B2 |
8367555 | Afzali-Ardakani et al. | Feb 2013 | B2 |
8426241 | Ahmed et al. | Apr 2013 | B2 |
8545998 | Kong et al. | Oct 2013 | B2 |
8629431 | Etori et al. | Jan 2014 | B2 |
8685858 | Hong et al. | Apr 2014 | B2 |
8748877 | Orita et al. | Jun 2014 | B2 |
20040200520 | Mulligan et al. | Oct 2004 | A1 |
20080035489 | Allardyce et al. | Feb 2008 | A1 |
20090017617 | Rohatgi et al. | Jan 2009 | A1 |
20100055422 | Kong et al. | Mar 2010 | A1 |
20100213455 | James et al. | Aug 2010 | A1 |
20110017291 | Morita et al. | Jan 2011 | A1 |
20110041911 | Lee et al. | Feb 2011 | A1 |
20110108115 | Deligianni et al. | May 2011 | A1 |
20120061790 | Ahmed et al. | Mar 2012 | A1 |
20120164827 | Rajagopalan et al. | Jun 2012 | A1 |
20120181529 | Tanaka et al. | Jul 2012 | A1 |
20120231575 | Okaniwa | Sep 2012 | A1 |
20120305066 | Fisher et al. | Dec 2012 | A1 |
20130065351 | Baker-O'Neal et al. | Mar 2013 | A1 |
Entry |
---|
PCT International Search Report and Written Opinion of the International Searching Authority for Application No. PCT/US2014/041973, Oct. 7, 2014, 7 sheets. |
Number | Date | Country | |
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20150004744 A1 | Jan 2015 | US |