Claims
- 1. A composition applied to skin having increased fragrance retention and fragrance longevity, comprising:
- a) at least about 0.01% by weight, of a fragrance delivery system comprising one or more pro-accords, provided each pro-accord:
- i) is formed from n number of fragrance raw materials;
- ii) contains n number of fragrance raw materials wherein n is an integer from 1 to 3 in a releasable form;
- iii) releases at least n+1 fragrance raw materials;
- iv) comprises fragrance raw materials having a molecular weight greater than or equal to about 100 g/mol;
- v) has a molecular weight greater than or equal to about 300 g/mol;
- vi) has a molecular weight at least two times greater than the lowest molecular weight fragrance raw material which comprises said pro-accord; and
- vii) has a fragrance release half-life of greater than or equal to 0.1 hours at pH 5.3 and less than or equal to about 12 hours at pH 2.5 when measured in NaH.sub.2 PO.sub.4 buffer;
- b) at least about 0.01% by weight, of one or more adjunct ingredients selected from the group consisting of surfactants, emollients, bactericides, gelling agents, desiccants, propellants, dyes, colorants, ointment bases, lanolin, antiperspirants, mineral oil, talc, abrasives, optical brighteners, phase stabilizing agents, absorbents, and mixtures thereof; and
- c) the balance carriers.
- 2. A composition according to claim 1 wherein said pro-accord has an odor value greater than or equal to 1 and a molecular weight greater than or equal to 300 g/mol.
- 3. A composition applied to skin having increased fragrance retention and fragrance longevity, comprising:
- a) at least about 0.01% by weight, of a fragrance delivery system comprising one or more pro-accords, provided at least one pro-accord:
- i) comprises fragrance raw materials having a molecular weight greater than or equal to about 100 g/mol;
- ii) has a molecular weight greater than or equal to about 300 g/mol;
- iii) has a molecular weight at least two times greater than the lowest molecular weight fragrance raw material which comprises said pro-accord; and
- iv) has a fragrance release half-life of greater than or equal to 0.1 hours at pH 5.3 and less than or equal to about 12 hours at pH 2.5 when measured in NaH.sub.2 PO.sub.4 buffer
- b) at least about 0.01% by weight, of one or more adjunct ingredients selected from the group consisting of surfactants, emollients, bactericides, gelling agents, desiccants, propellants, dyes, colorants, ointment bases, lanolin, antiperspirants, mineral oil, talc, abrasives, optical brighteners, phase stabilizing agents, absorbents, and mixtures thereof; and
- c) the balance carriers.
- 4. A composition according to claim 3 wherein said pro-accord is selected from the group consisting of acetals, ketals, orthoesters, orthocarbonates, and mixtures thereof.
- 5. A composition according to claim 3 wherein said pro-accord releases a binary accord.
- 6. A composition according to claim 4 wherein said pro-accord has the formula: ##STR17## wherein R is hydrogen, C.sub.1 -C.sub.8 linear alkyl, C.sub.3 -C.sub.20 branched alkyl, C.sub.3 -C.sub.20 cyclic alkyl, C.sub.6 -C.sub.20 branched cyclic alkyl, C.sub.6 -C.sub.20 linear alkenyl, C.sub.6 -C.sub.20 branched alkenyl, C.sub.6 -C.sub.20 cyclic alkenyl, C.sub.6 -C.sub.20 branched cyclic alkenyl, C.sub.6 -C.sub.20 substituted or unsubstituted aryl, and mixtures thereof; R.sup.1, R.sup.2 and R.sup.3 are independently C.sub.1 -C.sub.20 linear, branched, or substituted alkyl; C.sub.2 -C.sub.20 linear, branched, or substituted alkenyl; C.sub.3 -C.sub.20 substituted or unsubstituted cyclic alkyl; C.sub.6 -C.sub.20 substituted or unsubstituted aryl, C.sub.2 -C.sub.40 substituted or unsubstituted alkyleneoxy; C.sub.3 -C.sub.40 substituted or unsubstituted alkyleneoxyalkyl; C.sub.6 -C.sub.40 substituted or unsubstituted alkylenearyl; C.sub.6 -C.sub.32 substituted or unsubstituted aryloxy; C.sub.6 -C.sub.40 substituted or unsubstituted alkyleneoxyaryl; C.sub.6 -C.sub.40 oxyalkylenearyl, and mixtures thereof.
- 7. A composition according to claim 6 wherein said pro-accord compound releases a fragrance raw material alcohol selected from the group consisting of 4-(1-methylethyl)cyclohexanemethanol, 2,4-dimethyl-3-cyclohexen-1-ylmethanol, (2,4-dimethylcyclohex-1-yl)methanol, (2,4,6-trimethyl-3-cyclohexen-1-yl)methanol, 2-phenylethanol, 1-(4-isopropylcyclohexyl)-ethanol, 2,2-dimethyl-3-(3-methylphenyl)propan-l -ol, 3-phenyl-2-propen-1-ol, 2-methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, 3-methyl-5-phenylpentan-1-ol, 3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol, 2-methyl-4-phenylpentan-1-ol, cis-3-hexen-1-ol, 3,7-dimethyl-6-octen-1-ol, 3,7-dimethyl-2,6-octadien-1-ol, 7-methoxy-3,7-dimethyloctan-2-ol, 6,8-dimethylnonan-2-ol, cis-6-nonen-1-ol, 2,6-nonadien-1-ol, 4-methyl-3-decen-5-ol, benzyl alcohol, 2-methoxy-4-(1-propenyl)phenol, 2-methoxy-4-(2-propenyl)phenol, and mixtures thereof.
- 8. A composition according to claim 6 wherein said pro-accord compound releases a fragrance raw material ester having the formula: ##STR18## wherein R is hydrogen, methyl, ethyl, phenyl, and mixtures thereof; R.sup.1 is selected from the group consisting of 4-(1-methylethyl)cyclohexanemethyl, 2,4-dimethyl-3-cyclohexen- 1-ylmethyl, 2,4-dimethylcyclohex-1-ylmethyl, 2,4,6-trimethyl-3-cyclohexen-1-ylmethyl, 2-phenylethyl, 1-(4-isopropylcyclo-hexyl)ethyl, 2,2-dimethyl-3-(3-methylphenyl)propan-1-yl, 3-phenyl-2-propen-1-yl , 2-methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-yl, 3-methyl-5-phenylpentan-1-yl, 3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-yl, 2-methyl-4-phenylpentan-1-yl, cis-3-hexen-1-yl, 3,7-dimethyl-6-octen-1-yl, 3,7-dimethyl-2,6-octadien-1-yl, 7-methoxy-3,7-dimethyloctan-2-yl, 6,8-dimethylnonan-2-yl, cis-6-nonen-1-yl, 2,6-nonadien-1-yl, 4-methyl-3-decen-5-yl, benzyl, 2-methoxy-4-(1-propenyl)phenyl, 2-methoxy-4-(2-propenyl)phenyl, and mixtures thereof.
- 9. A composition according to claim 4 wherein said pro-accord is an acetal or a ketal having the formula: ##STR19## wherein R is C.sub.1 -C.sub.20 linear alkyl, C.sub.3 -C.sub.20 branched alkyl, C.sub.3 -C.sub.20 cyclic alkyl, C.sub.6 -C.sub.20 branched cyclic alkyl, C.sub.2 -C.sub.20 linear alkenyl, C.sub.6 -C.sub.20 branched alkenyl, C.sub.6 -C.sub.20 cyclic alkenyl, C.sub.6 -C.sub.20 branched cyclic alkenyl, C.sub.6 -C.sub.20 substituted or unsubstituted aryl, and mixtures thereof, R.sup.1 is hydrogen or R; R.sup.2 and R.sup.3 are each independently selected from the group consisting of C.sub.1 -C.sub.20 linear alkyl, C.sub.3 -C.sub.20 branched alkyl, C.sub.6 -C.sub.20 cyclic alkyl, C.sub.6 -C.sub.20 branched cyclic alkyl, C.sub.2 -C.sub.20 linear alkenyl, C.sub.3 -C.sub.20 branched alkenyl, C.sub.6 -C.sub.20 cyclic alkenyl, C.sub.6 -C.sub.20 branched cyclic alkenyl, C.sub.6 -C.sub.20 aryl, C.sub.7 -C.sub.20 substituted aryl, and mixtures thereof.
- 10. A composition according to claim 9 wherein said pro-accord compound releases a fragrance raw material aldehyde selected from the group consisting of 4-(4-hydroxy-4-methylpentyl)-3-cyclohexene-1-carboxaldehyde, phenylacetaldehyde, methylnonyl acetaldehyde, 2-phenylpropan-1-al, 3-phenylprop-2-en-1-al, 3-phenyl-2-pentylprop-2-en-1-al, 3-phenyl-2-hexylprop-2-enal, 3-(4-isopropylphenyl)-2-methylpropan-1-al, 3-(4-ethylphenyl)-2,2-dimethylpropan-1-al, 3-(4-tert-butylphenyl)-2-methyl-propanal, 3-(3,4-methylenedioxyphenyl)-2-methylpropan-1-al, 3-(4-ethylphenyl)-2,2-dimethylpropanal, 3-(3-isopropylphenyl)butan-1-al, 2,6-dimethylhep-5-en-1-al, n-decanal, n-undecanal, n-dodecanal, 3,7-dimethyl-2,6-octadien-1-al, 4-methoxybenzaldehyde, 3-methoxy-4-hydroxybenz-aldehyde, 3-ethoxy-4-hydroxybenzaldehyde, 3,4-methylenedioxy-benzaldehyde, 3,4-dimethoxybenzaldehyde, and mixtures thereof.
- 11. A composition according to claim 9 wherein said pro-accord compound releases a fragrance raw material alcohol selected from the group consisting of 4-(1-methylethyl)cyclohexanemethanol, 2,4-dimethyl-3-cyclohexen-1-ylmethanol, (2,4-dimethylcyclohex-1-yl)methanol, (2,4,6-trimethyl-3-cyclohexen-1-yl)methanol, 2-phenylethanol, 1-(4-isopropylcyclohexyl)-ethanol, 2,2-dimethyl-3-(3-methylphenyl)propan-1-ol, 3-phenyl-2-propen-1 -ol, 2-methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, 3-methyl-5-phenylpentan-1-ol, 3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol, 2-methyl-4-phenylpentan-1-ol, cis-3-hexen-1-ol, 3,7-dimethyl-6-octen- 1-ol, 3,7-dimethyl-2,6-octadien-1-ol, 7-methoxy-3,7-dimethyloctan-2-ol, 6,8-dimethylnonan-2-ol, cis-6-nonen-1-ol, 2,6-nonadien-1-ol, 9-decen-1-ol, 4-methyl-3-decen-5-ol, benzyl alcohol, 2-methoxy-4-(1-propenyl)phenol, 2-methoxy-4-(2-propenyl)phenol, and mixtures thereof.
- 12. A composition according to claim 9 wherein said pro-accord compound releases a fragrance raw material ketone selected from the group consisting of .alpha.-damascone, .beta.-damascone, .delta.-damascone, .beta.-damascenone, muscone, 6,7-dihydro-1,1,2,3,3-pentamethyl-4(5H)-indanone, cis-jasmone, dihydro-jasmone, .alpha.-ionone, .beta.-ionone, dihydro-.beta.-ionone, .gamma.-methyl ionone, .alpha.-iso-methyl ionone, 4-(3,4-methylenedioxyphenyl)butan-2-one, 4-(4-hydroxy-phenyl)butan-2-one, methyl .beta.-naphthyl ketone, methyl cedryl ketone, 6-acetyl-1,1,2,4,4,7-hexamethyltetralin, 1-carvone, 5-cyclohexadecen-1-one, and mixture thereof.
- 13. A composition according to claim 12 wherein said pro-accord compound releases a fragrance raw material alcohol selected from the group consisting of 4-(1-methylethyl)cyclohexanemethanol, 2,4-dimethyl-3-cyclohexen-1-ylmethanol, (2,4-dimethylcyclohex-1-yl)methanol, (2,4,6-trimethyl-3-cyclohexen-1-yl)methanol, 2-phenylethanol, 1-(4-isopropylcyclohexyl)-ethanol, 2,2-dimethyl-3-(3-methylphenyl)propan-1-ol, 3-phenyl-2-propen-1-ol, 2-methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, 3-methyl-5-phenylpentan-1-ol, 3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol, 2-methyl-4-phenylpentan-1-ol, cis-3-hexen-1-ol, 3,7-dimethyl-6-octen-1-ol, 3,7-dimethyl-2,6-octadien-1-ol, 7-methoxy-3,7-dimethyloctan-2-ol, 6,8-dimethylnonan-2-ol, cis-6-nonen-1-ol, 2,6-nonadien-1-ol, 9-decen-1-ol, 4-methyl-3-decen-5-ol, benzyl alcohol, 2-methoxy-4-(1-propenyl)phenol, 2-methoxy-4-(2-propenyl)phenol, and mixtures thereof.
- 14. A composition according to claim 4 wherein said pro-accord has the formula: ##STR20## wherein R.sup.1, R.sup.2, R.sup.3, and R.sup.4 are independently C.sub.1 -C.sub.20 linear, branched, or substituted alkyl; C.sub.2 -C.sub.20 linear, branched, or substituted alkenyl; C.sub.5 -C.sub.20 substituted or unsubstituted cyclic alkyl; C.sub.6 -C.sub.20 substituted or unsubstituted aryl, C.sub.2 -C.sub.40 substituted or unsubstituted alkyleneoxy; C.sub.3 -C.sub.40 substituted or unsubstituted alkyleneoxyalkyl; C.sub.6 -C.sub.40 substituted or unsubstituted alkylenearyl; C.sub.6 -C.sub.32 substituted or unsubstituted aryloxy: C.sub.6 -C.sub.40 substituted or unsubstituted alkyleneoxyaryl; C.sub.6 -C.sub.40 oxyalkylenearyl; and mixtures thereof.
- 15. A composition according to claim 14 wherein said pro-accord compound releases a fragrance raw material alcohol selected from the group consisting of 4-(1-methylethyl)cyclohexanemethanol, 2,4-dimethyl-3-cyclohexen-1-ylmethanol, (2,4-dimethylcyclohex-1-yl)methanol, (2,4,6-trimethyl-3-cyclohexen-1-yl)methanol, 2-phenylethanol, 1-(4-isopropylcyclohexyl)-ethanol, 2,2-dimethyl-3-(3-methylphenyl)propan-1-ol, 3-phenyl-2-propen-1-ol, 2-methyl-4-(2,2,3-trimethyl-3-cyclopenten-1-yl)-2-buten-1-ol, 3-methyl-5-phenylpentan-1-ol, 3-methyl-5-(2,2,3-trimethyl-3-cyclopenten-1-yl)-4-penten-2-ol, 2-methyl-4-phenylpentan-1-ol, cis-3-hexen-1-ol, 3,7-dimethyl-6-octen-1-ol, 3,7-dimethyl-2,6-octadien-1-ol, 7-methoxy-3,7-dimethyloctan-2-ol, 6,8-dimethylnonan-2-ol, cis-6-nonen-1-ol, 2,6-nonadien-1-ol, 9-decen-1-ol, 4-methyl-3-decen-5-ol, benzyl alcohol, 2-methoxy-4-(1-propenyl)phenol, 2-methoxy-4-(2-propenyl)phenol, and mixtures thereof.
Parent Case Info
This is a CIP of application Ser. No. 09/028,698, filed Feb. 24, 1998, pending.
This application claims benefit of Provisional Application No. 60/044,562.
US Referenced Citations (15)
Foreign Referenced Citations (1)
Number |
Date |
Country |
738 700 A1 |
Oct 1996 |
EPX |
Continuation in Parts (1)
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Number |
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028698 |
Feb 1998 |
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