This application is related to U.S. patent application Ser. No. 11/105,104 filed Apr. 13, 2005, and Ser. No. 12/138,975 filed Jun. 13, 2008, the entire disclosures of which are incorporated by reference herein.
This disclosure generally relates to the fabrication of composite parts, and deals more particularly with a method and apparatus for forming flat composite charges into highly contoured parts, especially contoured structural members.
Parts such as structural members formed from laminated composites may be fabricated using a flat multi-ply charge of prepreg materials. The charge may be formed into a desired part shape using a forming press having male and female dies that compress and form the charge into the desired shape, which is normally a straight or mildly contoured shape. Difficulty may be encountered, however, when attempting to form highly contoured structural members using dies as described above because of the tendency of the plies to form wrinkles as the charge is being compressed. Accordingly, the fabrication of highly contoured structural members using composites is generally limited to hand lay-up techniques in which each ply is laid up by hand over a die or other tool in order to reduce the possibility of wrinkling. This hand lay-up technique is labor intensive, and thus costly, as well as relatively slow.
A further problem with current techniques for forming highly contoured parts members is the limited flexibility of existing forming machines to accommodate differing part shapes that are highly contoured. Since the tooling normally has a permanent shape that may not be easily altered, separate tooling dies must be fabricated to accommodate differing part shapes.
Finally, existing solutions for forming highly contoured parts may require separate fixtures for forming, transporting and installing or placing the formed part on cure tooling or onto the surface of another laminate.
Accordingly, there is a need for a method and apparatus for forming highly contoured composite parts, especially structural members, that reduces or eliminates wrinkling during the forming process. There is also a need for apparatus for forming highly contoured parts that is easily reconfigurable to form parts having differing shapes and which may be used to transport and place the formed part.
The disclosed embodiments provide a method and apparatus for forming highly contoured composite parts, especially elongate parts such as structural members, using a substantially flat composite charge that may comprise multiple plies of prepreg material. The apparatus includes mating dies having contour shapes that may be easily and automatically reconfigured to produce a variety of parts having various contours. One of the dies has multiple die portions that are independently controllable to progressively form the charge in a manner that maintains the charge in tension in order to reduce or eliminate wrinkling. Using digital controls and suitable algorithms, the apparatus may form a part from the bottom up or the top down, or any combination therebetween, thus assuring that the composite charge will be formed substantially without wrinkles regardless of whether the contouring is concave, convex or a combination of both concave and convex anywhere along the length of the part. The method may ensure that the plies of the charge are constantly being formed and moved to a larger radius of the contour, and thus kept in tension. One of the dies may be used to support the formed part during transportation and handling, and may also be used to assist in placing the part on a substrate such as a skin layup, thus eliminating the need for special tooling for transporting and placing the part.
In accordance with one disclosed embodiment, apparatus is provided for forming a composite charge into a contoured part, comprising: first and second dies between which the charge may be formed, the first die having a plurality of first die portions individually displaceable and forming a changeable die contour; a plurality of actuators for respectively displacing the first die portions; and a programmed controller for controlling the first actuators to displace the first die portions to form a desired contour. The first die may include a flexible die tray and a plurality of die portions mounted on the die tray. The first die includes a plurality of die portions controlled by actuators which change the contour of the first die. The second die includes a plurality of die portions also controlled by actuators which displace the die portions of the second die sequentially in order to progressively form the charge in a manner that maintains the charge in tension during the forming process.
According to another disclosed embodiment, apparatus for forming a composite charge into a contoured part, comprises: first and second dies between which the charge may be formed, the first die having a contour corresponding to the contour of the part to be formed, the second die including a plurality of die portions; and, means for closing the die portions of the second die against the first die in a predetermined sequence that substantially maintains tension on the composite charge as the charge is being formed.
According to a further embodiment, apparatus is provided for forming a composite charge into a shaped part, comprising: a forming machine for forming the composite charge; a portable carrier for transporting the shaped part away from the forming machine; first and second dies between which the charge may be formed, the first die being mounted on the forming machine, and the second die being mounted on the portable carrier; and, means for releasably coupling the portable carrier with the forming machine.
According to a disclosed method embodiment, forming a contoured composite part comprises: placing an essentially flat composite charge between first and second dies; keeping the first and second dies separated by the thickness of the flat charge and moving the first and second dies together to form the contour of the centerline of the charge without forming the cross section of the part, then moving the second die towards the first die to form the part cross section in convex curves and the first die towards the second die to form the part cross section in concave curves. An optional disclosed method embodiment; forming a contoured composite part comprises: placing an essentially flat composite charge between first and second dies using the first and second dies to form a portion of charge to the steepest contour of the part; and, using the first and second dies to form the remaining portions of the charge to other contours of the part, including maintaining tension on the charge as the remaining portions of the charge are formed.
According to a another disclosed method embodiment, reducing wrinkles in a composite charge as the charge is being formed into a part having a contour, comprises: forming a first portion of the charge to a tightest part of the contour; and, then, forming other portions of the charge to other parts of the contour, including maintaining tension on the charge as the other portions of the charge are being formed.
According to a further disclosed method, forming composite charges into contoured composite parts, comprises: storing a plurality of data files respectively containing contour data representing the contours of a plurality of parts; selecting a part to be formed; retrieving contour data from one of the data files for the selected part; using the retrieved contour data to calculate the relative displacement between two dies that will maintain tension of the charge as the charge is being formed; and forming the flat charge between the dies, including relatively displacing the dies according to the calculated displacement.
According to yet another method embodiment, a manufacturing method comprises: placing a first die in a forming machine; placing a second die on a portable carrier; coupling the portable carrier to the forming machine such that the first and second dies are in registration with each other; using the first and second dies to form a composite charge into a shaped part; uncoupling the portable carrier from the forming machine after the shaped part has been formed; and transporting the shaped part away from the forming machine using the portable carrier, including using the second die to support the shaped part as the shaped part is being transported.
The disclosed embodiments satisfy the need for a method and apparatus for forming highly contoured composite parts that is easily configurable to form various contours and reduces or eliminates wrinkles in the formed parts.
Other features, benefits and advantages of the disclosed embodiments will become apparent from the following description of embodiments, when viewed in accordance with the attached drawings and appended claims.
Referring first to
The apparatus 30 broadly includes first and second dies 32, 34, respectively between which a flat composite charge 36 may be formed into a contoured part substantially free of wrinkles. The first die 32 includes a plurality of first die portions 32a that are independently displaceable relative to each other and react against a corresponding set of first anvils 78. The first die portions 32a collectively form a changeable die contour (
The first die 32 is supported on a flexible die tray 56 mounted on portable carrier 30b that is releasably coupled to the first anvils 78 by means of a releasable coupling 95. A set of contour control actuators 77 control the displacement of the first anvils 78, and thus control the independent displacement of the first die portions 32a to change the contour of the first die 32 along its length. A set of shape forming actuators 75 control displacement of the second anvils 80, and thus independently control the displacement of the second die portions 34a. Actuators 75, 77 are controlled by a programmed controller 134 which, as will be discussed later, uses operator inputs, an algorithm and part contour data to control the operation of the actuators 75, 77. Through the operation of the controller 134, the first die portions 32a may be individually displaced to collectively form a changeable die contour 37 (
The composite charge 36 may comprise multiple plies (not shown) of prepreg materials which may be knitted or woven fabrics pre-impregnated with a suitable resin binder. However, the disclosed method and apparatus may also be useful in forming dry charges where the fabrics have been pre-treated with resin materials that may cause the plies to wrinkle during the forming process. Similarly, the disclosed method and apparatus may be useful in forming multi-ply charges of dry fabric having “tackifiers” that tack the fabric plies together in a desired shape and/or alignment prior to resin infusion. Also, although the disclosed embodiments have been illustrated in connection with the forming of composite charges 36, they may also be useful in forming charges comprising other multi-ply materials having a tendency to wrinkle during the forming of highly contoured parts.
Referring now particularly to
The first die 32 is mounted on the portable carrier 30b, while the second die 34 is mounted on the forming machine 30a. The portable carrier 30b comprises a wheeled frame 62 having a beam 60 mounted thereon. The first die 32 comprises a plurality of individual die portions 32a that are individually displaceable relative to each other and thus form a changeable die contour 37. The die portions 32a are mounted on a flexible die tray 56 formed of any suitable flexible material, such as thin aluminum or a synthetic material. The die tray 56 is supported on a plurality of spaced apart push rods 58 that are each mounted for vertical displacement on the beam 60. As will be discussed later in more detail, the portable carrier 30b may be used to transport the first die 32 supporting a formed part 38 therein to a location where the part 38 may be transferred to either cure tooling (not shown) or placed upon a substrate, such as an uncured skin (not shown).
The second die 34 is mounted on the bottom of a flexible backing plate 48 which may comprise, for example and without limitation, relatively thin aluminum or other similar metals or flexible synthetic materials. The backing plate 48 is mounted on a plurality of second anvils for sliding movement along the x axis by a series of slide plates 54 that will be discussed in more detail below. The second anvils 80 are secured to brackets 76 mounted on corresponding slide arms 66. The slide arms 66 are mounted for independent vertical sliding movement along the y-axis, on vertical supports 70 which are in turn secured to a frame 64. The vertical supports 74 are displaceable by the shape forming actuators 75 along the y-axis.
The first anvils 78 are respectively secured to the slide arms 68 by brackets 81. The slide arms 68 are slideably mounted on the vertical supports 70 for movement along the y-axis. The support arms 68 are also secured to vertical supports 72 which are displaceable along the y-axis by contour control actuators 77. Thus, from the forgoing description, it can be appreciated that the first and second anvils 78, 80 respectively, are moveable toward and away from each other, respectively driven by the actuators 77, 75.
Referring now particularly to
As shown in
The backing plate 48 may include a plurality of longitudinally spaced, transversely extending grooves or slots 50 therein which reduce the thickness of the backing plate 48 at spaced apart locations that provide the backing plate 48, and thus the second die 34, with the necessary flexibility to bend and/or twist in order to form highly contoured part shapes.
Attention is now directed to
Slide plate 104, and thus the tray 56, are releasably connected to the upper bracket 98 by means of a hinge pin 108 that extends through ears 106 on the slide plate 104 and a portion 99 of the upper bracket 98. The hinge pin 108 may include a handle 108a that allows easy removal of the hinge pin 108. Removing the hinge pin 108 releases the tray 56 from the portable carrier 30b, thus allowing the tray 56 to be used in either placing the formed part 38 on a substrate (not shown), or transporting the formed part 38 to a curing die (not shown), or to be replaced with another tray 56 having a different die.
The tray 56 may slide on the upper surface of the plate 104 which remains stationarily connected to the upper bracket 98. Four sets of guides 112 are mounted on the tray 56 and include rollers 112a that engage the bottom and edges of the plate 104 in order to maintain alignment of the tray 56 relative to the plate 104 during sliding movement of the tray 56.
Reference is now also made to
Referring now also to
The first die 32 having been configured to a desired contour, the forming process is then commenced in which the second anvils 80 independently displace portions of the upper backing plate 48 which in turn displaces portions 34a of the flexible, second die 34. As will be described in more detail below, as the second die 34 is closed against the contoured first die 32, portions of the charge 36 are progressively formed to the desired contour by sequentially displacing second die portions 34a in a manner that maintains the charge in tension during the forming process.
As previously discussed, maintaining the charge in tension may reduce the possibility of wrinkling of the charge 36 during forming. The disclosed embodiments maintain the charge 36 in tension during the forming process by forming the charge 36 from the top down or the bottom up, depending upon the direction of a particular contour on the part 38. By forming from the top down or bottom up beginning at the steepest part of the contour, the plies of the charge 36 are constantly being formed toward a large radius of the contour, thus maintaining the plies in tension.
Attention is now directed to
In
Attention is now directed to
Based on a part number selected by an operator using the operator input controls 136, the controller 134 selectively actuates the contour control actuators 77 in order to configure the first die 32 to a contour corresponding to that of the selected part 38. The contour of the first die 32 having been configured, the controller 134 then selectively controls the shape forming actuators 75 to carry out progressive forming of the charge 36 using either top down or bottom up forming, or a combination of both, as described above. From the foregoing, it may be appreciated that automated control and algorithms, the apparatus 30 may form a flat charge 36 into a part 38 from the bottom up or top down or any combination in between. This allows any given part 38 to change form without wrinkles regardless of whether it is bent in a convex or concave direction or a combination of both anywhere along its length.
Attention is now directed to
At this point, the first and second dies 32, 34 respectively have been readied for forming. At 162, the controller 134 controls the shape forming actuators 75 to sequentially displace the second die portions 34a so that the charge 36 is progressively formed while tension is maintained on the charge throughout the forming process. When the first and second dies 32, 34 have been completely closed, the charge is formed to shape at step 164.
Attention is now directed to
Embodiments of the disclosure may find use in a variety of potential applications, particularly in the transportation industry, including for example, aerospace, marine and automotive applications. Thus, referring now to
Each of the processes of method 210 may be performed or carried out by a system integrator, a third party, and/or an operator (e.g., a customer). For the purposes of this description, a system integrator may include without limitation any number of aircraft manufacturers and major-system subcontractors; a third party may include without limitation any number of vendors, subcontractors, and suppliers; and an operator may be an airline, leasing company, military entity, service organization, and so on.
As shown in
Systems and methods embodied herein may be employed during any one or more of the stages of the production and service method 210. For example, components or subassemblies corresponding to production process 218 may be fabricated or manufactured in a manner similar to components or subassemblies produced while the aircraft 212 is in service. Also, one or more apparatus embodiments, method embodiments, or a combination thereof may be utilized during the production stages 218 and 220, for example, by substantially expediting assembly of or reducing the cost of an aircraft 212. Similarly, one or more of apparatus embodiments, method embodiments, or a combination thereof may be utilized while the aircraft 212 is in service, for example and without limitation, to maintenance and service 226.
Although the embodiments of this disclosure have been described with respect to certain exemplary embodiments, it is to be understood that the specific embodiments are for purposes of illustration and not limitation, as other variations will occur to those of skill in the art.
This application is a divisional application of U.S. patent application Ser. No. 12/258,404, filed Oct. 25, 2008.
Number | Name | Date | Kind |
---|---|---|---|
1433879 | Fancher et al. | Oct 1922 | A |
1504547 | Egerton | Aug 1924 | A |
1965716 | Thoms et al. | Jul 1934 | A |
2750629 | Georges | Jun 1956 | A |
2981976 | Maier | May 1961 | A |
3376184 | Ritchey et al. | Apr 1968 | A |
3526558 | Beeson | Sep 1970 | A |
3693924 | Blatherwick | Sep 1972 | A |
3843756 | Talbott et al. | Oct 1974 | A |
3975363 | Jones | Aug 1976 | A |
3990291 | Evertz et al. | Nov 1976 | A |
4132755 | Johnson | Jan 1979 | A |
4254735 | Postupack et al. | Mar 1981 | A |
4270964 | Flaskett | Jun 1981 | A |
4338070 | Nava | Jul 1982 | A |
4366698 | Gill | Jan 1983 | A |
4367644 | Kramer et al. | Jan 1983 | A |
4411148 | Aschauer et al. | Oct 1983 | A |
4416170 | Gibson et al. | Nov 1983 | A |
4443401 | Turner | Apr 1984 | A |
4475976 | Mittelstadt et al. | Oct 1984 | A |
4504341 | Radzwill et al. | Mar 1985 | A |
4614558 | Kobe | Sep 1986 | A |
4657717 | Cattanach et al. | Apr 1987 | A |
4726924 | Mittelstadt | Feb 1988 | A |
4780262 | VonVolkli | Oct 1988 | A |
4902215 | Seemann, III | Feb 1990 | A |
4922232 | Bosich | May 1990 | A |
4933232 | Trout et al. | Jun 1990 | A |
4946526 | Petty-Galis et al. | Aug 1990 | A |
4961700 | Dunbar | Oct 1990 | A |
5015168 | Boime et al. | May 1991 | A |
5022248 | Brooks et al. | Jun 1991 | A |
5040962 | Waszeciak et al. | Aug 1991 | A |
5060501 | Heath | Oct 1991 | A |
5087193 | Herbert, Jr. | Feb 1992 | A |
5108532 | Thein et al. | Apr 1992 | A |
5129813 | Shepherd | Jul 1992 | A |
5152949 | Leoni et al. | Oct 1992 | A |
5178812 | Sanford et al. | Jan 1993 | A |
5188787 | King et al. | Feb 1993 | A |
5286438 | Dublinski et al. | Feb 1994 | A |
5292475 | Mead et al. | Mar 1994 | A |
5304057 | Celerier et al. | Apr 1994 | A |
5327764 | Weykamp et al. | Jul 1994 | A |
5366431 | Smith et al. | Nov 1994 | A |
5366684 | Corneau, Jr. | Nov 1994 | A |
5464337 | Bernardon et al. | Nov 1995 | A |
5582058 | Knudson | Dec 1996 | A |
5683648 | Fortin | Nov 1997 | A |
5690973 | Kindt-Larsen et al. | Nov 1997 | A |
5707576 | Asher | Jan 1998 | A |
5714179 | Goodridge et al. | Feb 1998 | A |
5772950 | Brustad et al. | Jun 1998 | A |
5824255 | Ross et al. | Oct 1998 | A |
5830305 | Andersen et al. | Nov 1998 | A |
5846464 | Hoffman | Dec 1998 | A |
5882462 | Donecker et al. | Mar 1999 | A |
5939007 | Iszczyszyn et al. | Aug 1999 | A |
6089061 | Haas et al. | Jul 2000 | A |
6139942 | Hartness et al. | Oct 2000 | A |
6159414 | Tunis, III et al. | Dec 2000 | A |
6245275 | Holsinger | Jun 2001 | B1 |
6269677 | Torvinen et al. | Aug 2001 | B1 |
6299819 | Han | Oct 2001 | B1 |
6495086 | Uytterhaeghe et al. | Dec 2002 | B1 |
6511570 | Matsui | Jan 2003 | B2 |
6558590 | Stewart | May 2003 | B1 |
6692681 | Lunde | Feb 2004 | B1 |
6723272 | Montague et al. | Apr 2004 | B2 |
6749784 | Blanchon | Jun 2004 | B2 |
6814916 | Willden et al. | Nov 2004 | B2 |
6823578 | Anderson et al. | Nov 2004 | B2 |
6843953 | Filsinger et al. | Jan 2005 | B2 |
6855284 | Lanni et al. | Feb 2005 | B2 |
6862989 | Belanger et al. | Mar 2005 | B2 |
6929770 | Caldwell, Jr. | Aug 2005 | B2 |
6967000 | Vaara | Nov 2005 | B2 |
7021096 | Barnett | Apr 2006 | B2 |
7091300 | Luhmann et al. | Aug 2006 | B2 |
7118370 | Willden et al. | Oct 2006 | B2 |
7126496 | Greene | Oct 2006 | B2 |
7132161 | Knowles et al. | Nov 2006 | B2 |
7141199 | Sana et al. | Nov 2006 | B2 |
7160498 | Mataya | Jan 2007 | B2 |
7306450 | Hanson | Dec 2007 | B2 |
7334782 | Woods et al. | Feb 2008 | B2 |
7429172 | Chotard | Sep 2008 | B2 |
7464508 | Fournie et al. | Dec 2008 | B2 |
7527759 | Lee et al. | May 2009 | B2 |
7601421 | Khabashesku et al. | Oct 2009 | B2 |
7622066 | Brustad et al. | Nov 2009 | B2 |
7655168 | Jones et al. | Feb 2010 | B2 |
7708546 | Lee et al. | May 2010 | B2 |
7824171 | Hanson et al. | Nov 2010 | B2 |
7951318 | Hanson | May 2011 | B2 |
7959753 | Nunez Delgado et al. | Jun 2011 | B2 |
8105068 | Ross et al. | Jan 2012 | B2 |
8557165 | Jones et al. | Oct 2013 | B2 |
20010045684 | Blanchon | Nov 2001 | A1 |
20020167119 | Hemphill | Nov 2002 | A1 |
20030104094 | Sloman | Jun 2003 | A1 |
20030205156 | Belanger et al. | Nov 2003 | A1 |
20030234471 | Kuroiwa et al. | Dec 2003 | A1 |
20040041304 | Willden et al. | Mar 2004 | A1 |
20040043196 | Willden et al. | Mar 2004 | A1 |
20040071870 | Knowles et al. | Apr 2004 | A1 |
20040145080 | Tanaka | Jul 2004 | A1 |
20040145095 | McCollum et al. | Jul 2004 | A1 |
20040219855 | Tsotsis | Nov 2004 | A1 |
20050051932 | Danzik | Mar 2005 | A1 |
20050059309 | Tsotsis | Mar 2005 | A1 |
20050073076 | Woods et al. | Apr 2005 | A1 |
20050086991 | Barnett | Apr 2005 | A1 |
20050142239 | Frank | Jun 2005 | A1 |
20050178083 | Fournie et al. | Aug 2005 | A1 |
20060017200 | Cundiff et al. | Jan 2006 | A1 |
20060068170 | Hanson | Mar 2006 | A1 |
20060071817 | Greene | Apr 2006 | A1 |
20060166003 | Khabashesku et al. | Jul 2006 | A1 |
20060231981 | Lee et al. | Oct 2006 | A1 |
20070175171 | Delgado et al. | Aug 2007 | A1 |
20070176323 | Jones et al. | Aug 2007 | A1 |
20080054523 | Hanson | Mar 2008 | A1 |
20080286564 | Tsotsis | Nov 2008 | A1 |
20090123588 | Lee et al. | May 2009 | A1 |
20090320292 | Brennan et al. | Dec 2009 | A1 |
20100068326 | Jones et al. | Mar 2010 | A1 |
20100074979 | Cundiff et al. | Mar 2010 | A1 |
20100102482 | Jones et al. | Apr 2010 | A1 |
20110195230 | Hanson | Aug 2011 | A1 |
Number | Date | Country |
---|---|---|
2487697 | May 2006 | CA |
742682 | Dec 1943 | DE |
4234002 | Apr 1994 | DE |
19536675 | Feb 1997 | DE |
0659541 | Jun 1995 | EP |
1136239 | Sep 2001 | EP |
1393873 | Mar 2004 | EP |
1972428 | Sep 2008 | EP |
2133263 | Dec 2009 | EP |
2035314 | Dec 1970 | FR |
2162296 | Jul 1973 | FR |
2667013 | Mar 1992 | FR |
2771332 | May 1999 | FR |
2844472 | Mar 2004 | FR |
2139934 | Nov 1984 | GB |
S6143542 | Mar 1986 | JP |
2001310798 | Nov 2001 | JP |
WO2004025003 | Mar 2004 | WO |
WO2005095091 | Oct 2005 | WO |
WO2006014825 | Feb 2006 | WO |
WO2006039124 | Apr 2006 | WO |
WO2006048652 | May 2006 | WO |
WO2006113048 | Oct 2006 | WO |
WO2010047980 | Apr 2010 | WO |
Entry |
---|
Notice of Allowance, dated Nov. 26, 2013, regarding U.S. Appl. No. 13/090,746, 21 pages. |
European Search Report, dated Aug. 5, 2008, regarding Application No. EP08012344 (EP1972428), 6 pages. |
European Search Report, dated Oct. 10, 2011, regarding Application No. EP09251515 (EP2133263), 2 pages. |
International Search Report, dated Dec. 7, 2005, regarding Application No. PCT/US2005/026141 (WO2006014825), 3 pages. |
International Search Report, dated May 19, 2006, regarding Application No. PCT/US2005/033279 (WO2006039124), 5 pages. |
International Search Report, dated Oct. 16, 2006, regarding Application No. PCT/US2006/010825 (WO2006113048), 4 pages. |
International Search Report, dated Jan. 27, 2010, regarding Application No. PCT/US2009/060245 (WO2010047980), 3 pages. |
Ando et al., “Growing Carbon Nanotubes,” Materials Today, Oct. 2004, vol. 7, No. 10, pp. 22-29. |
Brittles, “New Developments in Resin Transfer Moulding,” Proc. 19th International Composites Congress, Nov. 1994, pp. 11-26. |
“A Composite Preform,” IP.com Prior Art Database Technical Disclosure No. IPCOM000007326D, dated Mar. 14, 2002, http://www.ip.com/IPCOM/000007326, 4 pages. |
Garcia et al., “Hybrid Carbon Nanotube-Composite Architectures,” MTL Annual Research Report, Sep. 2006, p. 208. |
“Growing Carbon Nanotubes Aligned With Patterns,” NASA Tech Briefs No. NPO-30205, Oct. 2002, http://nasatech.com/Briefs/Oct02/NPO30205.html, 2 pages. |
“The Longest Carbon Nanotubes You Have Ever Seen,” http://www.spacemart.com/reports/The—Longest—Carbon—Nanotubes—You—Have—Ever—Seen—999.html, May 14, 2007, 1 page. |
Musch et al., “Tooling With Reinforced Elastomeric Materials,” Composites Manufacturing, 1992, vol. 3, No. 2, pp. 101-111. |
“The Wondrous World of Carbon Nanotubes,” http://students.chem.tue.nl/ifp03/Wondrous%20World%20of%20Carbon%20Nanotubes—Final.pdf, Feb. 27, 2003, pp. 1-23. |
Office Action, dated Mar. 22, 2007, regarding U.S. Appl. No. 10/953,670, 19 pages. |
Notice of Allowance, dated Jul. 31, 2007, regarding U.S. Appl. No. 10/953,670, 6 pages. |
Office Action, dated Sep. 3, 2010, regarding U.S. Appl. No. 11/927,003, 14 pages. |
Notice of Allowance, dated Feb. 2, 2011, regarding U.S. Appl. No. 11/927,003, 9 pages. |
Office Action, dated Dec. 5, 2012, regarding U.S. Appl. No. 13/090,746, 38 pages. |
Final Office Action, dated May 15, 2013, regarding U.S. Appl. No. 13/090,746, 19 pages. |
Office Action, dated Apr. 4, 2008, regarding U.S. Appl. No. 10/899,660, 21 pages. |
Final Office Action, dated Oct. 16, 2008, regarding U.S. Appl. No. 10/899,660, 17 pages. |
Notice of Allowance, dated Jun. 22, 2009, regarding U.S. Appl. No. 10/899,660, 14 pages. |
Office Action, dated May 11, 2012, regarding U.S. Appl. No. 12/576,759, 19 pages. |
Final Office Action, dated Feb. 20, 2013, regarding U.S. Appl. No. 12/576,759, 41 pages. |
Office Action, dated May 28, 2008, regarding U.S. Appl. No. 11/105,104, 14 pages. |
Notice of Allowance, dated Jan. 7, 2009, regarding U.S. Appl. No. 11/105,104, 3 pages. |
Supplemental Notice of Allowance, dated Feb. 12, 2009, regarding U.S. Appl. No. 11/105,104, 4 pages. |
Office Action, dated May 27, 2009, regarding U.S. Appl. No. 12/354,856, 12 pages. |
Notice of Allowance, dated Dec. 23, 2009, regarding U.S. Appl. No. 12/354,856, 8 pages. |
Miscellaneous Communication, dated Mar. 2, 2010, regarding U.S. Appl. No. 12/354,856, 4 pages. |
Office Action, dated Oct. 15, 2008, regarding U.S. Appl. No. 11/344,458, 22 pages. |
Office Action, dated May 6, 2009, regarding U.S. Appl. No. 11/344,458, 6 pages. |
Notice of Allowance, dated Sep. 28, 2009, regarding U.S. Appl. No. 11/344,458, 7 pages. |
Supplemental Notice of Allowance, dated Oct. 30, 2009, regarding U.S. Appl. No. 11/344,458, 4 pages. |
Supplemental Notice of Allowance, dated Nov. 12, 2009, regarding U.S. Appl. No. 11/344,458, 5 pages. |
Office Action, dated Jan. 25, 2012, regarding U.S. Appl. No. 12/623,942, 17 pages. |
Notice of Allowance, dated May 8, 2012, regarding U.S. Appl. No. 12/623,942, 7 pages. |
Office Action, dated May 14, 2012, regarding U.S. Appl. No. 12/138,975, 12 pages. |
Final Office Action, dated Nov. 9, 2012, regarding U.S. Appl. No. 12/138,975, 32 pages. |
Office Action, dated Mar. 9, 2010, regarding U.S. Appl. No. 12/258,404, 9 pages. |
Final Office Action, dated Aug. 27, 2010, regarding U.S. Appl. No. 12/258,404, 10 pages. |
Final Office Action, dated Mar. 11, 2011, regarding U.S. Appl. No. 12/258,404, 8 pages. |
Office Action, dated Jul. 20, 2011, regarding U.S. Appl. No. 12/258,404, 6 pages. |
Final Office Action, dated Jan. 17, 2012, regarding U.S. Appl. No. 12/258,404, 7 pages. |
Notice of Allowance, dated Jun. 10, 2013, regarding U.S. Appl. No. 12/258,404, 38 pages. |
Office Action, dated Mar. 4, 2014, regarding U.S. Appl. No. 12/576,759, 14 pages. |
Final Office Action, dated Sep. 26, 2014, regarding U.S. Appl. No. 12/576,759, 12 pages. |
Notice of Allowance, dated Oct. 31, 2014, regarding U.S. Appl. No. 12/576,759, 7 pages. |
Number | Date | Country | |
---|---|---|---|
20140037780 A1 | Feb 2014 | US |
Number | Date | Country | |
---|---|---|---|
Parent | 12258404 | Oct 2008 | US |
Child | 14045797 | US |