Patent Application
20100062309
The present invention relates to a fuel cell provided with diffusion layers on both the surfaces of a membrane-electrode assembly and a method for manufacturing the fuel cell.
There is a fuel cell provided with a membrane-electrode assembly in which catalyst layers as a pair of electrodes are bonded on both sides of an electrolyte membrane, and diffusion layers arranged on both sides of this membrane-electrode assembly. Moreover, a method for manufacturing such a fuel cell includes a technology in which solutions of a diffusion layer, a catalyst layer, an electrolyte membrane, a catalyst layer and a diffusion layer are applied, respectively, laminated in a non-dried state, dried and then integrated (e.g., Japanese Patent Application Laid-Open No. 2004-14202).
However, in the above technology, a membrane-electrode assembly and diffusion layers are bonded and secured to each other by so-called hot pressing. Therefore, when the difference of a water expansion or a heat expansion is made between an electrolyte membrane of the membrane-electrode assembly and the diffusion layers owing to the formation of water and the generation of heat during power generation, stresses might be applied to catalyst layers interposed between the electrolyte membrane and the diffusion layers, thereby causing breakdown.
To solve the problem, an object of the present invention is to provide a fuel cell capable of alleviating the stresses acting on the catalyst layers, and a method for manufacturing the fuel cell.
To achieve the above object, a fuel cell of the present invention is a fuel cell comprising: a membrane-electrode assembly in which catalyst layers as a pair of electrodes are bonded to both the surfaces of an electrolyte membrane; and diffusion layers arranged on both the surfaces of this membrane-electrode assembly, wherein at least a part of contact surfaces between the membrane-electrode assembly and the diffusion layers along a plane direction has a non-bonding portion.
According to such a constitution, sliding and separating between the catalyst layers and the diffusion layers in the non-bonding portions are allowed. Therefore, even when the difference of a water expansion or a heat expansion is made between the electrolyte membrane of the membrane-electrode assembly and the diffusion layers owing to, for example, the formation of water and the generation of heat during power generation, it is possible to alleviate stresses acting on the catalyst layers interposed between the electrolyte membrane and the diffusion layers.
In this case, a part of the contact surfaces between the membrane-electrode assembly and the diffusion layers has a bonding portion, and the remaining part thereof may be a non-bonding portion.
According to such a constitution, the whole contact surfaces between the membrane-electrode assembly and the diffusion layers are not bonded, but a part of the contact surfaces is bonded, whereby the membrane-electrode assembly and the diffusion layers can be formed into a module, and treating properties can be improved.
Moreover, the contact surfaces of the diffusion layers with respect to the membrane-electrode assembly may be subjected to a smoothening treatment (e.g., pressing) before the diffusion layers are laminated.
According to such a constitution, it is possible to suppress damages (aggressive properties) on the membrane-electrode assembly due to the unevenness, fluffing or the like of the surfaces of the diffusion layers laminated on both the surfaces of the membrane-electrode assembly.
Moreover, a method for manufacturing a fuel cell according to the present invention is a method for manufacturing a fuel cell including a membrane-electrode assembly in which catalyst layers as a pair of electrodes are bonded to both the surfaces of an electrolyte membrane and diffusion layers arranged on both the surfaces of this membrane-electrode assembly, the method comprising: a laminating step of laminating the membrane-electrode assembly and the diffusion layers without bonding at least a part of contact surfaces between the membrane-electrode assembly and the diffusion layers along a plane direction.
According to such a constitution, the fuel cell can be manufactured so as to allow sliding and separating between the catalyst layers and the diffusion layers in a non-bonding portion.
In the laminating step, an adhesive may be applied to a part of the contact surfaces between the membrane-electrode assembly and the diffusion layers.
According to such a constitution, the membrane-electrode assembly and the diffusion layers can be formed into a module, and treating properties in the manufacturing process of the fuel cell can be improved.
The method has a step of subjecting, to a smoothening treatment, the contact surfaces between the diffusion layers and the membrane-electrode assembly among the surfaces of the diffusion layers, and the laminating step may laminate the diffusion layers subjected to the smoothening treatment on both the surfaces of the membrane-electrode assembly.
According to such a constitution, the fuel cell can be manufactured so as to suppress damages (aggressive properties) on the membrane-electrode assembly by the diffusion layers.
According to the present invention, stresses acting on the catalyst layers can be alleviated, and the durability of the catalyst layers, that is, the fuel cell can be improved.
A first embodiment of a fuel cell according to the present invention will be described with reference to
Moreover, at the other end of the stacked main body 3, a terminal plate 7 is disposed, and an insulating plate 8 is disposed outside the terminal plate. Further outside the insulating plate, a pressure plate 13 is disposed.
Each of the terminal plates 7 is provided with an output terminal 6. Outside the pressure plate 13, an end plate 9b constituting the frame 5 is disposed away from the pressure plate 13, and between the pressure plate 13 and the end plate 9b, a spring member 14 is interposed.
Between the two end plates 9a and 9b arranged on both sides of the stacked main body 3, a plurality of tension plates 11 are disposed along the stacking direction of the cells 2. Both ends of each tension plate 11 are fixed to the respective end plates 9a, 9b by bolts 12, respectively, and the tension plates constitute the frame 5 together with the two end plates 9a, 9b.
When the two end plates 9a, 9b are connected to each other via the plurality of tension plates 11, a compressive force is introduced to the spring member 14, and the spring member 14 exerts an urging force with respect to the stacked main body 3 in the stacking direction of the cells 2. The plurality of cells 2 are fastened by this urging force. A reactive force against the urging force of the spring member 14 is loaded on the tension plates 11, whereby a tensile force acts on the tension plates 11.
As shown in
The electrolyte membrane 15a is a proton conductive ion exchange membrane made of a polymer material such as a hydrated fluorine carbide or hydrocarbon material, and is specifically made of a perfluorosulfonic acid based resin (Nafion membrane). The catalyst layers 15b are one-size smaller than the electrolyte membrane 15a, and have a catalyst such as platinum or a platinum alloy for promoting an electrochemical reaction.
The diffusion layers 16 are made of a member having a gas permeability and an electron conductivity, for example, carbon paper containing a carbon fiber as a main component. The base material of the separators 17 is made of, for example, carbon, and this material is impregnated with the predetermined amount of a predetermined resin to obtain gas-impermeable carbon based composite separators, and further has a conductivity.
Although not shown, each of the separators 17 is provided with an oxidizing gas passage for supplying an oxidizing gas (usually air) to each catalyst layer 15b through each diffusion layer 16, a hydrogen gas passage for supplying a hydrogen gas, a coolant passage for circulating a coolant (usually water) and the like.
The oxidizing gas supplied to each cell 2 flows into the oxidizing gas passage defined between one of the separators 17 and the diffusion layer 16 adjacent to this separator to come in contact with the catalyst layer 15b as one electrode adjacent to the diffusion layer 16 through this diffusion layer, and the hydrogen gas supplied to each cell 2 flows into the hydrogen gas passage defined between the other separator 17 and the diffusion layer 16 adjacent to this separator to come in contact with the catalyst layer 15b as the other electrode adjacent to the diffusion layer 16 through this diffusion layer. The oxidizing gas and hydrogen gas which have come in contact with both the catalyst layers 15b, respectively, cause the electrochemical reaction in the electrolyte membrane 15a to generate an electromotive force, heat and water.
The electromotive force generated in each cell 2 can be taken from the output terminals 6 provided on the terminal plates 7. The heat generated in each cell 2 is collected by the coolant supplied to each cell 2 through the coolant passage. Water formed by a reaction between the oxidizing gas and the hydrogen gas is discharged from a system together with the remaining oxidizing gas through the oxidizing gas passage.
In the first embodiment, the cell 2 is manufactured as follows. First, as shown in
Alternatively, a paste containing the carbon powder carrying the above catalyst is formed into a membrane to prepare a sheet, and the sheet is pressed onto the electrolyte membrane 15a to form the catalyst layers 15b. In either case, the catalyst layers 15b are secured onto the electrolyte membrane 15a.
Next, as shown in
According to the above-mentioned first embodiment, the whole contact surfaces between the MEA 15 and the pair of diffusion layers 16 are not secured (bonded), and all the contact surfaces are non-bonding portions 100, whereby in the non-bonding portions 100, sliding and separating between the MEA 15 and the diffusion layers 16 are allowed. Therefore, for example, even when the difference of a water expansion, a heat expansion or the like is made between the electrolyte membrane 15a of the MEA 15 and the diffusion layers 16 owing to the formation of water or the generation of heat accompanying power generation, the stresses acting on the catalyst layers 15b can be alleviated.
That is, the electrolyte membrane 15a contains the water formed during the power generation to immediately expand. In addition, an immediate temperature rise is caused by the heat generated during the power generation, and the electrolyte membrane additionally thermally expands. On the other hand, the diffusion layers 16 do not contain any water to expand, and hardly thermally expand, whereby the inconformity of the expansion is generated between the electrolyte membrane and the diffusion layers.
Here, in the MEA 15, the electrolyte membrane 15a and the catalyst layers 15b are bonded and secured. Therefore, when the catalyst layers 15b and the diffusion layers 16 are bonded and secured, the above inconformity of the expansion needs to be absorbed by the catalyst layers 15b as intermediate layers between the electrolyte membrane and the diffusion layers, but during low-temperature start (especially during start below freezing point), the material hardens, freezes, and hence loses its flexibility, whereby the stresses noticeably act on the catalyst layers 15b as the weakest region to break the layers sometimes. Such a tendency becomes remarkable especially when the start below the freezing point is repeated.
On the other hand, in the fuel cell 1 according to the first embodiment, the MEA 15 and the pair of diffusion layers 16 are not bonded to each other but are only laminated, whereby in these non-bonding portions 100, sliding between the catalyst layers 15b of the MEA 15 and the diffusion layers 16 in a plane direction is allowed. Therefore, the breakdown generated in the catalyst layers 15b can be suppressed, and the durability of the fuel cell 1 can be improved.
Moreover, by the freezing of the water formed in a cooling process below the freezing point and during the start below the freezing point, ice is formed in a frost column-like manner in a direction vertical to the plane direction in the cells 2 sometimes. Even in this case, when the catalyst layers 15b and the diffusion layers 16 are bonded and secured, the push-up force of the ice is concentrated on the catalyst layers 15b as the weakest region, and the layers might break down. However, in the first embodiment, the MEA 15 and the diffusion layers 16 are not bonded to each other but are only laminated, whereby in these non-bonding portions 100, the separating of the catalyst layers 15b of the MEA 15 from the diffusion layers 16 is allowed in the direction vertical to the plane direction, so that the non-bonding portions 100 can be provided with a space for allowing the freezing in the frost column-like manner.
Therefore, also from this respect, the breakdown generated in the catalyst layers 15b can be suppressed, and the durability of the fuel cell 1 can be improved. It is to be noted that in this case, the separating of the catalyst layers 15b of the MEA 15 from the diffusion layers 16 in the direction vertical to the plane direction might temporarily cause a conduction defect and lower the performance of the cells. However, after a temperature rises above the freezing point, the layers come in contact with one another again, and hence usual power generation characteristics can be obtained.
Furthermore, the MEA 15 and the diffusion layers 16 are not hot-pressed, whereby thermal and mechanical damages on the electrolyte membrane 15a of the MEA 15 are alleviated, and the durability is further improved.
Next, a second embodiment of a fuel cell according to the present invention will be described mainly with respect to parts different from the first embodiment, mainly with reference to
In the first embodiment, the MEA 15 and the diffusion layers 16 are not absolutely bonded to each other but are only laminated, but in the second embodiment, a part of contact surfaces between them is bonded to obtain bonding portions 110 (see
That is, the MEA 15 has the above-mentioned constitution in which catalyst layers 15b one-size smaller than an electrolyte membrane 15a are secured to both the surfaces of the electrolyte membrane, but as shown in
In consequence, when the diffusion layers 16 are laminated on both the surfaces of the MEA 15, the diffusion layers 16 are bonded to the electrolyte membrane 15a by the adhesive 20, and only portions of the diffusion layers provided with the adhesive 20 are the bonding portions 110 having the secured state. Here, as the adhesive 20 for use, an adhesive which can be assimilated by the material of the catalyst layers 15b is used. Specifically, Nafion solution used during the preparation of the above catalyst layers 15b is applied in the point-like manner.
It is to be noted that applying conditions such as the amount of the adhesive 20 to be applied and an applying area are appropriately set so that the sliding and separating between the catalyst layers 15b of the MEA 15 and the diffusion layers 16 can be allowed, thereby suppressing the breakdown of the catalyst layers 15b after cooling and securing, and so that the bonding portions 110 between the MEA 15 and the diffusion layers 16 are provided with a light adhesive force to such an extent that the MEA 15 and the diffusion layers 16 can integrally be treated in a laminated state during the assembling or disassembling operation of the cells 2.
According to the above second embodiment, the MEA 15 and the diffusion layers 16 are partially bonded by the adhesive 20. In other words, the MEA 15 and the diffusion layers 16 are formed into a module by interposing the bonding portions 110, whereby the MEA 15 and the diffusion layers 16 can integrally be treated, and treating properties during the assembling operation or the disassembling operation can be improved.
Moreover, the same Nafion solution as the material of the catalyst layers 15b is used as the adhesive 20, and hence an influence on the performance of the cells 2 can be suppressed. Needless to say, an adhesive other than Nafion solution may be used as long as the adhesive can suppress the influence on the performance of the cells 2.
Next, a third embodiment of a fuel cell according to the present invention will be described mainly with respect to parts different from the first embodiment.
In the third embodiment, the MEA 15 and the diffusion layers 16 are not absolutely bonded to each other but are only laminated in the same manner as in the first embodiment, but in the third embodiment, the diffusion layers 16 are hot-pressed (a smoothening treatment) before laminated.
That is, the diffusion layers 16 are made of carbon paper containing a carbon fiber as a main component, whereby the diffusion layers 16 generate unevenness on the surfaces thereof, or the carbon fiber fluffs from the surfaces of the diffusion layers 16. When the diffusion layers are laminated as they are, the carbon fiber pierces the MEA 15 to damage the MEA 15, or produces an anchor effect with respect to the MEA 15. To suppress such a defect, the diffusion layers 16 are hot-pressed so that both the surfaces of each diffusion layer is sandwiched by a press machine in a planar manner.
In consequence, the contact surfaces of the diffusion layers 16 with respect to the MEA 15 among the surfaces of the diffusion layers can be smoothened. Thus, in the present embodiment, the hot-pressed diffusion layers 16 are laminated on the MEA 15 to form cells 2. Needless to say, the diffusion layers 16 and the MEA 15 are not bonded by hot pressing in the same manner as in the first embodiment. However, the diffusion layers 16 and the MEA 15 may partially be bonded to each other in the same manner as in the second embodiment.
According to the above third embodiment, the diffusion layers 16 are hot-pressed and hence smoothened, whereby damages (aggressive properties) on the MEA 15 due to the unevenness or fluffing of the surfaces of the diffusion layers 16 can be suppressed.
In addition, it is possible to suppress the anchor effect produced when the fluffs on the surfaces of the diffusion layers 16 pierce the MEA 15, and hence the sliding and separating between the catalyst layers 15b of the MEA 15 and the diffusion layers 16 can satisfactorily be allowed.
It is to be noted that the smoothening treatment is not limited to the planar hot pressing as long as the unevenness and fluffing of the diffusion layers 16 can be suppressed, and cold pressing may be performed. Furthermore, the treatment is not limited to the planar pressing, and roller pressing for sandwiching each layer between rollers and rotating the rollers or the like may be performed.
| Number | Date | Country | Kind |
|---|---|---|---|
| 2007-089648 | Mar 2007 | JP | national |
| Filing Document | Filing Date | Country | Kind | 371c Date |
|---|---|---|---|---|
| PCT/JP2008/056506 | 3/26/2008 | WO | 00 | 9/28/2009 |
