This invention relates to a method of forming a composite plastic panel or moulding from particulate material and fillers including suitable plastics and especially to a method which is useful for producing panels from a high proportion of recycled material.
There are a number of known processes for forming plastics materials into the required shapes for making relatively small articles, such as injection moulding, but such processes become progressively more unwieldy, and the associated equipment becomes much more expensive, when it is required to make relatively large panels such as building panels suitable for use as partitions, for example.
It is known to produce composite panels based on fibrous materials by forming a fibre layer or mat and then applying outer layers of expandable phenol resin and hot-pressing the assembly to consolidate it. Such a method of forming boards is described in U.S. Pat. No. 4,734,231 (Morita et al). JP2003112329 discloses a similar kind of board comprising a core of mixed carbon material and phenol resin powder, and a surface material comprising mixed solid phenol resin and chaff or straw, which is formed by compressing the mixtures and heating to cross-link the phenol resin. However, panels including such fibrous materials may not be sufficiently dense or strong for general building or construction purposes, and it is also difficult to achieve a smooth finish on the outer surface.
Furthermore if it is desired to utilise ground-up recycled waste material (for example) to make a more solid core, it is difficult to make a strong integral structure without employing a multi-stage process in which the core material is first combined with a binding material. This is because the thermoplastic material of the outer layer may not penetrate the core layer sufficiently to bind it together.
It is also known to make structural panels from moulded material, by separately forming relatively thin panels from a first, more fine grained material so as to provide a relatively well finished “skin”, and then arranging a pair of the relatively thin panels in a suitable mould or former, with a space between them in which another plastics material is formed into a foam, so as to provide a composite structure which is relatively strong, and may also be relatively coarse grained or contain a large volume of voids, so as to provide the resulting composite structure with good insulating qualities.
As an alternative to plastics or moulded materials for the external skins, of course, sheets of metal or other suitable sheet material may be utilised, but in any case the formation of such panels by conventional methods tends to involve a relatively slow and cumbersome multi-stage process, because of the necessity to pre-form some components and then to manipulate them into the required arrangement for forming the final structure. Where it is required to manufacture relatively large structural panels, for instance, sizes such as 2.4 m×1.2 m, it is consequently expensive to automate such known systems because of the need for complex handling equipment.
Accordingly the present invention provides a method of moulding articles from heat mouldable powdered material, comprising the steps of laying down at least two layers of material of different granular fineness in an open-topped mould, at least one of the layers including heat mouldable material, applying a top closure to the mould, and then heating the mould and the closure to melt and fuse the powdered material.
The layers of powdered material may be laid down in the mould by means of a known type of powder distributor comprising a trough which can be traversed over the mould, and has a dispensing roller arranged in the base which can be rotated at a suitable speed to control the dispensing rate.
In a typical embodiment, at least the coarser one of the layers includes a foaming agent which is heat or chemically-activated, so that the structure expands in the closed mould to form a rigid composite article. Preferably where there is one other layer of finer material, that layer includes a thermoplastic material so that application of heat to the mould while it is closed, assists in fusing or bonding the article together. Thus in a preferred form of the invention, there is a coarse-grained layer of material which may advantageously include ground-up, recycled waste material, mixed with a foaming agent, and a finer-grained layer which comprises or includes thermoplastic material which forms a smooth outer skin. Preferably, there are three layers, with both of the outer layers including thermoplastic material so that the article is formed with a relatively smooth skin on both sides.
A preferred form of the present invention provides a method for moulding panels having a relatively fine external finish, and a relatively coarse “core” structure which may include ground-up recycled materials, comprising the steps of:
(a) laying down a layer of first, fine grained, heat mouldable material in a lower mould half to form a lower layer;
(b) laying down a further layer of relatively coarse material to form a central layer;
(c) laying down a further layer of fine grained heat mouldable material, on top of the core material, to form an upper layer;
(d) moving the upper and/or lower mould so that the upper mould contacts the upper surface of the upper layer, so as to enclose the layers of material in the lower mould; and
(e) applying heat to the moulds, so as to fuse the outer layers of material to form an external skin, whilst the central layer is foamed so that it expands and fuses with the two outer skin layers, and the outer surfaces of the two skin layers are moulded into close contact with the base of the lower mould half and the underneath surface of the upper mould.
Preferably, the central layer includes a heat-activated or chemically-activated foaming agent.
It will be appreciated that heat may be applied to the moulds in advance of the addition of the moulding materials, and/or while they are being added, as well as after the moulds are closed.
In one embodiment of the invention, the layers of powder are laid down by means of a multi-compartment tray distributor having a roller type dispensing mechanism at the base of each compartment, which is arranged to traverse across the mould or moulds and adapted to distribute powder at controlled rates as it moves. Depending on the specific arrangement of layers and process stages, the tray may be arranged to distribute one or more layers in each pass.
In one example of the process, after the foaming agent has been activated the top-plate is gradually retracted by a predetermined distance, whilst maintaining contact with the product, to allow the panel to expand to a suitable thickness. In this way it is possible to produce a range of panel thicknesses using the same quantity of fill material, or different quantities to achieve different densities, by retracting the top plates by different distances. Normally this is done in a controlled fashion for example by means of hydraulic or pneumatic actuators with feedback control. Alternatively in a simplified form of the process, it may be achieved by means of a top closure for the mould which is suitably weighted relative to the strength of the foaming agent.
In one embodiment, the finer grained powder is in the range of 100 to 3000 μm, most preferably 500 to 1000 μm, and may include thermoplastic material such as polyethylene, whilst the coarser grained powder may include various kinds of suitable granular filler made by grinding a variety of recycled materials, and may have a granule size of up to 10 mm. Typically, in order to form 18 mm (¾ inch) building boards, the external skin layers may be 1 to 1½ mm thick, so that the internal core is approximately 15 mm thick, and panels may, for example, be made in a similar way, up to 30 mm thick, with the same outer skin thickness. However for special applications the external skin layers may be anywhere between ½ mm and 7 mm thick while the panel may have a total thickness of up to 10 cm.
In a preferred form of the method according to the invention, the powder is added to the mould, while still at least at ambient temperature, and the temperature is raised to a temperature of up to 350° C., but typically between 190° and 220° after the mould has been closed, and held there for a length of time which depends on the thickness and density of the resulting product but is usually in the range of 5 to 40 minutes. In a typical case it will be 10 to 20 minutes. Preferably, heat is applied by means of fluid passages in the material of the moulds which may be made from a relatively easily workable material such as aluminium, since the temperature and pressure involved in the process are not particularly high. However, if the materials used for the process include particularly corrosive substances, the moulds may be made from more resistant materials such as pyrex glass or ceramic. As an alternative to fluid heating, electric resistance, inductive, or microwave heating may be employed.
It will be appreciated, however, that because of the pressure generated by any foaming agent, which is included, the moulds must be rigidly supported, and the upper mould also requires a suitable mechanism behind it, such as an arrangement of pneumatic or hydraulic rams, to hold it in position during the process.
It will also be appreciated that because of the relatively simple method of distributing the powders into the lower mould, the process is able to utilise a wide range of recycled material, including paper, cardboard, rubber, plastics and metal, fibres and minerals, so long as it is of a suitable size, although preferably, a proportion of suitable thermoplastic material is included, especially in the outer skin layers, so as to fuse the material into a unitary structure.
Additional material can also be included such as glass or carbon fibre, reinforcement steel mesh or organic fibre such as bamboo or banana fibre as well as material intended to add specific properties such as fire-retardant or anti-ballistic material.
In a preferred method according to the invention, a plurality of tray-shaped lower moulds are arranged in an array and a corresponding array of upper moulds are arranged to be movable into a position above the filled lower moulds to be lowered into engagement with them, to form panels using the steps of the method set out above, and the formed panels can then be removed from the lower moulds which are then refilled so as to enable a continuous production process to be achieved.
One embodiment of the invention will now be described by way of example with reference to the accompanying drawings which show some suitable arrangements of panel forming equipment, in a succession of forming steps as follows:
In the detailed example of the invention that follows, a system is described which is capable of producing multiple sets of moulded articles simultaneously by means of corresponding sets of moulds. However, it will be appreciated that a simplified form of the process could utilise a single mould.
Female mould sets 2 and 4 are arranged beneath corresponding sets of vertically movable actuators, not shown, which are used as explained in more detail below, for bringing the corresponding male mould sets 6, and 8, into engagement with them in the course of the moulding process. A powder dosing unit 44, comprising a compartmented tray for moulding powders is arranged on a suitable support track so that it can traverse across the female mould sets 2 and 4.
At the start of the process (
Once the female mould 2 of mould set “A” is filled, heating of the male and female moulds begins (
In
In
The drawings at
In
In
Referring to
In this and the succeeding figures, the adjacent female moulds of one set are shown as “A” and “C”, with the male moulding being shown as “X”. Similarly the female moulds of the other set are shown as “B” and “D” and the male mould as “Y”, as indicated in
The dosing unit then continues to traverse in the same direction in
At this point the dosing unit can be moved laterally to a position between the second female mould sets “A” and “B” which are exposed by movement of the male moulds “S” and “Y” away from their mutual positions (
The cycle then continues as illustrated in
Upper moulds have generally been referred to as male in the above description but both could of course be female depending on the shape to be moulded.
It will be appreciated that although three compartments are shown, in some applications only one or two will be employed simultaneously.
Although the above description has been written the terms of a system in which the lower mould halves are held stationary and the upper mould halves are moved horizontally into positions covering them, it will of course be appreciated that it would equally be possible to arrange the system with the upper mould halves in one position and the lower mould halves movable into a position beneath them. This could have the advantage of simplifying the arrangement of the mechanisms (e.g. hydraulic/pneumatic) for providing vertical movements of the upper mould halves which might otherwise, have to be made movable in a horizontal plane as well.
Similarly, although the process has been described above with reference to shifting one or other set of moulds between different lateral positions, it will also be appreciated that an alternative possibility would be to have sets of moulds arranged on a carousel so that they could be rotated between respective stations for the various powder distribution, heating, cooling and panel removal stages of the process.
Some examples of suitable heat-mouldable materials which may be utilised in the present invention are thermoplastic materials including but not limited to polyolefins eg polyethylenes, styrenics eg polystyrene, polyesters (eg PET), thermosets eg phenolics and rubbers.
Some examples of a foaming or “blowing” agent which may be utilised are for chemical systems: exothermics, eg azodicarbonamide i.e. “Porofor” (Lanxess) or “Celogen” (Lion Copolymer), or sodium bicarbonate. Examples of endothermics are hydroxypropane tricarboxylic acid eg “Hydrocerol” (Clariant). Physical systems can include for instance nitrogen or other gases, for example a gas such as pentane may be preimpregnated in polystyrene or expanded polypropylene and then released as a gas. Alternatively nitrogen can be utilised in a system such as the “Zotefoam” nitrogen saturation process.
Number | Date | Country | Kind |
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GB 1005058.1 | Mar 2010 | GB | national |