The present invention is directed to a forming structure and an apparatus for forming a breathable, liquid impermeable, apertured formed film, a method for forming a breathable, liquid impermeable, apertured formed film, and a breathable, liquid impermeable, apertured formed film.
A variety of well-known absorbent articles are configured to absorb body fluids. Examples of such absorbent articles include, but are not limited to, feminine hygiene products, such as sanitary napkins, baby diapers, and adult incontinence products. A typical absorbent article is generally constructed with a fluid permeable user-facing topsheet, which may be a three dimensional apertured polymer film or a nonwoven web or a polymer film/nonwoven laminate, an absorbent core, and a fluid impermeable garment or outwardly-facing backsheet, which may be a solid polymer film, for example. For some absorbent articles, it is desirable for the backsheet to be “breathable” so that moisture vapors may pass through the backsheet and potentially improve comfort to the wearer or user of the absorbent article. Breathability may be achieved by incorporating fillers into the backsheet that create micropores that are large enough to allow moisture vapor to pass therethrough, but small enough to prevent liquids from passing therethrough.
Attempts have been made to include three-dimensional apertures in the backsheet that are angled so that there is no line of sight through the backsheet. Such structures are disclosed in, for example, U.S. Pat. Nos. 5,591,510, 6,413,247 and 6,570,059, as well as U.S. Patent Application Publication No. 2002/0133132. The three-dimensional apertures are designed to stay open when no pressure is applied to them, such as when the user is standing up, and to close when pressure is applied to them, such as when the user sits down. The larger apertures provide increased breathability, as compared to backsheets with micropores, when open. It has been found that three-dimensional apertures of the prior art may not prevent liquid from passing through the backsheet when the user stands up and the apertures re-open. This is due to the location of the opening of the three-dimensional aperture as compared to the level of the liquid being held by the absorbent article. If the structure of the three-dimensional aperture closes at a level below the level of the liquid, then when the structure of the three-dimensional aperture re-opens when pressure has been taken off of the structure, the structure may act as a pump and pull the liquid through the backsheet, which is undesirable.
It is desirable to have a backsheet for an absorbent article that allows moisture vapors to pass through, but not allow liquids to pass through.
According to an aspect of the invention, there is provided a forming structure for forming a breathable, liquid impermeable, apertured formed film. The forming structure has an outer surface configured to receive a polymer web, an inner surface, a thickness between the outer surface and the inner surface, and a plurality of openings extending through the thickness at an acute angle relative to a plane tangential to the outer surface. Each of the plurality of openings has a shape at the outer surface defined by a first ellipse having a first major axis and a first minor axis and a second ellipse having a second major axis and a second minor axis, the first major axis is substantially parallel to a machine direction and coincides with the second minor axis. The second major axis is substantially parallel to a transverse direction orthogonal to the machine direction and offset from the first minor axis.
In an embodiment, the acute angle is between about 15° and about 45°. In an embodiment, the acute angle is between about 20° and about 40°.
In an embodiment, centers of adjacent openings are spaced equidistant from each other.
In an embodiment, each of the plurality of openings has a shape at the inner surface the same as the shape at the outer surface.
In an embodiment, the thickness of the forming structure comprises a plurality of layers, with each layer staggered relative to an adjacent layer to define the plurality of openings through the thickness at the acute angle.
According to an aspect of the present invention, there is provided an apparatus for forming a breathable, liquid impermeable, apertured formed film. The apparatus includes a forming structure having an outer surface configured to receive a polymer web, an inner surface, a thickness between the outer surface and the inner surface, and a plurality of openings extending through the thickness at an acute angle relative to a plane tangential to the outer surface. Each of the plurality of openings has a shape at the outer surface defined by a first ellipse having a first major axis and a first minor axis, and a second ellipse having a second major axis and a second minor axis. The first major axis is substantially parallel to a machine direction and coincides with the second minor axis. The second major axis is substantially parallel to a transverse direction orthogonal to the machine direction and offset from the first minor axis. The apparatus also includes a vacuum system configured to create a vacuum at the inner surface of the forming structure and pull portions of the polymer web into the plurality of openings.
According to an aspect of the invention, there is provided a method for forming a breathable, liquid impermeable, apertured formed film. The method includes contacting a polymer web with a forming structure. The forming structure has an outer surface configured to receive a polymer web, an inner surface, a thickness between the outer surface and the inner surface, and a plurality of openings extending through the thickness at an acute angle relative to a plane tangential to the outer surface. Each of the plurality of openings has a shape at the outer surface defined by a first ellipse having a first major axis and a first minor axis, and a second ellipse having a second major axis and a second minor axis. The first major axis is substantially parallel to a machine direction and coincides with the second minor axis. The second major axis is substantially parallel to a transverse direction orthogonal to the machine direction and offset from the first minor axis. The method also includes applying a vacuum to the inner surface of the forming structure to draw portions of the polymer web into the plurality of openings and create a plurality of apertured protuberances in the breathable, liquid impermeable, apertured formed film.
According to an aspect of the invention, there is provided a breathable, liquid impermeable, apertured formed film. The film includes a first side and a second side opposite the first side. The first side includes a plurality of two-dimensional apertures separated by first land areas. Each of the plurality of two-dimensional apertures has a shape defined by a first ellipse having a first major axis and a first minor axis, and a second ellipse having a second major axis and a second minor axis. The first major axis is substantially parallel to a machine direction of the film and coincides with the second minor axis. The second major axis is substantially parallel to a transverse direction orthogonal to the machine direction and offset from the first minor axis. The second side includes a plurality of apertured protuberances extending at an acute angle from a second land area opposite the first land area and aligned with the plurality of two-dimensional apertures.
According to an aspect of the invention, there is provided a breathable, liquid impermeable, apertured formed film that includes a first side and a second side opposite the first side. The first side includes a first land area and a plurality of two-dimensional apertures, and the second side includes a plurality of apertured protuberances extending at an acute angle from a second land area opposite the first land area and aligned with the plurality of two-dimensional apertures. The breathable, liquid impermeable, apertured formed film has an Air Permeability of greater than 25 m3/m2/min, and a Liquid Impact of less than 10 g/m2.
In an embodiment, the Air Permeability is less than 100 m3/m2/min. In an embodiment, the Air Permeability is less than 50 m3/m2/min.
In an embodiment, the plurality of apertured protuberances close when pressure is applied to the breathable, liquid impermeable, formed film.
In an embodiment, the Caliper of the breathable, liquid impermeable, formed film is reduced by less than 50% when pressure of 12 psi is applied to the breathable, liquid impermeable, formed film.
These and other aspects, features, and characteristics of the present invention, as well as the methods of manufacturing and functions of the related elements of structure and the combination of parts and economies of manufacture, will become more apparent upon consideration of the following description and the appended claims with reference to the accompanying drawings, all of which form a part of this specification. It is to be expressly understood, however, that the drawings are for the purpose of illustration and description only and are not intended as a definition of the limits of the invention. As used in the specification and in the claims, the singular form of “a”, “an”, and “the” include plural referents unless the context clearly dictates otherwise.
The components of the following figures are illustrated to emphasize the general principles of the present disclosure and are not necessarily drawn to scale. Reference characters designating corresponding components are repeated as necessary throughout the figures for the sake of consistency and clarity.
Glossary
As used herein, the expression “absorbent articles” denote articles that absorb and contain body fluids and other body exudates. More specifically, an absorbent article includes garments that are placed against or in proximity to the body of a wearer to absorb and contain the various exudates discharged from a body. Non-limiting examples of absorbent articles include, but are not limited to feminine hygiene products, baby diapers, adult incontinence products, and bandages.
Throughout this description, the term “web” refers to a material capable of being wound into a roll. Webs can be film webs, nonwoven webs, laminate webs, apertured laminate webs, etc. The face of a web refers to one of its two dimensional surfaces, as opposed to one of its edges.
The term “composite web” or “composite material” refers to a web that comprises two or more separate webs that are attached to each other in a face to face relationship. The attachment can be through the edges of the component webs, although the component webs lie in a face to face relationship with each other, or the attachment can be at particular spot locations across the component webs, or the attachment can be continuous.
The term “film” or “polymer film” in this description refers to a web made by extruding a molten curtain or sheet of thermoplastic polymeric material by a cast or blown extrusion process and then cooling the sheet to form a solid polymeric web. Films can be monolayer films, coextruded films, coated films, and composite films.
“Composite films” are films comprising more than one film where the at least two films are combined in a bonding process. Bonding processes may incorporate adhesive layers between the film layers.
Throughout this description, the expression “apertured films” denotes films that have a plurality of holes that extend from a first surface of the film to a second surface of the film.
A “two-dimensional apertured film” is a film in which no three-dimensional structure exists in the holes, which then connect the second surface of a flat film to the first surface of the film.
A “formed film” or a “three-dimensional film” is a film with protuberances, protrusions, or extended cells extending from at least one side thereof, and an “apertured formed film” or a “three-dimensional apertured film” is a film in which a three-dimensional structure exists in the apertures (e.g., the apertures have a depth that is thicker than the thickness of the film), or the protuberances or protrusions or extended cells have apertures therethrough.
The term “protuberance” as used herein refers to a three-dimensional member comprising an apertured base portion located in the plane of the first surface of the film and a sidewall portion extending generally in the direction of the second surface of the film. Each base portion has an associated sidewall portion. Sidewall portions terminate in “distal ends” located in the plane of the second surface of the film. The ends of the protuberances may be apertured or unapertured.
“Apertured protuberance” as used herein refers to a protuberance that has an aperture at its base portion or proximal end in the plane of the second surface, as well as its distal or protubered end. The apertures in the base portions of the protuberances, also called “primary apertures,” may be in the shape of polygons, for example squares, hexagons, pentagons, ellipses, circles, ovals, or slots, or may have other shapes, in a regulated or random pattern. Additional shapes according to illustrated embodiments of the invention are described in further detail below. The apertured distal or protubered ends are called “secondary apertures,” and may be in the shape of polygons, such as squares, hexagons, pentagons, ellipses, circles, ovals, slots, or may be in other shapes. The sidewall portion of the apertured protuberance extends from the primary aperture to the secondary aperture.
The term “nonwoven” means a web comprising a plurality of fibers. The fibers may be bonded to each other or may be unbonded. The fibers may be staple fibers or continuous fibers or filaments. The fibers may comprise a single material or may comprise a multitude of materials, either as a combination of different fibers or as a combination of similar fibers with each comprised of different materials.
As used herein, “nonwoven web” is used in its generic sense to define a generally planar structure that is relatively flat, flexible and porous, and includes staple fibers or continuous fibers or filaments. The nonwoven web may be the product of any process for forming the same, such as nonwoven spunbond and melt blown nonwoven webs. The nonwoven web may include a composite or combination of webs. The nonwoven web may comprise any polymeric material from which a fiber can be produced and/or may comprise cotton or other natural fibers. In an embodiment, the nonwoven web may be a spunbond material, made of polypropylene fiber. Fibers that comprise different polymers may also be blended. In an embodiment, the fibers may be so-called bi-component (“bi-co”) fibers that comprise a core of one material and a sheath of another material.
The term “forming structure” as used herein refers to a three-dimensional molding apparatus that comprises indentations or openings used to form protuberances, extended cells or apertures in films, or protuberances in nonwoven webs. In an embodiment, forming structures comprise tubular members, having a width and a diameter. In alternative embodiments, forming structures may comprise belts having a width and a length. The transverse direction is the direction parallel to the width of the forming structure. The machine direction is the direction parallel to the direction of rotation of the forming structure, and is perpendicular to the transverse direction.
Test Methods
Caliper, which may also be referred to as loft or thickness, is measured generally following ASTM-D645 using a motorized micrometer having a 2-inch diameter anvil and dead weight load of 95 g/in2, and using a dwell time of 2-5 seconds. Results may be reported in mils or micrometers (μm).
Air Permeability is measured in a TEXTEST FX3300 Air Permeability Tester, which measures the volume of air that passes through a test sample per minute and is recorded in cubic meters of air per square meter (of test sample) per minute (m3/m2/min).
Liquid Impact is measured with an apparatus similar to the device described in U.S. Pat. No. 5,865,823 and associated method for measuring the dynamic fluid impact value of a sample after a single insult. Results are reported below in grams per square meter (g/m2).
Description of Embodiments of the Invention
Various embodiments of the present invention will now be highlighted. The discussion of any one embodiment is not intended to limit the scope of the present invention. To the contrary, aspects of the embodiments are intended to emphasize the breadth of the invention, whether encompassed by the claims or not. Furthermore, any and all variations of the embodiments, now known or developed in the future, also are intended to fall within the scope of the invention.
The topsheet 110, which may be in the form of a two-dimensional or three-dimensional apertured film, a nonwoven web, or a laminate of an apertured film and a nonwoven web, is permeable to fluids and is configured to face the user wearing the absorbent article 100 and contact the user's skin. The topsheet 110 receives insults of fluid from the user, and the fluid passes through the topsheet 110 to the fluid distribution material 140. The fluid distribution material 140 is also permeable and is configured to receive the fluid from the topsheet 110 and distribute the fluid to the absorbent core 130. The absorbent core 130, which includes absorbent materials, receives the fluid from the fluid distribution material 140 and stores the fluid until the absorbent article 100 is discarded.
The backsheet 120, discussed in further detail below, may be in the form of a polymer film or a laminate of a polymer film and nonwoven web, prevents liquid and other body exudates from leaking out of the bottom side of the absorbent core 130. The backsheet 120 may be breathable so that air and moisture vapor, but not liquid, may pass through.
As the polymer web 204 crosses over the vacuum slot 210 apertured protuberances are formed in the polymer web 204 (i.e., the solidified melt curtain) in substantially the same pattern that is provided by the forming structure 206. As the polymer web 204 is apertured, air flow is initiated through the apertured protuberances which cools and solidifies the apertured protuberances. The polymer web 204 is also cooled by the forming structure 206. The resulting vacuum formed film 220 is pulled off of forming structure 206 by a peel roller 222 and travels across one or more subsequent rollers 224 until it may be wound by a winder 230 into a roll 232. Additional rollers and/or other pieces of equipment may be used in the apparatus 200.
The illustrated embodiment is not intended to be limiting in any way. For example, in an embodiment, the apparatus 200 may also include additional equipment, such as a corona treatment apparatus, printers, festooning equipment, spooling equipment, and additional processing equipment that may emboss the vacuum formed film 220.
The fibers of the nonwoven web 312 adjacent to the polymer web 204 embed in the surface of the polymer web 204 as the two layers cross over the vacuum slot 210 together, where apertured protuberances are formed in the polymer web 204 in substantially the same pattern that is provided by the forming structure 206. As the polymer web 204 is apertured, air flow is initiated through the apertured protuberances which cools and solidifies the apertured protuberances. The polymer web is also cooled by the forming structure 206 as the fibers of the nonwoven web 312 are embedded in land areas between the apertured protuberances so that the nonwoven is bonded to the formed film layer at the land areas. The resulting vacuum formed composite web 320 is pulled off of forming structure 206 by the peel roller 222 and travels to the one or more subsequent rollers 224 until it may be wound by the winder 230 into a roll 332. Additional rollers and/or other pieces of equipment may be used in the apparatus 300.
The illustrated embodiment is not intended to be limiting in any way. For example, in an embodiment, the apparatus 300 may also include additional equipment, such as a corona treatment apparatus, printers, festooning equipment, spooling equipment, and additional processing equipment that may emboss the vacuum formed laminate 320.
In an embodiment, instead of extruding the polymer web 204 in the form of a melt curtain directly onto the forming structure 206, an already formed solid polymer web may be unwound from a roll, reheated to soften the solid polymer web, and fed to the forming structure 206 so that the apertured protuberances may be formed in the polymer web. The polymer web may include a single layer of material or may include multiple layers of material.
Films 500 that were made with the forming structure 400 and different blends of polyolefins at a target basis weight of 25 grams per square meter (gsm) were tested for Caliper, Air Permeability and Liquid Impact to determine suitability for use as a backsheet. The Caliper of the films were tested to be between about 336 μm and about 406 μm. The Air Permeability of the films were tested to be between about 27 m3/m2/min and about 41 m3/m2/min. The Liquid Impact of the films were tested to be between about 4 g/m2 and about 10 g/m2.
Films 700 that were made with the forming structure 600 and different blends of polyolefins at a target basis weight of 25 gsm were tested for Caliper, Air Permeability and Liquid Impact to determine suitability for use as a backsheet. The Caliper of the films were tested to be between about 357 μm and about 388 μm. The Air Permeability of the films were tested to be between about 30 m3/m2/min and about 34 m3/m2/min. The Liquid Impact of the films were tested to be between about 22 g/m2 and about 60 g/m2.
Films 800 that were made with the above-described forming structure and different blends of polyolefins at a target basis weight of 25 gsm were tested for Caliper, Air Permeability and Liquid Impact to determine suitability for use as a backsheet. The Caliper of the films were tested to be between about 436 μm and about 465 μm. The Air Permeability of the films were tested to be between about 114 m3/m2/min and about 136 m3/m2/min. The Liquid Impact of the films were tested to be between about 15 g/m2 and about 24 g/m2.
Films 900 that were made with the above-described forming structure and different blends of polyolefins at a target basis weight of 25 gsm were tested for Caliper, Air Permeability and Liquid Impact to determine suitability for use as a backsheet. The Caliper of the films were tested to be between about 429 μm and about 474 μm. The Air Permeability of the films were tested to be between about 79 m3/m2/min and about 93 m3/m2/min. The Liquid Impact of the films were tested to be between about 9 g/m2 and about 22 g/m2.
The caliper or overall height of the apertured protuberance 1000 was measured when different pressures where applied to the apertured protuberance 1000. Specifically, the overall height of the apertured protuberance 1000 was measured at 0 psi (height of 424 μm), 5.6 psi (height of 279 μm), 7 psi (height of 206 μm), and 12 psi (height of 147 μm). At 5.6 psi applied pressure, the height decreased by about 34% (relative to the height at 0 psi), at 7 psi, the height decreased by about 52% (relative to the height at 0 psi), and at 12 psi, the height decreased by about 65% (relative to the height at 0 psi).
The caliper or overall height of the apertured protuberance 1100 was measured when different pressures where applied to the apertured protuberance 1100. Specifically, the overall height of the apertured protuberance 1100 was measured at 0 psi (height of 370 μm), 5.6 psi (height of 300 μm), 7 psi (height of 262 μm), and 12 psi (height of 234 μm). At 5.6 psi applied pressure, the height decreased by about 19% (relative to the height at 0 psi), at 7 psi, the height decreased by about 29% (relative to the height at 0 psi), and at 12 psi, the height decreased by about 37% (relative to the height at 0 psi).
As indicated by the measurements listed in Table I, only the width between the sidewalls A and the height of the apertured protuberance 1100 changed under pressure. As illustrated in
As indicated by the measurements listed in Table II and illustrated in
Although embodiments of the present invention were described above with respect to films formed with the forming structure 206, it should be understood that laminate or composite materials of the above-described films and nonwoven webs are also within the scope of the present invention. Such composite materials may be made using the apparatus 300 illustrated in
The embodiments described herein represent a number of possible implementations and examples and are not intended to necessarily limit the present disclosure to any specific embodiments. Instead, various modifications can be made to these embodiments as would be understood by one of ordinary skill in the art. Any such modifications are intended to be included within the spirit and scope of the present disclosure and protected by the following claims.
This application claims the benefit of priority from U.S. Provisional Patent Application No. 62/800,255, filed Feb. 1, 2019, the entire content of which is incorporated herein by reference.
Filing Document | Filing Date | Country | Kind |
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PCT/US2020/015881 | 1/30/2020 | WO | 00 |
Number | Date | Country | |
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62800255 | Feb 2019 | US |