Different tools and techniques may be utilized for refrigeration and/or heat pumping. There may be a need for new tools and techniques that may improve performance and/or efficiency.
Methods, systems, and devices for freeze point suppression cycle control are provided in accordance with various embodiments. Some embodiments are applicable in the field of refrigeration and heat pumping. Some embodiments pertain to control of freeze point suppression cycles. Specifically, some embodiments focus on the control of a temperature at which a freeze point suppression cycle may be able to absorb heat.
For example, some embodiments include a method of freeze point suppression cycle control. The method may include flowing a liquid to a first sensor; the liquid may include a mixture of a melted solid and a freeze point suppressant. The method may include determining an indicator value of a freeze point suppressant property of the liquid utilizing the first sensor. The method may include controlling a flow of the liquid to a separator utilizing a flow controller based on at least the determined indicator value of the freeze point suppressant property of the liquid; the separator may form a concentrated freeze point suppressant from the liquid.
In some embodiments, the method may further include: determining a target property value of the concentrated freeze point suppressant based on the determined indicator value of the freeze point suppressant property of the liquid; determining an indicator value of a freeze point suppressant property of the concentrated freeze point suppressant utilizing a second sensor; and/or controlling further the flow of the liquid to the separator utilizing the flow controller based on at least the determined indicator value of the freeze point suppressant property of the concentrated freeze point suppressant and the determined target property value of the concentrated freeze point suppressant.
In some embodiments, determining the indicator value of the freeze point suppressant property of the liquid includes determining a temperature value of the liquid utilizing the first sensor and determining the indicator value of the freeze point suppressant property of the concentrated freeze point suppressant includes determining a temperature value of the concentrated freeze point suppressant utilizing the second sensor; the first sensor may include a temperature sensor and the second sensor may include a temperature sensor. In some embodiments, determining the indicator value of the freeze point suppressant property of the liquid includes determining a spectral signature of the liquid utilizing the first sensor and determining the indicator value of the freeze point suppressant property of the concentrated freeze point suppressant includes determining a refractive index of the concentrated freeze point suppressant utilizing the second sensor; the first sensor may include a spectrometer and the second sensor may include a refractometer. In some embodiments, determining the indicator value of the freeze point suppressant property of the liquid includes determining a temperature of the liquid utilizing the first sensor and determining the indicator value of the freeze point suppressant property of the concentrated freeze point suppressant includes determining a refractive index of the concentrated freeze point suppressant utilizing the second sensor; the first sensor may include a temperature sensor and the second sensor may include a refractometer.
Some embodiments include pumping the liquid from a tank to the first sensor; the liquid may be formed in the tank through combining the freeze point suppressant and a solid that forms the melted solid. Some embodiments include forming the concentrated freeze point suppressant from the liquid utilizing the separator. Some embodiments include combining the concentrated freeze point suppressant with a solid to form a portion of the liquid.
In some embodiments, the separator includes a distillation vessel. The separator may include at least a mechanical separator or a thermal separator.
In some embodiments, the indicator value of the freeze point suppressant property of the liquid includes at least a concentration value of the liquid, a density value of the liquid, a conductivity value of the liquid, a capacitance value of the liquid, a refractive index value of the liquid, a temperature value of the liquid, a pressure value of the liquid, a heat capacity value of the liquid, a freezing point value of the liquid, or a boiling point value of the liquid. In some embodiments, the target property value of the concentrated freeze point suppressant includes at least a concentration value of the concentrated freeze point suppressant, a density value of the concentrated freeze point suppressant, a conductivity value of the concentrated freeze point suppressant, a capacitance value of the concentrated freeze point suppressant, a refractive index value of the concentrated freeze point suppressant, a temperature value of the concentrated freeze point suppressant, a pressure value of the concentrated freeze point suppressant, a heat capacity value of the concentrated freeze point suppressant, a freezing point value of the concentrated freeze point suppressant, or a boiling point value of the concentrated freeze point suppressant. In some embodiments, the indicator value of the freeze point suppressant property of the concentrated freeze point suppressant includes at least a concentration value of the concentrated freeze point suppressant, a density value of the concentrated freeze point suppressant, a conductivity value of the concentrated freeze point suppressant, a capacitance value of the concentrated freeze point suppressant, a refractive index value of the concentrated freeze point suppressant, a temperature value of the concentrated freeze point suppressant, a pressure value of the concentrated freeze point suppressant, a heat capacity value of the concentrated freeze point suppressant, a freezing point value of the concentrated freeze point suppressant, or a boiling point value of the concentrated freeze point suppressant.
In some embodiments, forming the concentrated freeze point suppressant from the liquid utilizing the separator includes at least separating at least a portion of the freeze point suppressant from the liquid or separating at least a portion of the melted solid from the liquid.
In some embodiments, the flow controller includes a variable-speed compressor that creates suction with respect to the distillation vessel. Some embodiments include flowing the concentrated freeze point suppressant through a control valve coupled with the controller that controls at least a flow of the concentrated freeze point suppressant from the distillation vessel or a flow of liquid from the distillation vessel to reform the melted solid.
Some embodiments include a freeze point suppression cycle control system. The system may include a first sensor positioned to determine an indicator value of a freeze point suppressant property of a liquid; the liquid may include a mixture of a melted solid and a freeze point suppressant. The system may include a flow controller that controls a flow of the liquid to a separator. The system may include a controller coupled with the first sensor and with the flow controller; the controller may control the flow of the liquid to the separator utilizing the flow controller based on at least the determined indicator value of the freeze point suppressant property of the liquid. Some embodiments of the system may include a second sensor positioned to determine an indicator value of a freeze point suppressant property of a concentrated freeze point suppressant; the second sensor may be coupled with the controller.
In some embodiments of the system, the first sensor includes a temperature sensor and the second sensor includes a temperature sensor. In some embodiments, the first sensor includes a spectrometer and the second sensor includes a refractometer. In some embodiments, the first sensor includes a temperature sensor and the second sensor includes a refractometer
Some embodiments of the system include a pump that delivers the liquid to at least the first sensor or the flow controller. Some embodiments include the separator; the separator may form the concentrated freeze point suppressant from the liquid. The separator may include a distillation vessel. The separator may include at least a mechanical separator or a thermal separator. Some embodiments of the system include a mixing tank that combines the concentrated freeze point suppressant with a solid to form a portion of the liquid.
In some embodiments of the system, the controller utilizes the determined indicator value of the freeze point suppressant property of the liquid to determine a target property value of the concentrated freeze point suppressant. In some embodiments, the controller controls the flow of the liquid to the separator utilizing the flow controller based on at least the determined indicator value of the freeze point suppressant property of the concentrated freeze point suppressant or the determined target property value of the concentrated freeze point suppressant.
In some embodiments of the system, the separator forms the concentrated freeze point suppressant from the liquid through at least separating at least a portion of the freeze point suppressant from the liquid or separating at least a portion of the melted solid from the liquid. In some embodiments, the flow controller includes a variable-speed compressor that creates suction with respect the distillation vessel. The flow controller may further include a control valve coupled with the controller that controls at least a flow of the concentrated freeze point suppressant from the distillation vessel or a flow of liquid from the distillation vessel to reform the melted solid.
Some embodiments include methods, systems, and/or devices as described in the specification and/or shown in the figures.
The foregoing has outlined rather broadly the features and technical advantages of embodiments according to the disclosure in order that the detailed description that follows may be better understood. Additional features and advantages will be described hereinafter. The conception and specific embodiments disclosed may be readily utilized as a basis for modifying or designing other structures for carrying out the same purposes of the present disclosure. Such equivalent constructions do not depart from the spirit and scope of the appended claims. Features which are believed to be characteristic of the concepts disclosed herein, both as to their organization and method of operation, together with associated advantages will be better understood from the following description when considered in connection with the accompanying figures. Each of the figures is provided for the purpose of illustration and description only, and not as a definition of the limits of the claims.
A further understanding of the nature and advantages of different embodiments may be realized by reference to the following drawings. In the appended figures, similar components or features may have the same reference label. Further, various components of the same type may be distinguished by following the reference label by a dash and a second label that distinguishes among the similar components. If only the first reference label is used in the specification, the description is applicable to any one of the similar components having the same first reference label irrespective of the second reference label.
This description provides embodiments, and is not intended to limit the scope, applicability, or configuration of the disclosure. Rather, the ensuing description will provide those skilled in the art with an enabling description for implementing embodiments of the disclosure. Various changes may be made in the function and arrangement of elements.
Thus, various embodiments may omit, substitute, or add various procedures or components as appropriate. For instance, it should be appreciated that the methods may be performed in an order different than that described, and that various stages may be added, omitted, or combined. Also, aspects and elements described with respect to certain embodiments may be combined in various other embodiments. It should also be appreciated that the following systems, devices, and methods may individually or collectively be components of a larger system, wherein other procedures may take precedence over or otherwise modify their application.
Methods, systems, and devices for freeze point suppression cycle control are provided in accordance with various embodiments. Some embodiments are applicable in the field of refrigeration and heat pumping. Some embodiments pertain to control of freeze point suppression cycles. Specifically, some embodiments focus on the control of a temperature at which a freeze point suppression cycle may be able to absorb heat.
Some embodiments provide for the control of a low temperature inside a freeze point suppression cycle. Some embodiments involve the integration of multiple components coupled with a controller that may that automatically control the cycle temperature via electrical signals and automatic control loops.
Some embodiments include a low concentration side sensor, a flow modulator, and a controller. Some embodiments may also include a high concentration side sensor and one or more pumps.
The controller, such as a processor, may receive one or more signals from one or more components and may send signals to the one or more components, which may maintain a useful temperature inside the freeze point suppression cycle's mixing tank, for example.
This temperature's usefulness may be categorized namely by being below the melting point of the solid used in the freeze point suppression cycle. In some embodiments, the controller's goal may be to maintain a temperature as far below the pure freeze point of the solid used in the cycle as the user inputs; this may create useful refrigeration by the temperature difference between the pure freeze point and freeze point created by the mixture of the solid and the freeze point suppressant.
The physical process used by the controller may include modulating the flow through a separation system, which may concentrate a freeze point suppressant in order to maintain a concentration inside the mixing tank. To this end, the controller may capture the condition on the low concentration side of the cycle and the high concentration side in order to operate the separation system appropriately and maintain a low temperature, for example.
Turning now to
Some embodiments of the system 100 include a second sensor 106 positioned to determine an indicator value of a freeze point suppressant property of a concentrated freeze point suppressant 114; the second sensor 106 may be coupled with the controller 112. In some embodiments, the first sensor 108 includes a temperature sensor and the second sensor 106 includes a temperature sensor. In some embodiments, the first sensor 108 includes a spectrometer and the second sensor 106 includes a refractometer. In some embodiments, the first sensor 108 includes a temperature sensor and the second sensor 106 includes a refractometer. Some embodiments may utilize sensors for the first sensor 108 and/or the second sensor 106 that may include combinations or permutations of sensors configured to determine or facilitate determining temperature, spectrum, refractive index, density, concentration, conductivity, capacitance, pressure, heat capacity, freezing point, and/or boiling point, for example.
Some embodiments of the system 100 include a pump configured to deliver the liquid 113 to at least the first sensor 108 or the flow controller 110. The liquid 113 may also be referred to as a dilute freeze point suppressant. Some embodiments include the separator 117 configured to form the concentrated freeze point suppressant 114 from the liquid 113. In some embodiments, the separator 117 includes at least a thermal separator or a mechanical separator. In some embodiments, the separator 117 includes a distillation vessel; for example, the separator 117 may include a distillation column. Some embodiments may utilize separators such as an opened kettle boiler, a recirculating plate boiler and separator, and/or a random-packed distillation column.
Separator 117 may utilize a wide variety of separation tools and techniques including, but not limited to: reverse osmosis, nano-filtration, photonic-driven precipitation, precipitation by chemical reaction, precipitation by solubility change, surfactant absorption, ion exchange, activated carbon absorption, flash separation, distillation, multi-effect distillation, vapor compression distillation, evaporation, membrane distillation, and/or gas permeable membrane separation. Some embodiments include a mixing tank configured to combine the concentrated freeze point suppressant 114 with a solid to form a portion of the liquid 113.
In some embodiments, the controller 112 is further configured to utilize the determined indicator value of freeze point suppressant property of the liquid 113 to determine a target property value of the concentrated freeze point suppressant 114. In some embodiments, the controller 112 is further configured to control the flow of the liquid 113 to the separator 117 utilizing the flow controller 110 based on at least the determined indicator value of the freeze point suppressant property of the concentrated freeze point suppressant 114 and/or the determined target property value of the concentrated freeze point suppressant 114.
In some embodiments of system 100, the indicator value of the freeze point suppressant property of the liquid 113 includes at least a concentration value of the liquid, a density value of the liquid, a conductivity value of the liquid, a capacitance value of the liquid, a refractive index value of the liquid, a temperature value of the liquid, a pressure value of the liquid, a heat capacity value of the liquid, a freezing point value of the liquid, or a boiling point value of the liquid. In some embodiments, the target property value of the concentrated freeze point suppressant 114 includes at least a concentration value of the concentrated freeze point suppressant, a density value of the concentrated freeze point suppressant, a conductivity value of the concentrated freeze point suppressant, a capacitance value of the concentrated freeze point suppressant, a refractive index value of the concentrated freeze point suppressant, a temperature value of the concentrated freeze point suppressant, a pressure value of the concentrated freeze point suppressant, a heat capacity value of the concentrated freeze point suppressant, a freezing point value of the concentrated freeze point suppressant, or a boiling point value of the concentrated freeze point suppressant.
In some embodiments, the indicator value of the freeze point suppressant property of the concentrated freeze point suppressant 114 includes at least a concentration value of the concentrated freeze point suppressant, a density value of the concentrated freeze point suppressant, a conductivity value of the concentrated freeze point suppressant, a capacitance value of the concentrated freeze point suppressant, a refractive index value of the concentrated freeze point suppressant, a temperature value of the concentrated freeze point suppressant, a pressure value of the concentrated freeze point suppressant, a heat capacity value of the concentrated freeze point suppressant, a freezing point value of the concentrated freeze point suppressant, or a boiling point value of the concentrated freeze point suppressant. Some embodiments may utilize other indicators values with respect to these properties.
In general, the freeze point suppressant may include, but is not limited to, water, alcohol, ionic liquids, amines, ammonia, salt, non-salt soluble solids, organic liquid, inorganic liquid, triethylamine, cyclohexopuridine, mixtures of miscible materials, and/or a surfactant-stabilized mixture of immiscible materials. The melted solid may be formed from a solid that may include a fully or partially solid form of the following, but is not limited to, water, an organic material, an ionic liquid, an inorganic material, and/or DMSO.
One skilled in the art will recognize that this embodiment may represent a simple embodiment of the control architecture. The addition of multiple types of sensors, duplicate sensors, and/or duplicate methods of modulating the flow may result in better overall performance in accordance with various embodiments. Furthermore, the embodiments provided generally show how the control architecture may operate with different types of sensors and different types of separation equipment. Thus, the embodiments are not limited to a system with just one type of separation equipment or one type of sensor.
The result of this control loop 118-a may include electronic signal 111-b being sent to the speed controller 110-c, which may modulate the flow of dilute freeze point suppressant into the distillation vessel via the variable speed pump 104-b and may maintain proper operation of that equipment in order to achieve the target concentration at the inlet to the mixing vessel.
Electronic signal 111-d (or 111-d-1) may also sent to control valve 110-f (or 1104-1).
These embodiments generally show the consistent application of the control hardware and software across multiple sensor types and multiple separation technologies.
Regardless of the sensor type of separation technology, the control logic and hardware integration strategy may be applied to maintain the property concentration and temperature inside the mixing vessel and perform useful refrigeration at a temperature below the freezing point of the solid.
Turning now to
Turning now to
At block 710, a liquid may flow to a first sensor; the liquid may include a mixture of a melted solid and a freeze point suppressant. At block 720, an indicator value of a freeze point suppressant property of the liquid may be determined utilizing the first sensor. At block 730, a flow of the liquid to a separator may be controlled utilizing a flow controller based on at least the determined indicator value of the freeze point suppressant property of the liquid; the separator may form a concentrated freeze point suppressant from the liquid. In some embodiments, the separator may form the concentrated freeze point suppressant from the liquid by separating at least a portion of the freeze point suppressant from the liquid; this may also form a dilute freeze point suppressant. In some embodiments, the separator may form the concentrated freeze point suppressant from the liquid through separating at least a portion of the melted solid from the liquid; this may form a pure or higher purity melted solid in some embodiments.
In some embodiments, the method 700 may include: determining a target property value of the concentrated freeze point suppressant based on the determined indicator value of the freeze point suppressant property of the liquid; determining an indicator value of a freeze point suppressant property of the concentrated freeze point suppressant utilizing a second sensor; and/or controlling further the flow of the liquid to the separator utilizing the flow controller based on at least the determined indicator value of the freeze point suppressant property of the concentrated freeze point suppressant and the determined target property value of the concentrated freeze point suppressant.
In some embodiments of method 700, determining the indicator value of the freeze point suppressant property of the liquid includes determining a temperature value of the liquid utilizing the first sensor and determining the indicator value of the freeze point suppressant property of the concentrated freeze point suppressant includes determining a temperature value of the concentrated freeze point suppressant utilizing the second sensor; the first sensor may include a temperature sensor and the second sensor may include a temperature sensor. In some embodiments, determining the indicator value of the freeze point suppressant property of the liquid includes determining a spectral signature of the liquid utilizing the first sensor and determining the indicator value of the freeze point suppressant property of the concentrated freeze point suppressant includes determining a refractive index of the concentrated freeze point suppressant utilizing the second sensor; the first sensor may include a spectrometer and the second sensor may include a refractometer. In some embodiments, determining the indicator value of the freeze point suppressant property of the liquid includes determining a temperature of the liquid utilizing the first sensor and determining the indicator value of the freeze point suppressant property of the concentrated freeze point suppressant includes determining a refractive index of the concentrated freeze point suppressant utilizing the second sensor; the first sensor may include a temperature sensor and the second sensor may include a refractometer.
Some embodiments of method 700 may utilize sensors for the first sensor and the second sensor that may include combinations or permutations of sensors configured to determine or facilitate determining temperature, spectrum, refractive index, density, concentration, conductivity, capacitance, pressure, heat capacity, freezing point, or boiling point, for example.
Some embodiments of method 700 include pumping the liquid from a tank to the first sensor; the liquid may be formed in the tank through combining the freeze point suppressant and a solid that forms the melted solid. Some embodiments include forming the concentrated freeze point suppressant from the liquid utilizing the separator. Some embodiments include combining the concentrated freeze point suppressant with a solid to form a portion of the liquid.
In some embodiments, the separator includes a distillation vessel; for example, some embodiments may utilize a distillation column. The separator may include at least a mechanical separator or a thermal separator. Some embodiments may utilize separators such as an opened kettle boiler, a recirculating plate boiler and separator, and/or a random-packed distribution column.
A wide variety of separation techniques may be utilized with method 700, including, but are not limited to: reverse osmosis, nano-filtration, photonic driven precipitation, precipitation by chemical reaction, precipitation by solubility change, surfactant absorption, ion exchange, activated carbon absorption, flash separation, distillation, multi-effect distillation, vapor compression distillation, evaporation, membrane distillation, and/or gas permeable membrane separation.
In some embodiments of method 700, the indicator value of the freeze point suppressant property of the liquid includes at least a concentration value of the liquid, a density value of the liquid, a conductivity value of the liquid, a capacitance value of the liquid, a refractive index value of the liquid, a temperature value of the liquid, a pressure value of the liquid, a heat capacity value of the liquid, a freezing point value of the liquid, or a boiling point value of the liquid. In some embodiments, the target property value of the concentrated freeze point suppressant includes least a concentration value of the concentrated freeze point suppressant, a density value of the concentrated freeze point suppressant, a conductivity value of the concentrated freeze point suppressant, a capacitance value of the concentrated freeze point suppressant, a refractive index value of the concentrated freeze point suppressant, a temperature value of the concentrated freeze point suppressant, a pressure value of the concentrated freeze point suppressant, a heat capacity value of the concentrated freeze point suppressant, a freezing point value of the concentrated freeze point suppressant, or a boiling point value of the concentrated freeze point suppressant. In some embodiments, the indicator value of the freeze point suppressant property of the concentrated freeze point suppressant includes at least a concentration value of the concentrated freeze point suppressant, a density value of the concentrated freeze point suppressant, a conductivity value of the concentrated freeze point suppressant, a capacitance value of the concentrated freeze point suppressant, a refractive index value of the concentrated freeze point suppressant, a temperature value of the concentrated freeze point suppressant, a pressure value of the concentrated freeze point suppressant, a heat capacity value of the concentrated freeze point suppressant, a freezing point value of the concentrated freeze point suppressant, or a boiling point value of the concentrated freeze point suppressant.
In some embodiments of method 700, forming the concentrated freeze point suppressant from the liquid utilizing the separator includes at least separating at least a portion of the freeze point suppressant from the liquid or separating at least a portion of the melted solid from the liquid. In some embodiments, the flow controller includes a variable-speed compressor that creates suction with respect to the distillation vessel. Some embodiments include flowing the concentrated freeze point suppressant through a control valve coupled with the controller that control at least a flow of the concentrated freeze point suppressant from the distillation vessel or a flow of liquid from the distillation vessel to reform the melted solid.
Turning now to
At block 710-a, a liquid may flow to a first sensor where the liquid includes a mixture of a melted solid and a freeze point suppressant. At block 720-a, an indicator value of a freeze point suppressant property of a liquid may be determined utilizing the first sensor. At block 740, a target property value of a concentrated freeze point suppressant may be determined based on the determined indicator value of the freeze point suppressant property of the liquid. At block 750, an indicator value of a freeze point suppressant property of the concentrated freeze point suppressant may be determined utilizing a second sensor. At block 730-a, the flow of the liquid to a separator may be controlled utilizing a flow controller based on at least the determined indicator value of the freeze point suppressant property of the concentrated freeze point suppressant and the determined target property value of the concentrated freeze point suppressant
These embodiments may not capture the full extent of combination and permutations of materials and process equipment. However, they may demonstrate the range of applicability of the method, devices, and/or systems. The different embodiments may utilize more or fewer stages than those described.
It should be noted that the methods, systems, and devices discussed above are intended merely to be examples. It must be stressed that various embodiments may omit, substitute, and/or add various procedures or components as appropriate. For instance, it should be appreciated that, in alternative embodiments, the methods may be performed in an order different from that described, and that various stages may be added, omitted, or combined. Also, features described with respect to certain embodiments may be combined in various other embodiments. Different aspects and elements of the embodiments may be combined in a similar manner. Also, it should be emphasized that technology evolves and, thus, many of the elements are exemplary in nature and should not be interpreted to limit the scope of the embodiments.
Specific details are given in the description to provide a thorough understanding of the embodiments. However, it will be understood by one of ordinary skill in the art that the embodiments may be practiced without these specific details. For example, well-known circuits, processes, algorithms, structures, and techniques have been shown without unnecessary detail in order to avoid obscuring the embodiments.
Also, it is noted that the embodiments may be described as a process which may be depicted as a flow diagram or block diagram or as stages. Although each may describe the operations as a sequential process, many of the operations can be performed in parallel or concurrently. In addition, the order of the operations may be rearranged. A process may have additional stages not included in the figure.
Having described several embodiments, it will be recognized by those of skill in the art that various modifications, alternative constructions, and equivalents may be used without departing from the spirit of the different embodiments. For example, the above elements may merely be a component of a larger system, wherein other rules may take precedence over or otherwise modify the application of the different embodiments. Also, a number of stages may be undertaken before, during, or after the above elements are considered. Accordingly, the above description should not be taken as limiting the scope of the different embodiments.
Number | Date | Country | |
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62634461 | Feb 2018 | US |
Number | Date | Country | |
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Parent | PCT/US2019/019323 | Feb 2019 | US |
Child | 17000337 | US |