The present invention relates to a fuel cell arrangement with a fuel cell stack, which is deformable during operation. In particular, the invention relates to the fixation of a fuel cell stack, which is deformable during operation, in a support structure, for example in a housing surrounding the fuel cell stack. Here, in the present context the term “fixation” shall particularly be understood as the prevention of any movements of the stiff body in reference to the support structure.
In order to generate electric energy via fuel cells usually a larger number of fuel cells is arranged in the form of a stack along a longitudinal axis, with the fuel cells each showing an anode, a cathode, and an electrolyte arranged therebetween. The individual fuel cells are each separated from each other by bipolar plates and contacted electrically. In the longitudinal direction the fuel cell stack is limited by a first terminal plate at the beginning of the stack and a second terminal plate at the end of the stack. Power collectors are respectively provided at the anodes and cathodes serving on the one hand to electrically contact the anodes and/or cathodes and on the other hand to guide reaction gases past them. Sealing elements are respectively provided in the edge region of the anode, the cathode, and the electrolyte matrix, which form a lateral seal of the fuel cells and thus the fuel cell stack against any anode or cathode gas leaking out.
Different fuel cell types are known from prior art, such as polymer electrolyte fuel cells, solid oxide fuel cells, or molten carbonate fuel cells.
In a molten carbonate fuel cell the electrolyte material typically comprises binary or ternary molten alkali carbonate (for example molten mixtures of lithium and potassium carbonate), which are bonded in a porous matrix. During operation molten carbonate fuel cells typically reach operating temperatures of approx. 650° C. Here, at the anode side a reaction occurs of hydrogen and carbonate ions into water and carbon dioxide with the release of electrons. At the cathode side oxygen reacts with carbon dioxide into carbonate ions with the absorption of electrons. Here, heat is released. The molten alkali carbonate used here as the electrolyte yields on the one hand the carbonate ions required for the anode part of the reaction and on the other hand absorbs the carbonate ions developing during the cathode part of the reaction. In practice, usually an energy carrier comprising hydrocarbons and water is supplied to the anode side. Suitable energy carriers comprising hydrocarbons are for example methane, originating from natural gas or biogas, among other sources. By an internal reformation the hydrogen required for the anode part of the reaction is yielded from the mixture supplied. The anode exhaust is mixed with additionally supplied air and subsequently oxidized in a catalytic fashion to remove any components potentially still present. The gaseous mixture developing now comprises carbon dioxide and oxygen, thus particularly the gases required for the cathode part of the reaction, so that the anode exhaust after the supply of fresh air and a catalytic oxidation can be directly fed to the cathode part of the cell.
The hot exhaust emitted at the cathode output is free from hazardous substances and can be thermally processed. The electric efficiency of the molten carbonate fuel cell already reaches 45 to 50% and when the released heat is utilized here a total efficiency of approx. 90% can be yielded in the overall process.
The applicant has been able to integrate the fuel cell stack and all system components operating at high temperatures in a common, gas-tight protective housing. This way, on the one hand, the efficiency of the equipment is improved and, on the other hand, an arrangement could be realized, in which the cathode gas flow can freely circulate inside the protective housing and the anode exhaust flow can freely be introduced into the circulating cathode gas flow. The known fuel cell arrangements of the applicant are explained in greater detail for example in the international patent applications WO 96/02951 A1 and WO 96/20506 A1 and in the German patent application DE 195 48 297 A1.
Molten carbonate fuel cell stacks, but also other fuel cells designed for a higher performance range beyond 100 kW, such as solid oxide fuel cells, are subject to considerable deformations during operation due to internal forces caused by temperature profiles in the stack or by chemical reactions. In order to allow these deformations the above-described molten carbonate fuel cells of the applicant are supported, for example, on a support frame in a housing such that the terminal plates are pre-stressed in reference to each other, but simultaneously certain movements of the stack are ensured in the longitudinal and lateral directions. Additionally, external forces may impact the fuel cell stack, for example during the transportation of the fuel cell to a stationary place of application or during a mobile use of the fuel cell, for example on ships, but also in the stationary use, for example due to earthquakes. Thus it is advantageous for such applications to fixate the fuel cell stack inside a support structure, for example a housing or a carrier surrounded by a housing. The fastening must here prevent movements and deformations of the stack caused by external forces, such as ship movements, but simultaneously allow certain deformations of the stack, for example an extension, shrinkage, or bending due to internal forces. It is known for example to arrange fuel cell stacks vertically in a housing and here to fixate the lower terminal plate of the stack at said housing. Such an arrangement is only suitable for stationary operation or for stacks with a low height, because here external lateral forces can only be compensated by the friction between the individual cells. Additionally it is known to support fuel cell stacks in a horizontal fashion, and here to fixate one of the two terminal plates of the stack at a carrier. The stack may here rest over its entire length on a carrier, however it must be mobile in the longitudinal and the lateral direction in reference to the axis of the stack due to deformations caused by internal forces so that here, too, the compensation of external forces is limited.
The present invention is therefore based on the technical problem to provide a fuel cell arrangement, in which the fuel cell stack is fixated in a support structure such that on the one hand deformations are possible caused by internal forces but simultaneously forces impacting from the outside can be compensated by the support structure so that no excessive stack movement develops, which could damage the fuel cell stack.
This technical problem is attained in a fuel cell arrangement according to claim 1. Advantageous further developments of the invention are the objective of the dependent claims.
Accordingly, the invention relates to a fuel cell arrangement with at least one fuel cell stack, which comprises a first terminal plate, a second terminal plate, and numerous fuel cells, each comprising one anode and one cathode and an electrolyte arranged between the anode and the cathode, with the fuel cells being arranged along the longitudinal axis of the fuel cell stack between the first and the second terminal plate, a support structure in which the fuel cell stack is arranged, with the first terminal plate of the fuel cell stack being connected fixed to the support structure, if applicable, with the fuel cell arrangement according to the invention being characterized in that at least one bearing means is provided, different from the first terminal plate and perhaps connected fixed to the support structure, in order to compensate lateral forces impacting the fuel cell stack perpendicular in reference to the longitudinal axis of the stack.
According to the invention it is therefore suggested that when the first terminal plate is fixated to a support structure at least one additional bearing means is provided to compensate lateral forces impacting the fuel cell stack perpendicular in reference to the longitudinal axis extending in the direction of the stack. In case none of the terminal plates is fixated at the support structure, it is suggested according to the invention that at least one bearing means not representing a terminal plate is provided to compensate such lateral forces. The orientation of the fuel cell stack according to the invention is not subject to any restrictions, thus for example it can be vertical, preferably, however, horizontal. An orientation perpendicular to lateral forces acting in reference to the longitudinal axis of the stack and thus also the orientation of the bearing means provided to compensate these forces is not subject to any restrictions, either. In a horizontal orientation of the stack the respective bearing means may extend for example parallel (or anti-parallel) in reference to the direction of gravity or perpendicular in reference to the direction of gravity.
The support structure may represent a frame entirely or partially surrounding the fuel cell stack, which frame in turn may be surrounded by a housing. However, the support structure can also be formed by the housing itself surrounding the fuel cell stack.
Preferably the bearing means comprise at least one fastening plate arranged in the fuel cell stack, which is connected via a lateral bearing to the support structure. Here, a fastening plate arranged in the fuel cell stack is understood within the scope of the present invention as any fastening plate which is a part of the fuel cell stack, including the two terminal plates. In the present context a lateral bearing is understood as a bearing perpendicular in reference to the longitudinal axis of the fuel cell stack.
In case the first terminal plate is connected fixed to the support structure, as known from prior art, in a first variant of the fuel cell arrangement according to the invention at least one fastening plate may represent the second terminal plate limiting the fuel cell stack. In this variant the first terminal plate is connected via a fixed bearing to the support structure, while the second terminal plate, which forms the fastening plate to compensate lateral forces, is connected via a movable bearing to the support structure, so that the second terminal plate is mobile in the longitudinal direction of the stack, however fixed perpendicular in reference thereto. This way, deformations of the fuel cell stack between the two terminal plates are allowed, but simultaneously any lateral forces developing are compensated not only by the first terminal plate but also by the second terminal plate.
According to a second variant of the fuel cell arrangement according to the invention the fastening plate represents an intermediate plate arranged between two fuel cells of the fuel cell stack, which in turn is connected to the support structure in order to compensate lateral forces. According to one variant the intermediate plate arranged between two fuel cells represents the only support means to compensate lateral forces impacting the fuel cell stack perpendicular in reference to the longitudinal axis of the stack. In this case the two terminal plates of the fuel cell stack are freely mobile, except for their horizontal bearing or the vertical bearing of the first terminal plate. However, in reference to prior art, external lateral forces may also be introduced better into the support structure via the intermediate plate, because lateral forces no longer need to be transmitted over the entire length of the stack onto the support plate but respectively only along the portions of the stack located at both sides of the fastening plate. Therefore, preferably the intermediate plate is arranged essentially at midway of the length of the fuel cell stack. It is also possible to provide more than one intermediate plate, for example two intermediate plates, which then are arranged at one third and/or two thirds of the length of the stack.
In addition to the intermediate plate and/or the intermediate plates one or both terminal plates may also be embodied as fastening plates to compensate lateral forces.
The two terminal plates may for example be embodied as fixed bearings and/or movable bearings. In this case, any fixation of the intermediate plate perpendicular in reference to the longitudinal axis of the stack would lead to a statically undetermined bearing. Accordingly the lateral bearing for the intermediate plate is preferably embodied such that the intermediate plate is elastically connected to the support structure perpendicular in reference to the longitudinal axis of the stack.
According to one variant the intermediate plate can additionally be connected via a longitudinal bearing to the support structure. Preferably, in this case the intermediate plate is supported pivotal in the direction of the longitudinal axis of the fuel cell stack.
In larger fuel cell stacks, in addition to the intermediate plate, at least the second terminal plate is embodied as a mobile fastening plate connected via a lateral bearing to the support structure and elastic in the longitudinal axis of the fuel cell stack.
When at least three fastening plates are arranged in the fuel cell stack at least one of the fastening plates is arranged perpendicular in reference to the longitudinal axis of the stack. In order to achieve a statically determined bearing here the respective bearing means may be coupled to each other such that a compensation of the lateral forces is possible via the bearing means. For this purpose the bearing means may be connected to each other, for example, via a differential.
The lateral bearing engaging the fastening plate may represent a pendulum support, for example. In case of a horizontal fuel cell stack the pendulum support may, for example, also be arranged horizontally and connect the fastening plate to a lateral wall of the support structure and/or the housing.
According to another embodiment the lateral bearing comprises at least one passive adjustment cylinder. The adjustment cylinder may represent for example a passive servo jack for tensile forces and pressures, in which the side of the tensile force and the pressure side are connected such that compensating motions occur only very slowly. For example the side of the tensile force and the pressure side may be connected via a throttle valve. This way, briefly occurring external forces remain blocked, while forces impacting over an extended period are permitted. This way, for example ship movements can be blocked as a typical example of briefly occurring external forces, while the stack motion is permitted due to internal forces developing inside the stack caused by extended operation. According to a preferred embodiment of the adjustment cylinder here safety controls may be provided, which block the cylinder in critical operating conditions. A technical safety blocking of the cylinder can occur for example when a defined force is exceeded by a force-controlled shut-off valve. Further, the blocking valve can be closed via a tilt sensor when a defined angle of inclination has been exceeded. Additionally, a blocking of the cylinder can be triggered when a predetermined temperature is exceeded, which is determined via temperature sensors.
The bearing means preferably comprise isolation means, in order to isolate the fuel cell stack from the support structure at least electrically. In high-temperature fuel cells, such as molten carbonate fuel cells, the isolation means preferably also ensure the thermal insulation of the fuel cell stack from the support structure.
As known from prior art, preferably the first and the second terminal plate are elastically pre-stressed in reference to each other. According to a preferred variant here means for a controllable force are provided, which apply an essentially constant pre-tension upon the fuel cells arranged between the terminal plates.
In the following the invention is explained in greater detail with reference to the exemplary embodiment shown in the attached drawings.
The drawings show:
Usually, except for the fastening of the first terminal plate 12 described, no additional means are provided in order to compensate external forces, particularly lateral accelerations, thus forces impacting perpendicular in reference to the longitudinal axis 15 of the stack. The fuel cell arrangements of prior art designed for a higher performance range and thus comprising numerous fuel cells 14 arranged successively are therefore not suitable for mobile applications, for example, in which such external forces can occur during operation.
In order to allow such compensation of force it is now suggested according to the invention to provide at least one additional bearing means in the fuel cell stack 11 to compensate lateral forces acting upon the fuel cell stack 11 perpendicular in reference to the longitudinal axis 15 of the stack. For this purpose preferably at least one fastening plate is arranged in the fuel cell stack 11, which is connected by a lateral bearing to the support structure 17. In the following the concept suggested by the invention is explained in greater detail based on several exemplary embodiments.
The embodiments of the invention shown in
In case none of the terminal plates 12, 13 are fixated at the support structure 17 it is suggested according to the invention that at least one intermediate plate is provided in the fuel cell stack 11 to compensate lateral forces.
In the top view of a second embodiment of the fuel cell arrangement 11 according to the invention shown schematically in
According to one variant (not shown) of the embodiment of
In the exemplary embodiments of
In the top view of a fourth embodiment of the invention shown in
When at least three fastening plates are arranged in the fuel cell stack at least one of the fastening plates will be mobile perpendicular in reference to the longitudinal axis of the stack. In order to achieve a statically determined bearing here the respective bearing means can be coupled to each other such that a compensation of lateral forces accepted by the bearing means is possible. For this purpose, the bearing means may be connected to each other, for example via a compensation joint or a differential.
One variant of the embodiment of
The lateral bearings described in the various embodiments may represent a pendulum support, for example, which are perhaps also provided with a suitable electric and/or thermal insulation in order to isolate the fuel cell stack 11 from the support structure 17.
However,
In the variant of
In
Number | Date | Country | Kind |
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10 2010 051 753.4 | Nov 2010 | DE | national |
Filing Document | Filing Date | Country | Kind | 371c Date |
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PCT/EP11/05667 | 11/11/2011 | WO | 00 | 8/29/2013 |