Patent Application
20100151348
The present invention relates to a fuel cell and a method for manufacturing the same.
As the coming generation of energy, in recent years, there have been proposed various types of fuel cell apparatuses in which a stack of fuel cells are accommodated inside a housing.
A fuel cell for use in a fuel cell apparatus of conventional design is manufactured by laminating, on an electrically conductive support substrate, an inner electrode, a solid electrolyte, and an outer electrode one after another. In the solid electrolyte and a part of the inner electrode which is exposed from the outer electrode is disposed an interconnector so as not to make connection to the outer electrode. The electrically conductive support substrate has formed therein a plurality of gas channels constituting gas passages.
Electrical connection between one fuel cell and the other fuel cell is established by connecting the electrically conductive support substrate of one fuel cell to the outer electrode of the other fuel cell via the interconnector and a current-collecting member disposed in the electrically conductive support substrate. As is disclosed in Japanese Unexamined Patent Publication JP-A 2004-234969, the electrically conductive support substrate of a hollow flat plate-shaped or cylindrical-shaped fuel cell has customarily been manufactured by means of extrusion.
Moreover, as a method for manufacturing a flat plate-shaped fuel cell, there has been known a manufacturing process that employs a tape lamination method, as is disclosed in Japanese Unexamined Patent Publication JP-A 2003-297387.
However, according to JP-A 2004-234969, the support substrate is prepared by the extrusion forming method. This gives rise to a problem of lack of mass productivity. That is, in the case of adopting the extrusion forming method, it is necessary to prepare support substrate compacts on an individual basis. This leads to inefficiency in manufacturing and difficulty in mass production, in consequence whereof there results a problem of rising costs.
Furthermore, according to the description of JP-A 2003-297387, in the production of the flat plate-shaped fuel cell apparatus, green tapes are laminated on top of each other, and then polyethylene and carbon black are print-formed in a part of the laminate in which is formed a gas channel. Subsequently, the printed substances are caused to scatter and vanish during firing thereby to form the gas channel. However, in the case of adopting such a tape lamination method, a crack tends to be generated at a corner of the gas channel. Even granted that no crack appears in the course of manufacture, there is a possibility that generation and propagation of a crack occurs due to a long-time electric power generation that will eventually cause occurrence of gas leakage through the gas channel.
In addition, at the time of preparing a substrate by the tape lamination method (sheet lamination method), in general, green tapes are pressed through the application of pressure in the direction of the thickness thereof in order to improve the adherability between the green tapes. In this case, as shown in
An object of the invention is to provide a fuel cell capable of preventing occurrence of gas leakage through a gas channel, and a method for manufacturing a fuel cell that allows production of such a fuel cell in high volume with lower costs while preventing occurrence of cracking at corners of the gas channel.
The invention provides a fuel cell constituted such that on a support substrate having a gas channel formed inside, are laminated a first electrode, a solid electrolyte, and a second electrode one after another, the support substrate being formed by laminating a plurality of green tapes containing powder of a support substrate material on top of each other and thereafter firing a laminate of the plurality of green tapes, and a fillet portion being formed at a corner of the gas channel of the support substrate.
The invention provides a fuel cell constituted such that on a support substrate which has a gas channel formed inside and serves also as a first electrode are laminated a solid electrolyte and a second electrode one after another, the support substrate being formed by laminating a plurality of green tapes containing powder of a support substrate material on top of each other and thereafter firing a laminate of the plurality of green tape, and a fillet portion being formed at a corner of the gas channel of the support substrate.
According to the fuel cell thus constituted, by virtue of the fillet portion formed at the corner of the gas channel of the support substrate, occurrence of cracking at the corner of the gas channel can be suppressed in the course of manufacture of the fuel cell. Moreover, it is possible to prevent propagation of a crack from the corner of the gas channel resulting from a long-time electric power generation, and thereby prevent occurrence of gas leakage through the gas channel.
The invention provides a method for manufacturing a fuel cell constituted such that on a support substrate having a gas channel formed inside are laminated a first electrode, a solid electrolyte, and a second electrode one after another, the method comprising: forming a support substrate through a step of firing a support substrate compact which is formed by laminating a plurality of green tapes each of which has a through hole formed in a direction of thickness thereof and contains powder of a support substrate material, and which has a gas channel forming material composed of an inorganic material for forming a fillet portion at a corner of the gas channel and a to-be-scattered substance which is scattered during firing is accommodated in a space of a gas channel configuration that is formed by the through holes in the plurality of green tapes.
In the method for manufacturing the fuel cell according to the invention, it is preferable that the method comprises: a step of preparing a laminate on which the first electrode compact and the solid electrolyte compact are laminated one after another on the support substrate compact; a step of firing the laminate; and a step of forming the second electrode on the solid electrolyte of the sintered compact.
In the method for manufacturing the fuel cell according to the invention, it is preferable that the first electrode is a fuel-side electrode and the second electrode is an oxygen-side electrode.
The invention provides a method for manufacturing a fuel cell having a constitution such that on a support substrate which has a gas channel formed inside and serves as a first electrode are laminated a solid electrolyte and a second electrode one after another, the method comprising: forming a support substrate through a step of firing a support substrate compact which is formed by laminating a plurality of green tapes each of which has a through hole formed in a direction of thickness thereof and contains powder of a support substrate material, and which has a gas channel forming material composed of an inorganic material for forming a fillet portion at a corner of the gas channel and a to-be-scattered substance which is scattered during firing is accommodated in a space of a gas channel configuration that is formed by the through holes in the plurality of green tapes.
In the method for manufacturing the fuel cell according to the invention, it is preferable that the method comprises: a step of preparing a laminate on which the solid electrolyte compact is laminated on the support substrate compact; a step of firing the laminate; and a step of forming the second electrode on the solid electrolyte of the sintered compact.
In the method for manufacturing the fuel cell according to the invention, it is preferable that the support substrate is a support substrate which serves also as a fuel-side electrode and the second electrode is an oxygen-side electrode.
According to the method for manufacturing the fuel cell thus designed, since the gas channel forming material composed of an inorganic material and a to-be-scattered substance is accommodated inside the space of a gas channel configuration of the support substrate compact, upon firing the support substrate compact, the to-be-scattered substance contained in the gas channel forming material is caused to scatter, and simultaneously the inorganic material is caused to congregate to the corners of the gas channel, in particular to crevices of the corners created as a result of pressurizing the support substrate compact (peeled-off portions) under a capillary phenomenon. Then, following the completion of firing, the fillet portion can be formed and thereby the corners of the gas channel can be rounded off. This makes it possible to prevent occurrence of cracking in the course of manufacture of the cell. Moreover, with the provision of the fillet portion, propagation of a crack from the corners of the gas channel can be prevented.
Moreover, according to the method for manufacturing the fuel cell thus designed, by firing the support substrate compact, the first electrode compact, and the solid electrolyte compact at one time, or by firing the support substrate compact which serves also as the first electrode and the solid electrolyte compact at one time, it is possible to expedite mass production even further which brings costs down. In particular, by shaping the first electrode compact and/or the solid electrolyte compact in the form of a tape, it is possible to laminate, on the support substrate compact composed of a laminate of a plurality of green tapes, the tape-shaped first electrode compact and/or the tape-shaped solid electrolyte compact continuously. This helps expedite mass production.
The method for manufacturing the fuel cell according to the invention includes a process of forming the second electrode by firing it concurrently with the support substrate compact, the first electrode compact, and the solid electrolyte compact, or a process of forming the second electrode by firing it concurrently with the support substrate which serves also as the first electrode and the solid electrolyte compact. In this case, it becomes easier to achieve the manufacturing operation.
Moreover, the support substrate is formed by laminating a plurality of green tapes containing powder of the support substrate material on top of each other and thereafter firing the laminate of the plurality of green tapes. Therefore, it is possible to adopt the sheet lamination method, the screen printing method, and so forth as have conventionally been in use as a method for manufacturing a ceramic substrate, and thereby achieve mass production by means of automatic machinery. This makes cost reduction possible.
In the method for manufacturing the fuel cell according to the invention, it is preferable that a part of the surface of the support substrate compact which is free of a lamination of the solid electrolyte compact is covered with an insulating gas seal compact.
According to the method for manufacturing the fuel cell thus designed, since a part of the surface of the support substrate which is free of a lamination of the solid electrolyte is covered with an insulating gas seal layer, it is possible to prevent occurrence of gas leakage through the gas channel inside the support substrate with the provision of the solid electrolyte and the gas seal layer.
In the method for manufacturing the fuel cell according to the invention, it is preferable that the laminate has the solid electrolyte compact formed on its one principal surface as viewed in a direction in which the green tapes constituting the support substrate compact are laminated and has an interconnector compact formed on its other principal surface, and that the support substrate compact has its opposite side surfaces covered with the insulating gas seal compact respectively, and the periphery of the support substrate compact is covered with the solid electrolyte compact, the interconnector compact, and the gas seal compact.
According to the method for manufacturing the fuel cell thus designed, the surfaces of the support substrate are covered with the solid electrolyte, the interconnector, and the gas seal layer in such a manner as to surround the gas channel. It is thus possible to prevent occurrence of gas leakage through the gas channel inside the support substrate by the solid electrolyte, the interconnector, and the gas seal layer. In other words, the support substrate is hermetically sealed at its upper and lower surfaces with the solid electrolyte and the interconnector, and is also hermetically sealed at its side surfaces with the gas seal layer. In this way, the surfaces of the support substrate can be sealed air-tightly, wherefore a gas within and without the solid electrolyte can be confined completely without fail.
In the method for manufacturing the fuel cell according to the invention, it is preferable that a first support substrate tape and a second support substrate tape are prepared for use, in which the first support substrate tape has a plurality of gas seal material-filled through holes extending in the direction of the length thereof, whereas the second support substrate tape has further a plurality of gas channel forming material-filled through holes extending in the direction of the length thereof, which are arranged between the adjacent gas seal material-filled through holes of the first support substrate tape, and after a plurality of the first support substrate tapes are laminated on top of each other, a plurality of the second support substrate tapes are laminated on an upper surface thereof, and a plurality of the first support substrate are further laminated on an upper surface thereof, whereby a support substrate assembly compact is prepared, and the support substrate assembly compact is cut up in the direction of the length thereof in such a manner as to divide the gas seal material lying inside the through hole into two portions, whereupon a support substrate compact is formed having its opposite side surfaces covered with an insulating gas seal compact respectively.
In the method for manufacturing the fuel cell according to the invention, it is preferable that the gas seal compact contains a solid electrolyte material.
According to the method for manufacturing the fuel cell thus designed, as the material used for the gas seal layer, the solid electrolyte material can be used. Therefore, the number of kinds of materials to be used can be reduced, and sealing of a gas can be accomplished without fail because after firing, the solid electrolyte material becomes an insulating dense member.
Moreover, the fuel cell and the method for manufacturing the same according to the invention embrace a so-called interconnector-less type fuel cell in which the entire periphery of the support substrate compact is covered with the solid electrolyte compact and a method for manufacturing the same. Further, the fuel cell apparatus is manufactured by placing a plurality of the above-described fuel cells inside a housing.
Other and further objects, features, and advantages of the invention will be more explicit from the following detailed description taken with reference to the drawings.
Now referring to the drawings, preferred embodiments of the invention are described below.
A fuel cell according to the invention is, as shown in
That is, the support substrate 1 is formed of a platy and rod-like porous element and has four gas channels 10 each having a substantially rectangular sectional profile formed inside so as to pass therethrough in a lengthwise direction. On the upper surface of the support substrate 1 are laminated the porous fuel-side electrode 2, the dense solid electrolyte 3, and the porous oxygen-side electrode 4 one after another. On the other hand, on the lower surface of the support substrate 1 is laminated the dense interconnector layer 5. Moreover, on each of opposite side surfaces of the support substrate 1 is formed a dense insulating gas seal layer 13. The gas seal layer 13 has its lower end connected to the interconnector layer 5 and has its upper end connected to the solid electrolyte 3. In this way, the outer peripheral surface, exclusive of the lengthwise opposite end faces, of the support substrate 1 is covered with the solid electrolyte 3, the interconnector layer 5, and the dense insulating gas seal layer 13. Note that each of the lengthwise opposite end faces of the support substrate 1 has openings of the gas channels 10.
As shown in
Although it is preferable that the fillet portion S is made of the material constituting the support substrate 1 and is thus porous, the material constituting the fillet portion S does not have to be an inorganic material which is electrical conductive and porous as well, so long as it lends itself to the formation of the fillet portion S at the corner of the gas channel 10. For example, the fillet portion S can be made of alumina or a solid electrolyte material.
The support substrate 1 is rectangular in cross section and is made as a platy porous conductor on the whole. In order for a fuel gas to permeate to the fuel-side electrode 2, the support substrate 1 is designed to exhibit gas permeability. Moreover, it is required that the support substrate 1 be electrically conductive to collect electricity through the interconnector layer 5. In order to satisfy such a requirement and to avoid inconveniences resulting from a co-fired operation as well, it is desirable to constitute the support substrate 1 with use of an iron-group metal component and a specific rare earth oxide.
It is preferable that the thickness of the support substrate 1 is set to be greater than or equal to 1 mm in terms of supporting of a power generating portion on one hand, and is set to be smaller than or equal to 3 mm in terms of electrical conductivity between the oxygen-side electrode 4 and the interconnector layer 5 on the other hand.
The iron-group metal component is used to impart electrical conductivity to the support substrate 1. It is possible to use any of a single iron-group metal, an iron-group metallic oxide, an alloy of iron-group metal, and an alloy oxide thereof. The examples of the iron-group metal include iron, nickel, and cobalt. Although any one of these materials can be used in the invention, it is preferable that Ni and/or NiO are contained as the iron-group metal component from the standpoint of inexpensiveness and stability in a fuel gas.
Moreover, the rare earth oxide is used to approximate the thermal expansion coefficient of the support substrate 1 to that of ZrO2 containing a rare earth element constituting the solid electrolyte 2. In order to maintain a high electrical conductivity and to prevent diffusion of elements into the solid electrolyte 2 and so forth, an oxide containing at least one kind of rare earth element selected from the group consisting of Y, Lu, Yb, Tm, Er, Ho, Dy, Gd, Sm and Pr is used in combination with the aforementioned iron-group component. The specific examples of such a rare earth oxide include Y2O3, Lu2O3, Yb2O3, Tm2O3, Er2O3, Ho2O3, Dy2O3, Gd2O3, Sm2O3, and Pr2O3. Among them, the use of Y2O3, Yb2O3 is particularly desirable from a low cost standpoint.
In order to strengthen the connection between the support substrate 1 and the interconnector layer 5, an intermediary layer may be disposed therebetween. Moreover, a P-type semiconductor or the like may be disposed externally of the interconnector layer 5 to take out output.
The interconnector layer 5 is made of electrically conductive ceramics. Being brought into contact with a fuel gas (hydrogen) and an oxygen-containing gas, the interconnector layer 5 needs to be designed to exhibit resistance to reduction and resistance to oxidation. Therefore, as such electrically conductive ceramics, in general, a lanthanum chromite-based perovskite-type oxide (LaCrO3-based oxide) is used. Moreover, in order to prevent the leakage of a fuel gas which passes through the inside of the support substrate 1 and the leakage of an oxygen-containing gas which passes through the outside of the support substrate 1, the electrically conductive ceramics needs to be dense. It is thus preferable that the electrically conductive ceramics has a relative density of, for example, 93% or above, and more particularly 95% or above.
It is preferable that the interconnector layer 5 ranges in thickness from 10 to 200 μm from the standpoint of gas leakage prevention and electrical resistance.
The fuel-side electrode 2 is provided to produce an electrode reaction, and is made of an electrically conductive porous cermet which is well known per se. For example, the fuel-side electrode 2 is made of ZrO2 in which a rare earth element is solid-solved, and Ni and/or NiO. As the ZrO2 in which a rare earth element is solid-solved (stabilized zirconia), it is desirable to use a material similar to the one used to form the solid electrolyte 3 as will be described later.
It is preferable that the content of stabilized zirconia in the fuel-side electrode 2 falls in a range of from 35 to 65% by volume, and that the content of Ni or NiO therein falls in a range of from 65 to 35% by volume. It is also preferable that the open porosity of the fuel-side electrode 2 is greater than or equal to 15%, and more particularly falls in a range of from 20 to 40%. Further, it is preferable that the thickness of the fuel-side electrode 2 falls in a range of from 1 to 30 μm from the standpoint of enhancing performance capabilities and preventing occurrence of peeling or the like trouble resulting from the difference in thermal expansion between the solid electrolyte 3 and the fuel-side electrode 2.
The solid electrolyte 3 disposed on the fuel-side electrode 2 is made of dense ceramics which is ZrO2 in which a rare earth element is solid-solved (usually called: stabilized zirconia) in an amount of, in general, 3 to 15 mol %. The examples of the rare earth element include Sc, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu. Among them, the use of Y, Yb is particularly desirable from a low cost standpoint.
From the standpoint of gas permeation prevention, it is preferable that the stabilized zirconia ceramics constituting the solid electrolyte 3 is dense to have a relative density (according to the Archimedes' method) of 93% or above, and more particularly 95% or above, and that its thickness falls in a range of from 10 to 100 μm. Note that the solid electrolyte 3 may be made of a lanthanum gallate-based perovskite-type composite instead of the stabilized zirconia.
It is preferable that the gas seal layer 13 is composed of a solid electrolyte material membrane made of a solid electrolyte material in terms of a reduction in the number of kinds of materials to be used and reliable sealing of a gas. Nevertheless, the gas seal layer 13 may be formed of any given material so long as it is a dense insulating material. For example, the gas seal layer may be formed of alumina.
In a case where the gas seal layer 13 formed on each of the opposite side surfaces of the support substrate 1 is composed of the solid electrolyte material membrane, it is possible to use the same material as that constituting the solid electrolyte 3 formed on the upper surface of the fuel-side electrode 2. Nevertheless, there is no need to use exactly the same material as that constituting the solid electrolyte 3, and a material which is slightly different in composition from the material constituting the solid electrolyte 3 can also be used. It is thus possible to use a lanthanum gallate-based solid electrolyte material. Moreover, since this region does not contribute to electric power generation, it is not necessary to use a solid electrolyte material. As has already been described, commonly-used insulating dense ceramics can also be used. It is preferable that the thickness of the gas seal layer 13 composed of the solid electrolyte material membrane is, just as is the case with the solid electrolyte 3, adjusted to be greater than or equal to 10 μm from the standpoint of gas permeation prevention.
The oxygen-side electrode 4 is made of electrically conductive ceramics composed of a so-called ABO3 perovskite-type oxide. As such a perovskite-type oxide, a transition metal perovskite-type oxide, and more particularly at least one kind of substances selected from among an LaMnO3-based oxide having La in the A-site, an LaFeO3-based oxide, and an LaCoO3-based oxide are desirable. In terms of its high electrical conductivity at an operating temperature of approximately 600 to 1000° C., the use of the LaFeO3-based oxide is particularly desirable. Note that the above-described perovskite-type oxide may be such as to contain, in addition to La, Sr or the like in the A-site, and may also be such as to contain, in addition to Fe, Co, Mn, or the like in the B-site.
Moreover, the oxygen-side electrode 4 needs to be designed to exhibit gas permeability. Therefore, the electrically conductive ceramics (perovskite-type oxide) constituting the oxygen-side electrode 4 should preferably have an open porosity of greater than or equal to 20%, and more particularly an open porosity falling in a range of from 30 to 50%. It is preferable that such an oxygen-side electrode 4 ranges in thickness from 30 to 100 μm from the standpoint of electricity collecting property. An oxygen gas, oxygen-containing air, and the like are supplied to the oxygen-side electrode 4.
Being made to have a high open porosity, the oxygen-side electrode 4 is liable to suffer from breakage at its end portions. In light of this, as shown in
The fuel cell having the structure thus far described can be manufactured in the following manner. At the outset, an organic binder, a solvent, and so forth are admixed in powder of a predetermined raw material. The thus obtained admixture is compacted into tapes by the doctor blade method so as to form 6 varieties of tapes as shown in
Herein,
In each of the tapes, exclusive of the solid electrolyte tape 33, a through hole having a rectangular sectional profile can be created in the direction of thickness of the tape by means of stamping. The through hole can be filled with a paste containing the solid electrolyte material 43, as well as a paste containing the gas channel forming material 45 by means of screen printing. Alternatively, the solid electrolyte material 43 as well as the gas channel forming material 45 can be shaped into a sheet-like member and then housed in the through hole.
At first, as shown in
That is, the space having a rectangular sectional profile created as a result of laminating three pieces of the support substrate tapes 37b one after another, is filled with the gas channel forming material 45.
After that, as shown in
After that, the laminate is cut up at the positions indicated by alternate long and short dashed lines in
In the fuel cell manufactured by the sheet lamination method thus far described, the gas channel 10 has such a sectional profile as shown in
Moreover, according to the manufacturing method embodying the invention, the laminate is fired. At this time, the to-be-scattered substance constituting the gas channel forming material 45 is caused to scatter, and simultaneously, as indicated by a symbol S in
That is, in the fuel cell laminate, the degree of intimate contact among the tapes can be increased through the application of pressure. At this time, as shown in
Moreover, with the manufacturing method according to the invention, for example, even if the support substrate is made to have a thickness as small as approximately 1.5 mm, the thick gas seal layers can be formed on the side surfaces thereof, and therefore it is possible to improve the gas sealability.
In such a fuel cell, by virtue of the fillet portions S formed at the corners of the gas channel 10 of the support substrate 1, occurrence of peeling or cracking at the corners of the gas channel 10 can be suppressed in the course of manufacture of the fuel cell. As another advantage, it is possible to prevent propagation of a crack from the corners of the gas channel 10 resulting from a long-time electric power generation and thereby prevent occurrence of gas leakage through the gas channel 10.
Note that although the above embodiment description deals with the case where the oxygen-side electrode 4 is fired concurrently with the solid electrolyte tape 33, the support substrate tapes 37a, b, and so forth, the oxygen-side electrode may also be formed in the following manner. Following the completion of co-firing of the solid electrolyte tape and the support substrate tape, the oxygen-side electrode material is applied to the tapes by means of spray coating or otherwise so that it can be print-coated onto the solid electrolyte.
Moreover, although the above embodiment description deals with the case where the through holes of the support substrate tapes 37b are filled with the gas channel forming material 45 and subsequently these support substrate tapes 37b are laminated on top of each other, it is also practicable that, as shown in
Moreover, it is practicable that the core 53 is formed by applying an inorganic material 53b constituting the fillet portion S around a to-be-scattered substance 53a which is scattered during firing, and, after the thus obtained core 53 having a coating of the inorganic material 53b is housed inside the concavity 51, firing is carried out. In this way, as indicated by the symbol S in
Alternatively, it is practicable that, after the gas channel is formed through firing under the condition where a to-be-scattered substance which is scattered during firing is used as the gas channel forming material, the sintered compact thus obtained is immersed in a solution containing the inorganic material constituting the fillet portions S. In this way, the inorganic material is adhered to the corners of the gas channel. Then, heat treatment is carried out so that the inorganic material portions can be print-coated thereto, whereby the fillet portions S are formed.
Moreover, although the above embodiment description deals with the case where the interconnector layer tape 35, the support substrate tapes 37a and 37b, the fuel-side electrode tape 32, the solid electrolyte tape 33, and the oxygen-side electrode tape 34 are each laminated in the limited number, the invention is not limited to the number of layers given in the above description. In addition, the formation of an intermediary layer or the like on the tapes is not deemed to be a detriment to the implementation of the invention.
Moreover, in the invention, by making a change to the shape of the through hole which is formed in the support substrate tape 37b, it is possible to change the configuration of the gas channel 10 freely and thereby obtain a gas channel configuration which is ideal for an improvement in characteristics. For example, as shown in
That is, in a case where the gas channel 10 has a uniform cross-sectional area throughout in the direction of the length of the cell, the concentration of a gas is high at the gas inlet port of the fuel cell, whereas it is low at the gas outlet port thereof. Therefore, while gas diffusion can be achieved adequately with the cross-sectional area of the gas channel 10 at its inlet port reduced to thereby increase the velocity of flow of a gas, since the concentration of a gas is low at the outlet port, it is possible to increase the area of the gas channel 10 and thereby decrease the velocity of flow of a gas. As a consequence, satisfactory gas diffusion can be achieved.
Note that although the above embodiment description pertains to the fuel cell manufactured by forming the fuel-side electrode 2 on the support substrate 1, the invention is applicable to a case where the support substrate 1 serves also as the fuel-side electrode 2, in other words, as shown in
Moreover, although the above embodiment description pertains to the fuel cell constituted by forming, on the support substrate, the fuel-side electrode, the solid electrolyte, and the oxygen-side electrode one after another in the order named, the invention is applicable to a fuel cell constructed by forming, on the support substrate, the oxygen-side electrode, the solid electrolyte, and the fuel-side electrode one after another in the order named. Also in this case, it is possible to achieve the same effects as achieved in the above-described embodiment. In addition, even if the fuel cell is so deigned that the support substrate serves also as the oxygen-side electrode, it is possible to achieve the same effects as achieved in the above-described embodiment.
Moreover, the invention is also applicable to the production of a so-called interconnector-less type fuel cell as shown in
Moreover, although the above embodiment description deals with the case where the gas channel 10 having a rectangular sectional profile is formed, the invention is also applicable to a case where, as shown in
Moreover, the invention is also applicable to a case where, as shown in
The invention may be embodied in other specific forms without departing from the spirit or essential characteristics thereof. The present embodiments are therefore to be considered in all respects as illustrative and not restrictive, the scope of the invention being indicated by the appended claims rather than by the foregoing description and all changes which come within the meaning and the range of equivalency of the claims are therefore intended to be embraced therein.
According to the fuel cell embodying the invention, by virtue of the fillet portions formed at the corners of the gas channel of the support substrate, occurrence of cracking at the corners of the gas channel can be suppressed in the course of manufacture of the fuel cell. As another advantage, it is possible to prevent propagation of a crack from the corners of the gas channel resulting from a long-time electric power generation, and thereby prevent occurrence of gas leakage through the gas channel.
Moreover, according to the fuel cell manufacturing method embodying the invention, since the gas channel forming material composed of an inorganic material and the space corresponding to the configuration of the gas channel of the support substrate compact is filled with a to-be-scattered substance, upon firing the support substrate compact, the to-be-scattered substance contained in the gas channel forming material is caused to scatter, and simultaneously the inorganic material is caused to congregate to the corners of the gas channel, in particular to crevices of the corners created as a result of pressurizing the support substrate compact (peeled-off portions), under a capillary phenomenon. In this way, the fillet portions are formed and thereby the corners of the gas channel can be rounded off. This makes it possible to prevent occurrence of cracking in the course of manufacture of the cell. Moreover, with the provision of the fillet portions, propagation of a crack from the corners of the gas channel can be prevented.
Moreover, by firing the support substrate compact, the first electrode compact, and the solid electrolyte at one time, or by firing the support substrate compact which serves also as the first electrode and the solid electrolyte compact at one time, it is possible to expedite mass production even further which brings costs down. In particular, by designing the first electrode compact and/or the solid electrolyte compact in the form of a tape, it is possible to laminate, on the support substrate compact composed of a lamination of a plurality of green tapes, the tape-shaped first electrode compact and/or the tape-shaped solid electrolyte compact continuously. This helps expedite mass production.
Further, the support substrate is formed by laminating a plurality of green tapes containing powder of the support substrate material on top of each other and thereafter firing the laminate. Therefore, it is possible to adopt the sheet lamination method, the screen printing method, and so forth as have conventionally been in use as a method for manufacturing a ceramic substrate, and thus achieve mass production by means of automatic machinery. This makes cost reduction possible.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2005-271858 | Sep 2005 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2006/318642 | 9/20/2006 | WO | 00 | 3/19/2008 |
