The present invention relates to a fuel cell assembly, comprising at least a first flow field plate, a second flow field plate and a multilayer membrane electrode assembly. Such a fuel cell assembly is often referred to as unit fuel cell.
Usually, a fuel cell stack comprises a plurality of membrane electrode assemblies (MEAs), which are sandwiched by so called bipolar plates (BPP). The bipolar plates in turn are a combination of the above mentioned first flow field plate and the second flow field plate, and are usually made from an electrically conducting material, such as metal or graphite. Typically, the flow field plates have a flow field for the reactants at one side and a flow field for a cooling fluid on the other side. Thereby, the cooling fluid flow fields are facing each other, whereas the reactant fluid flow fields face the membrane electrode assemblies. However, also other designs, particularly with a third intermediate layer providing the cooling flow field, are also known. The electric current produced by the membrane electrode assemblies during operation of the fuel cell stack results in a voltage potential difference between the bipolar plate assemblies, and is strongly dependent on a uniform distribution of the reactants over the surface of the electrodes. Consequently, it is desired to distribute the reactant over the whole surface of the electrodes for achieving the highest electric current output.
Disadvantageously, the flow field of the flow field plates also constitutes a flow resistance for the reactant, so the reactant tends to bypass the flow field at the edges of the flow field plate (boundary region).
In the state of the art, it has been therefore suggested to provide bypass stopping elements in the boundary area between the flow field and a so called bead seal, which is adapted to provide a sealing of the unit fuel cell to an environment.
However, it has turned out that due to stacking imperfections the sealing contact between the bypass stopping elements and the adjacent multilayer membrane electrode assembly or the adjacent other flow field plate, respectively, may become insufficient.
It is therefore desirable to provide an improved bypass stopping element, which is reliably avoiding bypass of the reactant fluids of the flow field.
In the following a fuel cell assembly comprising at least a first flow field plate and a second flow field plate sandwiching a multilayer membrane electrode assembly is provided. Such a fuel cell assembly may also be referred to as unit fuel cell. The flow field plates themselves are usually placed back to back and thereby provide a so-called bipolar plate. Further, the multilayer membrane electrode assembly comprises at least one first electrode facing the first flow field plate, a second electrode facing the second flow field plate and a membrane separating the electrodes. Each flow field plate has a flow field structure protruding from a base level of the flow field plate for distributing reactant over an active area, defined by the respective electrode. Additionally, at the electrode facing front side at least one sealing element is arranged between the first and the second flow field plate, which is adapted to prevent leakage of the reactants to an environment, and in a boundary area between the flow field structure and the sealing element of at least one of the flow field plates at least one bypass stopping element is arranged for avoiding the reactant bypassing the flow field structure, wherein the bypass stopping element protrudes from the respective base level of the flow field plate.
For avoiding a bypass of the reactants even if stacking imperfections impact the sealing between the bypass stopping elements and the sandwiched membrane electrode assembly, it is suggested that the at least one bypass stopping element has a pointed portion which is adapted to compress the multilayer membrane electrode assembly. A pointed portion in accordance with this application is an area of the bypass stopping element, where at last a part of the surface interacting with the membrane electrode assembly is made as small as possible. Thereby, the sealing off function of the bypass stopping elements can be ensured even if a distance between the bypass stopping element and the membrane electrode assembly is slightly increased due to stacking tolerances. The pointed portion thereby increases the pressure in a small and confined area and thereby provides excellent sealing properties.
According to a preferred embodiment, the multilayer membrane electrode assembly further comprises at least one subgasket, wherein the at least one subgasket is adapted to frame the multi-layer membrane electrode assembly, wherein the at least one subgasket is adapted to extend at least partly over the at least one bypass stopping element, so that the pointed portion of the bypass stopping element compresses the at least one subgasket. Thereby it is ensured that the pressure force applied by the pointed portion or the bypass element in general does not damage the electrodes or the membrane of the multi-layer membrane electrode assembly.
According to a further preferred embodiment, the multi-layer membrane electrode assembly further comprises at least one gas diffusion layer, which is positioned between the first electrode and the first flow field plate, and preferably a second gas diffusion layer, which is positioned between the second electrode and the second flow field plate, wherein the at least one gas diffusion layer is adapted to extend at least partly over the at least one bypass stopping element, so that the pointed portion of the bypass stopping element compresses the at least one gas diffusion layer.
Usually, the gas diffusion layer provides a certain thickness over a subgasket encompassing and carrying the membrane electrode assembly. Thus, compressing the gas diffusion layer increases the force which is applied by the pointed portion and thereby increase the sealing properties of the bypass stopping element.
It is further preferred that the sealing element is a bead seal surrounding the flow field plate and thereby the flow field structure, wherein the bead seal protrudes from the base level and is adapted to be directly or indirectly in contact the bead seal of the respective other flow field plate for preventing leakage of the reactants to an environment. Bead seals have been proven to provide excellent sealing properties to the environment and are easily manufactured.
According to a further preferred embodiment, the first flow field plate has at least one first bypass stopping element and the second flow field plate has at least one second bypass stopping element, wherein the first bypass stopping element and the second bypass stopping element are arranged opposite to each other, so that the first and second bypass stopping elements form at least one bypass stopping element assembly, wherein the first bypass stopping element has a pointed portion and the second bypass stopping element as a blunt portion, wherein the blunt portion of the second bypass stopping element is adapted to be indented by the pointed portion of the first bypass stopping element. The synergistic effects of the both bypass stopping elements increase the sealing function even further.
Thereby it is advantageous, that, in cross-section, the blunt portion of the second bypass stopping element is wider than the pointed portion of first bypass stopping element. This allows for a certain stacking and alignment tolerance without deteriorating the function of the bypass stopping elements.
In a further advantageous embodiment, the bypass stopping element is a continuous element extending at least along a length of the flow field structure, wherein at least upstream of the flow field structure in direction of the reactant flow, the bypass stopping element is connected to the sealing element. This design allows for a simplified manufacturing. The known bypass stopping elements are discrete elements which have to be separately manufactured, which in turn increases the effort for the manufacture process.
However, it also possible to design the bypass stopping elements as a plurality of discrete bypass stopping elements, preferably a plurality of bypass stopping element assemblies, which are arranged in the boundary area between the flow field structure and the bead seal of at least one of the flow field plates. This allows using already existing manufacturing tools and processes for flow field plates, which has to be modified only slightly.
According to a further preferred embodiment, the first bypass stopping elements having the pointed portion are discrete elements and the second bypass stopping element having the blunt portion is a continuous element extending at least along the length of the flow field structure, or the first bypass stopping elements having the pointed portion is a continuous element extending at least along the length of the flow field structure and the second bypass stopping element having the blunt portion are discrete elements. By designing one of the bypass stopping elements as discrete elements and the other as continuous element, the stacking and aligning tolerances may be increased without deteriorating the sealing finction of the bypass stopping element.
The at least one bypass stopping element may be an integral part of the flow field plate, but it is also possible that the bypass stopping element is a separate element from the flow field plate, wherein particularly the bypass stopping element is a frame-like element. In case the bypass stopping element is part of the flow field plate, the bypass stopping element may be manufactured simultaneously with the flow field plate, which accelerates the manufacturing process. The separate element in turn allows for a very flexible arrangement.
Thereby, it is particularly preferred that the at least one bypass stopping element is an integral part of a subgasket or a gas diffusion layer. This reduces the overall number of parts which have to be stacked and thereby reduces any misalignment risks and increases the sealing function of the bypass stopping element.
Since hydrogen, the reactant supplied at the anode is a very small molecule, proper sealing of the anodes side is particularly difficult. Therefore, it is preferred that the bypass stopping element with the pointed portion is arranged at least at the anode side. By the increased local compressive pressure of the pointed portion, the sealing function of the bypass stopping element is increased.
A further aspect of the present invention relates to a flow field plate, particularly an anode flow field plate, for a fuel cell assembly as mentioned above, wherein the flow field plate has at least one bypass stopping element with pointed portion which is adapted to compress the multilayer membrane electrode assembly.
Further preferred embodiments are defined in the dependent claims as well as in the description and the figures. Thereby, elements described or shown in combi-nation with other elements may be present alone or in combination with other elements without departing from the scope of protection.
In the following, preferred embodiments of the invention are described in relation to the drawings, wherein the drawings are exemplarily only, and are not intended to limit the scope of protection. The scope of protection is defined by the accompanied claims, only.
The figures show:
In the following same or similar functioning elements are indicated with the same reference numerals. The drawings are schematic, only. Consequently, any distance, size or angle is only schematic and does not illustrate real dimensions.
In the illustrated embodiment, each flow field plate 2, 4 has a front side 20, 40 and a back side 21, 41. Both, front side and back side, are equipped with a flow field 22, 23, 42, 43, which define an active area at the flow field plate. The flow fields 22, 42 of the front sides 20, 40 are channel like structures which protrude from a base level 24, 44 of the flow field plates 2, 4 and are adapted to distribute reactant to the respective multilayer membrane electrode assemblies 10 (see
The multilayer membrane electrode assembly 10 usually comprise a 3-layer basic membrane electrode assembly 11 with an anode 12, a membrane 13 and a cathode 14. For providing a uniform distribution of the reactant to the electrodes, the multilayer membrane electrode assembly 10 further comprises gas diffusion layers 15, 16, which are arranged at the electrodes facing the respective flow field plate 2, 4. As illustrated, the gas diffusion layers 15, 16 are slightly larger than the flow field 22, 42 which ensures a homogenous distribution of the reactants to the flow field over the whole active area, which is defined by the size and extension of the respective electrodes 12, 14. Further, the gas diffusion layers 15, 16 and the 3-layer membrane electrode assembly 11 is framed by a so called subgasket(s) 17, 18, wherein the size and form of the sub-gaskets 17, 18 are adapted to the size and form of the flow field plates 2, 4.
Each flow field plate 2, 4 further comprises a fuel inlet 32, an oxidizing agent inlet 34 and a cooling fluid inlet 36, which are in fluid connection (not illustrated) with the respective flow field 22, 42, 23, 43 for providing and distributing fuel, particularly a hydrogen rich gas, oxidizing agent, particularly air, and cooling fluid, particularly water, to the active area of the bipolar plate.
Analogously, each flow field plate 2, 4 further comprises a fuel outlet 33, an oxidizing agent outlet 35 and a cooling fluid outlet 37, which are in fluid connection (not illustrated) with the respective flow field 22, 4223, 43 for discharge fuel, oxidizing agent, and cooling fluid, from the active area and also from the bipolar plate.
For avoiding unintended mixing of the fluids, each inlet 32, 34, 36 and each outlet 33, 35, 37 is framed by a bead seal 52, 53, 54, 55, 56, 57. Further, the flow field plate as such and the flow field 22, 42, in particular, are sealed by a bead seal 58, 59, which encompasses the whole plate. As illustrated in the cross section views, the bead seal protrudes from the base level 24, 44 and has a height which is higher than the height of the channel-like structures of the flow fields 22, 42; 23, 43. Other sealing means are also applicable.
As mentioned above, the flow field 22, 42 of the flow field plates 2, 4 constitutes a certain flow resistance for the reactant. Thus, the reactant tends to bypass the flow field in a boundary region 26, 46 between the flow field 22, 42 and the bead seal 58, 59. This tendency is supported by the gas diffusion layers 15, 16 overlapping the flow fields 22, 42, as the gas diffusion layers extend into the boundary region and therefore reactant is guided into this region as well.
For avoiding such a bypass, the flow field plates 2, 4 are equipped with bypass stopping elements 60 and 70, respectively, which protrude over the base level 24, 44 of the flow field plates 2, 4. Thereby, a height of the bypass stopping elements 60, 70 may be similar to or even higher than the height of the bead seal 58.
In the first embodiment illustrated in
As illustrated in the cross section of
Even if the cathode plate could be also left without bypass stopping element, it is also preferred to block the bypass of the oxidizing agent as well by means of extra bypass stopping elements. Consequently, as illustrated in
Preferably, the bypass stopping element 60 of the anode plate 2 and the bypass stopping element 70 of the cathode plate 4 are arranged in the same area (see also
In contrast to the bypass stopping element 60 of the anode flow field plate 2, the bypass stopping element 70 of the cathode plate 4 has no pointed part, but an extended blunt portion 77 (see
Further, it is even possible that the pointed portion 66 of the bypass stopping element 60 deforms, particularly indents, the blunt portion 77 of the cathode bypass stopping element 70, as is illustrated in the second embodiment shown in
However, for providing uniform dimensions of the fuel cell stack and also for avoiding different designs for flow field plates for the cathode, anode side, it is preferred to provide a flow field plate which may be used as anode plate and cathode plate, e.g. by simply flipping the plate. For such a case, a preferred design of the flow field plate 2, 4 is preferred which is schematically illustrated in
As can be further seen form the illustrated embodiments, a distance D (indicated in
The bypass stopping elements 60, 70 may be integral parts of the flow field plate, but it is also possible that the bypass stopping elements are separate elements which may be arranged between or bonded to the bipolar plate and/or being integral parts of the multilayer membrane electrode assembly 10, e.g. the subgasket 18, 19. It is also possible that parts of the bypass stopping elements are differently designed so that e.g. the elongated protrusion is portion of the membrane electrode assembly and the bypass blocking protrusions are integral parts of the bipolar plate or vice versa.
In the illustrated embodiments, the bypass stopping elements 60, 70 are hollow elements, but it is also possible that at least one bypass stopping element or portion of the bypass stopping element is solid.
Further it is also possible that a portion or the complete bypass stopping element 60, 70 is made from a resilient material. However, it is also possible that the bypass stopping element is non-elastic or in parts be made from elastic and non-elastic materials.
In summary due to the over compression of the gas diffusion layer, alongside the active area, an effective blocking of any bypass flow inside the gas diffusion layer is formed. As a result, the importance of controlling the width and location of the gas diffusion layer is greatly reduced. For providing the necessary compression force, at least one bypass stopping element is provided with a total surface which is as small as possible, particularly a pointed portion. Thereby the pointed portion allows a high gas diffusion layer compression without inflicting on other properties of the fuel cell, such as:
Further, having a high gas diffusion layer compression element minimizes the cross-sectional void int eh boundary region between the gas diffusion layer edge and gas sealing bead. The gas diffusion layer compression and bypass stopping element could be a part of the flow field plate material regardless of what material is used, such as stainless sheet metal or graphite. The gas diffusion layer compression and bypass stopping element could be made of a different material compared to the flow field plate and then bonded together with it. It could also be none uniform when it comes to material and shape to enable realization and/or the manufacturing process. The compression and bypass stopping element may be made hollow or solid or a combination thereof. Part of or the complete gas diffusion layer compression and bypass stopping element may be made of elastic of non-elastic materials or a combination thereof.
All in all, the proposed bypass stopping element allows for cost savings in manufacturing. The resulting possible increased fuel efficiency also increases value of the fuel cell stack as well as saves money during operation.
Number | Date | Country | Kind |
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2051498-0 | Dec 2020 | SE | national |
Filing Document | Filing Date | Country | Kind |
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PCT/SE2021/051146 | 11/16/2021 | WO |